CN102351379A - Viscose fiber waste water treatment method - Google Patents
Viscose fiber waste water treatment method Download PDFInfo
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- CN102351379A CN102351379A CN2011102286137A CN201110228613A CN102351379A CN 102351379 A CN102351379 A CN 102351379A CN 2011102286137 A CN2011102286137 A CN 2011102286137A CN 201110228613 A CN201110228613 A CN 201110228613A CN 102351379 A CN102351379 A CN 102351379A
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- waste water
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- zinc
- viscose fiber
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Abstract
The invention discloses a viscose fiber waste water treatment method. The viscose fiber waste water treatment method comprises air floatation and deposition, and muddy water separation. The viscose fiber waste water treatment method is characterized in that alkaline waste water comprising exhaust gas recovery waste water, stock solution and spinning head lifting waste water is collected and fed into an alkaline waste water tank; acidic waste water comprising acid station outlet water is collected and fed into an acidic waste water tank; zinc-containing waste water comprising spun fluff molding tank outlet water, acid removal water and two-bath process overflow is collected and fed into a zinc-containing waste water tank; the alkaline waste water and the zinc-containing waste water are fed into a mixing air-floatation tank for mixing, wherein in mixing air-floatation, a pH is adjusted to a value of 3.0 to 4.0; the water output by the mixing air-floatation tank and the acidic waste water are fed into a physicochemical treatment tank and a biochemical treatment tank to be subjected to precipitation and muddy water separation; and when the treated water reaches the standard, the treated water is discharged. The viscose fiber waste water treatment method solves the problem of difficult viscose fiber waste water. The viscose fiber waste water treatment method has the characteristics of simple processes and good effects.
Description
Technical field
The present invention relates to a kind of viscose fiber method of wastewater treatment.
Technical background
Viscose fiber waste water is subjected to the influence of viscose glue production technique, and reluctant factor mainly is Mierocrystalline cellulose residue, heavy metal zinc ion, sulfonium ion etc., usually causes the not good or system's fluctuation of service of wastewater treatment efficiency, and draining can not be up to standard.
In the viscose glue production technique, no matter produce nonwoven, high-strength, still common silk, the Mierocrystalline cellulose residue mainly results from the stoste processing procedure; Zine ion is mainly spinning experienced fine hair forming tank water outlet, disacidify wash water and two bath overflows from acid bath; Sulfonium ion mainly from adding of dithiocarbonic anhydride use with the waste gas recovery in acid, alkali cleaning.
Summary of the invention
Its purpose of the present invention just is to provide a kind of viscose fiber method of wastewater treatment, has solved the reluctant problem of viscose fiber waste water.Has simple, the good effectiveness of technology.
The technical scheme that realizes above-mentioned purpose and take comprises:
Air supporting and deposition, mud-water separation,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
Compared with prior art, beneficial effect of the present invention is, has adopted three strands of waste water to get into the sewage disposal method of combination treatment again, thereby has solved the reluctant problem of viscose fiber waste water.Has simple, the good effectiveness of technology.
Description of drawings
Below in conjunction with accompanying drawing the present invention is made further detailed description.
Accompanying drawing 1 is the inventive method process flow diagram.
Embodiment
Comprise air supporting and deposition, mud-water separation, shown in accompanying drawing 1,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
Described
A, alkaline waste water: PH12, COD2000 ~ 4000mg/l, S
2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
B, acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na
2SO
45000 ~ 30000 mg/l;
C, zinc-containing water: PH1.6, COD1500 mg/l, Zn
2+250 ~ 420 mg/l.
Embodiment
According to the situation of waste water factory effluent is divided into waste gas recovery, stoste, spins to practice and rise alkaline waste water that a waste water is master, be master's acid waste water and spin experienced fine hair forming tank water outlet, disacidify wash water and two and bathe zinc-containing water totally three bursts of entering sewage works that overflows are the master that with the draining of acid station purpose is for mixing again.
Pollutants in waste water after the shunting is according to producing common silk, nonwoven or high-strength difference, and situation is following basically:
In A, the alkaline waste water: PH12, COD2000 ~ 4000mg/l, S
2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
In B, the acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na
2SO
45000 ~ 30000 mg/l;
In C, the zinc-containing water: PH1.6, COD1500 mg/l, Zn
2+250 ~ 420 mg/l.
The alkaline waste water and the zinc-containing water that get into sewage work are mixed, PH is controlled at 3.0 ~ 4.0 mixes air supporting, effect is following:
A, can reduce the zinc-containing water water temperature;
B, zinc-containing water PH can be elevated to about 4 from about 1.6, reduce the anticorrosion grade of facility;
C, the Mierocrystalline cellulose residue can be removed 90%, thereby reduce waste water COD;
The mixing of D, sulfonium ion and zine ion can produce zinc sulphide, S
2-And Zn
2+Clearance can reach 80 ~ 90 not to be waited;
E, this method can efficiently be removed pollutent, for follow-up steady running provides better condition.
