CN102311694A - Rinsing-free CTP (cytidine triphosphate) coating fluid and preparation method thereof - Google Patents

Rinsing-free CTP (cytidine triphosphate) coating fluid and preparation method thereof Download PDF

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CN102311694A
CN102311694A CN201110125452A CN201110125452A CN102311694A CN 102311694 A CN102311694 A CN 102311694A CN 201110125452 A CN201110125452 A CN 201110125452A CN 201110125452 A CN201110125452 A CN 201110125452A CN 102311694 A CN102311694 A CN 102311694A
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mixed solution
coating fluid
flushing
preparation
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CN102311694B (en
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刘华礼
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Abstract

The invention discloses a rinsing-free CTP (cytidine triphosphate) coating fluid, comprising the following components: vinyl sulphonate polymer, infrared light absorbent dye, carboxyl phenolic resin, water-soluble polymer, colloidal silicon dioxide, acid catalyst, diethyl ether solvent and butanone. The invention also discloses a preparation method of the rinsing-free CTP coating fluid. The preparation method comprises the following steps of: adding the carboxyl phenolic resin into the diethyl ether solvent solution to form a mixed solution I; adding butanone to form a mixed solution II; adding the vinyl sulphonate polymer to form a mixed solution III; adding the infrared light absorbent dye to form a mixed solution IV; adding the water-soluble polymer to form a mixed solution V; adding the colloidal silicon dioxide to form a mixed solution VI; adding the acid catalyst to form a mixed solution VII; stirring for the eighth time after all the raw materials are added to form the rinsing-free CTP coating fluid; and filtering a crude finished product by virtue of a filter to form the finished product. The rinsing-free CTP coating fluid disclosed by the invention has high sensitivity, strong adhering force, ink-water balance and large coating latitude, high printing resistance rate and high film retention rate.

Description

A kind of flushing-free CTP coating fluid and preparation method thereof
Technical field
The present invention relates to a kind of flushing-free CTP coating fluid and preparation method thereof
Background technology
Flushing-free CTP version need not to develop with chemical development liquid after being plate-making, and only needs with flushing with clean water or need not to carry out any processing just directly to go up the plate that machine prints.Have only the thermosensitive CTP coating fluid in the market, and do not have flushing-free CTP coating fluid, the present invention has filled up blank.
Summary of the invention
The invention provides a kind of flushing-free CTP coating fluid and preparation method thereof, not only sensitivity is fast for it, and adhere to and stand by force, ink-water balance, the coating latitude is big, and press resistance rate is strong, film-remaining ratio is high.
The present invention has adopted following technical scheme: a kind of flushing-free CTP version coating fluid, it comprises following component: vinyl sulfonic acid ester polymer, infrared Absorption dyestuff, carboxylic phenolic resin, water-soluble polymers, colloidal silica, acid catalyst, ether solvent and butanone.
The weight of each component of the present invention is: vinyl sulfonic acid ester polymer 5-35 weight part, infrared Absorption dyestuff 2-5 weight part, carboxylic phenolic resin 30-80 weight part, water-soluble polymers 0.5-5 weight part, colloidal silica 0.5-5 weight part, acid catalyst 2-5 weight part, ether solvent 20-50 weight part, butanone 80-100 weight part.
A kind of preparation method of flushing-free CTP coating fluid, it may further comprise the steps: step 1 adds carboxylic phenolic resin and carries out stirring the first time back in the ether solvent solution and form mixed solution I; Step 2 adds butanone and carries out stirring the second time back in the mixed solution I and form mixed solution I I; Step 3 adds the vinyl sulfonic acid ester polymer and stirs back formation mixed solution I II for the third time in mixed solution I I; Step 4; Form mixed solution I V with carrying out stirring for the 4th time the back among the infrared Absorption dyestuff adding mixed solution I II; Then water-soluble polymers is added and carry out stirring for the 5th time back formation mixing solutions V among the mixed solution I V, at last colloidal silica is added to carry out among the mixing solutions V stirring for the 6th time forming and mix VI; Step 5 adds acid catalyst and carries out stirring for the 7th time the back among the mixing solutions VI and form mixing solutions VII, adds at raw material and carries out stirring for the 8th time the back again after finishing and form flushing-free CTP coating fluid; Step 6, the first finished product of flushing-free CTP coating fluid is filtered the back through strainer form finished product.
In the step 1 for the first time churning time be 1.5 hours; The time of stirring for the second time in the step 2 is 0.5 hour; In the step 3 for the third time churning time be 8 hours; The 4th churning time is 1 hour in the step 4, and the 5th time churning time is 1 hour, and the 6th time churning time is 1 hour; The 7th churning time in the step 5 is 1 hour, and the 8th time churning time is 8 hours; The step 6 middle filtrator is 3 microns a strainer.
The present invention has following beneficial effect: the present invention it not only sensitivity is fast, adhere to upright strong, ink-water balance, the coating latitude is big, and press resistance rate is strong, film-remaining ratio is high.
Embodiment
A kind of flushing-free CTP version coating fluid, it comprises following component: vinyl sulfonic acid ester polymer 5-35 weight part, infrared Absorption dyestuff 2-5 weight part, carboxylic phenolic resin 30-80 weight part, water-soluble polymers 0.5-5 weight part, colloidal silica 0.5-5 weight part, acid catalyst 2-5 weight part, ether solvent 20-50 weight part, butanone 80-100 weight part.
A kind of preparation method of flushing-free CTP coating fluid, it may further comprise the steps: step 1 adds carboxylic phenolic resin to carry out in the ether solvent solution stirring the first time and forms mixed solution I after 1.5 hours; Step 2 adds butanone to carry out in the mixed solution I stirring the second time and forms mixed solution I I after 0.5 hour; Step 3 adds the vinyl sulfonic acid ester polymer and stirs formation mixed solution I II after 8 hours for the third time in mixed solution I I; Step 4; Form mixed solution I V after 1 hour with carrying out the 4th stirring among the infrared Absorption dyestuff adding mixed solution I II; Then water-soluble polymers is added to carry out among the mixed solution I V stirring for the 5th time and form mixing solutions V after 1 hour, at last colloidal silica is added to carry out among the mixing solutions V stirring for the 6th time forming in 1 hour and mix VI; Step 5 adds acid catalyst to carry out among the mixing solutions VI stirring for the 7th time and forms mixing solutions VII after 1 hour, adds forming flushing-free CTP coating fluid after carrying out stirring 8 hours the 8th time after finishing at raw material again; Step 6, the first finished product of the flushing-free CTP coating fluid strainer through 3 microns is filtered the back form finished product.

