CN102349685B - Bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization - Google Patents

Bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization Download PDF

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Publication number
CN102349685B
CN102349685B CN201110210534A CN201110210534A CN102349685B CN 102349685 B CN102349685 B CN 102349685B CN 201110210534 A CN201110210534 A CN 201110210534A CN 201110210534 A CN201110210534 A CN 201110210534A CN 102349685 B CN102349685 B CN 102349685B
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tea leaves
antistaling agent
spherical
bulbous
tealeaves
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CN102349685A (en
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许庆华
许盛英
袁长兵
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JIANGSU JIAAN FOOD CO Ltd
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Abstract

The invention discloses a bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization, the technical scheme comprises that the bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization is composed of red bentonite, dolomite attapulgite clay, bauxite, sulphuric acid, high viscosity attapulgite clay powder and reduced iron powder. The burden of the bulbous tea leaves antistaling agent is placed in a stirrer for mixing and stirring, the bulbous tea leaves antistaling agent is sealed and packaged after uniformly stirring. The bulbous tea leaves antistaling agent is placed in a tea leaves packaging container, so that the functions of moisture protection, deoxidization, odor absorption and fresh preservation can be synchronously carried out, and the bulbous tea leaves antistaling agent can remove the free oxygen and free water in the tea leaves package, the oxygen content is controlled below 0.1%, the water content of the tea leaves is controlled below 6.5%, thereby the bulbous tea leaves antistaling agent is capable of keeping complete dry of the tea leaves, preventing the weathering and deterioration of tea leaves caused by oxidation, ensuring the original flavor and quality of the tea leaves and prolonging the shelf life. The bulbous tea leaves antistaling agent is suitable for being placed in various tea leaves packaging containers.

Description

The moistureproof deoxidizing antistaling agent of spherical tealeaves
Technical field
The present invention relates to deoxidizing antistaling agent, be specifically related to the moistureproof deoxidizing antistaling agent of a kind of spherical tealeaves.
Background technology
Tealeaves is easy to moisture absorption and absorbs peculiar smell, accelerates the speed of oxidation, destroys nutritional labeling and original local flavor of tealeaves, need note anti-oxidation, moistureproof and prevents the pollution of peculiar smell at lay up period, to guarantee tea leaf quality.
The tealeaves optimum is stored at itself water content condition lower seal below 5%, the moisture of national Specification tealeaves≤7.5%, tealeaves when its water content 8% when above, store and just had old tea smell in 6 months; When its water content 10% the time, just be easy to occur the smell that goes mouldy; When its water content surpassed 12%, mould was easy to grow in a large number, and the smell that goes mouldy can be strengthened, even mouldy caking, can't continue to drink.
The moistureproof deoxidation preservation method of tealeaves mainly contains at present: lime dehumidifying fresh-keeping method, the nitrogen-filled packaging fresh-keeping method of bleeding, vacuum-packing fresh-keeping method, Deoxygen Packaging fresh-keeping method and damp-prrof packing fresh-keeping method; Said method cuts both ways, but all can not reach the fresh-keeping effect of moistureproof deoxidation simultaneously.
Chinese patent Granted publication CN 1181767C; On December 29 2004 Granted publication day, name is called " a kind of deoxidier of bicomponent system ", disclose " a kind of deoxidier of bicomponent system; except containing iron, sodium chloride, active carbon, water-absorbing resin; it is characterized in that: contain the zinc that matches with iron, said zinc has the oxygen uptake function with the main body of iron as deoxidier; Contain ferrous sulfate with the sodium chloride pairing; Contain active soil with the active carbon pairing; Also contain urea with the water-absorbing resin pairing; Wherein zinc-iron antithetical phrase component, sodium chloride-ferrous sulfate antithetical phrase component, active carbon-active soil antithetical phrase component and water-absorbing resin-urea antithetical phrase component, its weight proportion is respectively 50-90%, 0.1-5%, 0.5-30% and 0.1-25%.Deoxidier of the present invention can be applied to different conditions, different moisture content, different oil-containing and grade and variously do, go in the bright article, thereby obtains out and out effect ".
Sodium chloride in the above-mentioned patent, ferrous sulfate and urea all are the very strong materials of wettability power; In air, be prone to deliquescence; The finished product water content of dispatching from the factory of active carbon and active soil allows≤10.0%, these materials in the process of pulverizing and mixing, will absorbed air in a large amount of moisture content; Fast zinc, iron, active carbon, active soil and water-absorbing resin are wrapped up; Reduced the effect of deoxidier, the only fast effect of suction of competence exertion in the aqueous solution of water-absorbing resin can not effectively be adsorbed sodium chloride, ferrous sulfate, urea, variously does, the moisture content in the bright article; Therefore, the weak point of above-mentioned patent is that this technology is produced the practical effect that " a kind of deoxidier of bicomponent system " directly has influence on deoxidier.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of have protection against the tide, deoxidation, absorption peculiar smell and the fresh-keeping moistureproof deoxidizing antistaling agent of multifunctional sphere tealeaves are provided.
The moistureproof deoxidizing antistaling agent of spherical tealeaves is made up of red bentonite, dolomite Concave-convex clay rod, bauxite, sulfuric acid, high sticking Concave-convex clay rod powder and reduced iron powder.
The production method of the moistureproof deoxidizing antistaling agent of spherical tealeaves: with the batching input mixer mixing stirring of the moistureproof deoxidizing antistaling agent of spherical tealeaves, packing after stirring is spherical tealeaves protection against the tide deoxidizing antistaling agent.
Iron oxide content >=14% in the red bentonite, alundum (Al content >=10%; The content of calcium oxide >=24% in the dolomite Concave-convex clay rod, magnesian content >=12%; Alundum (Al content >=55% in the bauxite; Red bentonite, dolomite Concave-convex clay rod and bauxite are mixed into mineral intermixture; The acidified processing of mineral intermixture back generates sulfate mixtures such as part of sulfuric acid calcium, magnesium sulfate, ferrous sulfate and aluminum sulfate; Calcium sulfate, magnesium sulfate, ferrous sulfate and aluminum sulfate all have higher wettability power; Mineral intermixture with acidification carries out activation heat treatment again, has improved the moisture sorption effect of the mineral intermixture of acidification greatly.
Red bentonite originates in horse race mining area, mountain, Gui Wu town, Xuyi County, Jiangsu Province, and main component has quartz, montmorillonite, kaolinite, bloodstone and feldspar, iron oxide content >=14%; The mining area reserves have more than 1,000,000 tons; Be an opencut,, still fail the large tracts of land exploitation at present because purposes is not extensive.
The Concave-convex clay rod soil property is fine and smooth, and water imbibition is strong, and tool viscosity and plasticity help the bonding between the raw material when wet, improve the adsorption capacity and the granule strength of spherical anti-blushing agent.
High sticking Concave-convex clay rod powder is meant gets 28.0g Concave-convex clay rod powder sample; Add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer; Under 11000 rev/mins of rotating speeds, stirred 20 minutes; To pass through the high-speed stirred sample suspension again and pour in the beaker of 250ml, the viscosity of using NDJ-1 type rotation viscometer to test its suspension, the Concave-convex clay rod powder of tested viscosity value >=2200 mPas is high sticking Concave-convex clay rod powder.
Reduced iron powder can absorb airborne oxygen, and 1 gram reduced iron powder deoxygenation ability is 300mL, amounts to air 1500mL, and deaerating effect is good, reduced iron powder grain fineness≤0.42 that the present invention selects for use millimeter.
Dolomite Concave-convex clay rod, bauxite and reduced iron powder are common commodity.
The present invention is achieved through following technical proposals:
1, the batching of the moistureproof deoxidizing antistaling agent of spherical tealeaves is made up of following component by weight percentage: spherical anti-blushing agent 30~70% and reduced iron powder 30~70%;
The production method of the moistureproof deoxidizing antistaling agent of spherical tealeaves: with the batching input mixer mixing stirring of the moistureproof deoxidizing antistaling agent of spherical tealeaves, packing after stirring is spherical tealeaves protection against the tide deoxidizing antistaling agent;
