CN102333853A - Compositions for laundering and subsequently drying delicate garments without incurring any damage and methods to use them - Google Patents

Compositions for laundering and subsequently drying delicate garments without incurring any damage and methods to use them Download PDF

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Publication number
CN102333853A
CN102333853A CN2009801574091A CN200980157409A CN102333853A CN 102333853 A CN102333853 A CN 102333853A CN 2009801574091 A CN2009801574091 A CN 2009801574091A CN 200980157409 A CN200980157409 A CN 200980157409A CN 102333853 A CN102333853 A CN 102333853A
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compsn
volume
described method
cleaning
exists
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法瑞波兹·德乌迪安
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/16—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40—Specific cleaning or washing processes
    • C11D2111/44—Multi-step processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)
  • Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)

Abstract

The present invention relates to compositions and methods for wet-cleaning, in professional or household washing machine equipment, and subsequent drying in a tumbler dryer, of garments made of protein-fibers (animal based fibers) such as wool, cashmere, silk and other sensitive fibers. Using water and certain additives instead of organic solvents, these compositions enable the cleaning, including oil stains removal, and subsequent drying without incurring dimensional changes, shrinkage, surface damages, dye or color loss of dry clean only labeled garments or other delicate garments labeled for special care.

Description

Be used to wash and subsequent drying rapid wear clothing and do not cause the compoistion and method of use of any damage
Background technology
The present invention relates to compsn and method; Be used for wash (comprise and remove oil stain) to the sensitive garment processed by water sensitive protein fibre (like wool, cashmere (cashmere) or silk) and other fabrics; And the drying in tumbler dryer subsequently, do not cause virtually any size change, surface fracture and dyestuff or colour loss simultaneously.Said compoistion and method of use can be applicable to specialty or household cleaning process.
Sensitive garment can use washing of specialty or dry-cleaning method with other fabrics or the modern household washing plant washs in many ways and drying.When the sensitive articles that comprises the clothing processed by hair, silk, Zantrel, animal wool, animal skin and blended material and fabric washed in water, they had the tendency of shrink.For fear of the shrink that washing is caused, many this type sensitive garment and fabric are dry-cleaned usually.
Dry-cleaning
Through definition, term " dry-cleaning " has been used to describe the method for using the non-aqueous solvent cleaning fabric.Dry-cleaning is a kind of ancient technology of finding in mid-term in 19th century at first, finds to use solvent based on oil to remove grease, wax and the oil-dirt on the yarn fabric at that time.The record the earliest of solvent cleaned is the United Kingdom of Great Britain and Northern Ireland in the sixties in 19th century, and it uses gasoline and kerosene as the initial solvent that uses.
Chlorinated solvent is introduced behind the World War I; Since middle 1930s, the most widely used solution is zellon, also claims tetrachloroethylene, and it has stable, nonflammable and has than advantages such as aqueous solvent better cleaning abilities aspect the removal oil-dirt.Since then, meeting glassware for drinking water has the most of fabric of tendency that shrinks, or thinks its too costliness or rapid wear and the fabric that can not wash is all dry-cleaned.
Though tetrachloroethylene is superior to by its substituted non-aqueous solvent, it also has some shortcomings.Particularly, tetrachloroethylene is a kind of air and groundwater pollutant (be listed in the clean air bill as pollutent by Environmental Protection Agency, and be declared as noxious chemical in 1991 by the California) of danger by identification; It also is considered to relevant with kidney disease with industrial neural system, serious skin irritation, liver always, and is classified as possible carcinogens in nineteen ninety-five by international cancer research institution (IARC).Recent research shows that the potential carcinogenesis of tetrachloroethylene is not limited in the people of industrial worker or operation dry-cleaning process; Some Commerical dryclean persons use so that a large amount of tetrachloroethylenes comes cleaning clothes, to such an extent as to thereby the clients that put on the clothing of firm dry-cleaning can suck the tetrachloroethylene of capacity makes risk of cancer slightly increase.Tetrachloroethylene will become illegal in 2023 in the California.
Because this hazard property of tetrachloroethylene uses its process in commercial undertaking, to accomplish.Traditional dry-cleaning process comprises cycles of washing and a plurality of filtration step that reclaims a part of solvent through the filtering unit that contains still pot and condensing surface that uses solution.Distilled solvent reclaims in dehydration (extraction) and dry recycle process.Dry-cleaning can produce the poisonous residual waste that must regularly be removed by the operator, like solid-state waste sludge, still contain the velveteen and the cartridge filter of trace solvent.Dry-clean peculiar other risks and also comprise the leakage of solvent and the leakage of the refrigerant gas that damages the ozone layer.
In recent years, industry has begun to adopt the hypotoxicity surrogate of tetrachloroethylene, comprises that hydro carbons is (available from the EcoSolv of CPChem TMDry-clean liquid) and glycol ether (glycol ether).A kind of glycol ether---dipropylene glycol positive propyl ether (DPnP) be used in combination as gathering sulfonic acid with other components (US 6,086,634; US 6,036, and 727).The another kind of tetrachloroethylene declares that eco-friendly surrogate can be available from GreenEarth.Use annular siloxane and optional glycol ether to clean (US 6,042,617 with US 6,063,135).Though siloxanes has lower toxicity, it has relatively low cleaning capacity, and therefore preferably avoids the use of siloxanes.Other glycol ethers have been recommended to be used for dry-cleaning, be more especially glycol tertiary butyl ether (PTB), propylene glycol n-butyl ether (PNB), dipropylene glycol uncle butyl ether (DPTB) and dipropylene glycol n-butyl ether (DPNB) (US 5,888,250; US 6,156, and 074; US 6,273,919 with US 6,350,287, available from Rynex Holdings Ltd.).In dry-cleaning, use the glycol ether representative to march toward and replace an important step of tetrachloroethylene, but still continuation need better tetrachloroethylene surrogate in the industry.
