CN102327732B - Chlorine-free drying agent for spherical mineral - Google Patents
Chlorine-free drying agent for spherical mineral Download PDFInfo
- Publication number
- CN102327732B CN102327732B CN 201110191382 CN201110191382A CN102327732B CN 102327732 B CN102327732 B CN 102327732B CN 201110191382 CN201110191382 CN 201110191382 CN 201110191382 A CN201110191382 A CN 201110191382A CN 102327732 B CN102327732 B CN 102327732B
- Authority
- CN
- China
- Prior art keywords
- chlorine
- mineral
- drying agent
- spherical
- free drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 63
- 239000011707 mineral Substances 0.000 title claims abstract description 63
- 239000002274 desiccant Substances 0.000 title claims abstract description 39
- 239000004927 clay Substances 0.000 claims abstract description 45
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000010459 dolomite Substances 0.000 claims abstract description 22
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000440 bentonite Substances 0.000 claims abstract description 14
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 12
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 9
- 238000012216 screening Methods 0.000 claims abstract description 5
- 238000000227 grinding Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 230000020477 pH reduction Effects 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 8
- 239000000428 dust Substances 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000004568 cement Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 239000012798 spherical particle Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 7
- 229960000892 attapulgite Drugs 0.000 abstract description 6
- 229910052625 palygorskite Inorganic materials 0.000 abstract description 6
- 230000003068 static effect Effects 0.000 abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000004806 packaging method and process Methods 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 239000010985 leather Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 2
- 230000000274 adsorptive effect Effects 0.000 abstract 1
- 238000007605 air drying Methods 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 45
- 239000002253 acid Substances 0.000 description 10
- 239000002699 waste material Substances 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 235000021110 pickles Nutrition 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The invention discloses a chlorine-free drying agent for a spherical mineral. The technical scheme of the invention has key point that the chlorine-free drying agent for the spherical mineral consists of red bentonite, dolomite and attapulgite clay, bauxite, sulfuric acid, high-viscosity attapulgite clay powder and sodium aluminate. The production method of the chlorine-free drying agent for the spherical mineral comprises the following steps of: mixing the red bentonite, the dolomite and attapulgite clay and the bauxite for acidating, tabletting and air-drying, then stirring, mixing, grinding, granulating, baking and screening the mixture with the sodium aluminate and the high-viscosity attapulgite clay powder and packaging the mixture into the chlorine-free drying agent for the spherical mineral. The chlorine-free drying agent for the spherical mineral has the advantages of high static water adsorptive capacity, chlorine freedom, no toxicity or odor and no contacted corrosion or pollution to the environment. The chlorine-free drying agent for the spherical mineral is suitably placed in various small-sized packaging bags and is suitable for preventing instruments and meters, electrical appliances, electronic products, medicines, foods, textiles, leather, shoes, clothes and other various packaged articles from being mildewed due to dampness or corroded.
Description
Technical field
The present invention relates to drier, be specifically related to a kind of chlorine-free drying agent for spherical mineral.
Background technology
Mineral agent mainly contains montmorillonite drier and attapulgite drier, montmorillonite drier outward appearance is broken shape, and easily efflorescence is expanded after moisture absorption, attapulgite drier hydroscopicity can be regulated, outward appearance is spherical, but it contains chlorion, and metallic article is had the contact corrosion, existing without the chlorine drier on market, although do not add the chloride ion-containing material, Static Water is adsorbed less than 20%, lower than the standard of relevant drier.
Chinese patent Granted publication CN 100562498C, November 25 2009 Granted publication day, name is called " containing the method that the dolomite Concave-convex clay rod is processed the Industry Waste acid solution and prepared drier ", disclose and a kind ofly " contained the method that the dolomite Concave-convex clay rod is processed the Industry Waste acid solution and prepared drier, it is characterized in that the volume mass ratio by acid pickle and dolomite Concave-convex clay rod is 0.4～1L/kg, add in the acid pickle and contain dolomite Concave-convex clay rod powder, dolomite in clay and acid pickle generation neutralization reaction, after reaction is finished, mixture pH is greater than 3, control the mixture water content, moisture wet mixture obtains the Concave-convex clay rod composite drying agent through the moulding calcining, the Industry Waste acid solution comprises the activated clay production acid waste liquid, produces the acid waste liquid of active silica etc. take Concave-convex clay rod or bentonite and hydrochloric acid or sulfuric acid as raw material.The present invention not only disposal and utilization Concave-convex clay rod or bentonite processing acid waste liquid, realize wastewater zero discharge, and saved common Concave-convex clay rod drier and prepare the raw materials such as required calcium chloride, binding agent, make Concave-convex clay rod composite drying agent production cost decrease.”
Above-mentioned patent weak point is: ⑴ adds in the acid pickle merely and contains dolomite Concave-convex clay rod powder calcination and obtain the Concave-convex clay rod composite drying agent, surveys the Static Water absorption of 24 hours less than 20%; ⑵ in the Concave-convex clay rod mining area exploitation, the dolomite Concave-convex clay rod is a kind of complete mineral, dolomite and Concave-convex clay rod are the monomers of having no idea to be divided into separately, therefore, above-mentioned patent " contains the dolomite Concave-convex clay rod described, by weight percentage, contains dolomite 10～60%; Concave-convex clay rod is 40～90% ", has no idea to realize in actual production.
Summary of the invention
The objective of the invention is to overcome weak point in prior art, a kind of chlorine-free drying agent for spherical mineral is provided.
Chlorine-free drying agent for spherical mineral is comprised of red bentonite, dolomite Concave-convex clay rod, bauxite, sulfuric acid, high sticking Concave-convex clay rod powder and sodium aluminate.
The production method of chlorine-free drying agent for spherical mineral: red bentonite, dolomite Concave-convex clay rod and bauxite are mixed carry out acidification, compressing tablet and airing, mix with sodium aluminate and high sticking Concave-convex clay rod powder again, abrasive dust, granulation, roasting and screening, be packaged as chlorine-free drying agent for spherical mineral.
Iron oxide content in red bentonite 〉=14%, alundum (Al2O3) content 〉=10%; The content of calcium oxide 〉=24% in the dolomite Concave-convex clay rod, magnesian content 〉=12%; Alundum (Al2O3) content in bauxite 〉=55%, red bentonite, dolomite Concave-convex clay rod and bauxite are mixed into mineral intermixture, the sulfate mixtures such as generating portion calcium sulfate, magnesium sulfate, ferrous sulfate and aluminum sulfate after the acidified processing of mineral intermixture, calcium sulfate, magnesium sulfate, ferrous sulfate and aluminum sulfate all have higher wettability power, mineral intermixture with acidification carries out activation heat treatment again, has greatly improved the moisture sorption effect of the mineral intermixture of acidification.
Red bentonite originates in horse race mining area, mountain, Gui Wu town, Xuyi County, Jiangsu Province, and main component has quartz, montmorillonite, kaolinite, bloodstone and feldspar, iron oxide content 〉=14%, reserve has more than 1,000,000 tons, an opencut, because purposes is not extensive, at present not yet can the large tracts of land exploitation.
The Concave-convex clay rod soil property is fine and smooth, and water imbibition is strong, and when wet, tool viscosity and plasticity, be conducive to the bonding between raw material, improves adsorption capacity and the granule strength of chlorine-free drying agent for spherical mineral.
High sticking Concave-convex clay rod powder refers to get 28.0g Concave-convex clay rod powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, stirred 20 minutes under the rotating speed of 11000 rev/mins, to pour in the beaker of 250ml through the high-speed stirred sample suspension again, the viscosity of using NDJ-1 type rotation viscometer to test its suspension, the Concave-convex clay rod powder of tested viscosity value 〉=2200 mPas is high sticking Concave-convex clay rod powder.
Sodium aluminate is strong basicity, easily absorbs moisture content in air.
Dolomite Concave-convex clay rod, bauxite and sodium aluminate are common commodity.
The present invention is achieved by following technical proposals:
1, the batching of chlorine-free drying agent for spherical mineral is comprised of following component by weight percentage: the tablet 60～85% after airing, sodium aluminate 5～35% and high sticking Concave-convex clay rod powder 2～25%;
The production method of chlorine-free drying agent for spherical mineral: 1. the batching with chlorine-free drying agent for spherical mineral adds stirring mixer to mix, and mixes abrasive dust in rear input grinding machine, the grain fineness after abrasive dust≤0.074 millimeter; 2. powder is inputted and carried out granulation in comminutor, the particle after granulation is spherical in shape, and spherical particle diameters is controlled at 0.5～5.0 millimeter; 3. spheric granules is inputted and carried out roasting in roaster, sintering temperature is controlled at 280～600 ℃, roasting time is controlled at 60～180 minutes, sieve after spheric granules is cooling through roasting, the crushed particles and the powder that produce in roasting process are screened out, pack the finished product into chlorine-free drying agent for spherical mineral after screening, the water content of package≤1.5%;
The production method of the tablet after described airing: 1. mineral intermixture is comprised of red bentonite, dolomite Concave-convex clay rod and bauxite, and the batching of mineral intermixture is comprised of following component by weight percentage: red bentonite 25～55%, dolomite Concave-convex clay rod 20～50% and bauxite 15～40%; 2. pulverize the mineral intermixture grain fineness after pulverizing≤0.50 millimeter after the batching of mineral intermixture being mixed; 3. the batching of acidification is comprised of following component by weight percentage: the mineral intermixture 55～75% after pulverizing and dilute sulfuric acid 25～45%; 4. the preparation of dilute sulfuric acid is comprised of following component by weight percentage: the sulfuric acid 2～20% of concentration 98 ﹪ and water 80～98%; 5. dilute sulfuric acid is slowly added in the mineral intermixture after pulverizing and carry out acidification, the mineral intermixture of acidified processing was stacked after 24～72 hours, and in the input twin rollers, extruding is tablet, and the THICKNESS CONTROL of tablet is at 1～5 millimeter; 6. tablet is transported to cement court and carries out airing, the tablet water content after airing≤15%.
After chlorine-free drying agent for spherical mineral is added measuring cup, being placed in the drier that fills saturated aqueous sodium chloride, is under the condition of 35 ℃ in temperature, the Static Water absorption 〉=20% of 24 hours, the water content of package≤1.5%.
Acidification technique of the present invention does not have discharge of wastewater, and method is simple, and is environment friendly and pollution-free.
Chlorine-free drying agent for spherical mineral is a kind of particle of ball shape, and intensity is high, not powder falling, rate of wear≤0.3%.
Chlorine-free drying agent for spherical mineral Static Water adsorbance is large, without chlorine, nontoxic, tasteless and contactless corrosivity.
The pH value of chlorine-free drying agent for spherical mineral meets the standard of dispatching from the factory of relevant mineral agent in 4.0～8.0 scopes.
After chlorine-free drying agent for spherical mineral used a period of time, drying effect can weaken, through the sun be exposed to the sun or dry after can reuse, capable of being fast degraded when general garbage disposal after chlorine-free drying agent for spherical mineral is entirely ineffective, there is no environmental pollution.
The chlorine-free drying agent for spherical mineral production technology is simple, and production cost is low, and is of many uses, is conducive to apply.
Chlorine-free drying agent for spherical mineral should be placed in various packaging bags, is applicable to prevent that instrument and meter, electric equipment, electronic product, medicine, food, textile, leather, footwear, clothes and other various connection with wrapping of piece from making moist goes mouldy or corrosion.
The specific embodiment
The invention will be further described below in conjunction with embodiment:
The batching of chlorine-free drying agent for spherical mineral is comprised of following component by weight percentage: the tablet 74% after airing, sodium aluminate 14% and high sticking Concave-convex clay rod powder 12%;
The production method of chlorine-free drying agent for spherical mineral: 1. the batching with chlorine-free drying agent for spherical mineral adds stirring mixer to mix, and mixes abrasive dust in rear input grinding machine, the grain fineness after abrasive dust≤0.074 millimeter; 2. powder is inputted and carried out granulation in comminutor, the particle after granulation is spherical in shape, and spherical particle diameters is controlled at 1.5～2.0 millimeters; 3. spheric granules is inputted and carried out roasting in roaster, sintering temperature is controlled at 320～350 ℃, roasting time is controlled at 90 minutes, sieve after spheric granules is cooling through roasting, the crushed particles and the powder that produce in roasting process are screened out, pack the finished product into chlorine-free drying agent for spherical mineral after screening, the water content of package≤1.5%;
The production method of the tablet after described airing: 1. mineral intermixture is comprised of red bentonite, dolomite Concave-convex clay rod and bauxite, and the batching of mineral intermixture is comprised of following component by weight percentage: red bentonite 38%, dolomite Concave-convex clay rod 36% and bauxite 26%; 2. pulverize the mineral intermixture grain fineness after pulverizing≤0.50 millimeter after the batching of mineral intermixture being mixed; 3. the batching of acidification is comprised of following component by weight percentage: the mineral intermixture 70% after pulverizing and dilute sulfuric acid 30%; 4. the preparation of dilute sulfuric acid is comprised of following component by weight percentage: the sulfuric acid 8% of concentration 98 ﹪ and water 92%; 5. dilute sulfuric acid is slowly added in the mineral intermixture after pulverizing and carry out acidification, the mineral intermixture after acidified processing was stacked after 56 hours, and in the input twin rollers, extruding is tablet, and the THICKNESS CONTROL of tablet is at 2 millimeters; 6. tablet is transported to cement court and carries out airing, water content in the tablet after airing≤15%.
On-the-spot test result: after chlorine-free drying agent for spherical mineral is added measuring cup, be placed in the drier that fills saturated aqueous sodium chloride, be under the condition of 35 ℃ in temperature, the Static Water absorption 〉=23% of 24 hours, the water content of package≤1.4% reaches the relevant standard of GB/T 10504-2008.
Claims (1)
1. a chlorine-free drying agent for spherical mineral, is characterized in that, the batching of chlorine-free drying agent for spherical mineral is comprised of following component by weight percentage: the tablet 60～85% after airing, sodium aluminate 5～35% and high sticking Concave-convex clay rod powder 2～25%;
The production method of chlorine-free drying agent for spherical mineral: 1. the batching with chlorine-free drying agent for spherical mineral adds stirring mixer to mix, and mixes abrasive dust in rear input grinding machine, the grain fineness after abrasive dust≤0.074 millimeter; 2. powder is inputted and carried out granulation in comminutor, the particle after granulation is spherical in shape, and spherical particle diameters is controlled at 0.5～5.0 millimeter; 3. spheric granules is inputted and carried out roasting in roaster, sintering temperature is controlled at 280～600 ℃, roasting time is controlled at 60～180 minutes, sieve after spheric granules is cooling through roasting, the crushed particles and the powder that produce in roasting process are screened out, pack the finished product into chlorine-free drying agent for spherical mineral after screening, the water content of finished product≤1.5%;
The production method of the tablet after described airing: 1. the batching of mineral intermixture is comprised of following component by weight percentage: red bentonite 25～55%, dolomite Concave-convex clay rod 20～50% and bauxite 15～40%; 2. pulverize the mineral intermixture grain fineness after pulverizing≤0.50 millimeter after the batching of mineral intermixture being mixed; 3. the batching of acidification is comprised of following component by weight percentage: the mineral intermixture 55～75% after pulverizing and dilute sulfuric acid 25～45%; 4. the preparation of dilute sulfuric acid is comprised of following component by weight percentage: the sulfuric acid 2～20% of concentration 98 ﹪ and water 80～98%; 5. dilute sulfuric acid is slowly added in the mineral intermixture after pulverizing and carry out acidification, the mineral intermixture of acidified processing was stacked after 24～72 hours, and in the input twin rollers, extruding is tablet, and the THICKNESS CONTROL of tablet is at 1～5 millimeter; 6. tablet is transported to cement court and carries out airing, water content in the tablet after airing≤15%;
The sticking Concave-convex clay rod powder of described height refers to get 28.0g Concave-convex clay rod powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, stirred 20 minutes under the rotating speed of 11000 rev/mins, to pour in the beaker of 250ml through the high-speed stirred sample suspension again the viscosity of using NDJ-1 type rotation viscometer to test its suspension, the Concave-convex clay rod powder of tested viscosity value 〉=2200 mPas into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110191382 CN102327732B (en) | 2011-07-10 | 2011-07-10 | Chlorine-free drying agent for spherical mineral |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110191382 CN102327732B (en) | 2011-07-10 | 2011-07-10 | Chlorine-free drying agent for spherical mineral |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102327732A CN102327732A (en) | 2012-01-25 |
| CN102327732B true CN102327732B (en) | 2013-06-19 |
Family
ID=45479851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110191382 Active CN102327732B (en) | 2011-07-10 | 2011-07-10 | Chlorine-free drying agent for spherical mineral |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102327732B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726104B (en) * | 2015-03-27 | 2018-04-13 | 盱眙欧佰特粘土材料有限公司 | The preparation method of heavy-metal contaminated soil improvement modified mineral composition |
| CN111635205A (en) * | 2020-06-03 | 2020-09-08 | 承德人和矿业有限责任公司 | Preparation method of illite composite material based desiccant and desiccant |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1164350C (en) * | 2001-12-06 | 2004-09-01 | 吴才来 | Mineral drying agent |
| US20030197305A1 (en) * | 2002-04-23 | 2003-10-23 | Mike Collins | Method of using clays to form absorbent materials |
| CN1219594C (en) * | 2003-10-28 | 2005-09-21 | 许盛英 | Natural desiccant and producing process thereof |
| CN100562498C (en) * | 2007-12-06 | 2009-11-25 | 合肥工业大学 | Contain the method that the rhombspar attapulgite clay is handled industrial waste acid liquid and prepared siccative |
-
2011
- 2011-07-10 CN CN 201110191382 patent/CN102327732B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102327732A (en) | 2012-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103880558A (en) | Salt-resistant soil-improving slow release fertilizer and preparation method thereof | |
| CN102327734B (en) | Drying agent for ball-shaped container | |
| CN102327731B (en) | Granular mineral chlorine-free drying agent | |
| CN102327732B (en) | Chlorine-free drying agent for spherical mineral | |
| CN102327733B (en) | Chlorine-free drying agent for strip mineral | |
| CN105339326B (en) | Process for producing pellets containing potassium chloride and magnesium sulfate hydrate | |
| CN105062500A (en) | Acid soil conditioner and preparation method thereof | |
| CN102327730B (en) | Chlorine-free drying agent for powdery mineral | |
| CN102327729B (en) | Drying agent for bar-shaped container | |
| KR910009598B1 (en) | Granular potassium sulfate and its production | |
| CN102294221A (en) | Preparation method of attapulgite-based adsorption drying agent suitable for high humidity environment | |
| CN102690143A (en) | Method for producing granular potassium chloride | |
| CN109956823A (en) | A kind of production method of potassium sulfate fertilizers particle | |
| CN103331081A (en) | Drying agent for air separation oxygen production and preparation method | |
| JP2013018684A (en) | Method for producing granular potassium chloride | |
| CN102327763B (en) | Spherical dehydrating agent for alcohol group sterilization preservation solution | |
| CN102326738B (en) | Spherical mildewproof and deoxidation antistaling agent for instant noodles | |
| CN102349685B (en) | Bulbous tea leaves antistaling agent with functions of moisture protection and deoxidization | |
| CN102327766B (en) | Bar-type alcohol group sterilization fresh-keeping liquid dehydrating agent | |
| KR20010099094A (en) | Manufacturing process of granule multinutrient fertilizer using crushed waste shells | |
| CN102326739B (en) | Granular mildew-proofing and deoxidizing preservative for instant noodles | |
| JPH0375287A (en) | Porous siliceous granule | |
| CN106552599A (en) | A kind of active mineral drier | |
| CN102326618B (en) | Spheroidal sausage mould-proof deoxy antistaling agent | |
| CN102326820B (en) | Granular tea moisture-proof deoxidizing and refreshing agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGSU ZHONGXIN RESOURCES GROUP CO., LTD. Free format text: FORMER OWNER: XU SHENGYING Effective date: 20131018 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 211700 HUAIAN, JIANGSU PROVINCE TO: 226300 NANTONG, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20131018 Address after: 226300 Industrial Park, Xianfeng Town, Nantong, Jiangsu, Tongzhou District Patentee after: Jiangsu ZhongXin Resources Group Co., Ltd. Address before: 211700 Huaian City, Jiangsu province Xuyi County Xu town Jin Yuan Road No. 22-1 Building 2 room 205 Patentee before: Xu Shengying |