In conjunction with follow-up materialization and biochemical treatment, reach national grade one discharge standard and be fully can and system stable.
Claims (2)
1. a viscose fiber method of wastewater treatment comprises air supporting and deposition, and mud-water separation is characterized in that,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
2. the described a kind of viscose fiber method of wastewater treatment of root a tree name claim 1 is characterized in that, and is described
A, alkaline waste water: PH12, COD2000 ~ 4000mg/l, S
2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
B, acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na
2SO
45000 ~ 30000 mg/l;
C, zinc-containing water: PH1.6, COD1500 mg/l, Zn
2+250 ~ 420 mg/l.
Priority Applications (1)
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CN2011102286137A CN102351379A (en) | 2011-08-11 | 2011-08-11 | Viscose fiber waste water treatment method |
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CN2011102286137A CN102351379A (en) | 2011-08-11 | 2011-08-11 | Viscose fiber waste water treatment method |
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CN102351379A true CN102351379A (en) | 2012-02-15 |
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CN2011102286137A Pending CN102351379A (en) | 2011-08-11 | 2011-08-11 | Viscose fiber waste water treatment method |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104445447A (en) * | 2014-10-20 | 2015-03-25 | 宜宾丝丽雅股份有限公司 | Treatment device for acid sewage generated in viscose staple fibre treatment |
CN112093960A (en) * | 2020-09-01 | 2020-12-18 | 北京理工大学 | Treatment method of nitrified bamboo cellulose washing wastewater |
CN112390448A (en) * | 2020-09-01 | 2021-02-23 | 江西吉润花炮新材料科技有限公司 | Treatment method of nitrified bamboo cellulose alkali cooking wastewater |
CN112456683A (en) * | 2020-11-25 | 2021-03-09 | 赛得利(九江)纤维有限公司 | Treatment method of viscose zinc-containing wastewater |
Citations (4)
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JPS5222359A (en) * | 1975-08-12 | 1977-02-19 | Mitsubishi Rayon Co Ltd | Process for removing zinc from vicose rayon waste liquid |
SU1171424A1 (en) * | 1983-11-03 | 1985-08-07 | Предприятие П/Я А-3844 | Method of cleaning solutions of viscose production spinning bath |
CN1583608A (en) * | 2004-06-15 | 2005-02-23 | 山东海龙股份有限公司 | Comprehensive treatment of cotton-dreg black liquid and waste water from production of viscose fiber |
CN101125720A (en) * | 2006-08-18 | 2008-02-20 | 宜宾长毅浆粕有限责任公司 | Synthetic treating process for pulp waste water |
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2011
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Patent Citations (4)
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JPS5222359A (en) * | 1975-08-12 | 1977-02-19 | Mitsubishi Rayon Co Ltd | Process for removing zinc from vicose rayon waste liquid |
SU1171424A1 (en) * | 1983-11-03 | 1985-08-07 | Предприятие П/Я А-3844 | Method of cleaning solutions of viscose production spinning bath |
CN1583608A (en) * | 2004-06-15 | 2005-02-23 | 山东海龙股份有限公司 | Comprehensive treatment of cotton-dreg black liquid and waste water from production of viscose fiber |
CN101125720A (en) * | 2006-08-18 | 2008-02-20 | 宜宾长毅浆粕有限责任公司 | Synthetic treating process for pulp waste water |
Non-Patent Citations (5)
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周晓东等: "物化-生化组合工艺处理化纤厂浆粕综合废水", 《环境工程》 * |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104445447A (en) * | 2014-10-20 | 2015-03-25 | 宜宾丝丽雅股份有限公司 | Treatment device for acid sewage generated in viscose staple fibre treatment |
CN104445447B (en) * | 2014-10-20 | 2016-08-24 | 宜宾丝丽雅股份有限公司 | A kind of short rayon fiber sour water processing means |
CN112093960A (en) * | 2020-09-01 | 2020-12-18 | 北京理工大学 | Treatment method of nitrified bamboo cellulose washing wastewater |
CN112390448A (en) * | 2020-09-01 | 2021-02-23 | 江西吉润花炮新材料科技有限公司 | Treatment method of nitrified bamboo cellulose alkali cooking wastewater |
CN112093960B (en) * | 2020-09-01 | 2021-10-29 | 北京理工大学 | Treatment method of nitrified bamboo cellulose washing wastewater |
CN112456683A (en) * | 2020-11-25 | 2021-03-09 | 赛得利(九江)纤维有限公司 | Treatment method of viscose zinc-containing wastewater |
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Application publication date: 20120215 |