CN102351379A - Viscose fiber waste water treatment method - Google Patents

Viscose fiber waste water treatment method Download PDF

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Publication number
CN102351379A
CN102351379A CN2011102286137A CN201110228613A CN102351379A CN 102351379 A CN102351379 A CN 102351379A CN 2011102286137 A CN2011102286137 A CN 2011102286137A CN 201110228613 A CN201110228613 A CN 201110228613A CN 102351379 A CN102351379 A CN 102351379A
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CN
China
Prior art keywords
waste water
water
zinc
viscose fiber
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011102286137A
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Chinese (zh)
Inventor
林戊坤
梁翌
张旭忠
林隆辉
张明山
刘丽华
占景炼
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Deli (jiangxi) Chemical Fiber Co Ltd
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Deli (jiangxi) Chemical Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Deli (jiangxi) Chemical Fiber Co Ltd filed Critical Deli (jiangxi) Chemical Fiber Co Ltd
Priority to CN2011102286137A priority Critical patent/CN102351379A/en
Publication of CN102351379A publication Critical patent/CN102351379A/en
Pending legal-status Critical Current

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  • Removal Of Specific Substances (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a viscose fiber waste water treatment method. The viscose fiber waste water treatment method comprises air floatation and deposition, and muddy water separation. The viscose fiber waste water treatment method is characterized in that alkaline waste water comprising exhaust gas recovery waste water, stock solution and spinning head lifting waste water is collected and fed into an alkaline waste water tank; acidic waste water comprising acid station outlet water is collected and fed into an acidic waste water tank; zinc-containing waste water comprising spun fluff molding tank outlet water, acid removal water and two-bath process overflow is collected and fed into a zinc-containing waste water tank; the alkaline waste water and the zinc-containing waste water are fed into a mixing air-floatation tank for mixing, wherein in mixing air-floatation, a pH is adjusted to a value of 3.0 to 4.0; the water output by the mixing air-floatation tank and the acidic waste water are fed into a physicochemical treatment tank and a biochemical treatment tank to be subjected to precipitation and muddy water separation; and when the treated water reaches the standard, the treated water is discharged. The viscose fiber waste water treatment method solves the problem of difficult viscose fiber waste water. The viscose fiber waste water treatment method has the characteristics of simple processes and good effects.

Description

A kind of viscose fiber method of wastewater treatment
Technical field
The present invention relates to a kind of viscose fiber method of wastewater treatment.
Technical background
Viscose fiber waste water is subjected to the influence of viscose glue production technique, and reluctant factor mainly is Mierocrystalline cellulose residue, heavy metal zinc ion, sulfonium ion etc., usually causes the not good or system's fluctuation of service of wastewater treatment efficiency, and draining can not be up to standard.
In the viscose glue production technique, no matter produce nonwoven, high-strength, still common silk, the Mierocrystalline cellulose residue mainly results from the stoste processing procedure; Zine ion is mainly spinning experienced fine hair forming tank water outlet, disacidify wash water and two bath overflows from acid bath; Sulfonium ion mainly from adding of dithiocarbonic anhydride use with the waste gas recovery in acid, alkali cleaning.
Summary of the invention
Its purpose of the present invention just is to provide a kind of viscose fiber method of wastewater treatment, has solved the reluctant problem of viscose fiber waste water.Has simple, the good effectiveness of technology.
The technical scheme that realizes above-mentioned purpose and take comprises:
Air supporting and deposition, mud-water separation,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
Compared with prior art, beneficial effect of the present invention is, has adopted three strands of waste water to get into the sewage disposal method of combination treatment again, thereby has solved the reluctant problem of viscose fiber waste water.Has simple, the good effectiveness of technology.
Description of drawings
Below in conjunction with accompanying drawing the present invention is made further detailed description.
Accompanying drawing 1 is the inventive method process flow diagram.
Embodiment
Comprise air supporting and deposition, mud-water separation, shown in accompanying drawing 1,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
Described
A, alkaline waste water: PH12, COD2000 ~ 4000mg/l, S 2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
B, acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na 2SO 45000 ~ 30000 mg/l;
C, zinc-containing water: PH1.6, COD1500 mg/l, Zn 2+250 ~ 420 mg/l.
Embodiment
According to the situation of waste water factory effluent is divided into waste gas recovery, stoste, spins to practice and rise alkaline waste water that a waste water is master, be master's acid waste water and spin experienced fine hair forming tank water outlet, disacidify wash water and two and bathe zinc-containing water totally three bursts of entering sewage works that overflows are the master that with the draining of acid station purpose is for mixing again.
Pollutants in waste water after the shunting is according to producing common silk, nonwoven or high-strength difference, and situation is following basically:
In A, the alkaline waste water: PH12, COD2000 ~ 4000mg/l, S 2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
In B, the acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na 2SO 45000 ~ 30000 mg/l;
In C, the zinc-containing water: PH1.6, COD1500 mg/l, Zn 2+250 ~ 420 mg/l.
The alkaline waste water and the zinc-containing water that get into sewage work are mixed, PH is controlled at 3.0 ~ 4.0 mixes air supporting, effect is following:
A, can reduce the zinc-containing water water temperature;
B, zinc-containing water PH can be elevated to about 4 from about 1.6, reduce the anticorrosion grade of facility;
C, the Mierocrystalline cellulose residue can be removed 90%, thereby reduce waste water COD;
The mixing of D, sulfonium ion and zine ion can produce zinc sulphide, S 2-And Zn 2+Clearance can reach 80 ~ 90 not to be waited;
E, this method can efficiently be removed pollutent, for follow-up steady running provides better condition.
In conjunction with follow-up materialization and biochemical treatment, reach national grade one discharge standard and be fully can and system stable.

