CN102351476A - Cement-based flexible sectional material and its manufacture method - Google Patents

Cement-based flexible sectional material and its manufacture method Download PDF

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Publication number
CN102351476A
CN102351476A CN2011101939102A CN201110193910A CN102351476A CN 102351476 A CN102351476 A CN 102351476A CN 2011101939102 A CN2011101939102 A CN 2011101939102A CN 201110193910 A CN201110193910 A CN 201110193910A CN 102351476 A CN102351476 A CN 102351476A
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China
Prior art keywords
cement
based flexible
flexible section
mineral filler
slurry
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CN2011101939102A
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Chinese (zh)
Inventor
吴日成
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Individual
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Priority to CN2011101939102A priority Critical patent/CN102351476A/en
Publication of CN102351476A publication Critical patent/CN102351476A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017—Aspects relating to the protection of the environment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a cement-based flexible sectional material and its manufacture method. The cement-based flexible sectional material comprises cement, an acrylic polymer emulsion, fiber, a pigment and an inorganic filling material. The manufacture method comprises the following steps: crushing the inorganic filling material, mixing the crushed inorganic filling material and other materials, adding water and stirring to obtain uniform slurry, coating, filling or extruding the slurry on a mould, solidifying at room temperature, and demoulding to obtain the product. When the cement-based flexible section of the invention is used to prepare a decorative plane materiel, the material is thin and light, has flexibility and low temperature-humidity shearing force and temperature-humidity tensile stress, and is applicable to outside walls decoration and high-rise building decoration and also applicable to interior decoration without hidden danger. When the cement-based flexible section is used to prepare landscape stones and embossed paintings, the products are light and easy to carry and construct. In addition, the raw materials of the cement-based flexible section have rich sources, various waste materials are fully utilized and the section is economical and environmentally friendly.

