CN102392389B - Rewritable UV (Ultraviolet) gloss oil - Google Patents
Rewritable UV (Ultraviolet) gloss oil Download PDFInfo
- Publication number
- CN102392389B CN102392389B CN201110232801.7A CN201110232801A CN102392389B CN 102392389 B CN102392389 B CN 102392389B CN 201110232801 A CN201110232801 A CN 201110232801A CN 102392389 B CN102392389 B CN 102392389B
- Authority
- CN
- China
- Prior art keywords
- gloss oil
- rewritable
- less
- erasable
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a rewritable UV (Ultraviolet) gloss oil. The rewritable UV gloss oil comprises the following components in percentage by weight: 20-50% of resin, 20-50% of active diluent, 4-8% of photoinitiator, 6-12% of auxiliary initiator, 0.1-2% of auxiliary and 0.2-2.5% of wax powder. Under the condition that the sunlight or ultraviolet irradiation is avoided and the relative humidity of the air is less than 70%, 20-50% of resin, 20-50% of active diluent, 4-8% of photoinitiator, 6-12% of auxiliary initiator and 0.1-2% of auxiliary in percentage by weight are slowly mixed in sequence until the materials are uniformly mixed; and in the mixing process, the temperature of the mixed material is kept to be less than 50 DEG C so that the rewritable UV gloss oil can be obtained. The rewriting can be realized while the rewritable UV gloss oil with the mixing ratio, provided by the invention, is adopted on the surfaces of various objects; and water shrinkage or diffusion cannot be generated during writing; and the surfaces of the objects can be completely cleaned after being written without remaining stains.
Description
Technical field
The present invention relates to be added into the material of paper, particularly relate to for repeating erasable handwriting pad printing UV gloss oil.
Background technology
Along with improving constantly of level of education, require a kind of erasable children's book, comprise the rudimentary knowledge such as learning text (Chinese character, English word), mathematics and some game drawing boards, various picture of having arranged in pairs or groups, will allow child after easily practising, increase a entertaining, also can greatly improve the effect of study.These type of books not only require exquisite appearance, and the more important thing is can Palingraphia, can allow children in the process of erasable repetition learning repeatedly, strengthen memory, enjoy the easily enjoyment of study.Meanwhile, environmental protection is a current large theme, can Palingraphia books, can save a large amount of paper, and reach environment protecting.
These type of books at present used by crossing UV gloss oil in surface to its surface treatment, but there are many shortcomings in present used UV gloss oil, because present UV gloss oil uses silicone based levelling agent substantially, cause writing effect undesirable, after writing, there will be ink to shrink or diffusion phenomena; Next is exactly can not wipe clean after writing, Palingraphia several times after, on cardboard, just there will be many spots, cause cannot again writing or affecting attractive in appearance.
Summary of the invention
The present invention mainly solves above-mentioned occurred problem, researches and develops a kind of brand-new board UV gloss oil, can repeat erasable UV gloss oil, use this can repeat erasable UV gloss oil, can reach repeat erasable, write Shi Buhui produce shrink or diffusion phenomena, after writing, can wipe clean completely, not leave stain.
The present invention solves the problems of the technologies described above the technical scheme proposing, and propose one and can repeat erasable UV gloss oil, by forming according to the component of weight percent meter below:
Resin 20-50%
Reactive diluent 20-50%
Light trigger 4%-8%
Aided initiating 6%-12%
Auxiliary agent 0.1%-2%
Wax powder 0.2%-2.5%
Described resin is one or more of epoxy acrylic tree, polyurethane acrylic resin, polyester acrylic resin, polyacrylic resin.
Described reactive diluent is dipropylene glycol class diacrylate, tripropylene glycol class diacrylate, trimethylolpropane triacrylate, dipentaerythritol acrylate, 1, one or more of 6-hexanediyl ester, pentaerythritol triacrylate, double pentaerythritol C5 methacrylate.
Described photosensitizer is that 1-hydroxycyclohexyl phenylketone, benzophenone, 2-hydroxy-methyl-phenylacetone, 2-hydroxy-2-methyl-1-are to hydroxyethyl ether benzylacetone, 2-Bian Ji-2-methylamino-1-(4-woods phenyl)-1-butanone, 2, one or more of the first base diphenyl phosphine oxide of 4,6-trimethylbenzene first, isopropyl thia grace ketone.
Described aided initiating is one or more of aliphatic tertiary amine, ethanolamines amine, tertiary amine benzoate and reactive amines.
Described auxiliary agent is Siloxane-Oxyalkylene Copolymers, one or more of esters of acrylic acid levelling agent, fluorine-carbon modified levelling agent.
Described wax powder is Tissuemat E.
