CN102389952A - Plunger type equal-liquid-level pressure amorphous strip maker - Google Patents

Plunger type equal-liquid-level pressure amorphous strip maker Download PDF

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Publication number
CN102389952A
CN102389952A CN2011103698825A CN201110369882A CN102389952A CN 102389952 A CN102389952 A CN 102389952A CN 2011103698825 A CN2011103698825 A CN 2011103698825A CN 201110369882 A CN201110369882 A CN 201110369882A CN 102389952 A CN102389952 A CN 102389952A
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China
Prior art keywords
plunger
pressure
liquid level
nozzle bag
nozzle
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CN2011103698825A
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Chinese (zh)
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郭莉
郭婧儒
尹娜
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TENGZHOU HIGH-TECH KANGNA ALLOY MATERIAL CO LTD
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TENGZHOU HIGH-TECH KANGNA ALLOY MATERIAL CO LTD
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Publication of CN102389952A publication Critical patent/CN102389952A/en
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Abstract

The invention discloses a plunger type equal-liquid-level pressure amorphous strip maker. According to the invention, liquid level height is used to generate pressure (0.3-0.4kg/cm<2>) so as to make an amorphous or amorphous nanocrystalline strip (less than 30 mu m), and a movable plunger is used to keep the liquid level height. The plunger type equal-liquid-level pressure amorphous strip maker comprises a non-vacuum induction furnace (71), a pressure sensor (72), a molten steel tank (73), a liquid level height gauge (74), a nozzle bag (75), a heating globar (76), a cooling roller (77), a plunger (78), a plunger lifting rod (79), a magnetic scale (710) and a lifting motor (711). The plunger type equal-liquid-level pressure amorphous strip maker has the characteristics of accurate pressure and convenience in operation, and has the advantages of low cost and high yield as compared with a strip injection machine using gas to apply pressure.

Description

Liquid level pressure amorphous pocket builders such as plunger type
Technical field
The present invention relates to be used to make the system carrying device of non-crystaline amorphous metal or amorphous and nanocrystalline soft magnetic alloy, particularly liquid level pressure amorphous pocket builder such as a kind of plunger type.
Background technology
Invented from nineteen sixty U.S. professor guwez that (cooling velocity is 10 with rapid quenching technique 6℃/s) since the preparation Au-Si series amorphous alloy, because its institutional framework, preparation technology, excellent material property receive the special concern of Material Physics scholar and industrial circle efficiently always.U.S. Allied-Signal company developed non-crystaline amorphous metal broadband fast quenching technology in 1979, made the big production of amorphous alloy strips become possibility.U.S. Allied-Signal company had possessed the production capacity that annual production reaches 60,000 tons of amorphous ribbons in 1989, and wherein representing the trade mark is 2605S-2, and composition is Fe78Si9B13.Present domestic annual requirement reaches 100,000 tons and goes up.
The Ji Zeke benevolence of FDAC metal Co., Ltd. in 1988 has been researched and developed the magnetically soft alloy of high magnetic conducting nanocrystalline grain, and typical composition is Fe73.5Cu1Nb3Si13.5B9.Present domestic annual production can reach more than the 5000t.
The amorphous nano peritectic alloy is just led excellent properties such as high-saturation magnetic induction, low-coercivity low-loss because of having height, becomes outstanding person in the market.But along with the development of electron electric power product, particularly range transformer have proposed high request with iron core aspect the loss.The formula of estimation eddy-current loss is on engineering:
Pe∝kδ 2
δ is the thickness of material in the formula, and ρ is the resistivity of material
The effective way that for this reason reduces eddy-current loss is the thickness that lowers material.So carried out the technology and the equipment of research and development spray amorphous nano-crystalline strip in recent years both at home and abroad, this spray band machine is commonly referred to as pressure spray band machine.
The production technology that the amorphous and nanocrystalline soft magnetic alloy band is general is: adopt vaccum sensitive stove or non-vacuum induction furnace to smelt the foundry alloy of amorphous nano-crystalline; Again through the non-vacuum induction furnace remelting, the nozzle bag through spray band machine is sprayed onto processes amorphous ribbon on the chill roll with foundry alloy.Common amorphous ribbon pocket builder is divided into two kinds usually, and two bag methods and three guarantees method are like Fig. 1,2.Among Fig. 1 11 is that non-vacuum induction furnace 12 is the nozzle bags that install nozzle additional; The nozzle bag adopts the resistance wire heating to play insulation effect; The induction furnace induced field injects in the nozzle bag when making molten steel temperature reach uniform temperature; Molten steel injects chill roll ejection amorphous ribbon through nozzle by the deadweight of molten steel, because the not high amorphous ribbon that can only produce greater than 30um of liquid level.Fig. 2 is the common spray band machine of three guarantees method; 21 is that non-vacuum induction furnace, 22 is that tundish, 23 is to be the globar heating resistor by the molten steel, 25 that induction furnace injects; Owing to adopt the globar heat tracing higher; Owing to adopt tundish, molten steel to make impurity come-up, favourable raising steel band quality at Bao Zhongke.
The spray band pressure of common spray band machine is to lean on the molten steel deadweight in the nozzle bag to produce.General liquid level height is about 200mm, the about 0.15kg/cm of the pressure of generation 2. the amorphous ribbon thickness average out to 33 μ m of spray, the mouth seam of nozzle is wide to be 0.7-0.8mm, the about 0.1mm of distance of nozzle and chill roll, for pressure, the induction furnace that keeps spraying band will constantly inject molten steel in the spray bag, usually each injection rate is 5-8kg.
Domestic a large amount of amorphous ribbon is all accomplished by common pocket builder at present.And the annual production of amorphous strip is no more than 400t.
The pressure of research and development sprays band machine such as Fig. 3,4,5,6 both at home and abroad.
Fig. 3: 31 are chill roll for heating rod, 37 for stopper rod, 36 for induction coil, 35 for the crucible of refractory material system, 34 for the gas interface, 33 of exerting pressure for peep hole, 32.Add foundry alloy in the crucible earlier during work, sealing, eddy-current heating when the foundry alloy fusing reaches temperature, draws back stopper rod and makes molten steel flow to chill roll spray band.
Fig. 3 is a Russian non-crystaline amorphous metal pressure spray band machine, and the nozzle bag of this machine seal, in the process of spray band is to rely on constantly the pressure of increase inert gas to keep spraying the pressure of band.But the band amount of unit interval ejection is difficult for tolerance, so follow the tracks of the force value of regulating inert gas certain degree of difficulty is arranged.This equipment foundry alloy melts through eddy-current heating in the nozzle bag.The magnetic field of induction can cause the metal material of nozzle bag support section because magnetic hysteresis is flexible size possibly to be changed, so the distance of nozzle and chill roll can be affected, so also just influenced the uniformity of the amorphous ribbon thickness that spray goes out.This pocket builder fixed nozzle position and stopper rod are all processed with meticulous graphite, and every spray one furnace zone, this part just needs to change once, so expense is bigger.This spray band machine can not be added molten steel in the nozzle bag in spray band process in addition, so the spray band amount of a stove has limitation.
Among Fig. 4: 41 for exert pressure pipeline, 47 for eddy-current heating induction coil, 48 for vacuum drying oven body of heater, 49 are crucible, 410 molten steel for pack foundry alloy fusing for quartz ampoule, 46 for quartzy nozzle, the 43 telescopic bellowss for sealing are used to adjust roll gap, 44 for vacuum lead, 45 for chill roll, 42; Foundry alloy is packed in the crucible during work; Sealing; Eddy-current heating, when molten steel temperature reached, the molten steel of exerting pressure sprayed to chill roll spray band from quartz ampoule.
Fig. 4 is the sketch map of German amorphous pressure pocket builder.This equipment was just introduced by China Shanxi as far back as 2002.But off-duty still at present.Beijing company in 2009 has also introduced should technology, but equipment is also in debugging.
The characteristics of this machine are following sprays, are with on chill roll cornerite big in theory, good cooling results.Be convenient to set up tension force if adopt the take-up of automatic band-retracting machine.Because foundry alloy is remelting under vacuum, degassing effect is good.
This equipment is found in debugging, because foundry alloy adopts the eddy-current heating remelting, the distance of nozzle and chill roll is difficult to stable, and is the same with Fig. 3.Owing to adopt spray down, crucible must insert the conduit (generally using quartz ampoule) of band nozzle in addition, in stove, exerts pressure during the spray band, makes molten steel in managing, spray to chill roll.Quartz ampoule bursts and happens occasionally in the use.Because of being difficult for temperature raising, nozzle exists the problem that when band spray gags somebody or belt surface is bad.This equipment manufacturing cost is high in addition, consumes greatly, and operating difficulties also is an objective reality.
Fig. 5 is melted foundry alloy by non-vacuum induction furnace; When temperature reaches; Logical burned steel mouth 51 injects in the nozzle bag 56, and by mobile stopper rod 511, molten steel arrives chill roll through the mouth of a river 57 through nozzle 59 and realizes the spray band; Wherein globar 55 is heating and heat preserving functions, the pressure of spray band by the molten steel height with apply air pressure and form.
Fig. 5 is the electric resistor heating type pressure spray band machine of Beijing research and development, and this machine is the domestic amorphous thin ribbon pocket builder that has formed industrialization, when this machine reaches uniform temperature by non-vacuum induction furnace remelting foundry alloy, is injected into molten steel in the nozzle bag, the sealed-in nozzles bag again.Exert pressure with inert gas during the spray band, promote stopper rod, regulate roll gap spray band.But owing to adopt gas pressure spray band, the nozzle bag seals, and in the process of spray band, can not add molten steel, so every stove spray band amount is limited.
Fig. 6: 61 is that peep hole, 62 is chill roll for stopper rod, 610 for nozzle, 69 for the pallets that move the nozzle bag, 68 for induction coil, 67 for nozzle bag graphite part, 66 for the carbon silicon of nozzle bag part, 65 for nozzle bag, 64 for capstan, 63; Putting into the nozzle bag to foundry alloy during work seals; Feed argon gas by forcing pipe,, use electromagnetic induction heating induction coil 66 energisings; By the pallet that moves the nozzle bag 67 adjustment roll gap is the distance of nozzle and chill roll; When temperature reached, pulling stopper rod 69 spray bands were adjusted air pressure along with molten steel descends.
Fig. 6 is a kind of amorphous pressure pocket builder of domestic research and development.This machine is similar with the pressure spray band machine of Russia design on the principle, and the nozzle bag of this machine adopts graphite and carborundum two bodies formation.Because the molten steel contact site is made up of graphite, molten steel is bigger to the corrosion of graphite, in molten steel, can pollute molten steel and a large amount of carbon is molten, influences the magnetic property of amorphous ribbon.Since in the nozzle bag, adopt eddy-current heating remelting foundry alloy, thus also exist roll gap gap problem of unstable, at present should technology prematurity still.
Summary of the invention
The present invention is directed to the deficiency of above-mentioned prior art, the liquid level pressure amorphous pocket builders such as plunger type that a kind of output is high, quality is good, easy to operate are provided.
Technical scheme of the present invention is: liquid level pressure amorphous pocket builders such as plunger type; Comprise non-vacuum induction furnace 71, pressure sensor 72, flume 73, level gauging appearance 74, nozzle bag 75, heating globar 76, chill roll 77, plunger 78, plunger elevating lever 79, magnetic scale 710, lifting motor 711, operating desk 712; It is characterized in that: plunger 78 and level gauging appearance 74 are set at nozzle bag 75; Plunger 78 moves up and down with the liquid surface lifting in the nozzle bag 75; Plunger 78 is connected with plunger elevating lever 79, on plunger elevating lever 79, is provided with magnetic scale 710, lifting motor 711 control plunger elevating levers 79.
Said plunger elevating lever 79 is control or control automatically manually.
Liquid level 400mm to 450mm in the said nozzle bag 75.
Said nozzle bag 75 adopts globar 76 heating.
Said plunger 78 is the moderate wooden stick of density, fully the anti-coating more than or equal to 1700 degrees centigrade of oven dry back surfaces coated.
Said non-vacuum induction furnace 71 can be used two simultaneously for replenishing molten steel in the nozzle bag 75.
Said nozzle bag 75 ejection pressure are 0.3-0.4kg/cm 2
Advantageous effect of the present invention is: liquid level pressure amorphous pocket builders such as this plunger type do not adopt the pressure of gas pressure control spray band, but the liquid level of the displacement of stopper rod maintenance molten steel is realized equal pressure spray band.The present invention is the continuous molten steel in the postinjector bag in the process of spray band; Even can use two non-vacuum induction furnaces in the nozzle bag, to replenish molten steel respectively; So spray band amount once can be very big, generally can reach more than the 400kg, still unprecedented at home at present.The equal pressure manually-operated is convenient in the present invention; Because of the liquid level naked eyes of nozzle bag can be observed; Thereby be convenient to regulate at any time the amount of feeding maintenance liquid level of stopper rod; Other gas pressure spray band machine nozzle bags seal, and there is indeterminable problem in liquid level, keep the error of spray band constant pressure also bigger so regulate pressure follow-up.The present invention is sprayed the nozzle bag of band machine with the heating of charcoal silicon rod, and the area of plane of nozzle Baogang liquid is less, is prone to keep the uniformity of temperature, compares with eddy-current heating with other gas pressure spray band machine nozzle bag, and the spacing of nozzle and chill roll is stable.Spray band machine design stopper rod of the present invention is regulated the molten steel amount greater than 22kg, if the molten steel of spray 200kg, the number of times that turns over the additional molten steel of stove is 7-8 time, and the required stove that turns over of common spray band machine spray 200kg replenishes number of times about 30 times.Because it is bigger that molten steel exposes airborne area, molten steel oxidation aggravation.
