CN102311593A - Digital painting material with high precision printing used in printer and its production method - Google Patents

Digital painting material with high precision printing used in printer and its production method Download PDF

Info

Publication number
CN102311593A
CN102311593A CN201110193966A CN201110193966A CN102311593A CN 102311593 A CN102311593 A CN 102311593A CN 201110193966 A CN201110193966 A CN 201110193966A CN 201110193966 A CN201110193966 A CN 201110193966A CN 102311593 A CN102311593 A CN 102311593A
Authority
CN
China
Prior art keywords
parts
embossing
rolling
lubricant
pvc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201110193966A
Other languages
Chinese (zh)
Other versions
CN102311593B (en
Inventor
涂志伟
姚桂松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG HAILIDE NEW MATERIAL CO Ltd
Original Assignee
ZHEJIANG HAILIDE NEW MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG HAILIDE NEW MATERIAL CO Ltd filed Critical ZHEJIANG HAILIDE NEW MATERIAL CO Ltd
Priority to CN2011101939668A priority Critical patent/CN102311593B/en
Publication of CN102311593A publication Critical patent/CN102311593A/en
Application granted granted Critical
Publication of CN102311593B publication Critical patent/CN102311593B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B29C47/92

Landscapes

  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Ink Jet (AREA)

Abstract

The invention relates to a high-molecular digital painting material used in a printer and its production method. The digital painting material with high precision printing takes PVC as a raw material and is produced by adding a plasticizer, soybean oil, a liquid stabilizing agent without adding a lubricant, nanometer calcium, titanium dioxide and color powder. The formula comprises the following materials by weight: 100 parts of PVC, 30-50 parts of plasticizer, 3-6 parts of soybean oil, 3-6 parts of liquid stabilizing agent without adding the lubricant, 30-100 parts of nanometer calcium, 0.3-5 parts of titanium dioxide and 0.01-5 parts of color powder. The production method comprises the following steps: mixing, plasticizing, filtering, molding, embossing, cold cutting, trimming, rolling, applying, secondary embossing, secondary cold cutting, secondary trimming and secondary rolling. The wetting tension force on the product surface is large and the free energy rises from original 35 dyne to 36 dyne. The digital painting material with high precision printing is capable of enhancing the ink absorption of the surface, the painting effect reaches high color saturation, the digital painting material with high precision printing has the advantages of good reductibility, brightness, beauty and the like, is suitable for a high-speed painting machine, and can be widely used for the field of the painting advertisements.