Description

Cement-based flexible section and method of manufacture thereof
Technical field
The present invention relates to a kind of building and landscape ornamental section bar and method of manufacture thereof, particularly a kind of cement-based flexible section and method of manufacture thereof.
Background technology
Ceramic veneer, stone material, metal plate curtain wall, coating are commonly used to as the buildings decoration for vertical face.The landscape ornamentals of doing commonly used such as view stone, relief painting.
Advantages such as as the buildings decoration for vertical face, ceramic veneer is comparatively cheap, and it is high to have impact resistance intensity, easy to clean, but the warm and humid shear-stress of ceramic veneer is big, influences its stable adhering to, and, have the hidden danger that comes off and hurt sb.'s feelings behind the life-time service from great.In addition, the ventilation property of ceramic veneer is poor, is used for cold district when outdoor, and freeze-thaw damage takes place easily.Stone material, metal plate curtain wall are used for decorating, and have elegance, steady characteristics, but because it involves great expense, installs complicacy, generally only are used for the decoration of top-grade building.These materials have from great shortcoming equally, and the danger of falling object from high altitude is also arranged.Coating is used for building decoration and has splendid security from heavy and light, but ornamental, pollution resistance, weather resistance are difficult to satisfy building decoration user's demand.
In the beautification of landscape design, the frequency of utilization of view stone, sandstone relief painting is increasingly high.View stone all picks up from mountain forest or beach, and quarrying needs labor human and material resources, financial resources, and has destroyed natural landscape.In addition, lithotome is heavier, when indoor or roof decoration, and the structure of possible crisis buildings.The sandstone relief painting then has big, the allochroic shortcoming when being difficult to carrying and outdoor application of weight.
Summary of the invention
The object of the present invention is to provide a kind of cement-based flexible section and method of manufacture thereof.Can be used to make landscape ornamental products such as building decoration plane materiel and view stone, relief painting.
The technical scheme that the present invention taked is:
A kind of cement-based flexible section contains cement 20～70%, acrylic emulsions 8～35%, fiber 0～2%, pigment 0～3%, and surplus is mineral filler.
Preferably, contain cement 24～40%, acrylic emulsions 8～35%, fiber 0～2%, pigment 0～3%, surplus is mineral filler.
Mineral filler comprises at least a in discarded construction cement building block, the discarded piece material in stone material factory, cinder, the discarded powder of ceramics factory, the silica sand.
Pigment is inorganic mineral pigments.
The method of manufacture of above-mentioned cement-based flexible section may further comprise the steps:
1) mineral filler is pulverized, the mineral filler after pulverizing is mixed with unclassified stores;
2) water that adds material total mass 0～40% stirs, and makes it become uniform sizing material;
3) slurry is applied, pours into or be squeezed on the mould, normal temperature or 50～150 ℃ of curing rear demouldings obtain product.
Preferably, after the slurry coating, pouring into or be squeezed on the mould, the middle or alkaline-resisting grid cloth of fitting behind at slurry, normal temperature or 50～150 ℃ of curing and demolding obtain the product with alkaline-resisting grid cloth.
Cement-based flexible section of the present invention when making decoration plane material, can approach and light, has flexibility, and warm and humid shearing force, warm and humid tensile stress are little, are specially adapted to decoration of exterior wall and Highrise buildings decorate, and also are applicable to indoor wall ground surface finishing, no potential safety hazard.
In section bar centre or the alkaline-resisting grid cloth of back side embedding, can further improve the mechanical property of section bar, enlarge the use range of product.
Mould can be three-dimensional hollow mould, and slurry perfusion in hollow layer, is obtained the three-dimensional section bar of hollow, the three-dimensional section bar that makes, and like view stone, weight is about 1/3 of the true stone of equal-volume, be prone to carrying, construction, and cost is low, and fidelity is high.
Make the employed raw material of cement-based flexible section of the present invention, wide material sources, low price, body material are that various buildings are abandoned material, waste materials such as ceramics factory, stone material factory, economic environmental protection.After flexible section was discarded, recyclable pulverizing was reused, and can fully realize the resource circulation use.
Embodiment
A kind of cement-based flexible section contains cement 20～70%, acrylic emulsions 8～35%, fiber 0～2%, pigment 0～3%, and surplus is mineral filler.
Wherein, cement is peptizer;
Through the consumption of adjustment acrylate polymer emulsion, flexibility and the water-absorbent that can regulate finished product;
Fiber can prevent that cement from chapping in process of setting, increase the tear strength of finished product.
The method of manufacture of above-mentioned cement-based flexible section may further comprise the steps:
1) mineral filler is pulverized, the mineral filler after pulverizing is mixed with unclassified stores;
2) water that adds material total mass 0～40% stirs, and makes it become uniform sizing material;
3) slurry is applied, pours into or be squeezed on the mould, normal temperature or 50～150 ℃ of curing rear demouldings obtain product.
Preferably, after the slurry coating, pouring into or be squeezed on the mould, the middle or alkaline-resisting grid cloth of fitting behind at slurry, normal temperature or 50～150 ℃ of curing and demolding obtain the product with alkaline-resisting grid cloth.
The mineral filler preferred powder is broken to 50～200 orders.
The thickness that slurry applies, pours into or push can be regulated as required, and its thickness is preferably 0.5～7mm.
Mineral filler among the present invention comprises at least a in discarded construction cement building block, the discarded piece material in stone material factory, cinder, the discarded powder of ceramics factory, the silica sand; Pigment is inorganic mineral pigments; Cement is commercially available cement, comprises white cement and black cement; Acrylate polymer emulsion is the commercially available acrylic polymer emulsions of various routines, can be the Chemicals of staple in order to XPA also, like commercially available emulsion-type waterproofing agent of cement mortar or concrete waterproofer, screen printing binding agent etc.; Fiber is commercially available fiber, comprises wood fibre, ceramic fiber, spun glass, polypropylene fibre, thomel and boron fibre etc.