Description of drawings
Fig. 1 is single rod method (single bag) structural representation
Fig. 2 is single rod method (three guarantees) structural representation
Fig. 3 is Russian non-crystaline amorphous metal pressure spray band machine
Fig. 4 is German non-crystaline amorphous metal pressure spray band machine
Fig. 5 is domestic electric resistor heating type pressure spray band machine
Fig. 6 is domestic induction heating type non-crystaline amorphous metal pressure spray band machine
Fig. 7 is the structural representation of liquid level pressure amorphous pocket builders such as plunger type of the present invention
Accompanying drawing indicates:
11 is that non-vacuum induction furnace, 12 is that nozzle bag, 13 is that induction coil, 14 is that molten steel, 15 is that direction of rotation, 16 is non-crystaline amorphous metal.
21 is that non-vacuum induction furnace, 22 is that tundish, 23 is that molten steel, 24 is that nozzle bag, 25 is the globar heating resistor.
31 are chill roll for heating rod, 37 for stopper rod, 36 for induction coil, 35 for the crucible of refractory material system, 34 for the gas interface, 33 of exerting pressure for peep hole, 32.
41 is that chill roll, 42 is that quartzy nozzle, 43 is that bellows, 44 is that vacuum lead, 45 is that quartz ampoule, 46 is that pressure pipeline, 47 is that eddy-current heating induction coil, 48 is that vacuum drying oven body of heater, 49 is that crucible, 410 is a molten steel.
51 is that burning steel mouth, 55 is that globar, 56 is that nozzle bag, 57 is that the mouth of a river, 59 is that nozzle, 511 is mobile stopper rod.
61 is that peep hole, 62 is chill roll for stopper rod, 610 for nozzle, 69 for the pallets that move the nozzle bag, 68 for induction coil, 67 for nozzle bag graphite part, 66 for the carbon silicon of nozzle bag part, 65 for nozzle bag, 64 for capstan, 63.
71 be non-vacuum induction furnace, 72 for pressure sensor, 73 for flume, 74 for the level gauging appearance, 75 for the nozzle bag, 76 for the heating globar, 77 for chill roll, 78 for plunger, 79 for the plunger elevating lever, 710 for magnetic scale, 711 for lifting motor, 712 for operating desk.
The specific embodiment
Below in conjunction with accompanying drawing the present invention is done further explanation.
Fig. 7 is a kind of specific embodiment of the present invention.Liquid level pressure amorphous pocket builders such as plunger type; Comprise non-vacuum induction furnace 71, pressure sensor 72, flume 73, level gauging appearance 74, nozzle bag 75, heating globar 76, chill roll 77, plunger 78, plunger elevating lever 79, magnetic scale 710, lifting motor 711, operating desk 712; It is characterized in that: plunger 78 and level gauging appearance 74 are set at nozzle bag 75; Plunger 78 moves up and down with the liquid surface lifting in the nozzle bag 75; Plunger 78 is connected with plunger elevating lever 79, on plunger elevating lever 79, is provided with magnetic scale 710, lifting motor 711 control plunger elevating levers 79.
Said plunger elevating lever 79 is control or control automatically manually.
Liquid level 400mm to 450mm in the said nozzle bag 75.
Said nozzle bag 75 adopts globar 76 heating.
Said plunger 78 is the moderate wooden stick of density, fully the anti-coating more than or equal to 1700 degrees centigrade of oven dry back surfaces coated.
Said non-vacuum induction furnace 71 can be used two simultaneously for replenishing molten steel in the nozzle bag 5.