Description

Break air brushing material and preparation method thereof in a kind of finishing impression polymer number
Technical field
The invention belongs to the macromolecular material production technical field, particularly relate in a kind of polymer number and break the air brushing material, relate to simultaneously and beat the air brushing preparation methods in this polymer number.
Background technology
The application of breaking the air brushing material at present in the advertising polymer number is increasingly extensive, and some high-end customers on the world market improve constantly the requirement of beating air brushing material absorbency in the polymer number.Along with release, especially the UV air brushing machine of high speed air brushing machine on the world market, air brushing speed is fast, is badly in need of the good print media of absorbency.Currently available products can not adapt to the high-end customer demands of applications because of the absorbency problem.Beat the big gap of air brushing material absorbency and international high-end product ubiquity in state's inner macromolecule number; The competition more and more fierce of advertising; High functions such as enterprise has proposed increasingly high requirement to the air brushing material produce, and high speed air brushing, colorimetric purity are high, Well-recovered, bright, gorgeous have been the certainty of advertisement field development.
Summary of the invention
The present invention has proposed to break the air brushing material in a kind of finishing impression polymer number in order to overcome the deficiency that prior art exists, and its absorbency excellent property simultaneously, the invention allows for and beats the air brushing preparation methods in this finishing impression polymer number.
The technical scheme that technical solution problem of the present invention is taked is:
Breaking the air brushing material in a kind of finishing impression polymer number, is raw material with PVC, and adding softening agent, VT 18, employing are not added liquid stabilisers, Namigai, white titanium pigment and the toner of lubricant and be prepared from; It is characterized in that its prescription is counted with weight part:
100 parts of PVC,
Softening agent 30-50 part,
VT 18 3-6 part,
Do not add liquid stabilisers 3-6 part of lubricant,
Namigai 30-100 part,
White titanium pigment 0.3-5 part,
Toner 0.01-5 part;
Its surface free energy reaches 36 dyne.
As a kind of preferred; The polymerization degree of said PVC is 700-1000; Said softening agent is DOP (DOP) or DINP (DINP), and the said liquid stabilisers that does not add lubricant is not for adding the barium cadmium zinc stabilizer of lubricant, and said Namigai is the activation Namigai; Said white titanium pigment is anatase thpe white powder or Rutile type Titanium Dioxide, and said toner is ultramarine and/or whitening agent and/or permanent violet.
Beat the air brushing preparation methods in a kind of finishing impression polymer number, it comprises prescription, mixing, plasticizing, filtration, moulding, embossing, cold cut, cutting edge, rolling, applying, secondary embossing, secondary cold cut, secondary cutting edge and secondary rolling step; Wherein,
⑴ prescription, in weight part:
100 parts of PVC,
Softening agent 30-50 part,
VT 18 3-6 part,
Do not add liquid stabilisers 3-6 part of lubricant,
Namigai 30-100 part,
White titanium pigment 0.3-5 part,
Toner 0.01-5 part;
⑵ mix: the raw material of the step of will filling a prescription ⑴ is put into impeller and is stirred, and controlled temperature is 100-130 ℃, churning time 300-500 second; Put into the cold stirrer stirring of low speed then and be cooled to 80-100 ℃;
⑶ plasticizing: through the planetary extruder extrusion plasticizing, the control extruder temperature is 160-190 ℃ with mixing step ⑵ gained compound; Move to two rolling turbines then and further plastify, 190-220 ℃ of turbine temperature rolled in control;
⑷ filter: after plasticizing step ⑶ fully plastified, again through the filter impurity screening, filtering the mesh number was the 80-120 order, and controlled temperature is 170-200 ℃;
⑸ moulding: get into the four-roll calender calendering formation then, controlled temperature is 165-210 ℃;
⑹ embossing, cold cut, cutting edge, rolling: promptly carry out embossing, cold cut then, cutting edge, rolling after the moulding;
⑺ fit: by the PVC film that forming step ⑸ obtains, after embossing, cold cut, cutting edge, each step of rolling, fit at rigging machine; Be about to the PVC film as counterdie and facial mask; Applying one deck screen cloth in the middle of counterdie and facial mask: counterdie is preheated to 110-140 ℃, and screen cloth is preheated to 80-110 ℃, gets into main heated wheel and fits; Binding temperature 170-200 ℃, laminate pressure 5-20kg; Simultaneously facial mask is preheated to 120-150 ℃, fits laminate pressure 15-50kg again at the main heated wheel and the counterdie of the screen cloth of having fitted;
⑻ secondary embossing, secondary cold cut, secondary cutting edge, secondary rolling: promptly carry out the secondary embossing after the applying, secondary embossing pressure 50-80kg carries out secondary cold cut, secondary cutting edge, secondary rolling then.
As a kind of preferred; In the said prescription, the polymerization degree of said PVC is 700-1000, and said softening agent is DOP (DOP) or DINP (DINP); The said liquid stabilisers that does not add lubricant is not for adding the barium cadmium zinc stabilizer of lubricant; Said Namigai is the activation Namigai, and said white titanium pigment is anatase thpe white powder or Rutile type Titanium Dioxide, and said toner is ultramarine and/or whitening agent and/or permanent violet.
