CN102392389A - Rewritable UV (Ultraviolet) gloss oil - Google Patents
Rewritable UV (Ultraviolet) gloss oil Download PDFInfo
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- CN102392389A CN102392389A CN2011102328017A CN201110232801A CN102392389A CN 102392389 A CN102392389 A CN 102392389A CN 2011102328017 A CN2011102328017 A CN 2011102328017A CN 201110232801 A CN201110232801 A CN 201110232801A CN 102392389 A CN102392389 A CN 102392389A
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- gloss oil
- erasable
- resin
- rewritable
- repeat
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Abstract
The invention provides a rewritable UV (Ultraviolet) gloss oil. The rewritable UV gloss oil comprises the following components in percentage by weight: 20-50% of resin, 20-50% of active diluent, 4-8% of photoinitiator, 6-12% of auxiliary initiator, 0.1-2% of auxiliary and 0.2-2.5% of wax powder. Under the condition that the sunlight or ultraviolet irradiation is avoided and the relative humidity of the air is less than 70%, 20-50% of resin, 20-50% of active diluent, 4-8% of photoinitiator, 6-12% of auxiliary initiator and 0.1-2% of auxiliary in percentage by weight are slowly mixed in sequence until the materials are uniformly mixed; and in the mixing process, the temperature of the mixed material is kept to be less than 50 DEG C so that the rewritable UV gloss oil can be obtained. The rewriting can be realized while the rewritable UV gloss oil with the mixing ratio, provided by the invention, is adopted on the surfaces of various objects; and water shrinkage or diffusion cannot be generated during writing; and the surfaces of the objects can be completely cleaned after being written without remaining stains.
Description
Technical field
The present invention relates to be added into the material of paper, particularly relate to and be used for to repeat erasable handwriting pad printing UV gloss oil.
Background technology
Along with improving constantly of level of education; Require a kind of erasable children's book; Comprise rudimentary knowledge and some recreation drawing boards such as learning text (Chinese character, English word), mathematics, various picture of having arranged in pairs or groups will let child after easily practising; Increase a entertaining, also can improve the effect of study greatly.These type of books not only require exquisite appearance, and the more important thing is can Palingraphia, and can let children in the process of erasable repetition learning repeatedly, enhance memory power is enjoyed the easily enjoyment of study.Simultaneously, environmental protection is a current big theme, but the Palingraphia books can be saved a large amount of paper, reach environment protecting.
These type of at present used books are through promptly crossing the UV gloss oil in the surface to its surface treatment; But there are many shortcomings in present employed UV gloss oil; Because present UV gloss oil uses silicone based levelling agent basically, causes writing effect undesirable, can occur ink after writing and shrink or diffusion phenomena; Next is exactly can not wipe clean after writing, Palingraphia several times after, many spots will appear on the cardboard, cause can't writing once more or influencing attractive in appearance.
Summary of the invention
The present invention mainly solves the above-mentioned problem that occurs, and researches and develops a kind of brand-new board UV gloss oil, can repeat erasable UV gloss oil; Use this can repeat erasable UV gloss oil, can reach and repeat erasablely, write that Shi Buhui produce to shrink or diffusion phenomena; Can wipe clean fully after writing, not leave stain.
The present invention solves the problems of the technologies described above the technical scheme that proposes, and proposes a kind of erasable UV gloss oil that repeats, and is made up of following component according to weight percent meter:
Resin 20-50%
Reactive diluent 20-50%
Light trigger 4%-8%
Aided initiating 6%-12%
Auxiliary agent 0.1%-2%
Wax powder 0.2%-2.5%
Said resin is one or more of epoxy acrylic tree, polyurethane acrylic resin, polyester acrylic resin, polyacrylic resin.
Said reactive diluent is one or more of DPG class diacrylate, tripropylene glycol class diacrylate, trimethylolpropane triacrylate, dipentaerythritol acrylate, 1,6 hexanediol diacrylate, pentaerythritol triacrylate, double pentaerythritol C5 methacrylate.
Said photosensitizer is that 1-hydroxycyclohexyl phenylketone, benzophenone, 2-hydroxyl-methyl-phenylacetone, 2-hydroxy-2-methyl-1-are to hydroxyethyl ether benzylacetone, 2-Bian Ji-2-methylamino-1-(4-woods phenyl)-1-butanone, 2; 4, one or more of the basic diphenyl phosphine oxide of 6-trimethylbenzene first elder generation, isopropyl thia grace ketone.
Said aided initiating is one or more of aliphatic tertiary amine, ethanolamines amine, tertiary amine property benzoate and reactive amines.
Said auxiliary agent is polyether-modified polysiloxanes, one or more of esters of acrylic acid levelling agent, fluorine-carbon modified levelling agent.
Said wax powder is a Tissuemat E.
Above-mentioned preparation method and the processing step that repeats erasable UV gloss oil is following:
Avoid daylight or UV-irradiation, relative air humidity less than 70% condition under; Be resin, 20%-50% reactive diluent, the 4%-8% light trigger of 20-50%, the aided initiating of 6%-12% slowly successively with weight percent content; The auxiliary agent of 0.1%-2%; Be stirred to mix and obtain end product, keep the mixed material temperature in the whipping process less than 50 ℃.
Above-mentioned preferable mixing speed is 500-700 rev/min.
Compared with prior art, the present invention has following significant effect:
(1) writing effect is good, can reach to repeat erasablely, writes that Shi Buhui produce to shrink or diffusion phenomena;
(2) can wipe clean fully after writing, not leave stain, not receive the influence of environmental condition, the highest can be anti-50 ℃;
(3) ABRASION RESISTANCE is high, compares in the prior art, and the present invention has added polyethylene micropowder wax slurry in the UV gloss oil, makes the wear-resisting better effects if of coating;
(4) because the present invention is mainly used in children's book or cribbage-board class,, can not damage child's torso health so aspect selection, more pay attention to safety.
The specific embodiment
Embodiment 1:
The present invention is a kind of to repeat erasable UV gloss oil, and its each component and weight percent content thereof are respectively: modified epoxy acrylate resin 25%, tripropylene glycol class diacrylate 24%, trimethylolpropane triacrylate 27%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, polyether-modified polysiloxanes 0.35%, esters of acrylic acid levelling agent 0.30%, Tissuemat E 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is following: avoid daylight or UV-irradiation, relative air humidity less than 70% condition under; Slowly 25% modified epoxy acrylate resin, 24% tripropylene glycol class diacrylate, 27% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% polyether-modified polysiloxanes, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E are added in the mixer successively; Stir while adding; Can obtain end product with 550 rev/mins of stirrings of rotating speed, the mixed material temperature is less than 50 ℃ in the operating process.
Embodiment 2:
The present invention is a kind of to repeat erasable UV gloss oil, and its each component and weight percent content thereof are respectively: polyurethane acrylic resin 26%, DPG class diacrylate 25%, trimethylolpropane triacrylate 25%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, polyether-modified polysiloxanes 0.35%, esters of acrylic acid levelling agent 0.30%, polyethylene 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is following: avoid daylight or UV-irradiation, relative air humidity less than 70% condition under; Slowly 26% polyurethane acrylic resin, 25% DPG class diacrylate, 25% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% polyether-modified polysiloxanes, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E are added in the mixer successively; Stir while adding, can obtain end product with 550 rev/mins of stirrings of rotating speed.The mixed material temperature is less than 50 ℃ in the operating process.
Embodiment 3:
The present invention is a kind of to repeat erasable UV gloss oil, and its each component and weight percent content thereof are respectively: modified epoxy acrylate resin 25%, DPG class diacrylate 25%, trimethylolpropane triacrylate 26%, dipentaerythritol acrylate 4%, benzophenone 6%, 1-hydroxycyclohexyl phenylketone 1%, reactive amines 12%, polyether-modified polysiloxanes 0.35%, esters of acrylic acid levelling agent 0.30%, Tissuemat E 0.35%.
The above-mentioned preparation method who repeats erasable UV gloss oil is following: avoid daylight or UV-irradiation, relative air humidity less than 70% condition under; Be that 25% modified epoxy acrylate resin, 25% DPG class diacrylate, 26% trimethylolpropane triacrylate, 4% dipentaerythritol acrylate, 6% benzophenone, 1% 1-hydroxycyclohexyl phenylketone, 12% reactive amines, 0.35% polyether-modified polysiloxanes, 0.30% esters of acrylic acid levelling agent, 0.35% Tissuemat E add in the mixer slowly successively with weight percent content; Stir while adding, can obtain end product with 550 rev/mins of stirrings of rotating speed.The mixed material temperature is less than 50 ℃ in the operating process.
Like prescription or the method for above-mentioned embodiment, adopt with the same or similar prescription of this embodiment or method obtained that other can repeat erasable UV gloss oil, all within protection domain of the present invention.
Claims (9)
1. one kind can be repeated erasable UV gloss oil, it is characterized in that, is made up of following following component according to weight percent meter:
Resin 20%-50%
Reactive diluent 20%-50%
Light trigger 4%-8%
Aided initiating 6%-12%
Auxiliary agent 0.1%-2%
Wax powder 0.2%-2.5%.
2. according to claim 1ly repeat erasable UV gloss oil, it is characterized in that: said resin is one or more of epoxy acrylic tree, polyurethane acrylic resin, polyester acrylic resin, polyacrylic resin.
3. according to claim 1ly repeat erasable UV gloss oil; It is characterized in that: said reactive diluent is one or more of DPG class diacrylate, tripropylene glycol class diacrylate, trimethylolpropane triacrylate, dipentaerythritol acrylate, 1,6 hexanediol diacrylate, pentaerythritol triacrylate, double pentaerythritol C5 methacrylate.
4. according to claim 1ly repeat erasable UV gloss oil; It is characterized in that: said photosensitizer is that 1-hydroxycyclohexyl phenylketone, benzophenone, 2-hydroxyl-methyl-phenylacetone, 2-hydroxy-2-methyl-1-are to hydroxyethyl ether benzylacetone, 2-Bian Ji-2-methylamino-1-(4-woods phenyl)-1-butanone, 2; 4, one or more of the basic diphenyl phosphine oxide of 6-trimethylbenzene first elder generation, isopropyl thia grace ketone.
5. according to claim 1ly repeat erasable UV gloss oil, it is characterized in that: said aided initiating is one or more of aliphatic tertiary amine, ethanolamines amine, tertiary amine property benzoate and reactive amines.
6. according to claim 1ly repeat erasable UV gloss oil, it is characterized in that: said auxiliary agent is one or more of polyether-modified polysiloxanes, esters of acrylic acid levelling agent, fluorine-carbon modified levelling agent.
7. according to claim 1ly repeat erasable UV gloss oil, it is characterized in that: said wax powder is a Tissuemat E.
8. according to described preparation method and the processing step that repeats erasable UV gloss oil of claim 1-7; It is characterized in that: avoid daylight or UV-irradiation, relative air humidity less than 70% condition under; Be resin, 20%-50% reactive diluent, the 4%-8% light trigger of 20-50%, the aided initiating of 6%-12% slowly successively with weight percent content; The auxiliary agent of 0.1%-2% is stirred to and mixes, and keeps the mixed material temperature less than 50 ℃ in the whipping process.
9. the preparation method who repeats erasable UV gloss oil according to claim 8 is characterized in that: described preferable mixing speed is 500-700 rev/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232801.7A CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232801.7A CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
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| Publication Number | Publication Date |
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| CN102392389A true CN102392389A (en) | 2012-03-28 |
| CN102392389B CN102392389B (en) | 2014-06-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201110232801.7A Active CN102392389B (en) | 2011-08-15 | 2011-08-15 | Rewritable UV (Ultraviolet) gloss oil |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103821029A (en) * | 2014-03-10 | 2014-05-28 | 艾捷舒尔物德包装（昆山）有限公司 | Antioxidant and moisture-retarding paper and preparation method thereof |
| CN104002571A (en) * | 2014-05-28 | 2014-08-27 | 广东金冠科技股份有限公司 | UV (Ultra Violet) printing and hot stamping process and UV matte varnish |
| CN106833362A (en) * | 2017-02-27 | 2017-06-13 | 上海超彩油墨有限公司 | A kind of gloss oil on tin printing ink |
| CN107118672A (en) * | 2017-06-29 | 2017-09-01 | 台昌树脂(佛山)有限公司 | Uv gloss oil and preparation method thereof |
| CN107619622A (en) * | 2017-08-02 | 2018-01-23 | 洋紫荆油墨(中山)有限公司 | A kind of glass water resistance UV gloss oil and preparation method thereof |
| CN109439126A (en) * | 2018-08-28 | 2019-03-08 | 佛山市南海区长彤新材料科技有限公司 | It is a kind of disposably to exempt to play low UV paint and preparation method thereof |
| CN111892862A (en) * | 2020-07-28 | 2020-11-06 | 上海蓝宝涂料有限公司 | Finishing varnish and preparation method thereof |
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| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN101284968A (en) * | 2008-05-30 | 2008-10-15 | 深圳市通产丽星股份有限公司 | Weatherproof bronzing UV gloss oil |
| CN101570652A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting UV light oil and operating method thereof |
| CN101955719A (en) * | 2009-07-14 | 2011-01-26 | 深圳市科彩印务有限公司 | Water mist proof UV (Ultraviolet) gloss oil |
-
2011
- 2011-08-15 CN CN201110232801.7A patent/CN102392389B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN101570652A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting UV light oil and operating method thereof |
| CN101284968A (en) * | 2008-05-30 | 2008-10-15 | 深圳市通产丽星股份有限公司 | Weatherproof bronzing UV gloss oil |
| CN101955719A (en) * | 2009-07-14 | 2011-01-26 | 深圳市科彩印务有限公司 | Water mist proof UV (Ultraviolet) gloss oil |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103821029A (en) * | 2014-03-10 | 2014-05-28 | 艾捷舒尔物德包装（昆山）有限公司 | Antioxidant and moisture-retarding paper and preparation method thereof |
| CN103821029B (en) * | 2014-03-10 | 2016-08-24 | 昆山美普森包装有限公司 | A kind of resistance oxygen resistance wet paper and preparation method thereof |
| CN104002571A (en) * | 2014-05-28 | 2014-08-27 | 广东金冠科技股份有限公司 | UV (Ultra Violet) printing and hot stamping process and UV matte varnish |
| CN106833362A (en) * | 2017-02-27 | 2017-06-13 | 上海超彩油墨有限公司 | A kind of gloss oil on tin printing ink |
| CN107118672A (en) * | 2017-06-29 | 2017-09-01 | 台昌树脂(佛山)有限公司 | Uv gloss oil and preparation method thereof |
| CN107619622A (en) * | 2017-08-02 | 2018-01-23 | 洋紫荆油墨(中山)有限公司 | A kind of glass water resistance UV gloss oil and preparation method thereof |
| CN109439126A (en) * | 2018-08-28 | 2019-03-08 | 佛山市南海区长彤新材料科技有限公司 | It is a kind of disposably to exempt to play low UV paint and preparation method thereof |
| CN111892862A (en) * | 2020-07-28 | 2020-11-06 | 上海蓝宝涂料有限公司 | Finishing varnish and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102392389B (en) | 2014-06-25 |
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