CN102329981A - High-tensile property brass band for lamp holder and production process thereof - Google Patents
High-tensile property brass band for lamp holder and production process thereof Download PDFInfo
- Publication number
- CN102329981A CN102329981A CN201110282477A CN201110282477A CN102329981A CN 102329981 A CN102329981 A CN 102329981A CN 201110282477 A CN201110282477 A CN 201110282477A CN 201110282477 A CN201110282477 A CN 201110282477A CN 102329981 A CN102329981 A CN 102329981A
- Authority
- CN
- China
- Prior art keywords
- lamp holder
- brass
- brass band
- finished product
- high stretch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001369 Brass Inorganic materials 0.000 title claims abstract description 46
- 239000010951 brass Substances 0.000 title claims abstract description 46
- 238000004519 manufacturing process Methods 0.000 title abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 77
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010949 copper Substances 0.000 claims abstract description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011701 zinc Substances 0.000 claims abstract description 13
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 13
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052718 tin Inorganic materials 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 238000000137 annealing Methods 0.000 claims description 23
- 238000005554 pickling Methods 0.000 claims description 20
- 238000005096 rolling process Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- 239000011133 lead Substances 0.000 claims description 11
- 235000011149 sulphuric acid Nutrition 0.000 claims description 11
- 239000001117 sulphuric acid Substances 0.000 claims description 11
- 238000007689 inspection Methods 0.000 claims description 9
- 239000011135 tin Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 8
- 238000005097 cold rolling Methods 0.000 claims description 7
- 230000000704 physical effect Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000012858 packaging process Methods 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000002161 passivation Methods 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 39
- 238000005520 cutting process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000003801 milling Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000005098 hot rolling Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229910001015 Alpha brass Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 238000005482 strain hardening Methods 0.000 description 3
- 229910001110 Alpha-beta brass Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 241000189524 Baccharis halimifolia Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 229910017752 Cu-Zn Inorganic materials 0.000 description 1
- 229910017943 Cu—Zn Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a high-tensile property brass band for a lamp holder and a production process thereof. The brass band comprises the following components in percentage by weight: less than or equal to 0.01 percent of lead, less than or equal to 0.02 percent of iron, less than or equal to 0.02 percent of tin, less than or equal to 0.02 percent of nickel, 0.001 to 0.003 percent of phosphor, 63.0 to 64.5 percent of copper, and the balance of zinc. Compared with the prior art, the high-tensile property brass band has the advantages that: the produced high-tensile property brass band for a lamp holder can fulfill the requirement for excellent plasticity in a lamp holder forming process, and prevent pitted surface of a product which is subjected to deep tension from influencing the appearance and yield by reasonably controlling the content of impure elements, grain sizes of finished products and deep drawability.
Description
Technical field:
The invention belongs to brass band and production technique thereof, belonging to lamp holder especially can brass band and production technique thereof with high stretch.
Background technology:
Brass has good processing properties and conduction, heat conductivility, and color and luster good (being close to the gold color and luster), in the copper strips alloy, uses very extensively, and it generally is used for hot-water heating sanitary equipment, five metals towards industries such as part, the auxilliary decoration of clothes, electrical accessories; Because its inherent element component content is different; The brass trade mark also has a lot; Aspects such as each trade mark brass mechanical property, processing characteristics also there are differences, and produce lamp holder on the just present industry and are mainly H62 and the H65 processing brass of thickness between 0.15～0.40mm with brass band, and its composition is as showing-1:
Table-1 GB/T 5231-2001 (processing brass chemical ingredients)
The main production process of lamp holder product is blanking, deep-draw, rolled thread, side cut etc.; Stretch because lamp holder formed product process experiences the continuous degree of depth, and after stretching, arrange the rolled thread operation, therefore require high material plasticity; Simultaneously because high-grade lamp holder product is higher to surperficial specification of quality; Especially true qualities product (finished product does not carry out electroplating processes) requires any surface finish, light, smooth, even the surface exists slight defect also possibly cause degradation to be handled; Simultaneously; The grain fineness number of brass has bigger influence to its cold-forming property, and mechanical property and cold deformation performance after the brass annealing depend primarily on grain-size, often under the prerequisite of pursuing moulding property of material, cause crystal grain thick easily; Cause finished product the pitted skin phenomenon to occur, have a strong impact on final product quality.
