CN102372341B - Device for generating electrolytic ionized water - Google Patents
Device for generating electrolytic ionized water Download PDFInfo
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- CN102372341B CN102372341B CN201110091726.7A CN201110091726A CN102372341B CN 102372341 B CN102372341 B CN 102372341B CN 201110091726 A CN201110091726 A CN 201110091726A CN 102372341 B CN102372341 B CN 102372341B
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Abstract
The present invention provides a method and a device for generating electrolytic ionized water, thus alkaline electrolytic water of the expected pH value can be generated with high efficiency and low cost. The device is provided with a generating storage tank for storing raw water; an electrolyte storage tank provided with electrolyte storage room capable of storing electrolytic water solution; an ion exchange film; and an anode plate and a cathode plate for clamping the ion exchange film. The electrolyte storage tank can be immersed inside the raw water of the generating storage tank. The ion exchange film can be used for separating the raw water inside the generating storage tank and the electrolytic water solution inside the electrolyte storage room of the electrolyte storage tank. The anode plate can be arranged on the side of the electrolyte storage room through contacting with the electrolytic water solution inside the electrolyte storage room. The cathode plate can be arranged on the side of the raw water through contacting with the raw water inside the generating storage tank. The generating tank and the electrolyte storage tank immersed in the raw water of the generating storage tank are insulated.
Description
Technical field
The present invention relates to electrolytic ionic water (basic ion water, electrolyzed alkaline water) generation method and generating apparatus thereof.
Background technology
The cleaning performance of known electrolytic ionized water is good, is also suitable as tap water, as being discharged from also, can not bring dysgenic rinse water or sweet water to receive much concern to global environment.
As one of electrolytic ion water generating device, there is electrolytic ion water generating device (patent documentation 1).This electrolytic ion water generating device is as illustrated in fig. 3, electrolyzer A is separated into cathode compartment C and the F of anolyte compartment by ion-exchange membrane B, in cathode compartment C, dispose negative plate E, in the F of anolyte compartment, dispose positive plate D, the upper negative pole that connects direct supply G of negative plate E, the upper positive pole that connects direct supply G of positive plate D.By flow rate regulating valve H, from outside to cathode compartment C, supply with continuously former water (for example pure water or tap water), aqueous electrolyte liquid in storage tank I (for example, wet chemical or sodium carbonate water capacity liquid) by recycle pump P, be continuously fed the F of anolyte compartment, by electricity, decompose the potassium ion generating and enter cathode compartment C side through described ion-exchange membrane B, in cathode compartment C, generate electrolyzed alkaline water, the electrolyzed alkaline water of generation is discharged from being located at the outlet pipe arrangement J of cathode compartment C.On the other hand, by the F of anolyte compartment, the aqueous electrolyte liquid of overflow returns to aqueous electrolyte liquid storage tank I from being located at the backflow pipe arrangement K of the F of anolyte compartment.
Patent documentation 1: TOHKEMY 2004-42025 communique
Conventionally, ion-exchange membrane B is as illustrated in fig. 4, at its two sides configuration cancellous spacing piece S made of insulating material, at its outside configuration negative plate E and positive plate D, and from its two outside, be held plate L and keep, to the negative potential T1 being connected with negative plate E, apply the negative potential of direct supply, the positive electrode T2 of pole plate D applies positive potential on the sunny side.The former water being supplied to is by the gap between ion-exchange membrane B, spacing piece S and negative plate E, and aqueous electrolyte liquid is by the gap between ion-exchange membrane B, positive plate D and spacing piece S.
As former water, use in the situation of tap water, owing to containing the impurity that is called as calcium or magnesium in tap water, these impurity adhere to and are solidificated on described ion-exchange membrane B, spacing piece S, negative plate E, gap between them is blocked, former shipwreck is to pass through, water-flowing amount reduces, and because the impact of these solid matters makes to the energising of electrode insufficiently, existence can not obtain the difficult point of the electrolytic ionic water of desired pH value.In addition, oxygen occurs in generative process in anode side, it becomes trickle bubble molten being stored in aqueous electrolyte liquid, this bubble flows into narrow gap together with aqueous electrolyte liquid, electricity decomposition is hindered, and electrolytic efficiency reduces, and has the difficult point of the formation efficiency reduction of electrolytic ionic water.In addition, due at cathode side, hydrogen becomes trickle bubble, and occurs in the gap of ion-exchange membrane B, negative plate E and spacing piece S, so electricity decomposes, is hindered, and electrolytic efficiency reduces.
Replace tap water to use in the situation of pure water, owing to must making tap water become the operation of pure water, so exist expend time in, the difficult point of cost.
Summary of the invention
Solution problem of the present invention is to provide a kind of electrolytic ionic water generation method and generating apparatus thereof, can high-level efficiency, generate at low cost the electrolyzed alkaline water of desired pH value.
Electrolytic ionic water generation method of the present invention is, former water is stored in and is generated in storage tank, electrolytic solution storage tank is immersed in the former water generating in storage tank with state of insulation, aqueous electrolyte liquid is stored in electrolytic solution storage tank, to be configured in and generate in storage tank and separate the aqueous electrolyte liquid in the former power and water solution liquid storage tank generating in storage tank by the ion-exchange membrane of negative plate and positive plate clamping, former water in making cathode-side and generating storage tank contacts, positive plate side is contacted with the aqueous electrolyte liquid in electrolytic solution storage tank, the negative pole that connects direct supply on negative plate, the positive pole that connects direct supply on positive plate, and between two electrodes, apply volts DS incoming call and decompose the described former power and water solution matter aqueous solution, by this electricity, decompose the positively charged ion generating in anode side (in electrolytic solution storage tank) and pass described ion-exchange membrane to cathode side (generating in storage tank), in generating storage tank, generate electrolytic ionic water, and take out from generating storage tank generating the electrolytic ionic water generating in storage tank, afterwards, to generating in storage tank, store new former water, carrying out described electricity decomposes, can in generating storage tank, repeatedly generate electrolytic ionic water thus.
Electrolytic ion water generating device of the present invention, has: the generation storage tank that can store former water; Electrolytic solution storage tank, has the electrolytic solution locker room that can store aqueous electrolyte liquid; Ion-exchange membrane; Positive plate and the negative plate of clamping ion-exchange membrane.Described electrolytic solution storage tank can be immersed in the former water in described generation storage tank, described ion-exchange membrane can be separated the aqueous electrolyte liquid in the electrolytic solution locker room that generates the former power and water solution liquid storage tank in storage tank, described positive plate is configured in electrolytic solution locker room side in the mode that can contact with the aqueous electrolyte liquid in electrolytic solution locker room, described negative plate is configured in former water side in the mode that can contact with the former water in generation storage tank, and described generation storage tank and the electrolytic solution storage tank being immersed in its former water are insulated.
In electrolytic ion water generating device of the present invention, the generation storage tank of described electrolytic ion water generating device and the both sides of electrolytic solution storage tank or a side are insulating material systems, can make to generate storage tank and be immersed in the electrolytic solution storage tank insulation in its former water.
In electrolytic ion water generating device of the present invention, positive plate and the negative plate of the ion-exchange membrane of electrolytic ion water generating device, clamping ion-exchange membrane are arranged on to electrolytic solution storage tank, positive plate is configured in to the inner face side of electrolytic solution storage tank, negative plate is configured in to the exterior side of electrolytic solution storage tank.
In electrolytic ion water generating device of the present invention, adopt the ion-exchange membrane of described electrolytic ion water generating device, positive plate and negative plate assembling all-in-one-piece box part, and can be with respect to the dismounting of electrolytic solution storage tank.
The effect of invention
Electrolytic ionic water generation method of the present invention has effect as described below.
(1) Jiang Yuanshui is stored in and generates in storage tank, and aqueous electrolyte liquid is stored in the electrolytic solution storage tank generating in storage tank, carrying out electricity decomposes, thereby can be only with necessary amount batch type in generating storage tank, generate electrolytic ionic water, in the situation that the concentration of the former water yield in generation storage tank and the aqueous electrolyte liquid in electrolytic solution storage tank is certain, the time that only regulates electricity to decompose just can generate the electrolyzed alkaline water of desired pH.
(2) owing to carrying out electricity under the state at the former power and water solution matter aqueous solution of storage, decompose, so can make the gap between ion-exchange membrane and electrode, situation than the continous way generation method of the former power and water solution matter aqueous solution of continuous supply is wider, the former power and water solution matter aqueous solution can both easily pass through gap, even contain the tap water of calcium or magnesium etc. in former water, be also difficult to adhere to calcium or magnesium on electrode or ion-exchange membrane.Thus, along with the process of electricity resolving time, electric decomposition efficiency can not reduce.In addition, by described gap is broadened, oxygen becomes bubble in anode side and occurs, and hydrogen becomes bubble at cathode side and occurs, because they are from interstitial diffusion, so can be by gas bubble blockage.Thus, the productivity of electrolytic ionic water is compared and is improved with continous way.
(3) owing to being difficult to adhere to calcium or magnesium etc., thus can make regularly cleaning during elongated, safeguard easily, can not interrupt because regularly cleaning makes to generate continually, so the productivity of electrolytic ionic water can not reduce yet.
Electrolytic ion water generating device of the present invention has following effect.
(1) due to have can store former water generation storage tank, can store the electrolytic solution storage tank of aqueous electrolyte liquid and can separate the ion-exchange membrane that generates the former water in storage tank and be immersed in the aqueous electrolyte liquid of the electrolytic solution storage tank in former water, so can be only with necessary amount batch type generate the electrolyzed alkaline water of desired pH.
(2) because Jiang Yuanshui is stored in generation storage tank, aqueous electrolyte liquid is stored in to electrolytic solution storage tank, can generate electrolytic ionic water, so can make the gap of gap, ion-exchange membrane and the positive plate of ion-exchange membrane and negative plate broaden, former water, aqueous electrolyte liquid can easily pass through these gaps, the liquid throughput of time per unit increases, many with the former water of two electrode contacts or total quantitative change of aqueous electrolyte liquid, thereby can compare the electrolyzed alkaline water that generates desired pH with the short period of time with continuous generating mode, the productivity of generation is high.
(3) owing to can making described gap broaden, even so contain calcium or magnesium etc. in former water, calcium or magnesium are also difficult to be attached on electrode or cationic exchange membrane, gap can not be stopped up, can maintain for a long time electric decomposition efficiency, contribute to the raising of the formation efficiency of electrolyzed alkaline water.In addition, even if be attached with calcium or magnesium etc., cleaning or maintenance easily, can easily be removed dirt settling by cleanings such as sour waters.Can make regularly cleaning during elongated, safeguard easily.In situation about making regular check on continually, for inspection makes the generation of electrolyzed alkaline water, stop, because its frequency tails off, productivity can not reduce yet temporarily.And even at the bubble of anode side generation oxygen, at the bubble of cathode side generation hydrogen, these bubbles are also difficult to stop up described gap, thereby are difficult to be blocked by the aqueous electrolyte liquid in described gap, the productivity of electrolytic ionic water is difficult to reduce.
(4) owing to generating electrolytic ionic water with batch type, so if make magnitude of voltage and current value certain, make the concentration of aqueous electrolyte liquid certain, only, by regulating conduction time, just can generate the electrolyzed alkaline water of desired pH value.
(5) because the generation storage tank of described electrolytic ion water generating device and the both sides of electrolytic solution storage tank or a side are insulating material system, so can make reliably to generate storage tank and be immersed in the electrolytic solution storage tank insulation in its former water.
(6) positive plate and the negative plate of the ion-exchange membrane of electrolytic ion water generating device, clamping ion-exchange membrane are arranged on to electrolytic solution storage tank, positive plate is configured in to the inner face side of electrolytic solution storage tank, negative plate is configured in to the exterior side of electrolytic solution storage tank, can changes ion-exchange membrane according to electrolytic solution storage tank.
(7) adopt ion-exchange membrane, positive plate and negative plate assembling all-in-one-piece box part, and can dismounting with respect to electrolytic solution storage tank, easy thereby the replacing of ion-exchange membrane becomes.
Accompanying drawing explanation
Fig. 1 means the explanatory view of an example of electrolytic ion water generating device of the present invention.
Fig. 2 is the details drawing of the ion-exchange membrane portions of Fig. 1.
Fig. 3 means the explanatory view of an example of electrolytic ion water generating device in the past.
Fig. 4 means the explanatory view of an example of the ion-exchange membrane that electrolytic ion water generating device is in the past used.
The explanation of Reference numeral
1 former water 9 top installation portions
2 generate storage tank 10a, 10b holding appliance
3 electrolytic solution storage tank 12 below installation portions
4 electrolytic solution locker room 13 nuts
5 upper surface 14 aqueous electrolyte liquids
6 water shoot A electrolyzers
7 ion-exchange membrane B ion-exchange membranees
8a, 8b holding appliance B1, B2 bolt
C cathode compartment J exports pipe arrangement
D positive plate K pipe arrangement
E negative plate L holding plate
The N1 of F anolyte compartment, N2 nut
G direct supply P recycle pump
G1, G2 gap S spacing piece
H flow rate regulating valve T1, T2 electrode terminal
I storage tank
Embodiment
(embodiment of electrolytic ion water generating device)
An example about the embodiment of electrolytic ion water generating device of the present invention, describes with reference to Fig. 1, Fig. 2.The electrolytic ion water generating device of present embodiment has: the generation storage tank 2 that can store former water 1; With the electrolytic solution storage tank 3 that generates storage tank 2 splits.Ionogen storage tank 3 has the electrolytic solution locker room 4 that can store aqueous electrolyte liquid.Former water 1 can be any one of pure water, tap water, underground water etc.
The box container that described generation storage tank 2 is upper surface open, can be at the former water 1 of storage inside.Generate upper surface 5 openings of storage tank 2.In the bottom surface that generates storage tank 2, be provided with for extracting the water shoot 6 of generated electrolytic ionic water out.At generation storage tank 2 subscripts, be marked with the upper limit of the clear and definite water yield and the margin scale of lower limit (LS).In this situation, can also be provided for reporting the notifying operator (not shown) that the water yield reaches LS.Generation storage tank 2 shown in Fig. 1 is containers of 10 liters, but its capacity can also can be fewer than 10 liters than more than 10 liters.Generating storage tank 2 preferably makes with insulating material.Generating storage tank 2 also can be for confirming the inner transparent material that adopts by naked eyes.
Ionogen storage tank 3 is Z-shaped shapes, and upper end and lateral opening are provided with cationic exchange membrane (ion-exchange membrane) 7 at its side opening oral area.This electrolytic solution storage tank 3 is formed with the electrolytic solution locker room 4 being surrounded by its perisporium and ion-exchange membrane 7.Ionogen storage tank 3 is also preferably made with insulating material.In addition, also can adopt the transparent material of can naked eyes confirming internal state.The shape of the electrolytic solution storage tank 3 shown in Fig. 1 is examples, also can adopt shape in addition.The shape of ionogen storage tank 3, size can change arbitrarily.
Cationic exchange membrane 7 can be used existing product also can use product innovation.Ion-exchange membrane 7 is for separating the parts of the electrolytic solution locker room 4 of described generation storage tank 2 and electrolytic solution storage tank 3, be have water can not by and the exchange membrane of the character can only positively charged ion passed through.Ion-exchange membrane 7 can be used existing product or product innovation, for example, uses " SELEMION " (registered trademark) of Asahi Glass Co., Ltd's system or the exchange membrane of Dupont Kabushiki Kaisha's system etc.
Ion-exchange membrane 7 is as illustrated in fig. 2, at its two sides configuration cancellous spacing piece S made of insulating material, at its outside configuration negative plate E and positive plate D, the upper end of negative plate E and positive plate D is by two holding appliance 8a, 8b clamping, these holding appliances 8a, the top installation portion 9 of 8b and ionogen storage tank 3 is fastened and be fixed on the top installation portion 9 of ionogen storage tank 3 by bolt B 1 and nut N 1, the bottom of negative plate E and positive plate D is by two holding appliance 10a, 10b clamping, these holding appliances 10a, the below installation portion 12 of 10b and ionogen storage tank 3 is fastened and be fixed on the below installation portion 12 of ionogen storage tank 3 by bolt B 2 and nut N 2.The cathode terminal T1 of screw-type is installed on described negative plate E, the positive pole terminal T2 of screw-type is installed at positive plate D.Between described ion-exchange membrane 7 and negative plate E because spacing piece S forms cathode side clearance G 1, between described ion-exchange membrane 7 and positive plate D because spacing piece S forms anode side clearance G 2, in cathode side clearance G 1, former water can pass through, in anode side clearance G 2, aqueous electrolyte liquid can pass through.Holding appliance 8a, 8b, 10a, 10b are ABS resin systems, can be also resins in addition.
The spacing piece S being arranged on the two sides of ion-exchange membrane 7 guarantees described clearance G 1, G2, and negative plate E, positive plate D directly contact with ion-exchange membrane 7, and ion-exchange membrane 7 burns when preventing from switching on.On the spacing piece S shown in Fig. 1, first adopt the net at the 5mm angle of nylon, also can adopt the net of various various mesh sizes made of insulating material.Also can adopt the material except net.
Negative plate E, positive plate D are applicable to the net of employing after the electroplating surface platinum of the wire netting (having through hole) of titanium system, but also can adopt material, structure in addition.Described terminal T1 is fixed bolt welding on negative plate E, and described terminal T2 is fixed bolt welding on positive plate T2, can connecting lead wire by the nut 13 screwing togather with them.
(embodiment of electrolytic ionic water generation method)
Use electrolytic ion water generating device of the present invention to generate electrolytic ionic water, can carry out as follows.
(1) as shown in Figure 1, electrolytic solution storage tank 3 is housed in and generates in storage tank 2.In this situation, electrolytic solution storage tank 3 is used holding appliance (not shown) engaging arbitrarily becoming the upper peripheral edge of storage tank 2 to be fixed.
(2) to generating the former water of the interior supply of storage tank 2 (tap water) 1.Former water 1 stops near reaching and being presented at the LS that generates storage tank 2 tops.Now, the water surface of confirming former water 1 is in the position higher than the upper end of ion-exchange membrane 7.Former water 1 can be used pure water, tap water, other liquid.
(3) to the interior supply wet chemical in electrolytic solution locker room 4 (aqueous electrolyte liquid 14) of electrolytic solution storage tank 3.Now, the water surface of confirming wet chemical is in the high position of the water surface than generating the former water 1 in storage tank 2.In addition, the negative plate E being arranged on electrolytic solution storage tank 3 contacts (being immersed in wherein) with the former water 1 in generating storage tank 2, make negative plate E contact (being immersed in wherein) with former water 1, make positive plate D contact (being immersed in wherein) with the aqueous electrolyte liquid in electrolytic solution storage tank 3.Because described ion-exchange membrane 7 has the intransitable character of water, so even electrolytic solution storage tank 3 is immersed in the former water 1 generating in storage tank 2, aqueous electrolyte liquid 14 and former water 1 can not mix yet.Aqueous electrolyte liquid 14 can be used aqueous solution having dissolved wet chemical, aqueous sodium carbonate, sodium bicarbonate aqueous solution, potassium bicarbonate aqueous solution, sodium bicarbonate alkali salt etc. etc.
(4) by terminal T1, the negative pole of the direct supply of Fig. 1 is connected with negative plate E, by terminal T2, positive pole is connected with positive plate D.
(5) under described connection state, turn on the power switch, between negative plate E, positive plate D, supply with galvanic current.When galvanic current is supplied to, the potassium ion decomposing in the 4 interior generations of electrolytic solution locker room by electricity enters and generates storage tank 2 sides through described ion-exchange membrane 7, and is generating the interior generation electrolytic ionic water of storage tank 2.
(6) water shoot 6 that the electrolytic ionic water generating can generate from being located at storage tank 2 is fetched to outside storage tank or container etc.
(7) the generation storage tank 2 after taking out electrolytic ionic water adds new former water.As required to electrolytic solution storage tank 3 supply aqueous electrolyte liquids 14.Under this state, repeatedly carry out the operation of described (4)～(6), can generate electrolytic ionic water with batch mode.
Industrial applicibility
Electrolytic ion water generating device of the present invention is to be widely used in the Cleaning of Parts after mechanical workout, the agricultural chemicals cleaning of farm crop, indoor cleaning, the cleaning of health etc. as rinse water free from environmental pollution, especially the sewage (pH value becomes acid and mephitic sewage) after the uses such as washing water of the water coolant as various machineries, application canopy (Tu dress Block one ス) is taken into as former water, by direct electricity, decompose, the pH value of this sewage can be reverted to 10～12 left and right.By making the water of reduction return to the former storage tank of cleaning machine, various machinery, application canopy etc., the water in former storage tank is restored to alkalescence more than pH10 from the acidity of pH5.Thus, kill bacterium and the corrupt environmental improvement of storage tank is become to not mephitic cleaning ambient.In addition, the number of times of liquid exchange also reduces, and can significantly cut down trade waste amount.
Claims (3)
1. an electrolytic ion water generating device, is characterized in that, has: the generation storage tank that can store former water; Electrolytic solution storage tank, has electrolytic solution locker room and the ion-exchange membrane that can store aqueous electrolyte liquid;
On the two sides of described ion-exchange membrane, configure the spacing piece of cancellous insulativity,
The negative plate and the positive plate that at the outside of each spacing piece configuration opening, have through hole, described positive plate is configured in electrolytic solution locker room side in the mode that can contact with the aqueous electrolyte liquid in electrolytic solution locker room, described negative plate is configured in former water side in the mode that can contact with the former water in generation storage tank, between described spacing piece and negative plate, form cathode side gap, between spacing piece and positive plate, form anode side gap
The upper end of described negative plate and positive plate is clamped by upside holding appliance and is fixed on electrolytic solution storage tank, and the bottom of negative plate and positive plate is clamped by downside holding appliance and is fixed on electrolytic solution storage tank,
Described electrolytic solution storage tank is immersed in the former water in described generation storage tank with state of insulation, aqueous electrolyte liquid in the electrolytic solution locker room of the former power and water solution liquid storage tank in described generation storage tank is separated by described ion-exchange membrane, described former water can pass through described cathode side gap by the through hole of described negative plate, aqueous electrolyte liquid can be by described anode side gap by the through hole of described positive plate
The negative pole that connects direct supply on described negative plate, the positive pole that connects direct supply on positive plate, and between two electrodes, apply volts DS incoming call and decompose the described former power and water solution matter aqueous solution, the positively charged ion that decomposes the anode side generation in electrolytic solution storage tank by this electricity arrives the cathode side generating in storage tank through described ion-exchange membrane, can in generating storage tank, generate electrolytic ionic water
The electrolytic ionic water generating in described generation storage tank is taken out from generating storage tank, afterwards, to generating in storage tank, stores new former water, carry out described electricity and decompose, can in generating storage tank, repeatedly generate electrolytic ionic water thus,
The ion-exchange membrane of electrolytic ion water generating device, be configured in two outsides of this ion-exchange membrane spacing piece, be configured in two outsides of these spacing pieces and clamp the positive plate of this ion-exchange membrane and spacing piece and negative plate is group all-in-one-piece box part, this box part can be with respect to the dismounting of electrolytic solution storage tank.
2. electrolytic ion water generating device as claimed in claim 1, is characterized in that, the both sides or the side that generate storage tank and electrolytic solution storage tank are insulating material systems, can make to generate storage tank and be immersed in the electrolytic solution storage tank insulation in its former water.
3. electrolytic ion water generating device as claimed in claim 1 or 2, it is characterized in that, electrolytic solution storage tank is Z-shaped shape or Z-shaped shape roughly, its upper opening, box part described in claim 1 or 2 is longitudinally installed in side, bottom, in the time of when electrolytic solution storage tank is immersed in the former water generating in storage tank with state of insulation in, aqueous electrolyte liquid in the electrolytic solution locker room of the former power and water solution liquid storage tank in described generation storage tank is separated by described ion-exchange membrane, described former water can pass through described cathode side gap by the through hole of described negative plate, aqueous electrolyte liquid can be by described anode side gap by the through hole of described positive plate.
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| JP2010-182952 | 2010-08-18 | ||
| JP2010182952A JP4967050B2 (en) | 2010-08-18 | 2010-08-18 | Electrolytic ion water generator |
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| CN102372341B true CN102372341B (en) | 2014-02-26 |
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| WO2016016954A1 (en) | 2014-07-29 | 2016-02-04 | 株式会社Ｅプラン | Electrolytic ion water generation method and electrolytic ion water generation apparatus |
| WO2016114372A1 (en) * | 2015-01-14 | 2016-07-21 | 株式会社 東芝 | Electrolyzed water generating device, electrode unit, and electrolyzed water generating method |
| TWM534190U (en) * | 2016-08-31 | 2016-12-21 | Nanoplus Ltd | Water generating device featuring electrolysis nano ions |
| JP6448043B1 (en) * | 2018-06-26 | 2019-01-09 | 株式会社Ｅプラン | Electrolytic ionic water generation method and electrolytic ionic water generation apparatus |
| CN111035956A (en) * | 2018-10-15 | 2020-04-21 | 内蒙古伊利实业集团股份有限公司 | Plant extract and preparation method thereof |
| CN109455797A (en) * | 2018-12-29 | 2019-03-12 | 东莞职业技术学院 | A kind of non-preparation facilities and preparation method thereof for drinking strong basicity electrolytic ionic water |
| EP4379116A2 (en) | 2019-01-31 | 2024-06-05 | Ecolab USA Inc. | Controlling water levels and detergent concentration in a wash cycle |
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| EP3918127A1 (en) | 2019-01-31 | 2021-12-08 | Ecolab USA Inc. | Controller for a rinse water reuse system and methods of use |
| WO2023286128A1 (en) * | 2021-07-12 | 2023-01-19 | 株式会社Ｅプラン | Virus inactivating agent and virus inactivation method |
| CN117800538A (en) * | 2024-01-24 | 2024-04-02 | 南京洪荒工业智能装备研究院有限公司 | Special water generating device for ship surface treatment and working method thereof |
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