The liquid stabilisers of lubricant is not added in the present invention's employing; Its principle is: not adding the liquid stabilisers of lubricant, in the course of processing, do not have lubricant to separate out, is that moistened surface tension force reduces because lubricant is separated out the surface free energy reduction that can make product; Thereby improved the product surface wetting tension greatly; Improve the free energy of product surface, strengthened the ink receptivity of product surface
Break the air brushing material in the finishing impression polymer number by preparation method of the present invention preparation, it is big to have moistened surface tension force, and free energy is brought up to 36 dyne by 35 original dyne; Strengthened the ink receptivity of product surface; Not only air brushing effect reaches colorimetric purity height, advantage such as Well-recovered, bright, gorgeous, also is fit to high speed air brushing machine, especially UV air brushing machine; Improve air brushing speed and air brushing efficient greatly, can be widely used in the painting advertisement field.
Description of drawings
Fig. 1 is preparing method's technological process of production figure of the present invention.
Embodiment
Embodiment 1: beat the prescription of air brushing material in a kind of finishing impression polymer number, in weight part:
The polymerization degree is 100 parts of 800 PVC,
40 parts of DOPs (DOP),
3 parts of VT 18s,
Do not add 5 parts of the barium cadmium zinc stabilizers of lubricant,
50 parts of Namigai,
0.4 part of anatase thpe white powder,
0.1 part in ultramarine.
Embodiment 2: beat the prescription of air brushing material in the another kind of finishing impression polymer number, in weight part:
The polymerization degree is 100 parts of 900 PVC,
37 parts of DOPs (DOP),
3 parts of VT 18s,
Do not add 5 parts of the barium cadmium zinc stabilizers of lubricant,
50 parts of Namigai,
0.4 part of Rutile type Titanium Dioxide,
0.1 part in ultramarine.
Embodiment 3: beat the prescription of air brushing material in another finishing impression polymer number, in weight part:
The polymerization degree is 100 parts of 900 PVC,
40 parts of DINPs (DINP),
3 parts of VT 18s,
Do not add 5 parts of the barium cadmium zinc stabilizers of lubricant,
50 parts of Namigai,
0.4 part of Rutile type Titanium Dioxide,
0.1 part in ultramarine,
0.1 part of permanent violet.
Embodiment 4: beat the prescription of air brushing material in another finishing impression polymer number, in weight part:
The polymerization degree is 100 parts of 800 PVC,
40 parts of DINPs (DINP),
5 parts of VT 18s,
Do not add 5 parts of the barium cadmium zinc stabilizers of lubricant,
50 parts of Namigai,
0.4 part of Rutile type Titanium Dioxide,
0.1 part in ultramarine,
0.1 part in whitening agent.
Embodiment 5: beat the air brushing preparation methods in a kind of finishing impression polymer number:
The raw material of embodiment 1 prescription is put into impeller in weight part stir, controlled temperature is 120 ℃, churning time 430 seconds; Put into the cold stirrer stirring of low speed subsequently and be cooled to 85 ℃; Drop into the planetary extruder extrusion plasticizing then, the control extruder temperature is 185 ℃; And then move to two rolling turbines and further plastify, 205 ℃ of turbine temperature are rolled in control; Through the filter impurity screening, filtering the mesh number is 100 orders again, and controlled temperature is 180 ℃; Get into the four-roll calender calendering formation then, controlled temperature is 190 ℃, and through embossing, cold cut, cutting edge, rolling.Resulting PVC film is fitted at rigging machine as counterdie and facial mask, and promptly applying one deck screen cloth in the middle of counterdie and facial mask is preheated to 130 ℃ with counterdie, and screen cloth is preheated to 100 ℃, gets into main heated wheel and fits 190 ℃ of binding temperatures, laminate pressure 7kg; Simultaneously facial mask is preheated to 130 ℃, fits laminate pressure 25kg again at the main heated wheel and the screen cloth counterdie of having fitted; Carry out embossing once more, embossing pressure 65kg carries out cold cut, cutting edge, rolling once more.Get product.
Embodiment 6: beat the air brushing preparation methods in the another kind of finishing impression polymer number:
The raw material of embodiment 3 prescriptions is put into impeller in weight part stir, controlled temperature is 115 ℃, churning time 470 seconds; Put into the cold stirrer stirring of low speed subsequently and be cooled to 80 ℃; Drop into the planetary extruder extrusion plasticizing then, the control extruder temperature is 185 ℃; And then further plastify to two rolling turbines, 206 ℃ of turbine temperature are rolled in control; Through the filter impurity screening, filtering the mesh number is 120 orders again, and controlled temperature is 187 ℃; Get into the four-roll calender calendering formation then, controlled temperature is 195 ℃, and through embossing, cold cut, cutting edge, rolling.Resulting PVC film is fitted at rigging machine as counterdie and facial mask, and promptly applying one deck screen cloth in the middle of counterdie and facial mask is preheated to 125 ℃ with counterdie, and screen cloth is preheated to 90 ℃, gets into main heated wheel and fits 198 ℃ of binding temperatures, laminate pressure 10kg; Simultaneously facial mask is preheated to 143 ℃, fits laminate pressure 30kg again at the main heated wheel and the screen cloth counterdie of having fitted; Carry out embossing once more, embossing pressure 60kg carries out cold cut, cutting edge, rolling once more.Get product.