Summary of the invention:
The 1st technical problem to be solved by this invention is: provide a kind of and can satisfy the requirement of moulding plasticity, the lamp holder that is unlikely to again to cause the finished product pitted skin is with high stretch ability brass band;
The 2nd technical problem to be solved by this invention is: the control method of the preparation method of above-mentioned brass band, especially composition, plasticity and grain fineness number.
The technical scheme of technical solution problem of the present invention is: a kind of lamp holder contains lead (Pb), iron (Fe), tin (Sn), nickel (Ni), copper (Cu), phosphorus (P), zinc with high stretch ability brass band;
Described lead (Pb) content≤0.01%, iron (Fe) content≤0.02%, tin (Sn) content≤0.02%, nickel (Ni) content≤0.02%, phosphorus (P) content are 0.001-0.003%; Copper (Cu) content 63.0-64.5%, surplus is a zinc.
In order to strengthen the plasticity of brass, also can in brass, add the cerium of 0.001-0.003%, the add-on of cerium is very few or too much, does not all have the plastifying effect.
Preparing method of the present invention comprises following operation:
1) founding operation:
2) heating, hot-rolled process: going out the ingot temperature is 820～850 ℃, and the heating time spent is 4 hours, guarantees before coming out of the stove that the ingot blank temperature is even;
3) mill the face operation: hot rolling gained ingot blank is carried out upper and lower surperficial milling, and two-sided milling thickness is about 0.9mm～1.0mm;
4) cold rolling process: adopt 7 passage rolling technology: 12.5mm-9.5mm-7.5mm-6.0mm-4.9mm-4.0mm-3.35mm-2.5mm;
5) rough annealing operation: the preheating zone design temperature is that 635 ℃, heating zone design temperature are that 645 ℃, heat preservation zone design temperature are 625 ℃, and the annealing cycle is 7 hours; Annealing back ingot blank physicals is by tension>=294N/mm
2, extend>=55% and carry out an acceptance inspection;
6) blank pickling process: the sulphuric acid soln of operating weight concentration 10～12% carries out pickling, and 90～110 ℃ of oven dry.
7) work in-process and finished product rolling process:
8) work in-process and finished product acid-washing:
First and second rolling process acid cleaning process: operating weight concentration is that 6～8% sulphuric acid soln carries out pickling, and 90～110 ℃ of oven dry.
The 3rd rolling process acid cleaning process: this operation is a finished product acid-washing, and operating weight concentration is that 4～6% sulphuric acid soln carries out pickling, and operating weight concentration is that 0.02% passivating solution carries out passivation, and 90～110 ℃ of oven dry.
9) inspection process: finished surface, tolerance, band shape and physicals are detected, if all meet standard for acceptance then be regarded as salable product, otherwise qualitative be defective products;
A) physicals standard for acceptance
| Finished product thickness | The cupping standard | The HV standard |
| ＞0.35～0.40 | ≥9.80mm | 75～90 |
| ＞0.30～0.35 | ≥9.60mm | 75～90 |
| ＞0.25～0.30 | ≥9.40mm | 80～95 |
| ＞0.20～0.25 | ≥9.20mm | 80～95 |
| ＞0.15～0.20 | ≥8.80mm | 80～95 |
10) side cut, packaging process: the base branch is cut into the required width of client in the future, and finished product is packed warehouse-in;
In the above-mentioned founding operation, equipment used is frequency cored induction furnace and vertical D.C.casting;
In the described heating process, equipment used is a walking beam furnace, and stove is divided into three sections of preheatings, heating, insulation, and it is 800～830 ℃ that H62 goes out the ingot temperature, and H65 goes out the ingot temperature and is about 800～850 ℃.