The batching of said spherical anti-blushing agent is made up of following component by weight percentage: tablet 80~95% after the airing and high sticking Concave-convex clay rod powder 5~20%;
The production method of spherical anti-blushing agent: 1. the batching of spherical anti-blushing agent is added stirring mixer and mix, mix pulverize thing in the back input grinding machine, the grain fineness of powder≤0.074 millimeter; 2. powder is imported and carried out granulation in the comminutor, the particle after the granulation is spherical in shape, and spherical particle diameters is controlled at 0.5~5.0 millimeter; 3. spheric granules is imported and carried out roasting in the roaster; Sintering temperature is controlled at 280~320 ℃; Roasting time was controlled at 60~180 minutes, and spheric granules sieves after cooling off through roasting, and crushed particles that produces in the roasting process and powder are screened out; The screening back is spherical anti-blushing agent, the water content of spherical anti-blushing agent≤1.0%;
The production method of the tablet after the said airing: 1. the batching of mineral intermixture is made up of following component by weight percentage: red bentonite 25~55%, dolomite Concave-convex clay rod 20~50% and bauxite 15~40%; 2. pulverize mineral intermixture grain fineness≤0.50 after the pulverizing millimeter after the batch mixes with mineral intermixture; 3. the batching of acidification is made up of following component by weight percentage: mineral intermixture 55~75% and dilute sulfuric acid 25~45% after the pulverizing; 4. the preparation of dilute sulfuric acid is made up of following component by weight percentage: sulfuric acid 2~20% and the water 80~98% of concentration 98 ﹪; 5. dilute sulfuric acid is slowly added in the mineral intermixture after the pulverizing and carry out acidification, the mineral intermixture after the acidified processing was stacked after 24~72 hours, and extruding is tablet in the input twin rollers, the thickness of tablet≤3 millimeter; 6. tablet is transported to cement court and carries out airing, water content in the tablet after the airing≤15%.
Acidification technology of the present invention does not have discharge of wastewater, and method is simple, and is environment friendly and pollution-free.
After spherical anti-blushing agent added measuring cup, placing in the drier that fills saturated aqueous sodium chloride, is under 35 ℃ the condition in temperature, 24 hours Static Water absorption>=20%, water content≤1.5% of the moistureproof deoxidizing antistaling agent package of spherical tealeaves.
Reduced iron powder can absorb airborne oxygen; 1 gram reduced iron powder deoxygenation ability is 300mL, amounts to air 1500mL, and deaerating effect is good; This is those skilled in the art's a common practise, but uses reduced iron powder can not reach the fresh-keeping effect of moistureproof deoxidation simultaneously separately; Be packaged as after adopting in the present invention that reduced iron powder and spherical anti-blushing agent are common and pulverizing have protection against the tide, deoxidation, absorption peculiar smell and the fresh-keeping moistureproof deoxidizing antistaling agent of multifunctional sphere tealeaves.
The moistureproof deoxidizing antistaling agent of spherical tealeaves is placed in the packing container of tealeaves, and protection against the tide, deoxidation, absorption peculiar smell and fresh-keeping carried out synchronously, and tealeaves carries out deoxidation and fresh-keeping under drying regime; Can remove free oxygen and free water in the tea packaging, oxygen content is controlled at below 0.1%, and the water content of tealeaves is controlled in 6.5%; Keep tealeaves fully dry; Prevent tealeaves because oxidation and mouldy and rotten, guarantee the original flavor and the quality of tealeaves, prolong its shelf life.
After the moistureproof deoxidizing antistaling agent of spherical tealeaves used, when general garbage disposal, degradable did not have environmental pollution.
The moistureproof deoxidizing antistaling agent of spherical tealeaves is applicable in the various packing containers that are placed on tealeaves.
The specific embodiment
Below in conjunction with embodiment the present invention is done further description:
1, the batching of the moistureproof deoxidizing antistaling agent of spherical tealeaves is made up of following component by weight percentage: spherical anti-blushing agent 52% and reduced iron powder 48%;
The production method of the moistureproof deoxidizing antistaling agent of spherical tealeaves: with the batching input mixer mixing stirring of the moistureproof deoxidizing antistaling agent of spherical tealeaves, packing after stirring is spherical tealeaves protection against the tide deoxidizing antistaling agent;
The batching of said spherical anti-blushing agent is made up of following component by weight percentage: tablet 86% after the airing and high sticking Concave-convex clay rod powder 14%;
The production method of spherical anti-blushing agent: 1. the batching of spherical anti-blushing agent is added stirring mixer and mix, mix pulverize thing in the back input grinding machine, the grain fineness of powder≤0.074 millimeter; 2. powder is imported and carried out granulation in the comminutor, the particle after the granulation is spherical in shape, and spherical particle diameters is controlled at 1.5~2.0 millimeters; 3. spheric granules is imported and carried out roasting in the roaster; Sintering temperature is controlled at 300~320 ℃; Roasting time was controlled at 90 minutes, and spheric granules sieves after cooling off through roasting, and crushed particles that produces in the roasting process and powder are screened out; The screening back is spherical anti-blushing agent, the water content of spherical anti-blushing agent≤1.5%;
The production method of the tablet after the said airing: 1. the batching of mineral intermixture is made up of following component by weight percentage: red bentonite 42%, dolomite Concave-convex clay rod 32% and bauxite 26%; 2. pulverize mineral intermixture grain fineness≤0.50 after the pulverizing millimeter after the batch mixes with mineral intermixture; 3. the batching of acidification is made up of following component by weight percentage: mineral intermixture 68% and dilute sulfuric acid 32% after the pulverizing; 4. the preparation of dilute sulfuric acid is made up of following component by weight percentage: sulfuric acid 8% and the water 92% of concentration 98 ﹪; 5. dilute sulfuric acid is slowly added in the mineral intermixture after the pulverizing and carry out acidification, the mineral intermixture after the acidified processing was stacked after 48 hours, and extruding is tablet in the input twin rollers, the thickness of tablet≤1.5 millimeter; 6. tablet is transported to cement court and carries out airing, water content in the tablet after the airing≤15%.
Through on-the-spot test, spherical anti-blushing agent added measuring cup after, place in the drier that fills saturated aqueous sodium chloride, be under 35 ℃ the condition in temperature, 24 hours Static Water absorption >=22.5%.

Claims (1)

1. the moistureproof deoxidizing antistaling agent of spherical tealeaves is characterized in that the batching of the moistureproof deoxidizing antistaling agent of spherical tealeaves is made up of following component by weight percentage: spherical anti-blushing agent 30~70% and reduced iron powder 30~70%;
The production method of the moistureproof deoxidizing antistaling agent of spherical tealeaves: with the batching input mixer mixing stirring of the moistureproof deoxidizing antistaling agent of spherical tealeaves, packing after stirring is spherical tealeaves protection against the tide deoxidizing antistaling agent;
The batching of said spherical anti-blushing agent is made up of following component by weight percentage: tablet 80~95% after the airing and high sticking Concave-convex clay rod powder 5~20%;
The production method of spherical anti-blushing agent: 1. the batching of spherical anti-blushing agent is added stirring mixer and mix, mix pulverize thing in the back input grinding machine, the grain fineness of powder≤0.074 millimeter; 2. powder is imported and carried out granulation in the comminutor, the particle after the granulation is spherical in shape, and spherical particle diameters is controlled at 0.5~5.0 millimeter; 3. spheric granules is imported and carried out roasting in the roaster; Sintering temperature is controlled at 280~320 ℃; Roasting time was controlled at 60~180 minutes, and spheric granules sieves after cooling off through roasting, and crushed particles that produces in the roasting process and powder are screened out; The screening back is spherical anti-blushing agent, the water content of spherical anti-blushing agent≤1.5%;
The production method of the tablet after the said airing: 1. the batching of mineral intermixture is made up of following component by weight percentage: red bentonite 25~55%, dolomite Concave-convex clay rod 20~50% and bauxite 15~40%; 2. pulverize mineral intermixture grain fineness≤0.50 after the pulverizing millimeter after the batch mixes with mineral intermixture; 3. the batching of acidification is made up of following component by weight percentage: mineral intermixture 55~75% and dilute sulfuric acid 25~45% after the pulverizing; 4. the preparation of dilute sulfuric acid is made up of following component by weight percentage: sulfuric acid 2~20% and the water 80~98% of concentration 98 ﹪; 5. dilute sulfuric acid is slowly added in the mineral intermixture after the pulverizing and carry out acidification, the mineral intermixture after the acidified processing was stacked after 24~72 hours, and extruding is tablet in the input twin rollers, the thickness of tablet≤3 millimeter; 6. tablet is transported to cement court and carries out airing, water content in the tablet after the airing≤15%.
CN201110210534A 2011-07-26 2011-07-26 Bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization Active CN102349685B (en)

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US4936665A (en) * 1987-10-25 1990-06-26 Whitney Theodore R High resolution imagery systems and methods
US4820325A (en) * 1987-10-22 1989-04-11 Stauffer Chemical Company Treatment of toxicant-impregnated filter cake
CN1102083A (en) * 1993-10-30 1995-05-03 邢益虎 Deoxidizing antistaling agent
CN101766211A (en) * 2009-01-07 2010-07-07 蒋进军 Lychee preservative
CN101703305A (en) * 2009-10-28 2010-05-12 李秀娟 Green tea preservative

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