Background technology
Electrolytic manganese residues is with residual solid waste behind the sulfuric acid solution processing manganese spar production manganese metal, the very high concentrations of sulfate, ammonia nitrogen, manganese.The electrolytic manganese residues discharge value is bigger, and 1 ton of manganese of every production will produce 6~10 tons of manganese slags.At present, the existing electrolytic manganese residues more than 5,000 ten thousand tons of China, and increasing with annual more than 1,000 ten thousand tons amount.Stacking to electrolytic manganese residues is disposed, and has strengthened entreprise cost, and consumes land resources, because long-term the stacking causes some harmful elements to penetrate into the face of land and underground water, causes environment pollution.The mineralogical composition of electrolytic manganese residues is quartzy, aquation dicalcium silicate and gypsum etc., and the radioactivity of electrolytic manganese residues is detected, and its internal radiation exponential sum external exposure index is respectively 0.2 and 0.3, all less than 1.0, thereby can be used as construction main body material.Yet, in the prior art, because technology limitation seldom adopts the raw material of electrolytic manganese residues as building block.Therefore existing building block manufacturing technology exists and can not utilize the shortcoming of electrolytic manganese residues as constructional materials well, and existing building block, particularly building-block also exist the less-than-ideal problem of heat insulation effect.
Summary of the invention
The objective of the invention is: provide a kind of and can utilize effectively that electrolytic manganese residues and manufacture craft product coefficient of thermal conductivity simple, that produce is little, the foamed plastics of high insulating effect and electrolytic manganese residues composite heat insulation block and preparation method thereof, thereby overcome the deficiency of prior art.
The present invention is achieved in that a kind of foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block are: this foamed plastics and electrolytic manganese residues composite heat insulation block are made up of electrolytic manganese residues building-block and foam plastics core, in the hollow part of electrolytic manganese residues building-block, are filled with foam plastics core.
The preparation method of a kind of foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block is: the composite material for preparing earlier the electrolytic manganese residues building-block as follows; Getting 20~40 parts of electrolytic manganese residues, 10~30 parts of cement, 20~50 parts of sands, 0.5~1.8 part of quicklime, 0.1~0.5 part in gypsum by weight ratio, is water with each raw material by ratio of water to material: material=0.45~0.85 amount adds entry promptly makes the composite material of electrolytic manganese residues building-block after mixing; The mode that this composite material by adopting mould is built is produced the electrolytic manganese residues building-block; Foam plastics core can make foamed plastics and electrolytic manganese residues composite heat insulation block to adopt the mode of mode or the moulding by casting of mechanical presses in electrolytic manganese residues building-block hollow, to fill completely.
When the mode that adopts mechanical presses is filled completely foam plastics core in electrolytic manganese residues building-block hollow; The mode that the composite material by adopting mould is built is produced the electrolytic manganese residues building-block earlier; Adopt XPS polystyrene foam plate, EPS polystyrene foam plate or polyurethane foam plastics plate to produce foam plastics core then, the mode through mechanical presses is with the foam plastics core extruding and fill up hollow part in the electrolytic manganese residues building-block afterwards.
When the mode that adopts moulding by casting is filled completely foam plastics core in electrolytic manganese residues building-block hollow; According to the hollow shape of the electrolytic manganese residues building-block that will make; Adopt XPS polystyrene foam plate, EPS polystyrene foam plate or polyurethane foam plastics plate to produce the shape foam plastics core identical earlier with the hollow shape of electrolytic manganese residues building-block; Then this foam plastics core is put into the mould of building the electrolytic manganese residues building-block; The composite that is prepared into is poured into a mould into this mould; And composite is wrapped foam plastics core and, can make foamed plastics and electrolytic manganese residues composite heat insulation block like this in die for molding by the mode of vibration.
When the mode that adopts moulding by casting is filled completely foam plastics core in electrolytic manganese residues building-block hollow; Also the mode that can earlier the composite material by adopting mould be built is produced the electrolytic manganese residues building-block; Adopting polystyrene foam plastics or polyurethane foam plastics then is foam materials; Foam materials is poured into a mould in electrolytic manganese residues building-block into hollow; Making its hollow part foaming at the electrolytic manganese residues building-block is foam plastics core, can make foamed plastics and electrolytic manganese residues composite heat insulation block like this.
When the mode that adopts moulding by casting is filled completely foam plastics core in electrolytic manganese residues building-block hollow; Also the mode that can earlier the composite material by adopting mould be built is produced the electrolytic manganese residues building-block; Make foamed plastics cement mortar mixed material after adopting polystyrene foam plastics or polyurethane foam plastics then and cement and water mixing; The foamed plastics cement mortar mixed material that makes is poured into a mould in electrolytic manganese residues building-block into hollow; Making its hollow part foaming at the electrolytic manganese residues building-block is foam plastics core, can make foamed plastics and electrolytic manganese residues composite heat insulation block like this.
Above-mentioned foamed plastics cement paste mixed material proportioning by weight is 80~90 parts of polystyrene foam plasticss, 15~20 parts of cement, 40~70 parts in water; Or 80~90 parts of polyurethane foam plastics, 15~20 parts of cement, 40~70 parts in water.