Said nozzle bag 75 ejection pressure are 0.3-0.4kg/cm 2
The specific embodiment of the invention one:
Device parameter
Non-vacuum induction furnace: charge weight 200kg
Nozzle bag parameter: volume 12x16x45cm material: carborundum
Nozzle material: BN
Stopper rod: material is with moderate 200 degrees centigrade of 48 hours the bakings of wooden stick warp of density, and surfaces coated silicon melten gel+zirconium English powder is again through 200 degrees centigrade of bakings in 48 hours, size: φ 11x50cm
Chill roll material: CrZrCu size: φ 60x20cm
Cooling water pressure: 1.8MPa
The spray band trade mark: 1K107
Cu1.3Si7.72B1.99Nb5.5Fe is surplus for the foundry alloy composition
The design spray mark cun wide 20mm of thickness 25 μ m
The jet size mouth stitches the long 20mm of wide 0.5mm
Chill roll speed 32m/s
Operation: manually
Check: hydraulic pressure, chill roll rotating speed, stove action intermediate frequency power supply is turned in the stopper rod displacement
Shove charge: with the 200kg foundry alloy less than 8cm 3Packaged crucible of going into non-vacuum induction furnace in, logical cooling water send electric 50kw, 100kw, 180kw
Induction furnace send electricity will spray band machine nozzle bag after 20 minutes and send
When the nozzle color is dark red, forward the nozzle bag on the chill roll to, the parallel axes of adjustment nozzle seam and roller, the mouth plane is parallel with roller.The adjusting roll gap is 0.2mm.
Rotate stopper rod, the adjustment stopper rod goes up and down, and affirmation is errorless to go back to original position with stopper rod nozzle bag, and with heat-preservation cotton temperature raising on the nozzle pocket.
When molten steel temperature reaches 1380 ℃, nozzle bag stopper rod is rotate in place, aim at and open band tuyere and flume.
Starting the chill roll water flowing ventilates
When furnace temperature reaches 1400 ℃, turning over the stove stopper rod turns up full blast a little
When the nozzle liquid level rises to 41cm, stop to annotate steel, make stopper rod contact molten steel face, at this moment constantly measure tape thickness; Regulate roll gap simultaneously; When tape thickness reaches fixedly roll gap of 25 μ m, regulate the liquid level that stopper rod is followed the tracks of the nozzle bag simultaneously, when stopper rod decline 33cm; Beginning is annotated steel for the second time, promotes stopper rod simultaneously.According to annotating the steel speed controlling stopper rod rate of climb., stopper rod stops to annotate steel when rising to 41cm.Carry out with the spray band, the stopper rod that descends again, reciprocal like this (about 6 times) begin little lifting nozzle bag when the decline stopper rod can not guarantee liquid level.Measure tape thickness, make tape thickness between 30-31 μ m, when nozzle bag liquid level descends less than 20cm, promote stopper rod moving nozzle inclusion, the rotary nozzle bag is gone into surplus flow in the graphite crucible, breaks off the chill roll power supply and opens band wind, stops intermediate frequency power supply.
Take-up, tape thickness: 25 μ m, the 2 μ m that fluctuate, wide 21mm, meter 170kg, 33-31 μ m counts 19kg, product 10kg, the surface is good.
The specific embodiment of the invention two:
The spray band trade mark: 2605S-2
The foundry alloy composition: Si5.14B2.65Fe is surplus
Density: 7.18g/cm 3
Design spray mark is very little: the wide 100mm of 25 μ m
Jet size: the long 100mm of the wide 0.5mm of nozzle
Chill roll speed: 32m/s
Operation: manually
Associative operation is with spray 1K107
Relevant difference:
The cast temperature is 1380 ℃
Nozzle liquid surface height controlling 42cm
More than be that specific embodiment structure provided by the present invention has been carried out detailed introduction; Present embodiment just is used for helping to understand method for designing of the present invention and core concept; Simultaneously; To those skilled in the art, it is essential identical that foundation thought of the present invention designs, all within protection domain of the present invention.In sum, this description can not be interpreted as limitation of the present invention.

Claims (7)

1. liquid level pressure amorphous pocket builder such as plunger type; Comprise non-vacuum induction furnace (1), pressure sensor (2), flume (3), level gauging appearance (4), nozzle bag (5), heating globar (6), chill roll (7), plunger (8), plunger elevating lever (9), magnetic scale (10), lifting motor (11), operating desk (12); It is characterized in that: plunger (8) and level gauging appearance (4) are set at nozzle bag (5); Plunger (8) moves up and down with the liquid surface lifting in the nozzle bag (5); Plunger (8) is connected with plunger elevating lever (9), on plunger elevating lever (9), is provided with magnetic scale (10), lifting motor (11) control plunger elevating lever (9).
2. liquid level pressure amorphous pocket builder such as plunger type according to claim 1 is characterized in that: said plunger elevating lever (9) manually control with or control automatically.