In the described hot-rolled process, equipment used is a two-roller reversible formula hot rolls, adopts the dilute emulsion cooling and lubricating, and coming base thickness is 165mm, and supplying base thickness is 13.5mm, and ingot blank adopts 11 passages rolling;
Described milling in the face operation, equipment used are that off-line mills the face machine, respectively the made-up belt upper and lower surfaces are carried out milling, and two-sided milling thickness 0.9～1.0mm mills ingot blank surface, back and should not have obvious wiping scuffing, is mingled with (sand), core, and lead angle is slick and sly, and knife mark is carefully shallow;
In the said cold rolling process, equipment used is a 4-roller reversible cold rolling mill, according to rolling accuracy can with rolling be divided into roughing, in roll, the finish rolling three major types, wherein be provided with the cutting edge operation after the roughing;
Described annealing operation, blank adopts the push-down lehre, and work in-process and finished product adopt the bell-jar lehre, and it is mainly used in the work hardening of eliminating brass alloys, makes it to recover again plasticity; According to hardenability, alloying constituent, performance requriements adjustment holding temperature and soaking time; The annealing design temperature is 390～650 ℃, and the annealing cycle is 7.0～20 hours;
Described pickling process, it is mainly used in the residual lubricant medium of removing (washing) copper strip surface, annealing dirt, surface oxide layer etc., mainly be provided with unreel, devices such as pickling, washing, water brush, oven dry, upright volume, wherein finished product acid-washing is provided with the passivation device.
Said inspection process, it is mainly used in check finished product qualification, mainly comprises tolerance of dimension, surface quality, band shape quality, physicals four broad aspect, and above four equal eligibles of check are regarded as salable product, can implement the finished product cutting edge to it, cut open bar;
Visible from the Cu-Zn binary system phase diagram, market brass is solid-state to have α (alpha+beta) phase respectively down, changes to β ' ordered solid solution at 454～468 ℃ of β disordered solid solutions.Zinc content was less than 36% o'clock, and its tissue is a αGu Rongti, and alpha brass plasticity is good, can hot and coldly process, and its room temperature elongation increases with the increase of zinc content, reached maximum value during to 30%～32% zinc.Zinc content was at 36%～46.5% o'clock; Its tissue is (alpha+beta) alpha-beta brass, and (alpha+beta) brass at room temperature contains hard and crisp ordered phase β ', so intensity is high, plasticity is low; And be easy to work hardening than alpha brass; Along with the increase of β ' phase, the plasticity of alpha-beta brass acutely reduces, and wants strict control working modulus during cold working.But the β of (alpha+beta) brass at high temperature more is prone to softening than α mutually mutually; So often being heated in the TR in β district, (alpha+beta) brass carries out hot-work; But it is too far away that Heating temperature should not surpass (alpha+beta)/β ' line of delimitation; Its best heating condition is to make still to keep a spot of α in the alloy structure and limit β phase grain growth mutually, avoids cracking.
Seldom solid solution is in copper-zinc alloy for phosphorus (P), and fragility phase Cu will appear in the phosphorus that in alpha brass, surpasses certain content
3P reduce brass plasticity, but carbamate additives for low phosphorus can make the grain refining of brass ingot casting, improves the grain fineness number of brass.
The present invention compared with prior art; The major technique advantage is embodied in: the lamp holder of being produced is with high stretch ability brass band; Through reasonable control impurity content, finished product grain fineness number and deep drawability; Can satisfy in the lamp holder moulding process the requirement of good plasticity, can avoid the degree of depth back goods pitted skin that stretches to influence outward appearance and yield rate again;
Embodiment
Below in conjunction with embodiment the present invention is done detailed explanation.
Cathode copper that this instance uses meets GB GB/T 467-1997, and the zinc ingot metal that uses meets GB GB/T470-2008, and the weight percent composition of the category-B material that uses is: Cu>=99.80%, Pb≤0.025%, Fe≤0.025%, P≤0.01%;
Embodiment 1: brass band H650.25 * 200M production technique
1, founding operation: this instance is pressed cathode copper 1:B class material 2, and surplus is that zinc ingot metal is thrown stove, and gained ingot blank composition weight percent is:
Copper: 64.2, lead: 0.0085, iron: 0.0050, tin: 0.0050, nickel: 0.0018, phosphorus: 0.0022, other impurity elements: 0.06, surplus is a zinc.