Compare with washing, have some limitations and/or shortcoming based on the dry-cleaning method of solvent:
Though the dry-cleaning method based on solvent is very effective for removing greasy filth and oil stain, it is not best for removing particulate (as clayey soil or water-soluble spot such as sugar---it extensively is present in many nectars and the soda pop); Thereby it also can require special treatment condition to remove protein-based spot.
Traditional dry-cleaning comprises the energy-intensive method, and it is than the energy of traditional the washing consumption of Duoing about 40%; And when the clothing of the same poundage of cleaning, the dry-cleaning process can consume more water.
In addition, and wash apparatus in comparison, dry-cleaning equipment is more capital intensive method.It also is being disadvantageous aspect running cost contrast, especially in the following areas: the higher repair and maintenance expense that solvent mud and strainer remove requirement, bring because of higher technical complexity, and higher energy and water consumption.
Wash
Wash the alternative method of the nontoxic and environmental protection that is dry-cleaning, use washing machine, biodegradable soap and the amendment of computer control, and the ironing equipment (pressing equipment) that is specifically designed to multiple different fabric and fiber type.Modern times wash technology by Miele in the early development nineties of 20th century, comprise with water to replace organic solvent and make solvent.Make water following advantage arranged as solvent:
About 98% of-all spots are water miscible, or can be taken away by water.
-water can clean nearly all fabric and leather, except some has the fabric of water-soluble coating.
The cleaning quality of-water is superior to any conventional solvent, and it is through removing spot but not the diffusion spot.
Specialty washes the method that washes in the operation, with washing clothes in the modern household washing machine be similarly, but under controling environment for speed, temperature and water capacity.The specially designed equipment of specialty washing manipulation require, as wash machine and clothes-drying machine.
Compare with dry-cleaning, because lower technical complexity, so specialty washes equipment operation and maintenance more easily; Because most of spots all are water miscible, so also need quite few preparatory decontamination to handle (pre-spotting).
Yet, wash process need and before cleaning, carry out more classification in advance, because need carry out more rapid wear cleaning; And also need the long slightly deadline.
Even the quality that washes is existing the improvement since the nineties in 20th century is early stage, the modern times wash compsn and method still causes the breakage to clothing, as change the breakage of the form of (as shrinking) with colour loss and size.
In traditional washing methods based on water, size changes and colour loss is because water infiltrates through the fiber hole, and the entering pressure that the water evaporation produces in cylinder in drying process causes the damage to protein fibre.
Therefore, for fear of or reduce potential shrink effect, cleaning is under low water temperature, to carry out, its cleaning effect is very poor, especially causes removing oil stain and oil soluble spot.
Proposed some prior art systems and be used for washing the dress material of common dry-cleaning:
US 5,634, and 947 disclose a kind of system that washes, and its use accounts for the propylene glycol monomethyl ether solvent of volume of water 4%-50%.
WO 98/56975 has instructed a kind of anti-dehydrating agent, and its terpenes and phenol that comprises at least a organic acid and plant origin is as its active principle.Except that other components of trace, listed acetate and methyl cyclopentenyl ketone (cyclotene), 2-cyclopentenone, p-cresol, meta-cresol, ortho-cresol, furfuryl alcohol (furfural alcohol) and the methyl catechol (guaiacol) in the organic acid together.The consumption of said anti-dehydrating agent is per 100 parts of conventional water 0.01-0.05 parts by volume.
At US 6; 139; Proposed in 587 a kind ofly to be used to wash the rapid wear clothing and to have compsn and the method that minimum wrinkling, shrink or color are damaged simultaneously, the method for its use is included under the specified conditions that need 5 different steps clothing is soaked in certain type the aqueous solution that contains tensio-active agent.
Yet after this washed process, clothing hung dry yesterday usually in air.Then, be softening glued together usually and produce the fiber on " coarse " surface, subsequently with clothing with the cold commentaries on classics of cylinder (tumbled cold).For fear of this coarse, wash the worker and in washing the last rinse cycle of round-robin, add cats product (softening agent) usually, avoid cohering thereby apply said clothing; Perhaps the exsiccant clothing is put in the clothes-drying machine and makes its softness with mechanical means.
Family expenses
CA 2,531, proposed the problem of the washing methods of rapid wear clothing in the conventional domestic washing machine in 324.Use the method for washing in the conventional washing machine much more more convenient and cheap than any other washing methods in fact, but when being applied to clothing large-scale rapid wear or that only can dry-clean, can produce unacceptable result.CA 2,531, and 324 system has been used wearing and tearing and the pressure of a kind of flexible polymer wrapping container to avoid the major injury clothing.
The family expenses cleaning product that can buy special preparation washs sensitive garment.Yet, wash similarly with the modern times, this still need be with the clothing hang airing, and this still causes cohering of fiber usually and cause coarse clothing surface.The use softening agent can cause residual and stay " oily " quality.
Traditionally, because the shortage method can not make all cleanings and in similar time range, accomplishing in water of all clothings with technology, wash operation and can not compete with dry-cleaning.
As stated; For following aspect obviously exist continue and the continuous demand of development: develop that simple water-based is washed and starched compsn and method cleans delicate fabrics, and at effective removal spot and earth and avoid reaching between fabric damage, dimensional change and the colour loss a suitable balance.
An object of the present invention is to avoid to dry-clean and wash the relevant known disadvantages of method of substitution with the typical case of sensitive garment; And propose effective and simple solution and be used for washing of specialty or housed device and drying, and do not have virtually any size change, shrink, surface fracture, dyestuff or colour loss.
Summary of the invention
Target of the present invention is to propose to be used for washing and exsiccant method and relevant compsn of all types of rapid wear clothings; Spot on the rapid wear clothing that allows effective removal to be inappropriate for usually to wash (comprise and remove greasy dirt) can not cause size change, shrink, surface fracture, dyestuff or colour loss simultaneously.Compsn of the present invention and method can be used in the washing plant and drum drying equipment of specialty or family expenses.
Through with protein fibre spreading supercoat, lax and softening momently, the clothing of all kinds fiber all can with based on the similar mode use solution washing of the dry-cleaning method of non-polar organic solvent with dry and can damaged fiber.
The present invention proposes to solve the cleaning of sensitive garment with dry and do not cause damage through a kind of method; Said method uses at least one main washing step that relates to the cleaning composition of describing among the present invention and optional two to relate to the preconditioned compsn described respectively among the present invention and/or the rinse step of care composition.
The compsn that allows to be used for the embodiment of the present invention method details as follows:
Hydrocerol A that said cleaning composition comprises SULPHOSUCCINIC ACID ESTER that the volume of the mixture of the non-anion surface activity component that the volume of the mixture of the anion surface activity component that the volume of alcohol that the volume of water, a kind of 5%-40% with said compsn TV exists, a kind of 4%-60% with said compsn TV exists, a kind of 4%-40% with said compsn TV exists, a kind of 4%-30% with said compsn TV exists, exist with the volume of the 0.1%-4% of said compsn TV and soluble salt thereof, the phosphoric acid that exists with the volume of the 0.1%-5% of said compsn TV and soluble salt thereof, the acetate and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV, and the organic amine that exists of the volume of a kind of 0.1%-4% with said compsn TV.
The pH value of said preconditioned compsn is adjusted in the 4-6 scope; The alcohol that its volume that comprises water, a kind of 5%-40% with said compsn TV exists, the SULPHOSUCCINIC ACID ESTER that exists with the volume of the 4%-30% of said compsn TV, the Hydrocerol A that exists with the volume of the 0.01%-5% of said compsn TV and soluble salt thereof, the phosphoric acid and the soluble salt thereof that exist than the volume of 1%-20% with said compsn TV, and the acetate and the soluble salt thereof that exist with the volume of the 0.01%-5% of said compsn TV.
The tripropylene glycol that said care composition comprises water, exists with the volume of the 0.1%-4% of said compsn TV, and the vinylformic acid fluoroalkyl ester copolymer that exists of the volume of a kind of 2%-15% with said compsn TV.
About washing and the preconditioned compsn:
Alcohol in the said compsn of-entering is selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4.
-SULPHOSUCCINIC ACID ESTER is selected from has alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.
-Citrate trianion is sodium salt, sylvite or ammonium salt or its mixture of Hydrocerol A.
-phosphoric acid salt is sodium salt, sylvite or ammonium salt or its mixture of phosphoric acid.
-acetate is sodium salt, sylvite or ammonium salt or its mixture of acetate.
About cleaning composition:
The mixture of-said AS is made up of the sec.-propyl amine salt of LABS mixture, and wherein said alkyl group comprises 7-14 carbon atom.The Phenylsulfonic acid that said linear alkylbenzene sulfonate had of about 19%-25% is on 2 of said alkyl group.
The mixture of-said non-AS is made up of nonionic primary alconol alcoxylates, and its middle-and-high-ranking straight chain primary alcohol accounts for 75%-85%, and comprises the even number that is lower than 20 and the carbochain of odd number carbon atom.Nonionic primary alconol alcoxylates is preferably the ethoxylated alcohol of the carbochain of a kind of 8-18 of having carbon atom.
-organic amine is selected from diethylolamine, trolamine or its mixture.
About said care composition:
-said vinylformic acid fluoroalkyl ester copolymer is by fluorinated monomer, contains monomeric vinylformic acid, and the calcium salt of vinylformic acid or styrene sulfonic acid, magnesium salts, ammonium salt are formed.
As stated, the present invention relates to a kind ofly be used to clean and dry method by the clothing of processing through the fabric of conventional cleaning/drying operation meeting damaged.Said method comprising the steps of: at least one is the washing step of the said clothing of washing in certain type the washing compsn that contains additive under given conditions, and optional two contain respectively special additive with the water-based preconditioned compsn that uses under given conditions and/or water-based care composition in the step of rinsing clothes.According to the needs that use these different waterborne compositions, be concrete draining, dehydration and the drying step that details hereinafter after the above-mentioned steps.The inventive method designed to be used the washing machine and drier or the washer/dryer of domestic type or professional type.
In first aspect, method of the present invention is suitable in having wool round-robin domestic type washing machine and drier or washer/dryer cleaning and dry sensitive garment and do not cause damage in tumble drier.In this first aspect, method of the present invention is characterised in that, in cleaning composition of the present invention, washs said clothing continuously, with the humidity in its roll-drying to the 10%-15% scope.Through flatiron or static dry all residual moistures of removing in the said clothing.
In second aspect, method of the present invention is suitable in commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer cleaning and dry sensitive garment and do not cause damage in tumble drier.In this second aspect; Method of the present invention is characterised in that; In cleaning composition of the present invention, wash said clothing continuously, the said clothing of rinsing in care composition of the present invention is with the humidity in its roll-drying to the 8%-10% scope.Through flatiron or static dry all residual moistures of removing in the said clothing.
In the third aspect, method of the present invention be suitable in the commercial Wet cleaning washing machine with water cycle ability and clothes-drying machine or washer/dryer cleaning and in tumble drier dry all kinds sensitive garment and do not cause damage.In this third aspect; Method of the present invention is characterised in that; In cleaning composition of the present invention, wash said clothing continuously; The said clothing of rinsing in preconditioned compsn of the present invention, and in the step in the end with the said clothing of care composition rinsing of the present invention, with its complete roll-drying or be dried to needed humidity.
Embodiment
In traditional washing process based on water, size changes or colour loss is because water infiltrates through the hole of fiber, and the entering pressure that the water evaporation produces in cylinder in drying process causes the damage to protein fibre.Through protein fibre temporarily being applied supercoat, lax and softening; The clothing of all kinds fiber can with based on the similar mode use solution washing of the dry-cleaning method of non-polar organic solvent with dry and can not cause damage to fiber, the effectiveness of method is washed in its increase.