3. liquid level pressure amorphous pocket builder such as plunger type according to claim 1 is characterized in that: the interior liquid level 400mm to 450mm of said nozzle bag (5).
4. liquid level pressure amorphous pocket builder such as plunger type according to claim 1, it is characterized in that: said nozzle bag (5) adopts globar (6) heating.
5. liquid level pressure amorphous pocket builder such as plunger type according to claim 1, it is characterized in that: said plunger (8) is the moderate wooden stick of density, fully the anti-coating more than or equal to 1700 degrees centigrade of oven dry back surfaces coated.
6. liquid level pressure amorphous pocket builder such as plunger type according to claim 1 is characterized in that: said non-vacuum induction furnace (1) be two simultaneously for replenishing molten steel in the nozzle bag (5).
7. liquid level pressure amorphous pocket builder such as plunger type according to claim 1, it is characterized in that: said nozzle bag (5) ejection pressure is 0.3-0.4kg/cm 2
CN2011103698825A 2011-11-21 2011-11-21 Plunger type equal-liquid-level pressure amorphous strip maker Pending CN102389952A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102836977A (en) * 2012-09-27 2012-12-26 孙新亚 Manufacturing method of amorphous ribbon
CN103357827A (en) * 2013-07-10 2013-10-23 浙江正耀环保科技有限公司 Three-bag amorphous strip spraying machine
CN103406510A (en) * 2013-08-21 2013-11-27 青岛云路新能源科技有限公司 Nozzle pack for amorphous belt manufacturing
CN103611895A (en) * 2013-11-25 2014-03-05 青岛云路新能源科技有限公司 Strip spraying device
CN104070147A (en) * 2014-04-22 2014-10-01 安徽众恒复合材料科技有限公司 Pressure spray bag for use in pressured making of amorphous strip and amorphous strip making method
CN104745914A (en) * 2015-04-15 2015-07-01 南通华禄新材料科技有限公司 Preparation method of nanogold strip
CN107377906A (en) * 2017-08-04 2017-11-24 芜湖君华材料有限公司 A kind of closed amorphous band topping mechanism for being easy to coutroi velocity
CN108580828A (en) * 2018-06-10 2018-09-28 安徽迪维乐普非晶器材有限公司 A kind of pocket builder automatic operation control system
CN109248995A (en) * 2018-11-29 2019-01-22 横店集团东磁股份有限公司 A kind of preparation method of spray belt bag and nanocrystalline strip
CN116984575A (en) * 2023-09-26 2023-11-03 唐山非晶科技有限公司 Bearing mechanism for amorphous strip production

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102836977A (en) * 2012-09-27 2012-12-26 孙新亚 Manufacturing method of amorphous ribbon
CN103357827A (en) * 2013-07-10 2013-10-23 浙江正耀环保科技有限公司 Three-bag amorphous strip spraying machine
CN103406510A (en) * 2013-08-21 2013-11-27 青岛云路新能源科技有限公司 Nozzle pack for amorphous belt manufacturing
CN103611895B (en) * 2013-11-25 2015-10-07 青岛云路新能源科技有限公司 The spray device of band
CN103611895A (en) * 2013-11-25 2014-03-05 青岛云路新能源科技有限公司 Strip spraying device
CN104070147A (en) * 2014-04-22 2014-10-01 安徽众恒复合材料科技有限公司 Pressure spray bag for use in pressured making of amorphous strip and amorphous strip making method
CN104745914A (en) * 2015-04-15 2015-07-01 南通华禄新材料科技有限公司 Preparation method of nanogold strip
CN107377906A (en) * 2017-08-04 2017-11-24 芜湖君华材料有限公司 A kind of closed amorphous band topping mechanism for being easy to coutroi velocity
CN107377906B (en) * 2017-08-04 2019-08-23 安徽智磁新材料科技有限公司 A kind of closed amorphous band topping mechanism convenient for coutroi velocity
CN108580828A (en) * 2018-06-10 2018-09-28 安徽迪维乐普非晶器材有限公司 A kind of pocket builder automatic operation control system
CN109248995A (en) * 2018-11-29 2019-01-22 横店集团东磁股份有限公司 A kind of preparation method of spray belt bag and nanocrystalline strip
CN116984575A (en) * 2023-09-26 2023-11-03 唐山非晶科技有限公司 Bearing mechanism for amorphous strip production
CN116984575B (en) * 2023-09-26 2023-12-08 唐山非晶科技有限公司 Bearing mechanism for amorphous strip production

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Application publication date: 20120328