Claims (9)

1. a flushing-free CTP version coating fluid is characterized in that it comprises following component: vinyl sulfonic acid ester polymer, infrared Absorption dyestuff, carboxylic phenolic resin, water-soluble polymers, colloidal silica, acid catalyst, ether solvent and butanone.
2. flushing-free CTP coating fluid according to claim 1 is characterized in that the weight of each component is: vinyl sulfonic acid ester polymer 5-35 weight part, infrared Absorption dyestuff 2-5 weight part, carboxylic phenolic resin 30-80 weight part, water-soluble polymers 0.5-5 weight part, colloidal silica 0.5-5 weight part, acid catalyst 2-5 weight part, ether solvent 20-50 weight part, butanone 80-100 weight part.
3. the preparation method of a kind of flushing-free CTP coating fluid according to claim 1 is characterized in that it may further comprise the steps:
Step 1 adds carboxylic phenolic resin and carries out stirring the first time back in the ether solvent solution and form mixed solution I;
Step 2 adds butanone and carries out stirring the second time back in the mixed solution I and form mixed solution I I;
Step 3 adds the vinyl sulfonic acid ester polymer and stirs back formation mixed solution I II for the third time in mixed solution I I;
Step 4; Form mixed solution I V with carrying out stirring for the 4th time the back among the infrared Absorption dyestuff adding mixed solution I II; Then water-soluble polymers is added and carry out stirring for the 5th time back formation mixing solutions V among the mixed solution I V, at last colloidal silica is added to carry out among the mixing solutions V stirring for the 6th time forming and mix VI;
Step 5 adds acid catalyst and carries out stirring for the 7th time the back among the mixing solutions VI and form mixing solutions VII, adds at raw material and carries out stirring for the 8th time the back again after finishing and form flushing-free CTP coating fluid;
Step 6, the first finished product of flushing-free CTP coating fluid is filtered the back through strainer form finished product.
4. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that in the step 1 that churning time is 1.5 hours for the first time.
5. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that the time of stirring for the second time in the step 2 is 0.5 hour.
6. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that in the step 3 that churning time is 8 hours for the third time.
7. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that the 4th churning time is 1 hour in the step 4, the 5th time churning time is 1 hour, and the 6th time churning time is 1 hour.
8. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that the 7th churning time in the step 5 is 1 hour, the 8th time churning time is 8 hours.
9. according to the preparation method of the said flushing-free CTP of claim 3 coating fluid, it is characterized in that the step 6 middle filtrator is 3 microns a strainer.
CN 201110125452 2011-05-10 2011-05-10 Rinsing-free CTP (cytidine triphosphate) coating fluid and preparation method thereof Active CN102311694B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106950799A (en) * 2017-03-28 2017-07-14 惠州市潮新科数字器材科技有限公司 Photosensitive glue composition and its application in electrochemical treatments heat-sensitive CTP plate is exempted from

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN1603956A (en) * 2003-09-30 2005-04-06 北京师范大学 Image-forming composition for heat-sensitive CTP image base, acid generating source for the composition and preparation thereof
JP2006133263A (en) * 2004-11-02 2006-05-25 Konica Minolta Medical & Graphic Inc Method for correcting lithographic printing plate and eradicating liquid
CN101316720A (en) * 2005-11-29 2008-12-03 柯尼卡美能达医疗印刷器材株式会社 Lithographic printing plate material and printing method
CN101636694A (en) * 2007-03-23 2010-01-27 三菱制纸株式会社 Photosensitive lithographic printing plate material developable with water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1603956A (en) * 2003-09-30 2005-04-06 北京师范大学 Image-forming composition for heat-sensitive CTP image base, acid generating source for the composition and preparation thereof
JP2006133263A (en) * 2004-11-02 2006-05-25 Konica Minolta Medical & Graphic Inc Method for correcting lithographic printing plate and eradicating liquid
CN101316720A (en) * 2005-11-29 2008-12-03 柯尼卡美能达医疗印刷器材株式会社 Lithographic printing plate material and printing method
CN101636694A (en) * 2007-03-23 2010-01-27 三菱制纸株式会社 Photosensitive lithographic printing plate material developable with water

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韩星周等: "可控丙烯酸制备水溶性酚醛树脂的研究", 《影像技术》, no. 5, 15 October 2007 (2007-10-15), pages 16 - 17 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106950799A (en) * 2017-03-28 2017-07-14 惠州市潮新科数字器材科技有限公司 Photosensitive glue composition and its application in electrochemical treatments heat-sensitive CTP plate is exempted from
CN106950799B (en) * 2017-03-28 2020-10-30 广东潮新科数字科技有限公司 Photosensitive emulsion composition and application thereof in electrochemical-free treatment of thermosensitive CTP (computer to plate)

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