Target of the present invention is to propose to be used for washing and exsiccant method and relevant compsn of all types rapid wear clothing; Spot on the rapid wear clothing that allows effective removal to be inappropriate for usually to wash (comprise and remove greasy dirt) can not cause size change, shrink, surface fracture, dyestuff or colour loss simultaneously.
Rapid wear or sensitive garment are meant responsive protein fibre especially, like wool, cashmere and silk, and the fabric that also useful hair, silk, Zantrel, animal wool, animal skin and blended material are processed, and other are labeled as the rapid wear clothing of particular care.
Cleaning among this paper or washing refer to earth and the spot of removing on the fabric.The dirt kind that is present in the fabric can be subdivided into water-soluble dirt and water-insoluble dirt, but but water-insoluble dirt partly form by soil suspension or emulsification dirt.Water-soluble dirt comprises, for example sugar, acid, salt and urea; Water-insoluble dirt comprises, for example sand, clay, protein, fat, oils, cigarette ash, dyestuff and mikrobe.Comprise with the emulsification dirt but can suspend, especially protein, starch, food, fat, oils and blood ingredient.Cleaning among this paper or washing also mean removes smell and cigarette, also has to burn and repairs.
Among this paper, shrinking is meant reducing at one or two different size of testing clothing.Particularly, woolen pants and woollen sweater are selected as the test clothing, are used for testing and compare with method and composition of the present invention, the shrink that the different cleaning method of use different cleaning compsn causes.These two different sizes be before each cycle of treatment be placed on the hard plane afterwards and pave with hand after measure.When using woolen pants as the test clothing, the size of reference is extremely to sit from the bottom of s trouser leg flanging of trouser legs to enclose the hemmed distance.When using woollen sweater as test fabric, the size of reference is the distance that extremely sleeve is connected to the about mid point of hemmed of shirt body from the bottom flap of a cuff.
Surface distress and dyestuff/colour loss refer to the integral body of fabric and the variation of outward appearance, and it can show in many ways.Staple fibre is extruded from woven and knit goods/fabric structure because of the mechanical effect of washing.These fibers of extruding can form velveteen, fine hair or bead, and it is that visible and the brand-new outward appearance change that makes said fabric weaken at fabric face.Because colour intensity weakens with in many cases because the form and aspect or the color change of color, further repeating to wash and starch and can remove the dyestuff in the fabric and fabric is had the outward appearance of fading fabric.
The compositions and methods of the invention are applicable to the washing machine and the drum drying equipment of specialty or family expenses.
The present invention proposes to solve the cleaning of sensitive garment with dry and do not cause damage through a kind of method; Said method uses method and optional two of at least one main washing step that relates to cleaning composition described in the present invention to relate to the preconditioned compsn described respectively among the present invention and/or the rinse step of care composition.
Allow the compsn of embodiment of the present invention method to detail as follows:
Cleaning composition of the present invention comprises the alcohol that the volume of water, a kind of 5%-40% with said compsn TV exists.Get into the alcohol of said compsn, be selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4, i.e. methyl alcohol, ethanol, propyl alcohol, Virahol and butanols.Said cleaning composition also comprises the mixture of the anion surface activity component that the volume of a kind of 4%-60% with said compsn TV exists.The mixture of this AS is made up of the sec.-propyl amine salt of LABS mixture, and wherein said alkyl group comprises 7-14 carbon atom.Alkyl benzene sulphonate(ABS) is the straight or branched configuration component that wherein said alkyl group comprises 7-14 carbon atom.Approximately the Phenylsulfonic acid that said linear alkylbenzene sulfonate had of 19%-25% is on 2 of said alkyl group.Said cleaning composition also comprises the mixture of the non-anion surface activity component that the volume of a kind of 4%-40% with said compsn TV exists.This non-anion surface activity component mixture is made up of nonionic primary alconol alcoxylates, and its middle-and-high-ranking straight chain primary alcohol accounts for 75%-85% and includes the even number that is lower than 20 and the carbochain of odd number carbon atom.Nonionic primary alconol alcoxylates is preferably the ethoxylated alcohol of the carbochain with 8-18 carbon atom.Said cleaning composition also contains the SULPHOSUCCINIC ACID ESTER that the volume of a kind of 4%-30% with said compsn TV exists.The SULPHOSUCCINIC ACID ESTER that in said cleaning composition, exists is selected from has alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.Phosphoric acid that said cleaning composition also comprises Hydrocerol A that the volume with the 0.1%-4% of said compsn TV exists and soluble salt thereof, exist with the volume of the 0.1%-5% of said compsn TV and soluble salt thereof, the acetate and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV.Citrate trianion, phosphoric acid salt and acetate are sodium salt, sylvite or ammonium salt or its mixture.Said cleaning composition also comprises the organic amine that the volume of a kind of 0.1%-4% with said compsn TV exists.Said organic amine is selected from diethylolamine, trolamine or its mixture.
Preconditioned compsn of the present invention comprises the alcohol that the volume of water, a kind of 5%-40% with said compsn TV exists.The alcohol that gets in the said compsn is selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4, i.e. methyl alcohol, ethanol, propyl alcohol, Virahol and butanols.Said preconditioned compsn also comprises the SULPHOSUCCINIC ACID ESTER that the volume of a kind of 4%-30% with said compsn TV exists.The SULPHOSUCCINIC ACID ESTER that in said preconditioned compsn, exists is selected from has alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.Phosphoric acid that said preconditioned compsn also comprises Hydrocerol A that the volume with the 0.1%-4% of said compsn TV exists and soluble salt thereof, exist with the volume of the 0.1%-5% of said compsn TV and soluble salt thereof, the acetate and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV.Citrate trianion, phosphoric acid salt and acetate are sodium salt, sylvite or ammonium salt or its mixture.The pH value of said preconditioned compsn is adjusted in the scope of 4-6, is preferably 5.