Claims (2)

1. a viscose fiber method of wastewater treatment comprises air supporting and deposition, and mud-water separation is characterized in that,
(1) alkaline waste water comprises waste gas recovery, stoste, spins the alkaline waste water that practice to rise a waste water and be collected into the alkaline waste water pond;
(2) acid waste water comprises that the acid waste water of acid station draining is collected into the acid waste water pond;
(3) zinc-containing water comprises that spinning experienced fine hair forming tank water outlet, disacidify wash water and two zinc-containing waters of bathing overflow is collected into the zinc-containing water pond;
(4) said alkaline waste water and zinc-containing water entering mixing air flotation pool mixes, and PH is controlled at 3.0 ~ 4.0 mixes air supporting;
(5) said mixing air flotation pool output and said acid waste water get into materialization, biochemical treatment tank;
(6) deposition, mud-water separation;
(7) qualified discharge.
2. the described a kind of viscose fiber method of wastewater treatment of root a tree name claim 1 is characterized in that, and is described
A, alkaline waste water: PH12, COD2000 ~ 4000mg/l, S 2-70 ~ 300 mg/l, the Mierocrystalline cellulose residue is many;
B, acid waste water: PH 4, COD1000 ~ 1500 mg/l, Na 2SO 45000 ~ 30000 mg/l;
C, zinc-containing water: PH1.6, COD1500 mg/l, Zn 2+250 ~ 420 mg/l.
CN2011102286137A 2011-08-11 2011-08-11 Viscose fiber waste water treatment method Pending CN102351379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011102286137A CN102351379A (en) 2011-08-11 2011-08-11 Viscose fiber waste water treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011102286137A CN102351379A (en) 2011-08-11 2011-08-11 Viscose fiber waste water treatment method

Publications (1)

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CN102351379A true CN102351379A (en) 2012-02-15

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445447A (en) * 2014-10-20 2015-03-25 宜宾丝丽雅股份有限公司 Treatment device for acid sewage generated in viscose staple fibre treatment
CN112093960A (en) * 2020-09-01 2020-12-18 北京理工大学 Treatment method of nitrified bamboo cellulose washing wastewater
CN112390448A (en) * 2020-09-01 2021-02-23 江西吉润花炮新材料科技有限公司 Treatment method of nitrified bamboo cellulose alkali cooking wastewater
CN112456683A (en) * 2020-11-25 2021-03-09 赛得利(九江)纤维有限公司 Treatment method of viscose zinc-containing wastewater

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5222359A (en) * 1975-08-12 1977-02-19 Mitsubishi Rayon Co Ltd Process for removing zinc from vicose rayon waste liquid
SU1171424A1 (en) * 1983-11-03 1985-08-07 Предприятие П/Я А-3844 Method of cleaning solutions of viscose production spinning bath
CN1583608A (en) * 2004-06-15 2005-02-23 山东海龙股份有限公司 Comprehensive treatment of cotton-dreg black liquid and waste water from production of viscose fiber
CN101125720A (en) * 2006-08-18 2008-02-20 宜宾长毅浆粕有限责任公司 Synthetic treating process for pulp waste water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5222359A (en) * 1975-08-12 1977-02-19 Mitsubishi Rayon Co Ltd Process for removing zinc from vicose rayon waste liquid
SU1171424A1 (en) * 1983-11-03 1985-08-07 Предприятие П/Я А-3844 Method of cleaning solutions of viscose production spinning bath
CN1583608A (en) * 2004-06-15 2005-02-23 山东海龙股份有限公司 Comprehensive treatment of cotton-dreg black liquid and waste water from production of viscose fiber
CN101125720A (en) * 2006-08-18 2008-02-20 宜宾长毅浆粕有限责任公司 Synthetic treating process for pulp waste water

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Title
周晓东等: "物化-生化组合工艺处理化纤厂浆粕综合废水", 《环境工程》 *
王刚等: "我国粘胶纤维行业水污染防治技术现状分析", 《干旱环境监测》 *
邵广林等: "粘胶短纤维生产废水处理工程", 《工业给排水》 *
金离尘: "粘胶纤维含锌废水的处理和回收", 《化学通报》 *
陈益明: "粘胶纤维废水处理新技术及其应用", 《水处理技术》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445447A (en) * 2014-10-20 2015-03-25 宜宾丝丽雅股份有限公司 Treatment device for acid sewage generated in viscose staple fibre treatment
CN104445447B (en) * 2014-10-20 2016-08-24 宜宾丝丽雅股份有限公司 A kind of short rayon fiber sour water processing means
CN112093960A (en) * 2020-09-01 2020-12-18 北京理工大学 Treatment method of nitrified bamboo cellulose washing wastewater
CN112390448A (en) * 2020-09-01 2021-02-23 江西吉润花炮新材料科技有限公司 Treatment method of nitrified bamboo cellulose alkali cooking wastewater
CN112093960B (en) * 2020-09-01 2021-10-29 北京理工大学 Treatment method of nitrified bamboo cellulose washing wastewater
CN112456683A (en) * 2020-11-25 2021-03-09 赛得利(九江)纤维有限公司 Treatment method of viscose zinc-containing wastewater

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Application publication date: 20120215