Below in conjunction with embodiment, further specify the present invention.
The per-cent that uses in following examples if no special instructions, all refers to mass percent.
Embodiment 1
Consisting of of cement-based flexible section:
Cement 26%; Acrylate polymer emulsion 20%; Mineral filler 54% is discarded construction cement building block.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 15% stirs, and makes it become uniform sizing material;
3) slurry is squeezed on the mould with bag, thick 4mm, ambient cure, demoulding obtain the imitative stone material product of this cement-based flexible section.
Embodiment 2
Consisting of of cement-based flexible section:
Cement 28%; Waterproofing agent of cement mortar 31%; Spun glass 1.0%; Mineral filler cinder 20%, the discarded powder 20% of ceramics factory are formed.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 8% stirs, and makes it become uniform sizing material;
3) slurry is squeezed on the mould with wood grain, thick 3mm, 60 ℃ solidify rear demoulding, obtain the imitative wood grain product of this cement-based flexible section.
Embodiment 3
Consisting of of cement-based flexible section:
White cement 30%; The copolymer emulsion 28% of all acrylic ester class, wood fibre 0.2%; Ultramarine blue 1%; Mineral filler silica sand 40.8%.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 10% stirs, and makes it become uniform sizing material;
3) slurry is coated in has on the ox-hide line mould, thick 4mm, 80 ℃ solidify rear demouldings, the imitation leather line product of this cement-based flexible section.
Embodiment 4
Consisting of of cement-based flexible section:
Cement 33%; The fine copolymer emulsion 24% of Bing Xisuandingzhi and propylene; Polypropylene fibre 0.3%; Sudan red 2%; Construction cement building block powder 36%, the discarded powder 14.7% of ceramics factory are discarded in mineral filler.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 12% stirs, and makes it become uniform sizing material;
3) with slurry perfusion on view stone hollow mould, the ambient cure rear demoulding obtains view stone product.
Embodiment 5
Consisting of of cement-based flexible section:
Cement 25%; The copolymerized macromolecule compound 19% of vinylformic acid and ester thereof; Ceramic fiber 1.4%; Mineral filler silica sand 20%, the discarded piece material 34.6% in stone material factory.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 20% stirs, and makes it become uniform sizing material;
3) slurry is coated on the light face mould tool, thick 2.5mm, the alkaline-resisting glass lattice cloth of fitting behind, 100 ℃ solidify rear demoulding, obtain the light face product of back side band grid cloth.
Embodiment 6
Consisting of of cement-based flexible section:
Cement 28%; Polyethyl acrylate, butyl polyacrylate, hydroxymethyl acrylamide copolymer 21%; Thomel 1.7%; Construction cement building block powder 20.3%, the discarded piece material 29% in stone material factory are discarded in mineral filler.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 10% stirs, and makes it become uniform sizing material;
3) with slurry perfusion in the view stone mould, normal temperature solidifies down, the demoulding obtains view stone product.
Embodiment 7
Consisting of of cement-based flexible section:
Cement 40%; Screen printing binding agent 25% (Jiande City, Zhejiang Province white sand chemical industry ltd, BS-WP); Ceramic fiber 2%; Mineral filler cinder 22%, the discarded powder 11% of ceramics factory.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 10% stirs, and makes it become uniform sizing material;
3) slurry is coated on the mould with the brick texture of riving, thick 2mm places alkaline-resisting nylon grid cloth on slurry, the 1mm slurry is coated on the nylon grid cloth 150 ℃ of curing and demolding, the imitative brick product of riving of band nylon grid cloth in the middle of obtaining again.
Embodiment 8
Consisting of of cement-based flexible section:
Cement 29%; Acrylic ester high molecular type copolymer emulsion 15%; Boron fibre 1.2%; Mineral filler ceramics factory discards powder 18%, silica sand 36%.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 22% stirs, and makes it become uniform sizing material;
3) slurry is squeezed on the relief die, obtains relief sculpture products.
Embodiment 9
The composition of cement-based flexible section consists of:
Cement 55%; Emulsion-type waterproofing agent of cement mortar 25%; Ceramic fiber 2%; Mineral filler silica sand 10%, the discarded powder 8% of ceramics factory.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 40% stirs, and makes it become uniform sizing material;
3) slurry is coated on the mould with the brick texture of riving, thick 2mm places alkaline-resisting nylon grid cloth on slurry, the 1mm slurry is coated on the nylon grid cloth demoulding after the ambient cure, the imitative brick product of riving of band nylon grid cloth in the middle of obtaining again.
Embodiment 10
Consisting of of cement-based flexible section:
Cement 66%; Acrylate polymer emulsion 33.5%; Ultramarine blue pigment 0.5%.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 15% stirs, and makes it become uniform sizing material;
3) slurry is squeezed on the mould with the brick of riving, thick 2mm, ambient cure, demoulding obtain the imitative brick product of riving of this cement-based flexible section.
Embodiment 11
Consisting of of cement-based flexible section:
Cement 70%; Acrylate polymer emulsion 28%; Ceramics factory discards powder 2%.
Its preparation method is following:
1) mineral filler is crushed to 50～200 orders;
2) mineral filler after will pulverizing mixes with unclassified stores, and the water that adds material total mass 25% stirs, and makes it become uniform sizing material;
3) slurry is squeezed on the mould with the brick of riving, thick 3mm, 80 ℃ of curing, demoulding obtain the imitative brick product of riving of this cement-based flexible section.
Cement-based flexible section of the present invention, stability to aging is good, and the ageing-resistant experiment of artificial acceleration was above 2000 hours.When making decoration plane material, thin and light, area density is merely 0.5kg/m 2～8kg/m 2Have flexibility, warm and humid shearing force, warm and humid tensile stress are little, are specially adapted to decoration of exterior wall and Highrise buildings and decorate, and also are applicable to interior decoration, no potential safety hazard.When making view stone, relief painting, weight is about 1/3 of true stone of equal-volume or sandstone relief painting weight, be prone to carrying, construction, and cost is low, and fidelity is high.