The tripropylene glycol that care composition of the present invention comprises water, exists with the volume of the 0.1%-4% of said compsn TV, and the vinylformic acid fluoroalkyl ester copolymer that exists of the volume of a kind of 2%-15% with said compsn TV.Vinylformic acid fluoroalkyl ester copolymer is by fluorinated monomer, contains monomeric vinylformic acid, and the calcium salt of vinylformic acid or styrene sulfonic acid, magnesium salts, ammonium salt are formed.
As stated, but the present invention relates to a kind of method that is used to clean with the dry clothing of processing via the fabric of conventional washing/drying operation damaged.Said method comprising the steps of: at least one is the washing step of the said clothing of washing in certain type the washing compsn that contains additive under given conditions, and optional two contain respectively special additive with the water-based preconditioned compsn that uses under given conditions and/or water-based care composition in the step of rinsing clothes.According to the needs that use these different waterborne compositions, after the above-mentioned steps concrete draining, dehydration and the drying step that hereinafter details.The inventive method designed to be used the washing machine and drier or the washer/dryer of domestic type or professional type.
In first aspect, method of the present invention is suitable in having wool round-robin domestic type washing machine and drier or washer/dryer washing and dry sensitive garment and do not cause damage in tumble drier.In this first aspect; The inventive method is characterised in that; In compsn of the present invention, wash said clothing continuously,, all be removed and accomplish its drying so that be dried in the said clothing all residual moistures through static state with the humidity in its roll-drying to the 10%-15% scope.In this first aspect, cleaning composition of the present invention is used for the cycles of washing of domestic type, and its time length, preferably in 3-12 minute scope, temperature was up to 40 ℃ in 1-15 minute scope.In this first aspect, after said washing step, said cleaning composition is discharged, and accomplish said circulation through rinse step and dehydrating step; The rotating speed of dehydration is 500rpm; Time length preferred 1 minute, is carried out drying afterwards in 0.5-2 minute scope.
In second aspect, method of the present invention is suitable in commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer cleaning and dry sensitive garment and do not cause damage in tumble drier.In this second aspect; Said method is characterised in that; In compsn of the present invention, wash said clothing continuously; Rinsing clothes in care composition of the present invention with the humidity in its roll-drying to the 8%-10% scope, is accomplished its drying so that all be removed through all residual moistures in static dry or flatiron to the said clothing.In this second aspect, cleaning composition of the present invention is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and its time length, preferably in 3-12 minute scope, temperature was up to 40 ℃ in 1-15 minute scope.In this second aspect, after said washing step, said cleaning composition is discharged, and accomplishes this circulation through dehydrating step, dehydrating speed is 500rpm, the time length in 0.5-2 minute scope, preferred 1 minute.In this second aspect, care composition of the present invention is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and its time length, preferred 7 minutes, temperature was up to 40 ℃ in 2-10 minute scope.In this second aspect, after said rinse step, said care composition to be discharged, and accomplish this circulation through dehydrating step, dehydrating speed is 500rpm, the time length preferred 1 minute, is carried out drying afterwards in 0.5-2 minute scope.
In the third aspect, method of the present invention is suitable in the commercial Wet cleaning washing machine with water cycle ability and clothes-drying machine or washer/dryer cleaning and dry sensitive garment and do not cause damage in tumble drier.In this third aspect, said method is characterised in that, in compsn of the present invention, washs said clothing continuously, and the said clothing of rinsing in preconditioned compsn of the present invention is so that with its complete roll-drying or be dried to needed humidity.In this third aspect; Cleaning composition of the present invention is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and is as described before, and its time length is in 1-15 minute scope; Preferably in 3-12 minute scope, temperature is up to 40 ℃.In this third aspect, after said washing step, said cleaning composition is discharged, and accomplishes this circulation through dehydrating step, dehydrating speed is 500rpm, the time length in 0.5-2 minute scope, preferred 1 minute.In this third aspect, preconditioned compsn of the present invention is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and its round-robin time length, preferred 4 minutes, temperature was up to 40 ℃ in 2-4 minute scope.In the 3rd embodiment, after said rinse step, said preconditioned compsn is discharged, and accomplishes this circulation through dehydrating step, dehydrating speed is 500rpm, the time length in 0.5-2 minute scope, preferred 1 minute.In this third aspect, care composition of the present invention is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and its time length, preferred 7 minutes, temperature was up to 40 ℃ in 2-10 minute scope.In this third aspect, after said rinse step, said care composition to be discharged, and accomplish this circulation through dehydrating step, dehydrating speed is 1000rpm, the time length preferred 4 minutes, is carried out drying afterwards in 2.5-5 minute scope.
Washing of the present invention, preconditioned and care composition are designed to optimize in specialty or housed device washing and the drying to sensitive garment, and avoid size change, shrink, surface fracture and colour loss.Should understand these compsns of the present invention and especially be suitable for the present invention's described method before.Also should understand cleaning and/or drying means and process that these compsns can be used for other individually, thereby be used for size change, shrink, surface disturbance and colour loss can taking place at specialty or housed device cleaning and/or dry rapid wear clothing.These washings of the present invention, preconditioned and care composition can be united use with employed other washings in the field of carrying out clean fabric with specialty or housed device, preconditioned and care composition, or are used in specialty or housed device and carry out in other washings in the field of clean fabric, preconditioned and Opsonizing method and the process.
Use some embodiment to explain and set forth the present invention below, but scope of the present invention is not limited to these embodiment.
Embodiment
Routine test
1. select the different wool clothings of many manufacturerss of 15kg and put it into the commercial Wet cleaning washing machine (trade mark: IMESA) of 55lb..
2. in the first step, with said clothing at 25 ℃ down with the solution washing of said cleaning composition 7 minutes.Said aqueous solution is discharged and under the 500rpm rotating speed, dewatered 1 minute.
3. in second step, with said clothing at 25 ℃ down with the solution rinsing of said preconditioned compsn 4 minutes.Said aqueous solution is discharged and under the 500rpm rotating speed, dewatered 1 minute.