Above-mentioned preparation method and the processing step that repeats erasable UV gloss oil is as follows:
Avoiding daylight or UV-irradiation, relative air humidity to be less than under 70% condition, the aided initiating of the resin that is slowly 20-50% by weight percent content successively, 20%-50% reactive diluent, 4%-8% light trigger, 6%-12%, the auxiliary agent of 0.1%-2%, be stirred to mix and can obtain end product, in whipping process, keep mixed material temperature to be less than 50 ℃.
Above-mentioned better mixing speed is 500-700 rev/min.
Compared with prior art, the present invention has following significant effect:
(1) writing effect is good, can reach repeat erasable, write Shi Buhui produce shrink or diffusion phenomena;
(2) can wipe clean completely after writing, not leave stain, not be subject to the impact of environmental condition, the highest can be resistance to 50 ℃;
(3) ABRASION RESISTANCE is high, compared to existing technology in, the present invention has added polyethylene micropowder wax slurry in UV gloss oil, makes the wear-resisting better effects if of coating;
(4), because the present invention is mainly used in children's book or cribbage-board class, so more focus on safety aspect selection, can not damage children's torso health.
The specific embodiment
Embodiment 1:
One of the present invention can repeat erasable UV gloss oil, its each component and weight percent content thereof respectively: modified epoxy acrylate resin 25%, tripropylene glycol class diacrylate 24%, trimethylolpropane triacrylate 27%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, Siloxane-Oxyalkylene Copolymers 0.35%, esters of acrylic acid levelling agent 0.30%, Tissuemat E 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is as follows: avoiding daylight or UV-irradiation, relative air humidity is less than under 70% condition, successively slowly by 25% modified epoxy acrylate resin, 24% tripropylene glycol class diacrylate, 27% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% Siloxane-Oxyalkylene Copolymers, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E adds in mixer, stir while adding, can obtain end product with 550 revs/min of stirrings of rotating speed, in operating process, mixed material temperature is less than 50 ℃.
Embodiment 2:
One of the present invention can repeat erasable UV gloss oil, its each component and weight percent content thereof respectively: polyurethane acrylic resin 26%, dipropylene glycol class diacrylate 25%, trimethylolpropane triacrylate 25%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, Siloxane-Oxyalkylene Copolymers 0.35%, esters of acrylic acid levelling agent 0.30%, polyethylene 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is as follows: avoiding daylight or UV-irradiation, relative air humidity is less than under 70% condition, successively slowly by 26% polyurethane acrylic resin, 25% dipropylene glycol class diacrylate, 25% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% Siloxane-Oxyalkylene Copolymers, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E adds in mixer, stir while adding, can obtain end product with 550 revs/min of stirrings of rotating speed.In operating process, mixed material temperature is less than 50 ℃.
Embodiment 3:
One of the present invention can repeat erasable UV gloss oil, its each component and weight percent content thereof respectively: modified epoxy acrylate resin 25%, dipropylene glycol class diacrylate 25%, trimethylolpropane triacrylate 26%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, Siloxane-Oxyalkylene Copolymers 0.35%, esters of acrylic acid levelling agent 0.30%, Tissuemat E 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is as follows: avoiding daylight or UV-irradiation, relative air humidity is less than under 70% condition, the modified epoxy acrylate resin that is slowly 25% by weight percent content successively, 25% dipropylene glycol class diacrylate, 26% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% Siloxane-Oxyalkylene Copolymers, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E adds in mixer, stir while adding, can obtain end product with 550 revs/min of stirrings of rotating speed.In operating process, mixed material temperature is less than 50 ℃.
As the formula of above-described embodiment or method, adopt other that obtain with the same or similar formula of this embodiment or method can repeat erasable UV gloss oil, all within protection domain of the present invention.
Claims (2)
1. can repeat an erasable UV gloss oil, it is characterized in that: by forming according to the following component of weight percent meter below:
Modified epoxy acrylate resin 25%
Tripropylene glycol class diacrylate 24%
Trimethylolpropane triacrylate 27%
Dipentaerythritol acrylate 4%
Benzophenone 6%
1-hydroxycyclohexyl phenylketone 1%
Reactive amines 12%
Siloxane-Oxyalkylene Copolymers 0.35%
Esters of acrylic acid levelling agent 0.30%
Tissuemat E 0.35%.
2. the preparation method who repeats erasable UV gloss oil according to claim 1, it is characterized in that: avoiding daylight or UV-irradiation, relative air humidity is less than under 70% condition, the modified epoxy acrylate resin that is slowly 25% by weight percent content successively, 24% tripropylene glycol class diacrylate, 27% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% Siloxane-Oxyalkylene Copolymers, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E adds mixer, mixing speed is 550 Zhuan ∕ minute, be stirred to and mix, in whipping process, keep mixed material temperature to be less than 50 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232801.7A CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232801.7A CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102392389A CN102392389A (en) | 2012-03-28 |
| CN102392389B true CN102392389B (en) | 2014-06-25 |
Family
ID=45859761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110232801.7A Active CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102392389B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103821029B (en) * | 2014-03-10 | 2016-08-24 | 昆山美普森包装有限公司 | A kind of resistance oxygen resistance wet paper and preparation method thereof |
| CN104002571B (en) * | 2014-05-28 | 2017-05-17 | 广东金冠科技股份有限公司 | UV (Ultra Violet) printing and hot stamping process and UV matte varnish |
| CN106833362A (en) * | 2017-02-27 | 2017-06-13 | 上海超彩油墨有限公司 | A kind of gloss oil on tin printing ink |
| CN107118672A (en) * | 2017-06-29 | 2017-09-01 | 台昌树脂(佛山)有限公司 | Uv gloss oil and preparation method thereof |
| CN107619622B (en) * | 2017-08-02 | 2020-11-24 | 洋紫荆油墨(中山)有限公司 | Water-resistant UV gloss oil for glass and preparation method thereof |
| CN109439126A (en) * | 2018-08-28 | 2019-03-08 | 佛山市南海区长彤新材料科技有限公司 | It is a kind of disposably to exempt to play low UV paint and preparation method thereof |
| CN111892862B (en) * | 2020-07-28 | 2021-06-22 | 上海蓝宝涂料有限公司 | Finishing varnish and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN101284968A (en) * | 2008-05-30 | 2008-10-15 | 深圳市通产丽星股份有限公司 | Weatherproof bronzing UV gloss oil |
| CN101570652A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting UV light oil and operating method thereof |
| CN101955719A (en) * | 2009-07-14 | 2011-01-26 | 深圳市科彩印务有限公司 | Water mist proof UV (Ultraviolet) gloss oil |
-
2011
- 2011-08-15 CN CN201110232801.7A patent/CN102392389B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN101570652A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting UV light oil and operating method thereof |
| CN101284968A (en) * | 2008-05-30 | 2008-10-15 | 深圳市通产丽星股份有限公司 | Weatherproof bronzing UV gloss oil |
| CN101955719A (en) * | 2009-07-14 | 2011-01-26 | 深圳市科彩印务有限公司 | Water mist proof UV (Ultraviolet) gloss oil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102392389A (en) | 2012-03-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102392389B (en) | Rewritable UV (Ultraviolet) gloss oil | |
| WO2016199611A1 (en) | Active light-curable inkjet ink set for three-dimensional printing, three-dimensional printing method and three-dimensional printing system | |
| CN101979449B (en) | Ultraviolet curing coating for white board | |
| CN101358101B (en) | Water-soluble varnish and method of preparing the same | |
| CN103951818B (en) | A kind of sulfonic acid type water-based unsaturated polyester and the application in coating thereof | |
| JP2009057548A (en) | Photocurable ink composition, method for inkjet recording, and recorded matter | |
| WO2013128452A1 (en) | Cationic polymerizable compositions and methods of use thereof | |
| CN100588691C (en) | Coating for UV cured plastic and use | |
| JP7207996B2 (en) | Active energy ray-curable composition | |
| CN105860664B (en) | It is a kind of can water cause the white board pen ink and preparation method thereof to fade | |
| CN101705034B (en) | Water-soluble dustfree chalks | |
| AU2010242326B2 (en) | Method of hydraulic transfer, product of hydraulic transfer, and coating agent for hydraulic transfer film | |
| CN110183899A (en) | UV snowflake printing ink | |
| CN103387655B (en) | Aqueous ultraviolet-curable automotive varnish and preparation method thereof | |
| Gottsegen | The painter's handbook | |
| CN106338887A (en) | Photoresist composition and application thereof | |
| JP2007332249A (en) | Water-erasable solid drawing material | |
| JP6790692B2 (en) | Active energy ray-polymerizable resin composition for optical three-dimensional modeling, and three-dimensional modeling | |
| Yunusaliev | THE VALUE OF WATERCOLOR AND GOUACHE MATERIAL IN THE TECHNIQUE OF WATER-BASED PAINT | |
| CN111378353B (en) | VOC (volatile organic compound) -emission-free environment-friendly UV gloss oil for coated iron and preparation method thereof | |
| CN102146232A (en) | Method for making environment-friendly and easily-erased liquid ink for teaching and writing and color paste used therein | |
| JP2007099860A (en) | Ink composition for oily marking pen | |
| JP2017141187A (en) | Removal solution for photocurable artificial nails, removal method of photocurable artificial nails, and nail art kit | |
| JP2020169266A (en) | Active energy ray-curable flexographic printing ink composition | |
| CN203418896U (en) | Calligraphy practicing table |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |