CN102352396B - Method of producing functional starch sugar through wheat starch - Google Patents

Method of producing functional starch sugar through wheat starch Download PDF

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CN102352396B
CN102352396B CN2011102611519A CN201110261151A CN102352396B CN 102352396 B CN102352396 B CN 102352396B CN 2011102611519 A CN2011102611519 A CN 2011102611519A CN 201110261151 A CN201110261151 A CN 201110261151A CN 102352396 B CN102352396 B CN 102352396B
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CN102352396A (en
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董得平
李林海
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Henan Feitian Biotechnology Co ltd
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HENAN FEITIAN AGRICULTURAL DEVELOPMENT Co Ltd
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Abstract

The invention discloses a method of producing functional starch sugar through wheat starch in the application of a technique for producing isomaltose oligosaccharide through wheat B starch. The production method comprises the steps of: size mixing the wheat B starch emulsion to 16-17 Be, regulating the pH of the emulsion to 5.0-6.0, adding 0.5-6 kg/t of high-temperature amylase, saccharifying for 44-48 h, and performing spray liquidation to control the DE value to 12-15; condensing the material in a protein aggregator for 2 h, and separating heat aggregated protein through a double-cone decanter centrifuge, adding fungal enzyme and glycoside enzyme to perform saccharification, adding yeast after the saccharification procedure, biodegrading and distilling to obtain a by-product of alcohol, separating the glucose oligosaccharide through a membrane separating device to further purify the syrup component, and evaporating in quintuple effect to obtain pure isomaltose oligosaccharide syrup. According to the invention, the method comprises the steps of using the double-cone decanter centrifuge to separate the heat aggregated protein, adding enzyme to perform saccharification and glycoside conversion, adding yeast to perform biodegradation to obtain the by-product alcohol, and finally producing the isomaltose oligosaccharide through wheat B starch via such novel techniques as membrane separation, and evaporating to obtain the pure product, so that the production cost is reduced.

Description

A kind of method of producing functional starch sugar through wheat starch
Technical field: the present invention relates to B-Starch from Wheat and produce the method for a kind of producing functional starch sugar through wheat starch of applying in the oligomeric isomaltose technological process.
Background technology: oligomeric isomaltose is a kind of mixing sugar, mainly by maltose, trisaccharide maltose and Fructus Hordei Germinatus eight sugar, formed, unambiguous essence, it is a kind of novel nourishing sweeting agent, having people's harmful intestinal tract bacteria growth and breeding effect of inhibition and special physiological function is arranged, is a kind of base-material of functional foodstuff.Produce both at home and abroad oligomeric isomaltose and mainly adopt double-enzyme method to produce namely take starch as raw material, to adopt amylorrhexis, then utilize the zymins such as oligosaccharidase or Pullulanase carry out refining after saccharification and obtain, therefore need a large amount of zymins of use.And oligomeric isomaltose is the wherein a kind of of functional starch sugar, the starting material of existing production and application mostly are W-Gum or rice, cost is high, the number benefit is lower, and in process of production because filtering separation is purified not, cause product purity lower and produce a large amount of impurity, affect quality product, increased production cost.
Summary of the invention: the present invention has overcome former functional starch sugar and oligomeric isomaltose exist in filtering separation technique drawback, provide and utilized B-Starch from Wheat to be raw material, innovation and application membrane sepn and interpolation yeast carry out the biological degradation novel process, make syrup purifying more, improve the quality of products, the method for a kind of producing functional starch sugar through wheat starch of the application that reduces production costs.The objective of the invention is to be achieved through the following technical solutions: described production method is: (1) with the B-Starch from Wheat breast 16-17Be that sizes mixing, the pH value is 5.0-6.0, adds alpha-amylase 0.5-6kg/ ton butt, carries out steam ejection liquefaction and controls DE value 12-15;
(2) made albumen generation heat-coagulation in 2 hours by the heat-coagulation device, by the crouch albumen of spiral shell heat of dissociation cohesion of bipyramid, be 5.3～6.0 regulating liquefier pH value, temperature 55-58 ℃. add transglucosidase 0.8kg-1.0kg fungal enzyme 0.4kg-0.6kg according to starch butt per ton, saccharification 44-48 hour, the DE value obtains 52-54 raw sugar slurry;
(3) then add yeast, utilize biological degradation that syrup is further purified, first distillation obtains by product alcohol, utilize again the difference of molecular size by membrane sepn, the glucose oligose is separated, then be dried to the oligomeric isomaltose powder through five schools evaporations, obtaining pure oligomeric isomaltose slurry or Direct spraying.
The invention has the beneficial effects as follows: owing to utilizing B-Starch from Wheat to produce functional starch sugar and oligomeric isomaltose, innovation and application the membrane sepn novel process, simple to operate, make syrup be easy to separation and purification, product purity is high, has improved quality product.The interpolation yeast carries out biological degradation and obtains byproduct alcohol, and then evaporation obtains pure product, has reduced production cost, has improved productivity effect.
Embodiment: embodiment 1: described production method is: (1) with the B-Starch from Wheat breast 16-17Be that sizes mixing, the pH value is 5.0-6.0, adds alpha-amylase 0.5-6kg/ ton butt, carries out steam ejection liquefaction and controls DE value 12-15;
(2) made albumen generation heat-coagulation in 2 hours by the heat-coagulation device, by the crouch albumen of spiral shell heat of dissociation cohesion of bipyramid, be 5.3～6.0 regulating liquefier pH value, temperature 55-58 ℃. add transglucosidase 0.8kg-1.0kg fungal enzyme 0.4kg-0.6kg according to starch butt per ton, saccharification 44-48 hour, the DE value obtains 52-54 raw sugar slurry;
(3) then add yeast, utilize biological degradation that syrup is further purified, first distillation obtains by product alcohol, utilize again the difference of molecular size by membrane sepn, the glucose oligose is separated, then be dried to the oligomeric isomaltose powder through five schools evaporations, obtaining pure oligomeric isomaltose slurry or Direct spraying.
Embodiment 2: described production method is: (1) with the B-Starch from Wheat breast 16-17Be that sizes mixing, the pH value is 5.5, adds alpha-amylase 3kg/ ton butt, carries out steam ejection liquefaction and controls DE value 13.5;
(2) made albumen generation heat-coagulation in 2 hours by the heat-coagulation device, by the crouch albumen of spiral shell heat of dissociation cohesion of bipyramid, regulating liquefier pH value is 5.6,56 ℃ of temperature. add transglucosidase 0.9kg, fungal enzyme 0.5kg according to starch butt per ton, saccharification 46 hours, DE value obtain 53 raw sugar slurries;
(3) then add yeast, utilize biological degradation that syrup is further purified, first distillation obtains by product alcohol, utilize the difference of molecular size by membrane sepn, the glucose oligose is separated, then be dried to the oligomeric isomaltose powder through five schools evaporations, obtaining pure oligomeric isomaltose slurry or Direct spraying.
Embodiment 3: describedly carry out after steam ejection liquefaction (1) flash distillation again and make temperature drop to 95 ℃, stopped 2 hours in the protein coacervation device, then by the bipyramid spiral shell that crouch, isolate most of albumen that condenses, be heated to 100 ° of enzymes 30 minutes of going out, obtain feed liquid 1.;
(2) regulate feed liquid 1. the pH value be 5.3～5.5, temperature 55-58 ℃. add transglucosidase 0.8kg-1.0kg fungal enzyme 0.4kg-0.6kg according to starch butt per ton, saccharification 44-48 hour, 2. the DE value obtains 52-54 raw sugar slurry liquid;
(3) 2. to adjust the pH value be 5.5～6.0 to feed liquid, by plate change and and slagging-off after 4. heat exchange of feed liquid, then by plate, change the heat exchange with water and be cooled to 35 ℃, get in fermentor tank, stop 3-5 days, detect component,, by the enzyme injector that the goes out enzyme that goes out, obtain feed liquid 3. after qualified;
(4) 3. feed liquid adjusts pH4.8-4.9 to the protein coacervation iso-electric point in the transfer tank, adds as solidifying agent, then, by adding super-cell, uses filter press to remove residue cohesion albumen, obtains feed liquid 4.;
(5) with feed liquid 4. through quintuple effect evaporator evaporation, utilize boiling point different separate to by product alcohol, obtain in addition feed liquid 5.;
(6) then 5. feed liquid change and 2. heat exchange of feed liquid by plate, changing with steam heat-exchanging and rising to 78-85 ℃ by plate, get in bleacher, by bottom feed, then overflow to another bleacher, keep 30-40 minute in bleacher, and stir, the gac addition is 20-40KG/ ton starch, obtains feed liquid 6.;
(7) 6. feed liquid filters by bag, then by plate, changes and 8. heat exchange of feed liquid, then by plate, changes with the water heat exchange to 45-50 ℃, enters from handing over purifying, and discharging pH4.2-5.9, electricity lead＜100 μ s/cm, obtain feed liquid 7.;
(8) feed liquid, 7. by membrane separation plant, is utilized the difference of molecular size, and glucose, oligose are separated, and 8. grape content≤10%, obtain feed liquid;
(9) 8. the feed liquid after heat exchange enters vaporizer, and be concentrated into solid substance 〉=75% and directly as liquid oligomeric isomaltose slurry, sell, perhaps 60%-65%, then spray-dried tower is dried to moisture≤5%, is packaged into powdery oligomeric isomaltose powder.
Embodiment 4: describedly carry out after steam ejection liquefaction (1) flash distillation again and make temperature drop to 95 ℃, stopped 2 hours in the protein coacervation device, then by the bipyramid spiral shell that crouch, isolate most of albumen that condenses, be heated to 100 ° of enzymes 30 minutes of going out, obtain feed liquid 1.;
(2) regulate feed liquid 1. the pH value be 5.4,57 ℃ of temperature. add transglucosidase 0.9kg, fungal enzyme 0.5kg according to starch butt per ton, saccharification 46 hours, 2. the DE value obtains 53 raw sugar slurry liquids;
(3) 2. to adjust the pH value be 5.8 to feed liquid, by plate change and and slagging-off after 4. heat exchange of feed liquid, then by plate, change the heat exchange with water and be cooled to 35 ℃, get in fermentor tank, stopped 4 days, detect component, qualified afterwards by the enzyme injector that the goes out enzyme that goes out, obtain feed liquid 3.;
(4) 3. feed liquid adjusts pH4.8-4.9 to the protein coacervation iso-electric point in the transfer tank, adds as solidifying agent, then, by adding super-cell, uses filter press to remove residue cohesion albumen, obtains feed liquid 4.;
(5) with feed liquid 4. through quintuple effect evaporator evaporation, utilize boiling point different separate to by product alcohol, obtain in addition feed liquid 5.;
(6) then 5. feed liquid change and 2. heat exchange of feed liquid by plate, rise to 81 ℃ changing by plate with steam heat-exchanging, get in bleacher, by bottom feed, then overflow to another bleacher, kept 35 minutes in bleacher, and stir, the gac addition is 30KG/ ton starch, obtains feed liquid 6.;
(7) 6. feed liquid filters by bag, then by plate, changes and 8. heat exchange of feed liquid, then by plate, changes and water heat exchange to 47 ℃, enters from handing over purifying, and discharging pH5.0, electricity lead＜100 μ s/cm, obtain feed liquid 7.;
(8) feed liquid, 7. by membrane separation plant, is utilized the difference of molecular size, and glucose, oligose are separated, and 8. grape content≤10%, obtain feed liquid;
(9) 8. the feed liquid after heat exchange enters vaporizer, and be concentrated into solid substance 〉=75% and directly as liquid oligomeric isomaltose slurry, sell, perhaps 63%, then spray-dried tower is dried to moisture≤5%, is packaged into powdery oligomeric isomaltose powder.

Claims (4)

1. the method for a producing functional starch sugar through wheat starch, it is characterized in that described production method is: (1) is with the B-Starch from Wheat breast 16-17Be that sizes mixing, the pH value is 5.0-6.0, adds alpha-amylase 0.5-6kg/ ton butt, carries out steam ejection liquefaction and controls DE value 12-15;
(2) made albumen generation heat-coagulation in 2 hours by the heat-coagulation device, by the crouch albumen of spiral shell heat of dissociation cohesion of bipyramid, regulating liquefier pH value is 5.3～6.0, temperature 55-58 ℃, add transglucosidase 0.8kg-1.0kg, fungal enzyme 0.4kg-0.6kg according to starch butt per ton, saccharification 44-48 hour, obtain the raw sugar slurry of DE value for 52-54;
(3) then add yeast, utilize biological degradation that syrup is further purified, first distillation obtains by product alcohol, utilize again the difference of molecular size by membrane sepn, the glucose oligose is separated, then through five effect evaporations, obtain pure oligomeric isomaltose slurry or Direct spraying and be dried to the oligomeric isomaltose powder.
2. the method for a kind of producing functional starch sugar through wheat starch according to claim 1, it is characterized in that described production method is: (1) is with the B-Starch from Wheat breast 16-17Be that sizes mixing, the pH value is 5.5, adds alpha-amylase 3kg/ ton butt, carries out steam ejection liquefaction and controls DE value 13.5;
(2) made albumen generation heat-coagulation in 2 hours by the heat-coagulation device, by the crouch albumen of spiral shell heat of dissociation cohesion of bipyramid, regulating liquefier pH value is 5.6,56 ℃ of temperature, add transglucosidase 0.9kg, fungal enzyme 0.5kg according to starch butt per ton, saccharification 46 hours, obtain the DE value and be 53 raw sugar slurry;
(3) then add yeast, utilize biological degradation that syrup is further purified, first distillation obtains by product alcohol, utilize the difference of molecular size by membrane sepn, the glucose oligose is separated, then through five effect evaporations, obtain pure oligomeric isomaltose slurry or Direct spraying and be dried to the oligomeric isomaltose powder.
3. the method for a kind of producing functional starch sugar through wheat starch according to claim 1, it is characterized in that describedly carrying out after steam ejection liquefaction (1) flash distillation again and making temperature drop to 95 ℃, stopped 2 hours in the protein coacervation device, then isolate most of cohesion albumen by the bipyramid spiral shell that crouches, be heated to 100 ° of enzymes 30 minutes of going out, obtain feed liquid 1.;
(2) regulate feed liquid 1. pH value be 5.3～5.5, temperature 55-58 ℃, add transglucosidase 0.8kg-1.0kg, fungal enzyme 0.4kg-0.6kg according to starch butt per ton, 2. saccharification 44-48 hour obtains the DE value and is the raw sugar slurry liquid of 52-54;
(3) 2. to adjust the pH value be 5.5～6.0 to feed liquid, by plate change and remove the gred after 4. heat exchange of feed liquid, then by plate, change the heat exchange with water and be cooled to 35 ℃, get in fermentor tank, stop 3-5 days, detect component,, by the enzyme injector that the goes out enzyme that goes out, obtain feed liquid 3. after qualified;
(4) 3. feed liquid adjusts pH4.8-4.9 to the protein coacervation iso-electric point in the transfer tank, adds as solidifying agent, then, by adding super-cell, uses filter press to remove residue cohesion albumen, obtains feed liquid 4.;
(5) 4. feed liquid is evaporated through quintuple effect evaporator, utilize boiling point to obtain by product alcohol different the separation, obtain in addition feed liquid 5.;
(6) then 5. feed liquid change and 2. heat exchange of feed liquid by plate, changing with steam heat-exchanging and rising to 78-85 ℃ by plate, get in bleacher, by bottom feed, then overflow to another bleacher, keep 30-40 minute in bleacher, and stir, the gac addition is 20-40KG/ ton starch, obtains feed liquid 6.;
(7) 6. feed liquid filters by bag, then by plate, changes and 8. heat exchange of feed liquid, then by plate, changes with the water heat exchange to 45-50 ℃, enters from handing over purifying, and discharging pH4.2-5.9, electricity lead＜100 μ s/cm, obtain feed liquid 7.;
(8) feed liquid, 7. by membrane separation plant, is utilized the difference of molecular size, and glucose, oligose are separated, and 8. glucose content≤10%, obtain feed liquid;
(9) 8. the feed liquid after heat exchange enters vaporizer, is concentrated into solid substance 60%-65%, and then spray-dried tower is dried to moisture≤5%, is packaged into powdery oligomeric isomaltose powder.
4. the method for a kind of producing functional starch sugar through wheat starch according to claim 3, it is characterized in that describedly carrying out after steam ejection liquefaction (1) flash distillation again and making temperature drop to 95 ℃, stopped 2 hours in the protein coacervation device, then isolate most of cohesion albumen by the bipyramid spiral shell that crouches, be heated to 100 ° of enzymes 30 minutes of going out, obtain feed liquid 1.;
(2) regulate feed liquid 1. the pH value be 5.4,57 ℃ of temperature, add transglucosidase 0.9kg, fungal enzyme 0.5kg according to starch butt per ton, 2. saccharification 46 hours obtains the DE value and is 53 raw sugar slurry liquid;
(3) 2. to adjust the pH value be 5.8 to feed liquid, by plate change and and slagging-off after 4. heat exchange of feed liquid, then by plate, change the heat exchange with water and be cooled to 35 ℃, get in fermentor tank, stopped 4 days, detect component, qualified afterwards by the enzyme injector that the goes out enzyme that goes out, obtain feed liquid 3.;
(4) 3. feed liquid adjusts pH4.8-4.9 to the protein coacervation iso-electric point in the transfer tank, adds as solidifying agent, then, by adding super-cell, uses filter press to remove residue cohesion albumen, obtains feed liquid 4.;
(5) 4. feed liquid is evaporated through quintuple effect evaporator, utilize boiling point to obtain by product alcohol different the separation, obtain in addition feed liquid 5.;
(6) then 5. feed liquid change and 2. heat exchange of feed liquid by plate, rise to 81 ℃ changing by plate with steam heat-exchanging, get in bleacher, by bottom feed, then overflow to another bleacher, kept 35 minutes in bleacher, and stir, the gac addition is 30KG/ ton starch, obtains feed liquid 6.;
(7) 6. feed liquid filters by bag, then by plate, changes and 8. heat exchange of feed liquid, then by plate, changes and water heat exchange to 47 ℃, enters from handing over purifying, and discharging pH5.0, electricity lead＜100 μ s/cm, obtain feed liquid 7.;
(8) feed liquid, 7. by membrane separation plant, is utilized the difference of molecular size, and glucose, oligose are separated, and 8. glucose content≤10%, obtain feed liquid;
(9) 8. the feed liquid after heat exchange enters vaporizer, and being concentrated into solid substance is 63%, and then spray-dried tower is dried to moisture≤5%, is packaged into powdery oligomeric isomaltose powder.
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CN102747118B (en) * 2012-06-18 2014-02-12 张雄杰 Method for directly producing feeding isomaltooligosaccharide syrup by using wheat
CN103695503B (en) * 2013-12-30 2015-06-24 河南飞天农业开发股份有限公司 Maltose syrup with high sugaring off temperature and preparation method of maltose syrup
CN105316374A (en) * 2014-07-11 2016-02-10 武汉中粮食品科技有限公司 Sugar making method
CN107604031B (en) * 2017-09-15 2020-11-10 郑州新威营养技术有限公司 Method for co-producing wheat oligopeptide and starch sugar
CN108265093A (en) * 2017-12-27 2018-07-10 河南飞天农业开发股份有限公司 A kind of syrup dedicated production technology of toffee
CN109875052A (en) * 2019-03-21 2019-06-14 长春大学 A kind of three clean bodies prebiotics exempt from the preparation method of digestion mung bean protein peptide
CN111607622B (en) * 2020-05-15 2022-02-22 山东省食品发酵工业研究设计院 Process method for producing 3-hydroxy butanone by using wheat B starch
CN112137116B (en) * 2020-09-23 2023-06-13 江南大学 Starch-based dietary fiber for high yield of butyric acid and processing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999767A (en) * 2006-11-29 2007-07-18 甘肃昆仑生化有限责任公司 Tech, process of producing high pureness oligoiso maltose by yeast
CN101805767A (en) * 2010-03-31 2010-08-18 保龄宝生物股份有限公司 High-purity isomaltose hypgather and alcohol co-production preparation method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999767A (en) * 2006-11-29 2007-07-18 甘肃昆仑生化有限责任公司 Tech, process of producing high pureness oligoiso maltose by yeast
CN101805767A (en) * 2010-03-31 2010-08-18 保龄宝生物股份有限公司 High-purity isomaltose hypgather and alcohol co-production preparation method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
俞斌.小麦B淀粉糖制备技术的研究及其麦芽糊精在蛋糕中的应用.《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》.2009,(第3期),B024-208.
小麦B淀粉糖制备技术的研究及其麦芽糊精在蛋糕中的应用;俞斌;《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》;20090315(第3期);B024-208 *

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