4. in the 3rd step, with said clothing at 25 ℃ down with the solution rinsing of said care composition 7 minutes.Said aqueous solution is discharged and under the 1000rpm rotating speed, dewatered 4 minutes.
5. in the 4th step, with said clothing at the commercial clothes-drying machine (trade mark: be dried to 3% humidity IMESA) of 75lb..
Assessment subsequently shows that said clothing does not have size to change, and does not have dyestuff/colour loss, and very clean, and only has the few wrinkle that is similar to the dry-cleaning process.
Comparison test 1
Comparable (washing) product does not have oil stain to remove ability, and does not recommend the washing of said clothing and drying subsequently.The drying of recommending is to spend the night with rollers roll 3 minutes and hang airing.
Comparison test 1 only limits to said cleaning course.
Select three kinds of different commercially available products that wash, and the clothing of same type all is based on said cleaning product manufacturer's recommendation and cleans.
Evaluate and test the cleaning effect of the clothing that said cleaning crosses and to the effect of said fiber.All three kinds of cleaning product and method all produce visible surface and color change.
Comparison test 2
In comparison test 2, carry out drying to relatively testing 1 clothing subsequently.
Evaluating and testing said cleaning crosses with the cleaning of the dry clothing of crossing and drying effect and to the effect of said fiber.
All three kinds of cleaning product and method all produce the change of visible size, shrink and fulling milling (felting), and color change.
Domestic washing machine test 1
1. select four kinds of different woolen pants of a plurality of manufacturerss and put it in the hand washing of Miele W 1926 (domestic washing machine)/wool circulation.
2. in the first step, with said clothing solution washing with said cleaning composition under 25 ℃.Said aqueous solution is discharged and dehydration.
3. in second step, only with the said clothing of clear water rinsing.Said aqueous solution is discharged and dehydration.
4. in the 3rd step, with the solution rinsing with said care composition under 25 ℃ of said clothing.Said aqueous solution is discharged and dehydration.
5. in the 4th step, said clothing is provided with drying with manual flatiron in Miele dryer T 1526 under low temperature.
Assessment subsequently shows that said woolen pants do not have size to change, and do not have dyestuff/colour loss, and are very clean, and only have the few wrinkle that is similar to the dry-cleaning process.
Domestic washing machine test 2
1. hand washing/wool circulation of selecting four kinds of different woollen sweaters of a plurality of manufacturerss and putting into Miele W 1926 (domestic washing machine).
2. in the first step, with said clothing solution washing with said cleaning composition under 25 ℃.Said aqueous solution is discharged and dehydration.
3. in second step, only with the said clothing of clear water rinsing.Said aqueous solution is discharged and dehydration.
4. in the 3rd step, with the solution rinsing with said care composition under 25 ℃ of said clothing.Said aqueous solution is discharged and dehydration.
5. in the 4th step, said clothing is provided with drying with manual flatiron in Miele dryer T 1526 under low temperature.
Assessment subsequently shows that said woollen sweater does not have size to change, and does not have dyestuff/colour loss, and is very clean, and only has the few wrinkle that is similar to the dry-cleaning process.
The compare test of domestic washing machine
Compare test with same Miele washing machine and drier and three kinds of commercially available cleaning product that are used for wool and responsive fiber.
The cleaning of the clothing of crossing with drying of evaluating and testing that said cleaning crosses and drying effect and to the effect of said fiber.All three kinds of cleaning product and method all produce the change of visible size, shrink and fulling milling, and color change.

Claims (41)

  1. One kind be used for specialty or family expenses washing machinery and equipment cleaning and in tumbler dryer drying clothes and other fibers do not cause the method for size change, surface fracture and colour loss simultaneously; Wherein said clothing and other fibers comprise that water sensitive protein fibre such as wool, cashmere, silk and other are labeled as the only sensitive garment of dry-cleaning, and said method comprises following steps:
    A) wash with a kind of cleaning composition that contains following composition to major general's clothing:
    1) water;
    2) alcohols that exists of the volume of a kind of 5%-40% with said compsn TV;
    The mixture of the anion surface activity component that 3) exists with the volume of the 4%-60% of said compsn TV;
    The mixture of the non-anion surface activity component that 4) exists with the volume of the 4%-40% of said compsn TV;
    5) SULPHOSUCCINIC ACID ESTER that exists of the volume of a kind of 4%-30% with said compsn TV;
    6) Hydrocerol A and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV;
    7) phosphoric acid and the soluble salt thereof that exist with the volume of the 0.1%-5% of said compsn TV;
    8) acetate and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV;
    9) organic amine that exists of the volume of a kind of 0.1%-4% with said compsn TV;
    B) randomly clothing is carried out rinsing with a kind of preconditioned compsn, the pH value of said compsn is adjusted in the 4-6 scope, and it contains following composition:
    1) water;
    2) alcohol that exists of the volume of a kind of 5%-40% with said compsn TV;
    3) SULPHOSUCCINIC ACID ESTER that exists of the volume of a kind of 4%-30% with said compsn TV;
    4) Hydrocerol A and the soluble salt thereof that exist with the volume of the 0.01%-5% of said compsn TV;
    5) phosphoric acid and the soluble salt thereof that exist with the volume of the 1%-20% of said compsn TV;
    6) acetate and the soluble salt thereof that exist with the volume of the 0.01%-5% of said compsn TV;
    C) alternatively clothing is carried out rinsing with a kind of care composition, this compsn contains:
    1) water;
    2) tripropylene glycol that exists with the volume of the 0.1%-4% of said compsn TV;
    3) the vinylformic acid fluoroalkyl ester copolymer that exists of the volume of a kind of 2%-15% with said compsn TV.
  2. 2. the described method of claim 1, wherein said alcohol is selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4.
  3. 3. the described method of claim 1; The sec.-propyl amine salt that wherein said anion surface activity component is the LABS mixture; Wherein said alkyl group comprises 7-14 carbon atom, and the Phenylsulfonic acid that said linear alkylbenzene sulfonate had of about 19%-25% is on 2 of said alkyl group.
