CN102381735A - Semi-dry process air humidifying and dehumidifying type seawater desalinating system and method - Google Patents
Semi-dry process air humidifying and dehumidifying type seawater desalinating system and method Download PDFInfo
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- CN102381735A CN102381735A CN201110304566XA CN201110304566A CN102381735A CN 102381735 A CN102381735 A CN 102381735A CN 201110304566X A CN201110304566X A CN 201110304566XA CN 201110304566 A CN201110304566 A CN 201110304566A CN 102381735 A CN102381735 A CN 102381735A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/138—Water desalination using renewable energy
- Y02A20/142—Solar thermal; Photovoltaics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/208—Off-grid powered water treatment
- Y02A20/212—Solar-powered wastewater sewage treatment, e.g. spray evaporation
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Abstract
The invention discloses a semi-dry process air humidifying and dehumidifying type seawater desalinating system and method utilizing solar energy, and belongs to the technical field of seawater desalination. The system comprises a solar air heat collector, a jetting bed evaporator, a bag dust remover, a horizontal-tube falling-film condenser and a steam-water separator, wherein the output end of the solar air heat collector is connected with a bottom spray nozzle of the jetting bed evaporator; a seawater input source is connected with a top seawater inlet guide pipe of the jetting bed evaporator; the output end of the jetting bed evaporator is sequentially connected with the bag dust remover, the horizontal-tube falling-film condenser and the steam-water separator; and the output end of the steam-water separator is used for outputting freshwater. The system runs under normal pressure without need of a vacuum pump; the jetting bed evaporator is used in the system to enhance air moisture absorption process and improve the seawater evaporation efficiency; the horizontal-tube falling-film condenser is used to improve the heat exchange efficiency of the condenser; and a semi-dry process evaporation flow is adopted, thus a concentrated saline storage or circulation device is not needed and salt particles can be recovered by the bag dust remover.
Description
Technical field
The present invention relates to a kind of semidrying gas humidification desiccant seawater desalination system and method for utilizing sun power, belong to field of sea water desalting technology.
Background technology
Present industrial applications desalination technology the most widely comprises MSF method, multiple-effect evaporation method and reverse osmosis method.These methods all will consume a large amount of fuel or electric power resource.Utilize renewable energy source-sun power to carry out sea water desaltination, the energy and the environmental problem that can avoid a large amount of fuel and electric power resource consumption to bring.But sun power is a kind of low-quality heat energy, if do not adopt complicated beam condensing unit, sun power only can be heated to certain temperature with working medium.When being used for the straight run distillation seawater, need many vacuum pumps of configuration could accomplish still-process.The humidifying-dehumidifying desalination technology utilizes gas saturated humidity difference to carry out sea water desaltination, can effectively utilize inferior solar thermal energy.
Retrieval through to prior art is found; Title " spraying propulsion ventilation evaporation-condensation formula fresh-water generator " (number of patent application is CN00109939.6), " utilizing the method for desalting seawater of air saturation psychrometric difference " (number of patent application is CN03144279.X), " spray evaporation air moistening desiccant solar energy sea water desalination apparatus " (number of patent application is CN201010509740.X) etc.; These patents are all carried out sea water desaltination based on the air humidification-process of drying; Art recognized, but all have evaporation of seawater or condensation efficiency problem of lower.Improve heat transfer, mass transfer coefficient between air and seawater, and the evaporation area that increases seawater is to improve the key of vaporization efficiency, and the thermal resistance that reduces between wet air and low-temperature receiver is to improve the key of water vapor condensation efficient.In addition, more than technology some adopts extraneous recirculated water to make low-temperature receiver in the water vapor condensation process, cause heat waste, and some is in order to utilize this part heat of condensation, increased the several separate interchanger and made system too complicated.Seawater all can not evaporate fully in the vaporizer of above technology, all is provided with strong brine storer or circulation line, the waste that this causes strong brine to carry heat on the one hand, and pipeline subjects to corrosion on the other hand.The part technology is used the nozzle atomization seawater in order to improve the evaporation of seawater area, but considers the corrodibility of seawater, and nozzle damages easily.
Summary of the invention
To the defective that exists in the above-mentioned prior art; The objective of the invention is to propose a kind of semidrying gas humidification desiccant seawater desalination system and method for utilizing sun power; This system can move under normal pressure, and the needing no vacuum pump need not the high density seawater and stores or circulation device; And can be according to solar energy air heat collector temperature and both air flow modulation evaporator outlet wet air temperature and generation fresh water amount, recyclable salt grain.
In order to realize the foregoing invention purpose, system of the present invention realizes through following technical scheme:
Semidrying gas humidification desiccant seawater desalination system; Comprise solar energy air heat collector, spray movable bed vaporizer, sack cleaner, horizontal tube falling film condensing surface and steam separator; Spray movable bed vaporizer comprises housing, air nozzle, sea intake conduit, bed material particle and wet air delivery channel; Wherein, said air nozzle is fixedly set in the intravital bottom of shell, and its input terminus is connected with the output terminal of solar energy air heat collector; Said sea intake conduit is arranged at the intravital top of shell, and is connected with the seawater input source; Said bed material particle is positioned over bottom in the housing; Said wet air delivery channel is arranged at housing top, and its output terminal connects sack cleaner, horizontal tube falling film condensing surface and steam separator successively; The output terminal output fresh water of said steam separator, its gas output end connects induced draft fan in order to air-flow power to be provided.
Wherein, spray movable bed evaporator outlet end connects sack cleaner in order to collect the solid granulates in the wet air, and major part is the salt grain; Horizontal tube falling film condensing surface output terminal connects gas-liquid separator in order to separate fresh.
Described spray movable bed evaporator shell adopts stainless material to process, and the outside is wrapped up by the asbestos thermal insulation layer.Spray movable bed vaporizer is chosen the quartz sand particle of particle diameter about 350 μ m and is made the bed material, and particle is separated into drop by the warm air fluidisation with the import seawater, and drop is attached on its surface evaporates.Particle has enlarged the contact area of air and seawater to the dispersion of seawater and the effect of sticking; And improved the residence time of sea water drops in spray movable bed vaporizer; Simultaneously particle spouted fluidized in bed causes heat transfer, mass transfer coefficient between gas-liquid to be greatly improved, thereby improved evaporation of seawater efficient.Therefore seawater evaporation fully in spray movable bed vaporizer need not to be provided with high density seawater storing unit.
Described horizontal tube falling film condensing surface shell side leads to wet air, and tube side is divided into two independent sectors up and down, top connecting the sea water; Seawater is set into and out of port; The lower section blowing air is provided with air into and out of port, wherein; Sea intake is connected with the seawater storage tank, and seawer outlet is connected with spray movable bed vaporizer seawater conduit; Gas feed is connected with gas blower, and pneumatic outlet is connected with solar energy air heat collector.Wet air skims over the condensing surface shell side, and in transverse tube outer wall condensation heat release, this horizontal tube falling film condensing mode effectively reduces the inside and outside thermal-conduction resistance of pipe, increases the outer convection transfer rate of pipe, makes that the heat release condensation in the condensing surface is very efficient.
Method of the present invention is to carry out work in the following manner: the high temperature air from solar energy air heat collector gets into spray movable bed vaporizer through the air nozzle, and the fluidized bed material particle also evaporates seawater; Bed material particles dispersed after seawater is fluidized is a drop; Part is attached on the evaporation of bed material particle surface; Part direct evaporation, the particle strenuous exercise in bed has strengthened the evaporation area and the vaporization efficiency of seawater, and has improved the residence time of seawater in vaporizer; Air after the moisture absorption at first gets into sack cleaner and removes the grain that desalts; Get into the horizontal tube falling film condenser condenses then; This horizontal tube falling film condensing mode effectively reduces the inside and outside thermal-conduction resistance of pipe, increases the outer convection transfer rate of pipe, makes the heat release condensation process very efficient; The heat of condensation of water vapor is used for preheating gas and seawater simultaneously, can not cause the waste of heat.
The present invention utilizes spray movable bed vaporizer and horizontal tube falling film condensing surface that sufficient reinforcement has been carried out in air moisture absorption and dehumidification process.Adopt the semidry process flow process, seawater is evaporation fully in vaporizer, has avoided because the corrosion of pipeline, water pump and storage receptacle that the strong brine circulation causes.And the use of sack cleaner avoided in the wet air salt grain to the wearing and tearing and the corrosion of horizontal tube falling film condensing surface, and recyclable salt grain.
Description of drawings
Fig. 1 is the structure iron of semidrying gas humidification desiccant seawater desalination system of the present invention.
Embodiment
Below in conjunction with accompanying drawing specific embodiment of the present invention is elaborated.Present embodiment provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment being to implement under the prerequisite with technical scheme of the present invention.
The semidrying gas humidification desiccant seawater desalination system that the present invention proposes, as shown in Figure 1.Present embodiment comprises: solar energy air heat collector 1, spray movable bed vaporizer 2, sack cleaner 3, horizontal tube falling film condensing surface 4 and steam separator 5; Wherein: the output terminal of solar energy air heat collector 1 is connected with spray movable bed vaporizer 2 bottom nozzles; The seawater input source is connected with spray movable bed vaporizer 2 top sea intake conduits, and the output terminal of spray movable bed vaporizer 2 connects sack cleaner 3, horizontal tube falling film condensing surface 4 and steam separator 5 successively.The output terminal output fresh water of steam separator 5.
Solar energy air heat collector 1 is for solar collecting device and heat energy is provided.
Spray movable bed vaporizer 2 comprises: housing 11 and bed material 12.Housing 11 adopts stainless material to process, and the outside is wrapped up by the asbestos thermal insulation layer.Choose the quartz sand particle of medium particle diameter (about 350 μ m) and make bed material 12, bed material 12 places housing 11 bottoms.Bed material 12 is separated into drop by the warm air fluidisation with the import seawater, and drop is attached on its surface evaporates.
On the sea intake conduit at spray movable bed vaporizer 2 tops flow director 6 is set, in order to control import seawater amount.
Spray movable bed vaporizer 2 exit end connect sack cleaner 3, and in order to collect the solid granulates in the wet air, major part is the salt grain.
Horizontal tube falling film condensing surface 4 shell sides lead to wet air, and tube side is divided into two independent sectors up and down, and the top connecting the sea water is provided with seawater into and out of port, and the lower section blowing air is provided with air into and out of port.Sea intake is connected with sea-water pump 7, and seawer outlet is connected with spray movable bed vaporizer 2 sea intake conduits.Gas feed is connected with gas blower 8, and pneumatic outlet is connected with solar energy air heat collector 1.Wet air skims over the condensing surface shell side, in transverse tube outer wall condensation heat release.
Horizontal tube falling film condensing surface 4 output terminals connect gas-liquid separator 5 in order to divided gas flow and fresh water, and fresh water is stored in the fresh water torage tank 10, and gas is drawn by induced draft fan 9.
Present embodiment carries out work in the following manner: the high temperature air from solar energy air heat collector 1 gets into spray movable bed vaporizer 2 through nozzle, and fluidized bed material also evaporates seawater.Bed material after seawater is fluidized is separated into drop, and part is attached on the surface evaporation of bed material, part direct evaporation.Air after the moisture absorption at first gets into sack cleaner 3 and removes the grain that desalts, and gets into 4 condensations of horizontal tube falling film condensing surface then.This horizontal tube falling film condensing mode effectively reduces the inside and outside thermal-conduction resistance of pipe, increases the outer convection transfer rate of pipe, makes the heat release condensation process very efficient.The heat of condensation of water vapor is used for preheating gas and seawater simultaneously, can not cause the waste of heat.
Claims (6)
1. semidrying gas humidification desiccant seawater desalination system; Comprise solar energy air heat collector, spray movable bed vaporizer, sack cleaner, horizontal tube falling film condensing surface and steam separator; It is characterized in that: spray movable bed vaporizer comprises housing, air nozzle, sea intake conduit, bed material particle and wet air delivery channel; Wherein, said air nozzle is fixedly set in the intravital bottom of shell, and its input terminus is connected with the output terminal of solar energy air heat collector; Said sea intake conduit is arranged at the intravital top of shell, and is connected with the seawater input source; Said bed material particle is positioned over bottom in the housing; Said wet air delivery channel is arranged at housing top, and its output terminal connects sack cleaner, horizontal tube falling film condensing surface and steam separator successively; The output terminal output fresh water of said steam separator, its gas output end connects induced draft fan.
2. semidrying gas humidification desiccant seawater desalination system according to claim 1 is characterized in that, the housing of said spray movable bed vaporizer adopts stainless material to process, and its outside is wrapped up by the asbestos thermal insulation layer.
3. semidrying gas humidification desiccant seawater desalination system according to claim 1 is characterized in that, the bed material particle of said spray movable bed vaporizer is selected the quartz sand particle of the about 350 μ m of particle diameter for use.
4. semidrying gas humidification desiccant seawater desalination system according to claim 1 is characterized in that, on the sea intake conduit of said spray movable bed vaporizer flow director is set, in order to control import seawater amount.
5. semidrying gas humidification desiccant seawater desalination system according to claim 1; It is characterized in that; Said horizontal tube falling film condensing surface shell side leads to wet air, and its tube side is divided into two independent sectors up and down: the top connecting the sea water is provided with seawater into and out of port; Said sea intake is connected with the seawater storage tank, and said seawer outlet is connected with the sea intake conduit of spray movable bed vaporizer; The lower section blowing air is provided with air into and out of port, and said air is connected with gas blower, and said air is connected with solar energy air heat collector.
6. utilize the method for semidrying gas humidification desiccant seawater desalination system as claimed in claim 1; It is characterized in that; Said method is carried out work in the following manner: the high temperature air from solar energy air heat collector gets into spray movable bed vaporizer through the air nozzle, and the fluidized bed material particle also evaporates seawater; Bed material particles dispersed after seawater is fluidized is a drop, and part is attached on the evaporation of bed material particle surface, part direct evaporation; Air after the moisture absorption at first gets into sack cleaner and removes the salt grain in the wet air, gets into the horizontal tube falling film condenser condenses then, and the heat of condensation of water vapor is used for preheating gas and seawater simultaneously.
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CN201110304566XA CN102381735B (en) | 2011-10-10 | 2011-10-10 | Semi-dry process air humidifying and dehumidifying type seawater desalinating system and method |
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CN201110304566XA CN102381735B (en) | 2011-10-10 | 2011-10-10 | Semi-dry process air humidifying and dehumidifying type seawater desalinating system and method |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102910696A (en) * | 2012-11-26 | 2013-02-06 | 山东科院天力节能工程有限公司 | Solar seawater desalination device |
CN104114250A (en) * | 2012-04-25 | 2014-10-22 | 盐场科技有限公司 | Modular humidification-dehumidification apparatus for concentrating solutions |
CN105621509A (en) * | 2016-03-07 | 2016-06-01 | 清华大学 | Humidification and dehumidification type water purification device for evaporation enhancement of fluidized bed |
CN106927528A (en) * | 2017-04-12 | 2017-07-07 | 南京师范大学 | A kind of air wetting dehumidification type desulfurizing waste water processing device of utilization solar energy |
CN107328254A (en) * | 2016-04-29 | 2017-11-07 | 江苏傲伦达科技实业股份有限公司 | A kind of new and effective condenser |
CN109721122A (en) * | 2019-01-18 | 2019-05-07 | 湖南铁道职业技术学院 | A kind of small-sized solar absorption refrigeration production water installations and production water method of freezing |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4341601A (en) * | 1980-02-20 | 1982-07-27 | E. I. Du Pont De Nemours And Company | Water evaporation process |
CN1597540A (en) * | 2003-09-16 | 2005-03-23 | 程方 | Sea water desalination method using air saturation humidity difference |
CN201052976Y (en) * | 2007-04-24 | 2008-04-30 | 华南理工大学 | Solar energy seawater desalting device with cross-pipe falling-film evaporator and cross-pipe type surface-cooling equipment |
CN101186358A (en) * | 2007-12-17 | 2008-05-28 | 何宗彦 | Sea water desalination and poor water purification device and method |
CN201626849U (en) * | 2009-12-30 | 2010-11-10 | 山东山大能源环境有限公司 | Horizontal tube falling film evaporation device utilizing solar energy or waste heat |
-
2011
- 2011-10-10 CN CN201110304566XA patent/CN102381735B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4341601A (en) * | 1980-02-20 | 1982-07-27 | E. I. Du Pont De Nemours And Company | Water evaporation process |
CN1597540A (en) * | 2003-09-16 | 2005-03-23 | 程方 | Sea water desalination method using air saturation humidity difference |
CN201052976Y (en) * | 2007-04-24 | 2008-04-30 | 华南理工大学 | Solar energy seawater desalting device with cross-pipe falling-film evaporator and cross-pipe type surface-cooling equipment |
CN101186358A (en) * | 2007-12-17 | 2008-05-28 | 何宗彦 | Sea water desalination and poor water purification device and method |
CN201626849U (en) * | 2009-12-30 | 2010-11-10 | 山东山大能源环境有限公司 | Horizontal tube falling film evaporation device utilizing solar energy or waste heat |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104114250A (en) * | 2012-04-25 | 2014-10-22 | 盐场科技有限公司 | Modular humidification-dehumidification apparatus for concentrating solutions |
US9259667B2 (en) | 2012-04-25 | 2016-02-16 | Saltworks Technologies Inc. | Modular humidification-dehumidification apparatus for concentrating solutions |
CN104114250B (en) * | 2012-04-25 | 2016-08-24 | 苏特沃克技术有限公司 | For concentrating the modularization humidifying-dehumidifying device of solution |
CN102910696A (en) * | 2012-11-26 | 2013-02-06 | 山东科院天力节能工程有限公司 | Solar seawater desalination device |
CN105621509A (en) * | 2016-03-07 | 2016-06-01 | 清华大学 | Humidification and dehumidification type water purification device for evaporation enhancement of fluidized bed |
CN105621509B (en) * | 2016-03-07 | 2019-01-15 | 清华大学 | The humidification of fluidized bed enhanced water evaporation removes wet type water purification installation |
CN107328254A (en) * | 2016-04-29 | 2017-11-07 | 江苏傲伦达科技实业股份有限公司 | A kind of new and effective condenser |
CN106927528A (en) * | 2017-04-12 | 2017-07-07 | 南京师范大学 | A kind of air wetting dehumidification type desulfurizing waste water processing device of utilization solar energy |
CN109721122A (en) * | 2019-01-18 | 2019-05-07 | 湖南铁道职业技术学院 | A kind of small-sized solar absorption refrigeration production water installations and production water method of freezing |
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