Owing to adopted technique scheme; It is that feedstock production goes out the electrolytic manganese residues building-block that the present invention has effectively utilized electrolytic manganese residues; And filled this cheap and good-quality heat preserving and insulating material of foamed plastics compound in its hollow part; Because foamed plastics is the plastic products that process on the basis, inside has countless apertures with synthetic resin; It is low that it has a coefficient of thermal conductivity, is prone to advantages such as machine-shaping.Polystyrene foam plastics and polyurethane foam plastics are at present commonly used, heat-insulating property heat insulating materials preferably.Polystyrene foam plastics is to be primary raw material with the polystyrene resin, and the inside of processing through the blowing agent foaming has the material of countless closed porosities; Polystyrol plastic foam plate is a kind of plastic foamboard that is made up of the cellular polyhedron of complete closed, by the expandable polystyrene bead that contains the volatile liquid blowing agent, after heating is sent out in advance, in die for molding, has the design feature of fine closed pore.Polyurethane foam plastics is to be processed through the polymerization foaming by isocyanates and hydroxy compounds, and the reaction of isocyanates and polyalcohol produces great amount of heat, and the temperature of reaction system raises, and impels the blowing agent volatilization, and foam expands and solidifies.Polystyrene foam plastics and polyurethane foam plastics have all that apparent density is little, and coefficient of thermal conductivity is little, and water absorption rate is low, and sound insulation value is good, and mechanical strength is high, characteristics such as even structure.The present invention is a load-bearing material with the electrolytic manganese residues building-block; Make it have load-bearing and thermal insulation dual-use function in the hollow part syntactic foam; Through evidence, the intensity of foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block is 3~20MPa, and unit weight is 1000~1700kg/m
3, reached the index of national regulation fully.
Technical scheme of the present invention; It utilizes the amount of electrolytic manganese residues can reach 20%~40%; Problems such as environment pollution that this industrial solid castoff of electrolytic manganese residues brings, land resources waste had both been helped solving; Can pass through syntactic foam again; Give this NEW TYPE OF COMPOSITE building material product heat insulation, heat-insulating property, make it really satisfy the needs of green, low-carbon (LC), energy-saving and environmental protection.Therefore; The present invention compared with prior art; The present invention not only has the advantage of can be effectively and utilizing electrolytic manganese residues in a large number, reducing environment pollution, reduce the wasting of resources, turn waste into wealth, but also have that manufacture craft is simple, advantages such as low preparation cost, the product coefficient of thermal conductivity produced are little, high insulating effect.Of the present invention applying must make total energy-conservation being greatly improved of building.
The specific embodiment
The present invention is further illustrated below in conjunction with accompanying drawing and embodiment.
Embodiment 1: the structure of foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block as shown in Figure 1; This foamed plastics and electrolytic manganese residues composite heat insulation block are made up of electrolytic manganese residues building-block 1 and foam plastics core 2, in the hollow part of electrolytic manganese residues building-block 1, are filled with foam plastics core 2; During making; Prepare earlier the composite material of electrolytic manganese residues building-block 1 as follows; Getting 20~40 parts of electrolytic manganese residues, 10~30 parts of cement, 20~50 parts of sands, 0.5~1.8 part of quicklime, 0.1~0.5 part in gypsum by weight ratio, is water with each raw material by ratio of water to material: material=0.45~0.85 amount adds entry promptly makes the composite material of electrolytic manganese residues building-block 1 after mixing; The mode that this composite material by adopting traditional moulds is built is produced electrolytic manganese residues building-block 1; Directly adopt existing XPS polystyrene foam plate, EPS polystyrene foam plate or polyurethane foam plastics plate to produce foam plastics core 2 then, the mode of foam plastics core 2 through mechanical presses squeezed into and fill up to make foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block in the hollow part in the electrolytic manganese residues building-block 1.
Embodiment 2: the composite of producing electrolytic manganese residues building-block 1 according to the mode of embodiment 1 earlier; Then according to the hollow shape of the electrolytic manganese residues building-block 1 that will make; Adopt XPS polystyrene foam plate, EPS polystyrene foam plate or polyurethane foam plastics plate to produce the shape foam plastics core 2 identical earlier with the hollow shape of electrolytic manganese residues building-block 1; The foam plastics core 2 of this moulding is put into the mould of building electrolytic manganese residues building-block 1; Then the composite of the electrolytic manganese residues building-block 1 that is prepared into is poured into a mould into this mould; And the mode by tradition vibration makes composite that foam plastics core 2 is wrapped and after die for molding, can make foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block like this.
Embodiment 3: the composite of producing electrolytic manganese residues building-block 1 according to the mode of embodiment 1; The mode that this composite material by adopting traditional moulds is built is produced electrolytic manganese residues building-block 1; Adopting existing polystyrene foam plastics or polyurethane foam plastics then is foam materials; This foam materials is poured into a mould in electrolytic manganese residues building-block 1 into hollow by traditional pouring type; Making its hollow part foaming at electrolytic manganese residues building-block 1 is foam plastics core 2, can make foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block like this.
Embodiment 4: the composite material of producing electrolytic manganese residues building-block 1 according to the mode of embodiment 1; The mode that this composite material by adopting mould is built is produced electrolytic manganese residues building-block 1; Make foamed plastics cement paste mixed material after adopting polystyrene foam plastics or polyurethane foam plastics then and cement and water mixing; This foamed plastics cement paste mixed material proportioning by weight is: 80~90 parts of polystyrene foam plasticss, 15~20 parts of cement, 40~70 parts in water, or 80~90 parts of polyurethane foam plastics, 15~20 parts of cement, 40~70 parts in water; The foamed plastics cement paste mixed material that makes is poured into a mould in electrolytic manganese residues building-block 1 into hollow; Making its hollow part foaming at electrolytic manganese residues building-block 1 is foam plastics core 2, can make foamed plastics of the present invention and electrolytic manganese residues composite heat insulation block like this.