  4. 4. the described method of claim 1, said non-anion surface activity component is selected from nonionic primary alconol alcoxylates, and its middle-and-high-ranking straight chain primary alcohol accounts for 75%-85%, and comprises the even number that is lower than 20 and the carbochain of odd number carbon atom.
  5. 5. the described method of claim 4, wherein said nonionic primary alconol alcoxylates is the ethoxylated alcohol with carbochain of 8-18 carbon atom.
  6. 6. the described method of claim 1, wherein said SULPHOSUCCINIC ACID ESTER is selected from has alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.
  7. 7. the described method of claim 1, wherein said Citrate trianion are sodium salt, sylvite or ammonium salt or its mixture of Hydrocerol A.
  8. 8. the described method of claim 1, wherein said phosphoric acid salt are sodium salt, sylvite or ammonium salt or its mixture of phosphoric acid.
  9. 9. the described method of claim 1, wherein said acetate are sodium salt, sylvite or ammonium salt or its mixture of acetate.
  10. 10. the described method of claim 1, wherein said organic amine is selected from diethylolamine, trolamine or its mixture.
  11. 11. the described method of claim 1, wherein said multipolymer are vinylformic acid fluoroalkyl ester copolymers, it contains fluorinated monomer, contains monomeric vinylformic acid, and the calcium salt of vinylformic acid or styrene sulfonic acid, magnesium salts, ammonium salt.
  12. 12. each described method among claim 1a, the 2-11; It is characterized in that; Sensitive garment is in having wool round-robin domestic type washing machine and drier or washer/dryer; Be to use cleaning composition to wash continuously, the humidity in roll-drying to the 10%-15% scope, thereby and through static dry all residual water-contents in clothing all be removed accomplish dry.
  13. 13. the described method of claim 12 is characterized in that said cleaning composition is used for the wash cycle of domestic type, circulating continuancing time is in 1-15 minute scope, and temperature is up to 40 ℃.
  14. 14. the described method of claim 13 is characterized in that, after washing step, said cleaning composition is discharged; And accomplish said circulation through rinsing and dehydrating step; The rotating speed of its dehydration is at 500rpm, and the time length is carried out drying afterwards in 0.5-2 minute scope.
  15. 15. each described method among claim 1a, 1c, the 2-11; It is characterized in that; Sensitive garment is to use said cleaning composition to wash continuously, rinsing in care composition in commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer; Humidity in roll-drying to the 8%-10% scope, thereby and through static dry or flatiron all residual moistures in clothing all be removed accomplish dry.
  16. 16. the described method of claim 15 is characterized in that, said cleaning composition is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and circulating continuancing time is in 1-15 minute scope, and temperature is up to 40 ℃.
  17. 17. the described method of claim 16 is characterized in that, after washing step, said cleaning composition is discharged, and accomplishes said circulation through dehydrating step, the rotating speed of its dehydration is 500rpm, and the time length is in 0.5-2 minute scope.
  18. 18. the described method of claim 15 is characterized in that, said care composition is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and circulating continuancing time is in 2-10 minute scope, and temperature is up to 40 ℃.
  19. 19. the described method of claim 18 is characterized in that, after rinse step, said care composition is discharged; And accomplish said circulation through dehydrating step; The rotating speed of its dehydration is 500rpm, and the time length is carried out drying afterwards in 0.5-2 minute scope.
  20. 20. each described method among the claim 1-11; It is characterized in that; Sensitive garment is to use said cleaning composition to wash continuously in the commercial Wet cleaning washing machine with water cycle ability and clothes-drying machine or washer/dryer, in the rinsing of preconditioned compsn; In the care composition rinsing, complete roll-drying or be dried to required humidity.
  21. 21. the described method of claim 20 is characterized in that, said cleaning composition is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and circulating continuancing time is in 1-15 minute scope, and temperature is up to 40 ℃.
  22. 22. the described method of claim 21 is characterized in that, after washing step, said cleaning composition is discharged, and accomplishes said circulation through dehydrating step, the rotating speed of its dehydration is 500rpm, and the time length is in 0.5-2 minute scope.
  23. 23. the described method of claim 20 is characterized in that, said preconditioned compsn is used for commercial Wet cleaning washing machine and clothes-drying machine or washer/dryer circulation, and circulating continuancing time is in 2-4 minute scope, and preferred 4 minutes, temperature was up to 40 ℃.
  24. 24. the described method of claim 23 is characterized in that, after rinse step, said preconditioned compsn is discharged, and accomplishes said circulation through dehydrating step, the rotating speed of its dehydration is 500rpm, and the time length is in 0.5-2 minute scope.
  25. 25. the described method of claim 20 is characterized in that, said care composition is used for the circulation of commercial Wet cleaning washing machine or washer/dryer, and circulating continuancing time is in 2-10 minute scope, and temperature is up to 40 ℃.
  26. 26. the described method of claim 25 is characterized in that, after rinse step, said care composition is discharged; And accomplish said circulation through dehydrating step; The rotating speed of its dehydration is 1000rpm, and the time length is carried out drying afterwards in 2.5-5 minute scope.
  27. 27. cleaning composition; Be used at specialty or family expenses washing machinery and equipment cleaning and drying clothes and other fibers in tumbler dryer; Do not cause simultaneously size change, surface fracture or colour loss; Said clothing and other fibers comprise that water sensitive protein fibre such as wool, cashmere, silk and other are labeled as the rapid wear clothing that only can dry-clean, and said compsn comprises following composition:
    1) water;
    2) alcohol that exists of the volume of a kind of 5%-40% with said compsn TV;
    The mixture of the anion surface activity component that 3) exists with the volume of the 4%-60% of said compsn TV;
    The mixture of the non-anion surface activity component that 4) exists with the volume of the 4%-40% of said compsn TV;
    5) SULPHOSUCCINIC ACID ESTER that exists of the volume of a kind of 4%-30% with said compsn TV;
    6) Hydrocerol A and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV;
    7) phosphoric acid and the soluble salt thereof that exist with the volume of the 0.1%-5% of said compsn TV;
    8) acetate and the soluble salt thereof that exist with the volume of the 0.1%-4% of said compsn TV;
    9) organic amine that exists of the volume of a kind of 0.1%-4% with said compsn TV.
  28. 28. the described compsn of claim 27, wherein said alcohol is selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4.
  29. 29. the described compsn of claim 27; The sec.-propyl amine salt that wherein said anion surface activity component is the LABS mixture; Wherein said alkyl group comprises 7-14 carbon atom, and the Phenylsulfonic acid that said linear alkylbenzene sulfonate had of about 19%-25% is on 2 of said alkyl group.
  30. 30. the described compsn of claim 27, wherein said non-anion surface activity component is selected from nonionic primary alconol alcoxylates, and its middle-and-high-ranking straight chain primary alcohol accounts for 75%-85%, and comprises the even number that is lower than 20 and the carbochain of odd number carbon atom.
  31. 31. the described compsn of claim 30, wherein said nonionic primary alconol alcoxylates is the ethoxylated alcohol with carbochain of 8-18 carbon atom.
  32. 32. being selected from, the described compsn of claim 27, wherein said SULPHOSUCCINIC ACID ESTER have alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.
  33. 33. the described compsn of claim 27, wherein said Citrate trianion are sodium salt, sylvite or ammonium salt or its mixture of Hydrocerol A.
  34. 34. preconditioned compsn; Be used at specialty or family expenses washing machinery and equipment cleaning and drying clothes and other fibers in tumbler dryer; Do not cause simultaneously size change, surface fracture or colour loss; Said clothing and other fibers comprise that water sensitive protein fibre such as wool, cashmere, silk and other are labeled as the rapid wear clothing that only can dry-clean, and said compsn comprises following composition:
    1) water;
    2) alcohol that exists of the volume of a kind of 5%-40% with said compsn TV;
    3) SULPHOSUCCINIC ACID ESTER that exists of the volume of a kind of 4%-30% with said compsn TV;
    4) Hydrocerol A and the soluble salt thereof that exist with the volume of the 0.01%-5% of said compsn TV;
    5) phosphoric acid and the soluble salt thereof that exist with the volume of the 1%-20% of said compsn TV;
    6) acetate and the soluble salt thereof that exist with the volume of the 0.01%-5% of said compsn TV.
  35. 35. the described compsn of claim 34, wherein said alcohol is selected from formula C nH 2n+1The alcohol of OH, wherein n is 1,2,3 or 4.
  36. 36. being selected from, the described compsn of claim 34, wherein said SULPHOSUCCINIC ACID ESTER have alkyl oxide carbochain C 12-C 15Compound monoesters or diester with EO-2-10.
  37. 37. the described compsn of claim 34, wherein said Citrate trianion are sodium salt, sylvite or ammonium salt or its mixture of Hydrocerol A.
  38. 38. the described compsn of claim 34, wherein said phosphoric acid salt are sodium salt, sylvite or ammonium salt or its mixture of phosphoric acid.
  39. 39. the described compsn of claim 34, wherein said acetate are sodium salt, sylvite or ammonium salt or its mixture of acetate.
  40. 40. care composition; Be used in specialty or the family expenses washing machinery and equipment and clean and drying clothes and other fibers in tumbler dryer; Do not cause simultaneously size change, surface fracture or colour loss; Said clothing and other fibers comprise that water sensitive protein fibre such as wool, cashmere, silk and other are labeled as the rapid wear clothing that only can dry-clean, and said compsn comprises following composition:
    1) water;
    2) tripropylene glycol that exists with the volume of the 0.1%-4% of said compsn TV;
    3) the vinylformic acid fluoroalkyl ester copolymer that exists of the volume of a kind of 2%-15% with said compsn TV.
  41. 41. the described compsn of claim 40, wherein said multipolymer are vinylformic acid fluoroalkyl ester copolymers, it contains fluorinated monomer, contains calcium salt, magnesium salts, the ammonium salt of monomeric vinylformic acid and vinylformic acid or styrene sulfonic acid.
CN2009801574091A 2009-02-25 2009-02-25 Compositions for laundering and subsequently drying delicate garments without incurring any damage and methods to use them Pending CN102333853A (en)

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CN102851934A (en) * 2012-09-11 2013-01-02 启东市万隆电气光源有限公司 Fabric dry cleaning agent
CN102877282A (en) * 2012-09-11 2013-01-16 南通华豪巨电子科技有限公司 Fabric dry cleaning agent
WO2016196555A1 (en) * 2015-06-02 2016-12-08 Stepan Company Cold-water cleaning method
CN108779417A (en) * 2016-07-06 2018-11-09 汉高股份有限及两合公司 The acceleration of cloth drying

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EP2714980A1 (en) 2011-05-31 2014-04-09 Dewudian, Fariborz Method and apparatus for cleaning delicate textiles
US9695215B2 (en) * 2012-06-26 2017-07-04 Al.Pre.Tec. Srl Allergy Prevention Technology Italia Method for producing fibroin powder from silk products or filaments
CN104004600A (en) * 2014-06-17 2014-08-27 陈建宝 Special detergent for woollen sweater

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CN102877282A (en) * 2012-09-11 2013-01-16 南通华豪巨电子科技有限公司 Fabric dry cleaning agent
WO2016196555A1 (en) * 2015-06-02 2016-12-08 Stepan Company Cold-water cleaning method
CN108779417A (en) * 2016-07-06 2018-11-09 汉高股份有限及两合公司 The acceleration of cloth drying
CN108779417B (en) * 2016-07-06 2021-10-29 汉高股份有限及两合公司 Acceleration of clothes drying

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AU2009341014A8 (en) 2012-06-07
CA2753153A1 (en) 2010-09-02
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Application publication date: 20120125