The gained ingot blank is of a size of: thickness 165mm, width 210mm, length 4000mm;
2, heating, hot-rolled process: the heat tracing zone design temperature is 920 ℃, and actual to go out the ingot temperature be 820～850 ℃, and the heating time spent is 4 hours, guarantees before coming out of the stove that the ingot blank temperature is even; After coming out of the stove, uses ingot blank 11 passage hot rollings;
Gained made-up belt thickness 13.5mm, width 230mm;
3, mill the face operation: hot rolling gained ingot blank is carried out upper and lower surperficial milling, and two-sided milling thickness is about 0.9mm～1.0mm;
Gained made-up belt thickness 12.5mm, width 230mm;
4, cold rolling, cutting edge operation: adopt 7 passage rolling technology: 12.5mm-9.5mm-7.5mm-6.0mm-4.9mm-4.0mm-3.35mm-2.5mm; Preceding two passages of roughing are polished, are eliminated to ensure confession base quality the ingot blank surface imperfection, roll the back roughing blank is carried out cutting edge;
Gained made-up belt thickness 2.5mm, width 210mm;
5, annealing operation: the preheating zone design temperature is that 635 ℃, heating zone design temperature are that 645 ℃, heat preservation zone design temperature are 625 ℃, and the annealing cycle is about 7 hours; Annealing back ingot blank physicals is by tension>=294N/mm
2, extend>=55% and carry out an acceptance inspection;
6, blank pickling process: the sulphuric acid soln of operating weight concentration 10～12% carries out pickling, and 90～110 ℃ of oven dry.
7, rolling, the annealing process of work in-process and finished product is seen table-4;
Table-4 work in-process and finished product production technique
8, work in-process and finished product acid-washing technology:
First and second rolling process acid cleaning process: operating weight concentration is that 6～8% sulphuric acid soln carries out pickling, and 90～110 ℃ of oven dry.
The 3rd rolling process acid cleaning process: this operation is a finished product acid-washing; Operating weight concentration is that 4～6% sulphuric acid soln carries out pickling; And operating weight concentration is that 0.02% passivating solution (hc-10, Hangzhou Baimu Surface Technology Co., Ltd.) carries out passivation, and 90～110 ℃ of oven dry.
9, inspection process: finished surface, tolerance, band shape and physicals are detected, if all meet standard for acceptance then be regarded as salable product, otherwise qualitative be defective products;
End properties value: cupping: 9.42mm, HV value 88.6, the about 0.020mm of grain-size;
10, side cut, packaging process: in the future base width 210mm divides and is cut into the required width 200mm of client, and promptly finished product is: H650.25 * 200mm, and finished product packed warehouse-in;
Embodiment 2 (embodiment 1 Comparative Examples): brass band H650.25 * 200M production technique
1, founding operation: this instance is pressed cathode copper 1:B class material 4, and surplus is that zinc ingot metal is thrown stove, and gained ingot blank composition weight percent is:
Copper: 64.3, lead: 0.0090, iron: 0.018, tin: 0.025, nickel: 0.020, phosphorus: 0.004, other impurity elements: 0.072, surplus is a zinc.
The gained ingot blank is of a size of: thickness 165mm, width 210mm, length 4000mm;
2, heating, hot-rolled process, mill face operation, cutting edge operation, rough annealing operation, blank pickling process, work in-process and finished product acid-washing technology, inspection process, side cut, packaging process such as embodiment 1;
3, rolling, the annealing process of work in-process and finished product is seen table-5;
Table-5 work in-process and finished product production technique
End properties value: cupping: 9.45mm, HV value 87.2, the about 0.03mm of grain-size;
Because brass impurity component phosphorus exceeds standard of the present invention among the embodiment 2; Though in work in-process and finished product annealing process, make end properties satisfy requirement of the present invention through rationally adjusting annealing temperature; But its grain fineness number is bigger, is prone to the pitted skin phenomenon in the lamp holder drawing process, can not satisfy customer requirement;
Embodiment 3: brass band H650.25 * 200M production technique
1, founding operation: this instance is pressed cathode copper 1:B class material 4, and surplus is that zinc ingot metal is thrown stove, and gained ingot blank composition weight percent is:
Copper: 64.2, lead: 0.0075, iron: 0.012, tin: 0.018, nickel: 0.015, phosphorus: 0.0023, cerium: 0.002:0.0055, other impurity elements: 0.062, surplus is a zinc.
The gained ingot blank is of a size of: thickness 165mm, width 210mm, length 4000mm;
2, heating, hot-rolled process, mill face operation, cutting edge operation, rough annealing operation, blank pickling process, work in-process and finished product acid-washing technology, inspection process, side cut, packaging process such as embodiment 1;
3, rolling, the annealing process of work in-process and finished product is seen table-6;
Table-6 work in-process and finished product production technique
End properties value: cupping: 10.05mm, HV value 86.8, the about 0.025mm of grain-size;
Since the adding among the embodiment 3 in the brass rare-earth element cerium, its Erichsen number is significantly improved.