Claims (7)

1. a cement-based flexible section contains cement 20～70%, acrylic emulsions 8～35%, fiber 0～2%, pigment 0～3%, and surplus is mineral filler.
2. a kind of cement-based flexible section according to claim 1 is characterized in that: said cement-based flexible section contains cement 24～40%, acrylic emulsions 8～35%, fiber 0～2%, pigment 0～3%, and surplus is mineral filler.
3. a kind of cement-based flexible section according to claim 1 and 2 is characterized in that: at least a in discarded construction cement building block, the discarded piece material in stone material factory, cinder, the discarded powder of ceramics factory, the silica sand of mineral filler.
4. a kind of cement-based flexible section according to claim 1 and 2 is characterized in that: pigment is inorganic mineral pigments.
5. the method for manufacture of claim 1 or 2 said cement-based flexible sections may further comprise the steps:
1) mineral filler is pulverized, the mineral filler after pulverizing is mixed with unclassified stores;
2) add water and stir, make it become uniform sizing material;
3) slurry is applied, pours into or be squeezed on the mould, normal temperature or 50～150 ℃ of curing rear demouldings obtain product.
6. according to the method for manufacture of the said cement-based flexible section of claim 5; It is characterized in that: after the slurry coating, pouring into or be squeezed on the mould; Middle or the alkaline-resisting grid cloth of fitting behind at slurry, normal temperature or 50～150 ℃ of curing and demolding obtain the product with alkaline-resisting grid cloth.
7. according to the method for manufacture of the said cement-based flexible section of claim 5, it is characterized in that: during stirring, the add-on of water is 10～40% of a material total mass.
CN2011101939102A 2010-07-13 2011-07-12 Cement-based flexible sectional material and its manufacture method Pending CN102351476A (en)

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CN2010102256391A CN101891423A (en) 2010-07-13 2010-07-13 Cement-based flexible section and preparation method thereof
CN201010225639.1 2010-07-13
CN2011101939102A CN102351476A (en) 2010-07-13 2011-07-12 Cement-based flexible sectional material and its manufacture method

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN107814525A (en) * 2017-11-27 2018-03-20 广西福美新材料有限公司 A kind of antistatic flexible floor and preparation method thereof
CN107986690A (en) * 2017-11-27 2018-05-04 广西福美新材料有限公司 A kind of flexible decorative walling for removing formaldehyde and preparation method thereof
CN111499326A (en) * 2020-04-17 2020-08-07 四川海聚环保科技有限责任公司 Preparation method of water-based cement elastic emulsion-based flexible veneer substrate
CN113666672A (en) * 2021-09-02 2021-11-19 万卓（江苏）新材料有限公司 Light photocatalytic stone-like composite material and preparation method thereof

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CN102977251B (en) * 2012-12-17 2015-01-21 利达科技（福建）有限公司 Internal plasticization artware molding emulsion as well as preparation method and use thereof
CN105130298A (en) * 2015-08-18 2015-12-09 祝莉玲 Artificial panel formula
CN106045422A (en) * 2016-06-08 2016-10-26 石磊 Manufacturing method of flexible decorative sheet
CN109988527A (en) * 2019-04-02 2019-07-09 王谦 A kind of flexible polymer cement seal material and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107814525A (en) * 2017-11-27 2018-03-20 广西福美新材料有限公司 A kind of antistatic flexible floor and preparation method thereof
CN107986690A (en) * 2017-11-27 2018-05-04 广西福美新材料有限公司 A kind of flexible decorative walling for removing formaldehyde and preparation method thereof
CN111499326A (en) * 2020-04-17 2020-08-07 四川海聚环保科技有限责任公司 Preparation method of water-based cement elastic emulsion-based flexible veneer substrate
CN111499326B (en) * 2020-04-17 2022-06-21 四川海聚环保科技有限责任公司 Preparation method of water-based cement elastic emulsion-based flexible veneer substrate
CN113666672A (en) * 2021-09-02 2021-11-19 万卓（江苏）新材料有限公司 Light photocatalytic stone-like composite material and preparation method thereof

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Application publication date: 20120215