CN102408604B - Application of high-pressure polyethylene material - Google Patents

Application of high-pressure polyethylene material Download PDF

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Publication number
CN102408604B
CN102408604B CN 201110250272 CN201110250272A CN102408604B CN 102408604 B CN102408604 B CN 102408604B CN 201110250272 CN201110250272 CN 201110250272 CN 201110250272 A CN201110250272 A CN 201110250272A CN 102408604 B CN102408604 B CN 102408604B
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pressure polyethylene
minute
banburying
corner protector
blowing agent
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CN 201110250272
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CN102408604A (en
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洪惠泉
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Zhongkeluda Fujian Transportation Technology Co ltd
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Individual
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Abstract

The invention discloses an application of high-pressure polyethylene material, wherein the material is used for producing angle bead. The high-pressure polyethylene material in the invention is produced from specific proportioning of the materials, and the angle bead produced from the high-pressure polyethylene material has high strength, good thermostability, creep resistance, abrasive resistance and fatigue resistance.

Description

The application of high-pressure polyethylene material
Technical field
The invention belongs to the protecting materials field, more specifically relate to a kind of corner protector of high-pressure polyethylene material.
Background technology
Corner protector is the corner protection packing for product, and protection article, carton, wooden case etc. are avoided extraneous extruding and damaged damage.Modern packaging mainly contains two kinds on plastics and paper, namely is Plastic protective corner and corrugated board corner protector, and these two kinds of products are widely used in the every profession and trade logistics transportation now.
The finishing corner protector is widely used in the construction in indoor and outdoor corner, and construction can not only guarantee straight attractive in appearance, the raising speed of application of lines in corner by corner protector, and has effectively strengthened the firm degree in corner, plays the effect of crashproof anti-collision.Use the corner protector construction can also significantly reduce workman's labour intensity, shorten the engineering time, reduce project cost; The corner that high-intensity section bar is embedded in indoor and outdoor is located, and also can play the effect of stiffening web, improves the crashproof intensity in corner.
Summary of the invention
The object of the present invention is to provide a kind of corner protector of high-pressure polyethylene material, the corner protector intensity of the high-pressure polyethylene material of producing by the specified raw material proportioning is high, has good thermostability, creep resistance, wear resistance and fatigue resistance.
For achieving the above object, the present invention adopts following technical scheme:
The corner protector of this high-pressure polyethylene material is that ethylene-vinyl acetate copolymer, calcium carbonate, blowing agent AC, crosslink agent DCP, stearic acid, the zinc oxide of 5-18% forms by high-pressure polyethylene, VA content; The mass fraction of each component is: high-pressure polyethylene 60-70 part, VA content are ethylene-vinyl acetate copolymer 10-30 part, calcium carbonate 20-30 part, blowing agent AC 2-5 part, crosslink agent DCP 0.6-0.7 part, stearic acid 1-1.5 part, zinc oxide 1-1.5 parts of 5-18%.
The preparation method of the corner protector of this high-pressure polyethylene material specifically may further comprise the steps:
(1) batch mixing: press the proportioning raw materials raw materials weighing, other raw material except blowing agent AC and crosslink agent DCP is all dropped in the high-speed mixer mix discharging when temperature reaches 120 ℃;
(2) banburying: the raw material that step (1) is mixed, poured in the Banbury mixer banburying 5-7 minute, when treating that temperature reaches 100-102 ℃, add blowing agent AC and bridging agent, again started the Banbury mixer banburying 5-7 minute, until temperature is when continuing to be elevated to 108-110 ℃, all raw materials mix, and pour out material;
(3) open refining: the compound that banburying is good is plasticated in two roller mills, and front roll temperature 75-85 ℃, rear roll temperature 70-80 ℃, time 1-3 minute, slice thickness was the 1-1.5 millimeter;
(4) foaming: foaming is 25-30 minute in the thermostat container that the sheet work in-process input that will plasticate is 150-163 ℃;
(5) cold pressing: the sheet material after will foaming is put into immediately while hot 30-40 ℃ on the tapering mould at 80-90 degree angle and was colded pressing 10-15 minute;
(6) deburring: finished product is a kind of corner protector with 87 degree angles, and each color even is consistent.
Remarkable advantage of the present invention is:
The corner protector intensity of the high-pressure polyethylene material of (1) producing by the specified raw material proportioning is high, has good thermostability, creep resistance, wear resistance and fatigue resistance.
(2) prescription of the present invention has solved this technical barrier, if the too soft wrinkle that has been easy to is expected at the angle on two tops when namely colding pressing at degree of depth angle, material is easy to cracking too firmly.
(3) intensity and the elasticity of the corner protector of the high-pressure polyethylene material of the present invention's production have reached a desirable balance, and is with low cost with the rubber phase ratio that uses under the equivalent environment, has significant economic and social benefit.
Embodiment
Embodiment 1
Raw material and proportioning: 70 parts of high-pressure polyethylenees, VA content are 1.5 parts of 0.7 part of 5 parts of 30 parts in 30 parts of ethylene-vinyl acetate copolymers, calcium carbonate, blowing agent ACs, crosslink agent DCP, stearic acid, 1.5 parts in the zinc oxide of 5-18%.
The preparation method specifically may further comprise the steps:
(1) batch mixing: press the proportioning raw materials raw materials weighing, other raw material except blowing agent AC and crosslink agent DCP is all dropped in the high-speed mixer mix discharging when temperature reaches 120 ℃;
(2) banburying: with the raw material that step (1) mixes, poured in the Banbury mixer banburying into 7 minutes, when treating that temperature reaches 102 ℃, add blowing agent AC and bridging agent, again started the Banbury mixer banburying 7 minutes, until temperature is when continuing to be elevated to 110 ℃, all raw materials mix, and pour out material;
(3) open refining: the compound that banburying is good is plasticated in two roller mills, 85 ℃ of front roll temperatures, and 80 ℃ of rear roll temperatures, 1 minute time, slice thickness is 1 millimeter;
(4) foaming: foaming is 25 minutes in the thermostat container that the sheet work in-process input that will plasticate is 150 ℃;
(5) cold pressing: the sheet material after will foaming is put into immediately while hot 30 ℃ on the tapering mould at 80-90 degree angle and was colded pressing 15 minutes;
(6) deburring: finished product is a kind of corner protector with 87 degree angles, and each color even is consistent.
Embodiment 2
Raw material and proportioning: 60 parts of high-pressure polyethylenees, VA content are 1 part of 0.6 part of 2 parts of 20 parts in 10 parts of ethylene-vinyl acetate copolymers, calcium carbonate, blowing agent ACs, crosslink agent DCP, stearic acid, 1 part in the zinc oxide of 5-18%.
The preparation method specifically may further comprise the steps:
(1) batch mixing: press the proportioning raw materials raw materials weighing, other raw material except blowing agent AC and crosslink agent DCP is all dropped in the high-speed mixer mix discharging when temperature reaches 120 ℃;
(2) banburying: with the raw material that step (1) mixes, poured in the Banbury mixer banburying into 5 minutes, when treating that temperature reaches 100 ℃, add blowing agent AC and bridging agent, again started the Banbury mixer banburying 5 minutes, until temperature is when continuing to be elevated to 108 ℃, all raw materials mix, and pour out material;
(3) open refining: the compound that banburying is good is plasticated in two roller mills, 75 ℃ of front roll temperatures, and 70 ℃ of rear roll temperatures, 3 minutes time, slice thickness is 1.5 millimeters;
(4) foaming: foaming is 30 minutes in the thermostat container that the sheet work in-process input that will plasticate is 163 ℃;
(5) cold pressing: the sheet material after will foaming is put into immediately while hot 40 ℃ on the tapering mould at 80-90 degree angle and was colded pressing 10 minutes;
(6) deburring: finished product is a kind of corner protector with 87 degree angles, and each color even is consistent.
Embodiment 3
Raw material and proportioning: 65 parts of high-pressure polyethylenees, VA content are 1.2 parts of 0.65 part of 3 parts of 25 parts in 20 parts of ethylene-vinyl acetate copolymers, calcium carbonate, blowing agent ACs, crosslink agent DCP, stearic acid, 1.2 parts in the zinc oxide of 5-18%.
The preparation method specifically may further comprise the steps:
(1) batch mixing: press the proportioning raw materials raw materials weighing, other raw material except blowing agent AC and crosslink agent DCP is all dropped in the high-speed mixer mix discharging when temperature reaches 120 ℃;
(2) banburying: with the raw material that step (1) mixes, poured in the Banbury mixer banburying into 6 minutes, when treating that temperature reaches 101 ℃, add blowing agent AC and bridging agent, again started the Banbury mixer banburying 6 minutes, until temperature is when continuing to be elevated to 109 ℃, all raw materials mix, and pour out material;
(3) open refining: the compound that banburying is good is plasticated in two roller mills, 80 ℃ of front roll temperatures, and 75 ℃ of rear roll temperatures, 2 minutes time, slice thickness is 1.2 millimeters;
(4) foaming: foaming is 28 minutes in the thermostat container that the sheet work in-process input that will plasticate is 156 ℃;
(5) cold pressing: the sheet material after will foaming is put into immediately while hot 35 ℃ on the tapering mould at 80-90 degree angle and was colded pressing 12 minutes;
(6) deburring: finished product is a kind of corner protector with 87 degree angles, and each color even is consistent.
The above only is preferred embodiment of the present invention, and all equalizations of doing according to the present patent application claim change and modify, and all should belong to covering scope of the present invention.

Claims (1)

1. the application of a high-pressure polyethylene material is characterized in that: described high-pressure polyethylene material is for the production of corner protector;
The corner protector of described high-pressure polyethylene material is that ethylene-vinyl acetate copolymer, calcium carbonate, blowing agent AC, crosslink agent DCP, stearic acid, the zinc oxide of 5-18% forms by high-pressure polyethylene, VA content; The mass fraction of each component is: high-pressure polyethylene 60-70 part, VA content are ethylene-vinyl acetate copolymer 10-30 part, calcium carbonate 20-30 part, blowing agent AC 2-5 part, crosslink agent DCP 0.6-0.7 part, stearic acid 1-1.5 part, zinc oxide 1-1.5 parts of 5-18%;
The preparation method of the corner protector of described high-pressure polyethylene material specifically may further comprise the steps:
(1) batch mixing: press the proportioning raw materials raw materials weighing, other raw material except blowing agent AC and crosslink agent DCP is all dropped in the high-speed mixer mix discharging when temperature reaches 120 ℃;
(2) banburying: the raw material that step (1) is mixed, poured in the Banbury mixer banburying 5-7 minute, when treating that temperature reaches 100-102 ℃, add blowing agent AC and bridging agent, again started the Banbury mixer banburying 5-7 minute, until temperature is when continuing to be elevated to 108-110 ℃, all raw materials mix, and pour out material;
(3) open refining: the compound that banburying is good is plasticated in two roller mills, and front roll temperature 75-85 ℃, rear roll temperature 70-80 ℃, time 1-3 minute, slice thickness was the 1-1.5 millimeter;
(4) foaming: foaming is 25-30 minute in the thermostat container that the sheet work in-process input that will plasticate is 150-163 ℃;
(5) cold pressing: the sheet material after will foaming is put into immediately while hot 30-40 ℃ on the tapering mould at 80-90 degree angle and was colded pressing 10-15 minute;
(6) deburring: finished product is a kind of corner protector with 87 degree angles, and each color even is consistent.
CN 201110250272 2011-08-29 2011-08-29 Application of high-pressure polyethylene material Active CN102408604B (en)

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CN102408604B true CN102408604B (en) 2013-01-23

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374167A (en) * 2012-04-27 2013-10-30 东北林业大学 High-filling calcium carbonate/polyethylene bacteriostatic foam material and preparation method thereof
CN105670074A (en) * 2016-01-15 2016-06-15 林彬 Foamed plastic pad as well as preparation method and production line

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CN1258692A (en) * 1998-12-31 2000-07-05 中国科学院近代物理研究所 Crosslinked halide-free fireproof composite polyolefine material and its preparation
CN1370798A (en) * 2001-02-26 2002-09-25 四川大学 Irradiation crosslinking process of preparing ethylene-vinyl acetate copolymer/linear low-density polyethylene foam plastic
CN101392079B (en) * 2008-10-10 2011-05-04 常州天晟新材料股份有限公司 Conductive ethylene-vinyl acetate co-polymer foamed profile and preparation method thereof

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Application publication date: 20120411

Assignee: FUJIAN LUDA TRAFFIC FACILITIES CO.,LTD.

Assignor: Hong Huiquan

Contract record no.: 2013350000134

Denomination of invention: Application of high-pressure polyethylene material

Granted publication date: 20130123

License type: Exclusive License

Record date: 20130815

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Address after: 363118 Longhai City, Fujian Province town house in the village and the former Yan CuO Road (Longhai city of Fujian province Yan CuO Zhen Yang Puxi No. 18)

Patentee after: FUJIAN LUDA TRAFFIC FACILITIES CO.,LTD.

Address before: 363100, Yan Town, Zhangzhou, Fujian, Longhai

Patentee before: Hong Huiquan

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Effective date of registration: 20230613

Address after: Building 9, Zone A, Haina Pan Cultural Digital Industrial Park, No. 8, Jinbin Road, Wenwusha Street, Changle District, Fuzhou City, Fujian Province 350005

Patentee after: Zhongkeluda (Fujian) Transportation Technology Co.,Ltd.

Address before: 363118 Heli Road Crossing, Zhaiqian Village, Yancuo Town, Longhai City, Fujian Province (No. 18, Shangyang Puxi, Yancuo Town, Longhai City, Fujian Province)

Patentee before: FUJIAN LUDA TRAFFIC FACILITIES CO.,LTD.

TR01 Transfer of patent right