Embodiment 4: brass band H620.35 * 3004M production technique
1, founding operation: this instance is pressed category-B material 2: our factory H65 feed back 1, surplus are that zinc ingot metal is thrown stove, and gained ingot blank staple weight percent is:
Copper: 63.2, lead: 0.0090, iron: 0.0190, tin: 0.015, nickel: 0.0036, phosphorus: 0.0026, other impurity elements: 0.062, surplus is a zinc.
The gained ingot blank is of a size of: thickness 165mm, width 310mm, length 4000mm;
2, heating, hot rolling, to mill face, cold rolling, cutting edge, annealing, blank pickling process identical with embodiment 1;
3, work in-process and finished product production technique are seen table-7;
Table-7 work in-process and finished product production technique
4, work in-process and finished product acid-washing technology:
First and second rolling process acid cleaning process: operating weight concentration is that 6～8% sulphuric acid soln carries out pickling, and 90～110 ℃ of oven dry.
The 3rd rolling process acid cleaning process: this operation is a finished product acid-washing, and operating weight concentration is that 4～6% sulphuric acid soln carries out pickling, and operating weight concentration is that 0.02% passivating solution carries out passivation, and 90～110 ℃ of oven dry.
5, check, side cut, packaging process are identical with embodiment 1;
End properties value: cupping: 9.72mm, HV:89.5, the about 0.025mm of grain-size.
Claims (8)
1. lamp holder is with high stretch ability brass band, and it is characterized in that: described brass contains lead, iron, tin, nickel, copper, phosphorus, zinc;
Described lead content≤0.01%, iron level≤0.02%, tin content≤0.02%, nickel content≤0.02%, phosphorus content are 0.001-0.003%; Copper content 63.0-64.5%, surplus is a zinc.
2. lamp holder according to claim 1 is characterized in that: the cerium that also can in brass, add 0.001-0.003% with high stretch ability brass band.
Claim 1 or 2 described lamp holders with high stretch can brass band the preparation method, comprise following operation: founding operation, heating, hot-rolled process, mill face operation, cold rolling process, rough annealing operation, blank pickling process, work in-process and finished product rolling process, work in-process and finished product acid-washing, inspection process, side cut, packaging process.
4. lamp holder according to claim 3 is characterized in that with the preparation method of high stretch ability brass band:
Described heating, hot-rolled process: going out the ingot temperature is 820～850 ℃, and the heating time spent is 4 hours, guarantees before coming out of the stove that the ingot blank temperature is even.
5. lamp holder according to claim 3 is characterized in that with the preparation method of high stretch ability brass band:
Described cold rolling process: adopt 7 passage rolling technology: 12.5mm-9.5mm-7.5mm-6.0mm-4.9mm-4.0mm-3.35mm-2.5mm.
6. lamp holder according to claim 3 is characterized in that with the preparation method of high stretch ability brass band:
Described rough annealing operation: the preheating zone design temperature is that 635 ℃, heating zone design temperature are that 645 ℃, heat preservation zone design temperature are 625 ℃, and the annealing cycle is 7 hours; Annealing back ingot blank physicals is by tension>=294N/mm
2, extend>=55% and carry out an acceptance inspection.
7. lamp holder according to claim 3 is characterized in that with the preparation method of high stretch ability brass band:
Described blank pickling process: the sulphuric acid soln of operating weight concentration 10～12% carries out pickling, and 90～110 ℃ of oven dry.
8. lamp holder according to claim 3 is characterized in that with the preparation method of high stretch ability brass band:
Described work in-process and finished product acid-washing operation:
First and second rolling process acid cleaning process: operating weight concentration is that 6～8% sulphuric acid soln carries out pickling, and 90～110 ℃ of oven dry;
The 3rd rolling process acid cleaning process: this operation is a finished product acid-washing, and operating weight concentration is that 4～6% sulphuric acid soln carries out pickling, and operating weight concentration is that 0.02% passivating solution carries out passivation, and 90～110 ℃ of oven dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110282477 CN102329981B (en) | 2011-09-22 | 2011-09-22 | High-tensile property brass band for lamp holder and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110282477 CN102329981B (en) | 2011-09-22 | 2011-09-22 | High-tensile property brass band for lamp holder and production process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102329981A true CN102329981A (en) | 2012-01-25 |
| CN102329981B CN102329981B (en) | 2013-07-31 |
Family
ID=45481941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110282477 Active CN102329981B (en) | 2011-09-22 | 2011-09-22 | High-tensile property brass band for lamp holder and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102329981B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266239A (en) * | 2013-05-28 | 2013-08-28 | 宁波盛发铜业有限公司 | Tin-bismuth brass and production process thereof as well as device for producing tin-bismuth brass |
| CN103484718A (en) * | 2013-10-10 | 2014-01-01 | 铜陵金威铜业有限公司 | Lock making copper strip and preparation method thereof |
| CN104087881A (en) * | 2014-07-16 | 2014-10-08 | 安徽鑫科新材料股份有限公司 | Manufacturing technology for brass zipper wire |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5770247A (en) * | 1980-10-22 | 1982-04-30 | Hitachi Chem Co Ltd | Wear resistant and high tension brass alloy |
| EP1502965A1 (en) * | 2003-08-01 | 2005-02-02 | Kovohute Celakovice, a.s. | Free cutting brass alloy |
| CN1793394A (en) * | 2004-12-24 | 2006-06-28 | 株式会社神户制钢所 | Copper alloy having bendability and stress relaxation property |
| CN101077510A (en) * | 2007-06-08 | 2007-11-28 | 广州铜材厂有限公司 | Process for manufactruing blaster fuse frame copper alloy strip steel rolled stock used for integrate circuit |
| CN101100714A (en) * | 2007-07-20 | 2008-01-09 | 中铝洛阳铜业有限公司 | Corrosion resistant brass alloy material for plate heat exchanger and processing technique thereof |
| CN101654749A (en) * | 2009-09-14 | 2010-02-24 | 安徽精诚铜业股份有限公司 | Easily-cutting brass and processing method of strips thereof |
-
2011
- 2011-09-22 CN CN 201110282477 patent/CN102329981B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5770247A (en) * | 1980-10-22 | 1982-04-30 | Hitachi Chem Co Ltd | Wear resistant and high tension brass alloy |
| EP1502965A1 (en) * | 2003-08-01 | 2005-02-02 | Kovohute Celakovice, a.s. | Free cutting brass alloy |
| CN1793394A (en) * | 2004-12-24 | 2006-06-28 | 株式会社神户制钢所 | Copper alloy having bendability and stress relaxation property |
| CN101077510A (en) * | 2007-06-08 | 2007-11-28 | 广州铜材厂有限公司 | Process for manufactruing blaster fuse frame copper alloy strip steel rolled stock used for integrate circuit |
| CN101100714A (en) * | 2007-07-20 | 2008-01-09 | 中铝洛阳铜业有限公司 | Corrosion resistant brass alloy material for plate heat exchanger and processing technique thereof |
| CN101654749A (en) * | 2009-09-14 | 2010-02-24 | 安徽精诚铜业股份有限公司 | Easily-cutting brass and processing method of strips thereof |
Non-Patent Citations (3)
| Title |
|---|
| 张娟: "《微量元素对铝黄铜的腐蚀性能影响》", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 * |
| 金泉等: "高精度H65带的生产及展望", 《电子工业用铜合金材料研讨推广会文集》 * |
| 黎文献: "《有色金属材料工程概论》", 31 December 2007 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266239A (en) * | 2013-05-28 | 2013-08-28 | 宁波盛发铜业有限公司 | Tin-bismuth brass and production process thereof as well as device for producing tin-bismuth brass |
| CN103484718A (en) * | 2013-10-10 | 2014-01-01 | 铜陵金威铜业有限公司 | Lock making copper strip and preparation method thereof |
| CN103484718B (en) * | 2013-10-10 | 2016-06-29 | 铜陵金威铜业有限公司 | Lockmaking copper strips and its preparation method |
| CN104087881A (en) * | 2014-07-16 | 2014-10-08 | 安徽鑫科新材料股份有限公司 | Manufacturing technology for brass zipper wire |
| CN104087881B (en) * | 2014-07-16 | 2016-01-13 | 安徽鑫科新材料股份有限公司 | A kind of manufacturing process of brass teeth zipper line |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102329981B (en) | 2013-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105195510B (en) | A kind of 8B cold rolled precisions steel band and its manufacture method | |
| CN103014445B (en) | 5052 aluminum alloy end stock substrate and production method thereof | |
| CN105234171B (en) | A kind of 4B cold rolled precisions steel band and its manufacture method | |
| TW201702403A (en) | Steel sheet for hot stamping, method for manufacturing same, and hot stamp molded article | |
| CN104480391B (en) | A kind of hot rolling acid-cleaning plate and production method thereof | |
| CN103014452A (en) | 5182 aluminum alloy tab stock substrate and production method thereof | |
| CN111085542B (en) | Method for improving pitting defects on surface of cold-rolled 316L stainless steel | |
| CN108155281A (en) | A kind of small dimension LED copper strips production technologies | |
| CN111041327A (en) | Production method of cold-rolled steel strip with yield strength below 210MPa | |
| CN102794301A (en) | Manufacture method of cold-rolled electrolytic tin substrate | |
| CN109628803B (en) | Aluminum alloy checkered plate in 4017-H2X state and preparation method thereof | |
| CN108165822A (en) | A kind of preparation method of low-intensity, easily molded welded tube TA2 cold rolled titanium bands | |
| CN105537311A (en) | Production technology of copper strip for automobile contact | |
| CN104962812A (en) | Hot-continuous-rolled axle housing steel with favorable plate shape and manufacturing method thereof | |
| CN105088257B (en) | A kind of method for reducing blaster fuse frame material surface roughness | |
| CN102329981B (en) | High-tensile property brass band for lamp holder and production process thereof | |
| EP3354359B1 (en) | Method for manufacturing plated steel sheet having excellent clarity of image after coating | |
| CN103484718B (en) | Lockmaking copper strips and its preparation method | |
| CN109468505B (en) | 6061-H2X state aluminum alloy checkered plate and preparation method thereof | |
| CN110479774A (en) | The method for eliminating thin gauge hot rolling acid-cleaning steel surface pit defect | |
| CN109182918A (en) | A kind of vanadium Nb-microalloying low-carbon hot-rolling ribbon steel and preparation method thereof | |
| CN108149085A (en) | Excellent aluminium of a kind of surface quality of no annealing and preparation method thereof | |
| CN108060331A (en) | A kind of 3003H14 aluminum alloy plate materials and its production method | |
| CN108500066B (en) | Coordinated control method for tail thickness difference cold and hot rolling process of T5 hard tin plate | |
| CN108431286B (en) | Hot press molded article with suppressed microcrack and process for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 241008 Anhui province Wuhu City Jiuhua economic and Technological Development Zone No. 8 North Road Patentee after: ANHUI TRUCHUM ADVANCED MATERIALS AND TECHNOLOGY Co.,Ltd. Address before: 241008 Anhui province Wuhu City Jiuhua economic and Technological Development Zone No. 8 North Road Patentee before: ANHUI JINGCHENG COPPER Co.,Ltd. |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20120125 Assignee: QINGYUAN CHUJIANG COPPER CO.,LTD. Assignor: ANHUI JINGCHENG COPPER Co.,Ltd. Contract record no.: 2015440000648 Denomination of invention: High-tensile property brass band for lamp holder and production process thereof Granted publication date: 20130731 License type: Exclusive License Record date: 20150928 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170418 Address after: Chong Hing two high tech Industrial Development Zone, Guangdong province Qingyuan City Road 511500 No. 15 Patentee after: QINGYUAN CHUJIANG COPPER CO.,LTD. Address before: 241008 Anhui province Wuhu City Jiuhua economic and Technological Development Zone No. 8 North Road Patentee before: ANHUI TRUCHUM ADVANCED MATERIALS AND TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230406 Address after: 511500 No. 15, Chuangxing Second Road, high tech Industrial Development Zone, Qingyuan City, Guangdong Province (one site and multiple photos) Patentee after: Qingyuan Chujiang high precision copper strip Co.,Ltd. Address before: No.15, Chuangxing 2nd Road, Qingyuan hi tech Industrial Development Zone, Guangdong 511500 Patentee before: QINGYUAN CHUJIANG COPPER CO.,LTD. |