Claims (4)

1. breaking the air brushing material in a finishing impression polymer number, is raw material with PVC, and adding softening agent, VT 18, employing are not added liquid stabilisers, Namigai, white titanium pigment and the toner of lubricant and be prepared from; It is characterized in that its prescription is counted with weight part:
100 parts of PVC,
Softening agent 30-50 part,
VT 18 3-6 part,
Do not add liquid stabilisers 3-6 part of lubricant,
Namigai 30-100 part,
White titanium pigment 0.3-5 part,
Toner 0.01-5 part;
Its surface free energy reaches 36 dyne.
2. break the air brushing material in a kind of finishing impression polymer number according to claim 1; It is characterized in that the polymerization degree of said PVC is 700-1000, said softening agent is DOP or DINP; The said liquid stabilisers that does not add lubricant is not for adding the barium cadmium zinc stabilizer of lubricant; Said Namigai is the activation Namigai, and said white titanium pigment is anatase thpe white powder or Rutile type Titanium Dioxide, and said toner is ultramarine or whitening agent or permanent violet.
3. beat the air brushing preparation methods in a kind of finishing impression polymer number according to claim 1, comprise prescription, mixing, plasticizing, filtration, moulding, embossing, cold cut, cutting edge, rolling, applying, secondary embossing, secondary cold cut, secondary cutting edge and secondary rolling step; It is characterized in that: wherein,
⑴ prescription, in weight part:
100 parts of PVC,
Softening agent 30-50 part,
VT 18 3-6 part,
Do not add liquid stabilisers 3-6 part of lubricant,
Namigai 30-100 part,
White titanium pigment 0.3-5 part,
Toner 0.01-5 part;
⑵ mix: the raw material of the step of will filling a prescription ⑴ is put into impeller and is stirred, and controlled temperature is 100-130 ℃, churning time 300-500 second; Put into the cold stirrer stirring of low speed then and be cooled to 80-100 ℃;
⑶ plasticizing: through the planetary extruder extrusion plasticizing, the control extruder temperature is 160-190 ℃ with mixing step ⑵ gained compound; Move to two rolling turbines then and further plastify, 190-220 ℃ of turbine temperature rolled in control;
⑷ filter: after plasticizing step ⑶ fully plastified, again through the filter impurity screening, filtering the mesh number was the 80-120 order, and controlled temperature is 170-200 ℃;
⑸ moulding: get into the four-roll calender calendering formation then, controlled temperature is 165-210 ℃;
⑹ embossing, cold cut, cutting edge, rolling: promptly carry out embossing, cold cut then, cutting edge, rolling after the moulding;
⑺ fit: by the PVC film that forming step ⑸ obtains, after embossing, cold cut, cutting edge, each step of rolling, fit at rigging machine; Be about to the PVC film as counterdie and facial mask; Applying one deck screen cloth in the middle of counterdie and facial mask: counterdie is preheated to 110-140 ℃, and screen cloth is preheated to 80-110 ℃, gets into main heated wheel and fits; Binding temperature 170-200 ℃, laminate pressure 5-20kg; Simultaneously facial mask is preheated to 120-150 ℃, fits laminate pressure 15-50kg again at the main heated wheel and the counterdie of the screen cloth of having fitted;
⑻ secondary embossing, secondary cold cut, secondary cutting edge, secondary rolling: promptly carry out the secondary embossing after the applying, secondary embossing pressure 50-80kg carries out secondary cold cut, secondary cutting edge, secondary rolling then.
4. beat the air brushing preparation methods in a kind of finishing impression polymer number according to claim 3; It is characterized in that; In the said prescription, the polymerization degree of said PVC is 700-1000, and said softening agent is DOP or DINP; The said liquid stabilisers that does not add lubricant is not for adding the barium cadmium zinc stabilizer of lubricant; Said Namigai is the activation Namigai, and said white titanium pigment is anatase thpe white powder or Rutile type Titanium Dioxide, and said toner is ultramarine or whitening agent or permanent violet.
CN2011101939668A 2011-07-12 2011-07-12 Preparation method of digital painting material with high precision printing used in printer Active CN102311593B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101939668A CN102311593B (en) 2011-07-12 2011-07-12 Preparation method of digital painting material with high precision printing used in printer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101939668A CN102311593B (en) 2011-07-12 2011-07-12 Preparation method of digital painting material with high precision printing used in printer

