CN102417252A - Adjustable mechanical flocculation reaction method for enhancing coagulation by using grids - Google Patents
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- 238000005189 flocculation Methods 0.000 title claims abstract description 59
- 230000016615 flocculation Effects 0.000 title claims abstract description 59
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 19
- 230000015271 coagulation Effects 0.000 title claims abstract description 17
- 238000005345 coagulation Methods 0.000 title claims abstract description 17
- 230000002708 enhancing effect Effects 0.000 title 1
- 238000003756 stirring Methods 0.000 claims abstract description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910001220 stainless steel Inorganic materials 0.000 claims description 18
- 239000010935 stainless steel Substances 0.000 claims description 8
- 238000003466 welding Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000701 coagulant Substances 0.000 description 7
- 238000013019 agitation Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
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Abstract
一种利用格网强化混凝的可调式机械絮凝反应方法,它涉及一种水处理领域,以解决现有水处理利用搅拌桨进行混凝,且不能将能量均匀分布在水中的问题。方法:一、分别在一级搅拌桨和二级搅拌桨的桨叶上的水平轴与竖直轴之间的每个区域内设置一个格网,一级搅拌桨上的每个格网的网孔内切圆直径为5~50mm,二级搅拌桨上的每个格网的网孔内切圆直径为10~60mm,二级搅拌桨上的每个格网的网孔内切圆直径应大于一级搅拌桨上的每个格网的网孔内切圆直径5~15mm;二、一级搅拌桨的转数为2~5转/分钟,二级搅拌桨的转数为1~3.5转/分钟,三级搅拌桨的转数为0.5~2.5转/分钟。本发明用于水处理及化工等行业。
The invention discloses an adjustable mechanical flocculation reaction method using a grid to strengthen coagulation, which relates to the field of water treatment, and aims to solve the problem that the existing water treatment uses stirring paddles for coagulation and cannot uniformly distribute energy in water. Method: 1. Set a grid in each area between the horizontal axis and the vertical axis on the blades of the first-stage stirring paddle and the second-stage stirring paddle, and the grid of each grid on the first-stage stirring paddle The diameter of the inscribed circle of the hole is 5-50 mm, the diameter of the inscribed circle of each grid on the secondary stirring paddle is 10-60 mm, and the diameter of the inscribed circle of each grid on the secondary stirring paddle should be The diameter of the inscribed circle of each grid on the first-stage stirring paddle is 5-15 mm; the number of rotations of the second-stage stirring paddle is 2-5 rpm, and the number of rotations of the second-stage stirring paddle is 1-3.5 revolutions per minute, and the revolutions of the three-stage stirring paddles are 0.5 to 2.5 revolutions per minute. The invention is used in industries such as water treatment and chemical industry.
Description
技术领域 technical field
本发明涉及一种水处理领域,具体涉及一种机械搅拌式絮凝反应方法。The invention relates to the field of water treatment, in particular to a mechanical stirring type flocculation reaction method.
背景技术 Background technique
混凝是指水处理行业在进行水处理过程中,通过投加混凝剂,水解产生高电荷低聚合度的产物压缩双电子层,加以适当的混合搅拌后,使水中的胶体颗粒克服排斥力结合在一起并形成絮凝,利于进一步的沉淀、气浮或过滤处理。现有的絮凝设备主要分为两大类:水力搅拌式和机械搅拌式,水力搅拌式絮凝设备不能根据水质水量调节运行参数,适应能力差;目前,最为常用的絮凝设备为机械搅拌式,该方案可以根据水质水量调节转速等参数,但是机械搅拌式的搅拌桨(见图2)不能将能量均匀分布在水中,搅拌桨桨叶附近速度梯度大,容易将形成的絮体打碎,由于两个桨叶上的水平轴与竖直轴之间的区域扰动不足,絮体不能充分成长,为解决絮体打碎和絮体不能充分成长的问题,有的在絮凝池中垂直于水流方向安装固定式格网,但是固定式的格网不能随原水情况调节,水量低时扰动不足,水温低时也不能增加能量的输入促进絮体生成,且拆卸安装复杂,在实际应用中受到限制;还有的水厂通过调节原水pH、增加混凝剂的投量、使用混凝剂和助凝剂等手段来强化混凝过程,但是增加混凝剂的投量和调节pH,一方面会增加污泥量和水处理药剂的残留,另一方面增加了水处理的运行成本。Coagulation means that in the process of water treatment in the water treatment industry, by adding a coagulant, hydrolysis produces a product with a high charge and a low degree of polymerization to compress the double electron layer, and after proper mixing and stirring, the colloidal particles in the water can overcome the repulsive force Combine together and form flocculation, which is beneficial for further sedimentation, air flotation or filtration treatment. Existing flocculation equipment is mainly divided into two categories: hydraulic agitation and mechanical agitation. Hydraulic agitation flocculation equipment cannot adjust operating parameters according to water quality and quantity, and has poor adaptability. At present, the most commonly used flocculation equipment is mechanical agitation. The scheme can adjust the speed and other parameters according to the water quality and quantity, but the mechanical stirring paddle (see Figure 2) cannot evenly distribute the energy in the water, and the velocity gradient near the paddle blade is large, which is easy to break the formed flocs. The area between the horizontal axis and the vertical axis on each blade is not sufficiently disturbed, and the flocs cannot grow fully. In order to solve the problems of floc breaking and flocs not growing fully, some are installed perpendicular to the direction of water flow in the flocculation tank. Fixed grid, but the fixed grid cannot be adjusted according to the raw water conditions, the disturbance is insufficient when the water volume is low, and the energy input cannot be increased to promote the formation of flocs when the water temperature is low, and the disassembly and installation are complicated, which is limited in practical application; Some water plants strengthen the coagulation process by adjusting the pH of raw water, increasing the dosage of coagulants, and using coagulants and coagulants. However, increasing the dosage of coagulants and adjusting pH will increase pollution on the one hand. The amount of mud and the residue of water treatment chemicals increase the operating cost of water treatment on the other hand.
发明内容 Contents of the invention
本发明的目的是为了解决现有水处理采用机械搅拌式的絮凝方法,利用搅拌桨进行混凝,由于两个桨叶上的水平轴与竖直轴之间有通透的区域,该区域不能将能量均匀分布在水中,导致扰动不足,絮体不能充分成长的问题,提供一种利用格网强化混凝的可调式机械絮凝反应方法。The purpose of the present invention is to solve the existing water treatment using mechanical agitation flocculation method, using stirring paddles for coagulation, because there is a transparent area between the horizontal axis and the vertical axis on the two paddles, this area cannot Evenly distributing energy in water leads to insufficient disturbance and insufficient growth of flocs. An adjustable mechanical flocculation reaction method using grids to strengthen coagulation is provided.
本发明的方法是通过以下步骤实现的:所述方法基于机械絮凝反应池来实现的,所述机械絮凝反应池有三级,分别为一级絮凝反应池、二级絮凝反应池和三级絮凝反应池,一级絮凝反应池、二级絮凝反应池和三级絮凝反应池由絮凝池进水端至絮凝池出水端依次设置,每级絮凝池中有一个搅拌桨,一级絮凝反应池、二级絮凝反应池和三级絮凝反应池中对应的搅拌桨分别为一级搅拌桨、二级搅拌桨和三级搅拌桨;步骤一、将一级搅拌桨和二级搅拌桨铺设格网:分别在一级搅拌桨和二级搅拌桨的桨叶上的水平轴与竖直轴之间的每个区域内设置一个格网,每个格网的四周与其对应的水平轴和竖直轴连接,一级搅拌桨上的每个格网的网孔内切圆直径为5mm~50mm,二级搅拌桨上的每个格网的网孔内切圆直径为10mm~60mm,二级搅拌桨上的每个格网的网孔内切圆直径应大于一级搅拌桨上的每个格网的网孔内切圆直径5mm~15mm;步骤二、确定各级搅拌桨的转数:一级搅拌桨的转数为2转/分钟~5转/分钟,二级搅拌桨的转数为1转/分钟~3.5转/分钟,三级搅拌桨的转数为0.5转/分钟~2.5转/分钟。The method of the present invention is realized through the following steps: the method is realized based on a mechanical flocculation reaction tank, and the mechanical flocculation reaction tank has three stages, which are respectively a primary flocculation reaction pond, a secondary flocculation reaction pond and a tertiary flocculation reaction pond The reaction tank, the first-level flocculation reaction tank, the second-level flocculation reaction tank and the third-level flocculation reaction tank are arranged sequentially from the water inlet of the flocculation tank to the water outlet of the flocculation tank. There is a stirring paddle in each level of flocculation tank. The corresponding agitating paddles in the secondary flocculation reaction tank and the tertiary flocculation reaction tank are the primary agitating paddle, the secondary agitating paddle and the tertiary paddle;
本发明与现有技术相比具有以下有益效果:一、本发明通过在机械絮凝反应池的一级搅拌桨和二级搅拌桨上设置格网2,格网2作为固相介质在水中可以作为混凝核心,同时可以破坏胶体水化膜,产生大量利于混凝的微涡旋,并可使能量更均匀的分布到水中,因此,扰动充足,絮体能充分成长,特别适合低温低浊水的强化处理。二、本发明在一级搅拌桨和二级搅拌桨上的格网2的网孔孔径依次递增,能明显的提高混凝效果,降低15~20%的混凝剂的投加量,节约了水处理成本。三、本发明在出水水质相同的条件下可以明显的降低投药量,并具有投资小、安装维护方便的优点。Compared with the prior art, the present invention has the following beneficial effects: one, the present invention is provided with
附图说明 Description of drawings
图1是一级搅拌桨或二级搅拌桨上设置格网2后搅拌桨的结构示意图,图2是现有机械搅拌式的搅拌桨的结构示意图。Fig. 1 is a schematic diagram of the structure of the first-stage or second-stage agitator with a
具体实施方式 Detailed ways
具体实施方式一:结合图1说明本实施方式,本实施方式是通过以下步骤实现的:本实施方式基于机械絮凝反应池来实现的,机械絮凝反应池有三级,分别为一级絮凝反应池、二级絮凝反应池和三级絮凝反应池,一级絮凝反应池、二级絮凝反应池和三级絮凝反应池由絮凝池进水端至絮凝池出水端依次设置,且一级絮凝反应池、二级絮凝反应池和三级絮凝反应池内的水相通,每级絮凝池中有一个搅拌桨,一级絮凝反应池、二级絮凝反应池和三级絮凝反应池中对应的搅拌桨分别为一级搅拌桨、二级搅拌桨和三级搅拌桨;步骤一、将一级搅拌桨和二级搅拌桨铺设格网2:分别在一级搅拌桨和二级搅拌桨的桨叶1上的水平轴1-1与竖直轴1-2之间的每个区域内设置一个格网2,每个格网2的四周与其对应的水平轴1-1和竖直轴1-2捆绑、焊接或连接元件连接,一级搅拌桨上的每个格网2的网孔内切圆直径为5mm~50mm,二级搅拌桨上的每个格网2的网孔内切圆直径为10mm~60mm,二级搅拌桨上的每个格网2的网孔内切圆直径应大于一级搅拌桨上的每个格网2的网孔内切圆直径5mm~15mm,对于新建机械絮凝池,格网2的网孔内切圆直径可以选取较小值,对于现有机械絮凝池的改造,格网2的网孔内切圆直径相应选取大一些;步骤二、确定各级搅拌桨1的转数:一级搅拌桨的转数为2转/分钟~5转/分钟,二级搅拌桨的转数为1转/分钟~3.5转/分钟,三级搅拌桨的转数为0.5转/分钟~2.5转/分钟。可以根据搅拌桨电机连接的功率测试仪的测试结果自动调节搅拌桨的转速,当功率表读数低于设定值时,增加搅拌桨转速;当功率表读数高于设定值时,降低搅拌桨转速;可以根据水质水温和水量的变化调节搅拌桨上增加格网的面积和网眼大小,当水温低时,功率表设定值提高,要增加搅拌桨上增加的格网面积并采用大网眼的格网。Specific embodiment 1: This embodiment is described in conjunction with Fig. 1. This embodiment is realized through the following steps: This embodiment is realized based on a mechanical flocculation reaction tank. , the secondary flocculation reaction pool and the third-stage flocculation reaction pool; , the water in the second-level flocculation reaction tank and the third-level flocculation reaction tank are connected, and there is one stirring paddle in each level of flocculation reaction tank, and the corresponding stirring paddles in the first-level flocculation reaction tank, the second-level flocculation reaction tank and the third-level flocculation reaction tank are respectively One-stage stirring paddle, two-stage stirring paddle and three-stage stirring paddle;
具体实施方式二:结合图1说明本实施方式,本实施方式的步骤一中每个格网2由不锈钢外框2-1和不锈钢丝网2-2组成,不锈钢丝网2-2四周与不锈钢外框2-1焊接。其它步骤与具体实施方式一相同。Specific embodiment two: this embodiment is described in conjunction with Fig. 1, each
具体实施方式三:结合图1说明本实施方式,本实施方式的不锈钢丝网2-2的网孔为矩形、三角形或多边形。其它步骤与具体实施方式一相同。Specific Embodiment Three: This embodiment is described with reference to FIG. 1 . The mesh of the stainless steel wire mesh 2-2 in this embodiment is rectangular, triangular or polygonal. Other steps are the same as in the first embodiment.
具体实施方式四:结合图1说明本实施方式,本实施方式的不锈钢丝网(2-2)上的不锈钢丝的直径为0.8mm~5mm。对于新建机械絮凝池,不锈钢丝的直径略粗些,对于现有机械絮凝池的改造,锈钢丝的直径可细一些,以减小阻力和重量,避免对原有系统造成过大的改动。其它步骤与具体实施方式一相同。Specific Embodiment Four: This embodiment is described in conjunction with FIG. 1 . The diameter of the stainless steel wire on the stainless steel wire mesh (2-2) of this embodiment is 0.8 mm to 5 mm. For the new mechanical flocculation tank, the diameter of the stainless steel wire is slightly thicker. For the transformation of the existing mechanical flocculation tank, the diameter of the stainless steel wire can be thinner to reduce resistance and weight and avoid excessive changes to the original system. Other steps are the same as in the first embodiment.
具体实施方式五:结合图1说明本实施方式,本实施方式的步骤一中在三级搅拌桨的桨叶1上的水平轴1-1与竖直轴1-2之间的每个区域内设置一个格网2,该格网2的四周与其对应的水平轴1-1和竖直轴1-2捆绑、焊接或连接元件连接,三级搅拌桨上的每个格网2的网孔内切圆直径为20mm~70mm,三级搅拌桨上的每个格网2的网孔内切圆直径应大于二级搅拌桨上的每个格网2的网孔内切圆直径10mm。其它步骤与具体实施方式一相同。Specific Embodiment Five: This embodiment is described in conjunction with FIG. 1. In step one of this embodiment, in each area between the horizontal axis 1-1 and the vertical axis 1-2 on the
本发明的应用实例:Application example of the present invention:
本实例是某新建水厂,絮凝池尺寸为:长×宽×高=6.3m×4.3m×4.6m,水平轴式搅拌桨。对一级搅拌桨和二级搅拌桨进行改造;分别在一级搅拌桨和二级搅拌桨的桨叶1上的水平轴1-1与竖直轴1-2之间的每个区域内设置一个格网2,采用不锈钢丝的直径为1.5mm,每个格网2的网孔孔径以网孔内切圆直径计为25mm,不锈钢外框2-1尺寸为:长×宽=4mm×3mm;电机频率为18HZ,电机线电流为3.5A,电机转速为2.4转/分。通过上述模拟实验的结果为:增加格网2后,当投药量为60mg/L时,絮凝池中的混凝效果就接近不加格网投药量为80mg/L时的效果;增加格网2后,当投药量为70mg/L时,絮凝池中的混凝效果就超过不加格网投药量为80mg/L时的效果。实验证明,在水质相同的情况下,本发明方法可以节省15%~20%的混凝剂投入量,增加格网后在能耗接近的条件下能耗增加很少。This example is a newly built water plant, the size of the flocculation tank is: length × width × height = 6.3m × 4.3m × 4.6m, horizontal shaft stirring impeller. Retrofit the first-stage stirring paddle and the second-stage stirring paddle; set them in each area between the horizontal axis 1-1 and the vertical shaft 1-2 on the
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