Publications (2)

Publication Number Publication Date
CN102311593A true CN102311593A (en) 2012-01-11
CN102311593B CN102311593B (en) 2013-01-23

Family

ID=45425182

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011101939668A Active CN102311593B (en) 2011-07-12 2011-07-12 Preparation method of digital painting material with high precision printing used in printer

Country Status (1)

Country Link
CN (1) CN102311593B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102719033A (en) * 2012-06-07 2012-10-10 浙江海利得新材料股份有限公司 Ceiling decorative soft film material and production process thereof
CN103435942A (en) * 2013-09-09 2013-12-11 苏州睿智同策广告有限公司 PVC (Polyvinyl Chloride) base film, spray printing cloth for light box advertising and manufacturing method of spray printing cloth
CN105109178A (en) * 2015-09-10 2015-12-02 浙江亦阳新材料有限公司 Production equipment for multi-roll heat-attaching shading ultra-flat advertisement cloth
CN106739351A (en) * 2016-12-14 2017-05-31 张明玉 Compound tablecloths of a kind of heat-resisting medical stone powder PVC and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
孙永明等: "高分子数码喷绘网格材料的研制", 《合成纤维》 *
王林等: "喷绘广告布的研制", 《塑料科技》 *
黄晶: "聚氯乙烯高吸附数码喷绘基膜的开发与生产", 《聚氯乙烯》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102719033A (en) * 2012-06-07 2012-10-10 浙江海利得新材料股份有限公司 Ceiling decorative soft film material and production process thereof
CN103435942A (en) * 2013-09-09 2013-12-11 苏州睿智同策广告有限公司 PVC (Polyvinyl Chloride) base film, spray printing cloth for light box advertising and manufacturing method of spray printing cloth
CN105109178A (en) * 2015-09-10 2015-12-02 浙江亦阳新材料有限公司 Production equipment for multi-roll heat-attaching shading ultra-flat advertisement cloth
CN106739351A (en) * 2016-12-14 2017-05-31 张明玉 Compound tablecloths of a kind of heat-resisting medical stone powder PVC and preparation method thereof

Also Published As

Publication number Publication date
CN102311593B (en) 2013-01-23

Similar Documents

Publication Publication Date Title
CN104594065B (en) Method for producing jacquard synthetic leather
CN102311593B (en) Preparation method of digital painting material with high precision printing used in printer
CN107443945B (en) A kind of elasticity thermal transfer is carved characters film and its production method
CN101581042B (en) Non-curling flexible composite material
CN105440493A (en) High-cold-resistant embossed printed polyvinyl chloride sheet and preparation method thereof
CN105058936A (en) High-strength flame-retardant mould-proof embossed wall cloth and production technology thereof
CN103465669A (en) Heat transfer printing membrane and manufacturing method thereof
CN103602143A (en) Transfer printing ink with release function
CN105274897A (en) Preparation method of digital inkjet printing paper paint
CN102344625A (en) Weather-resistant polymer digital internal-printing spray-drawing material and preparation method thereof
CN108274864A (en) A kind of modified TPU film-fabric compound and preparation method thereof
CN104312278A (en) Green and environment-friendly printing ink for plastic film and making method thereof
CN104745114B (en) A kind of inducing QI traffic allowance and preparation method thereof
CN102408686B (en) Tape-cast polyester film and preparation method thereof
CN110219434A (en) A kind of TPU stone plastic floor of high abrasion and preparation method thereof
CN110452476A (en) A kind of high glaze PVC light tunica albuginea and its production technology
CN103061158B (en) Trademark leather and preparation method thereof
CN102321292B (en) Metallocene polyethene (PE) rich mineral paper and making method thereof
CN106905643A (en) A kind of scratch resistance bloom PVC film and preparation method thereof
CN102873890B (en) Preparation method of polyethylene polymer composite membrane
CN109320868A (en) A kind of high covering lamp box film
CN106317796A (en) PETG cast film and preparation process thereof
CN103483964A (en) Ultraviolet-resistant release agent for PET (polyethylene terephthalate) heat transfer film and preparation method of release agent
CN112537107A (en) High-performance styrene-butadiene block copolymer-based superfine fiber synthetic leather and production method thereof
CN109130677A (en) Clinquant skin sense decorating film and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant