CN102310159A - Water-based powder-type dip-coating coating for cast iron cold-box core - Google Patents

Water-based powder-type dip-coating coating for cast iron cold-box core Download PDF

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Publication number
CN102310159A
CN102310159A CN201010583092A CN201010583092A CN102310159A CN 102310159 A CN102310159 A CN 102310159A CN 201010583092 A CN201010583092 A CN 201010583092A CN 201010583092 A CN201010583092 A CN 201010583092A CN 102310159 A CN102310159 A CN 102310159A
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agent
coating
powder
surplus
water
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CN201010583092A
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CN102310159B (en
Inventor
陈莉
蔡安克
郭亚辉
李锋军
刘文曾
董选普
程俊伟
袁书仓
王海平
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China Yituo Group Corp Ltd
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China Yituo Group Corp Ltd
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Abstract

The invention relates to water-based powder-type coatings and provides a water-based powder-type dip-coating coating for a cast iron cold-box core. The coating comprises the following ingredients in percentage by weight: 1.5%-2.0% of L-bentonite, 2.5%-3.0% of paligorskite, 0.1%-0.3% of hydroxyethyl cellulose, 0.2%-0.4% of flatting agent, 0.7%-1.0% of defoaming agent, 0.01%-0.03% of corrosion preventive, 0.8%-1.2% of binding agent, 0.5%-1.0% of wetting agent, 5%-10% of agglutinant and the rest amount of refractory aggregate, wherein the aggregate consists of quartz powder, pyrophillite powder and graphite powder which respectively has the grain diameter of 200-320 meshes, the quartz powder is 50-65% of the rest amount, the pyrophillite powder is 20-35% of the rest amount, and the graphite powder is 10-20% of the rest amount.

Description

A kind of cast iron cold-box core water original washing powder shape dip-coating paint
[technical field]
The present invention relates to casting water original washing powder shape coating, mainly propose a kind of cast iron cold-box core water original washing powder shape dip-coating paint.
[background technology]
Main casting cylinder body on the engine, cylinder cap be the general cold-box core assembly that adopts in casting process, and core manufacturing craft is complicated, and required precision is high; The cold-box water based paint is the main body coating that vital part cores such as engine cylinder-body, cylinder cap are used, and the quality of its performance is directly connected to the casting quality quality.According at present domestic and international engine cylinder-body, the cylinder cap condition of production; Producing the water-based dip applicating paint that adopts all is import or joint manufacturer production, and crucial auxiliary material quality used in the coating is good, and the various performance indications of coating are high; Coating like manufacturer production such as Foseco, Asland, HA; After the coating brushing, surface-brightening is smooth, no hole, crackle, stays defectives such as trace.External coating quality is good, but costs an arm and a leg, and homemade coating also has reasonable, and coating quality is unstable, and total quality is bigger with external coating gap.Homemade coating has the deficiency of following several respects;
1, the defoaming effect of coating is poor
Homemade coating all can have bubble more or less in use, have very big, have very little, eliminate foam fully and not be easy to, therefore, antifoaming agent select the defoaming effect that directly has influence on coating for use.
2, the levelability of coating is not good
After the core dip-coating, the surface has significantly stays trace, accumulation, and coating layer thickness is inhomogeneous up and down, therefore, selects which kind of levelling agent for use and the refractory material system that can be complementary with it is very important.
3, the wetability of coating and core is poor
After the core dip-coating, coating and core wetability are poor, and coating can not effectively infiltrate the core surface fast, and on vertical plane, coutinuity of coating is destroyed, and causes coating one's water breaks defective, therefore, selecting for use of wetting agent, also most important to the cold-box water based paint.
 
[summary of the invention]
To the technological difficulties in the background technology, the invention provides a kind of cast iron cold-box core water original washing powder shape dip-coating paint.
In order to realize that the object of the invention adopts following technical scheme:
A kind of water base powdery dip-coating paint that is used for the cast iron cold-box core, the compositions in weight percentage of said coating:
Lithium bentonite 1.5%~2.0%;
Palygorskite soil 2.5%~3.0%;
Hydroxyethylcellulose 0.1%~0.3%;
Levelling agent 0.2%~0.4%;
Antifoaming agent 0.7%~1.0%;
Anticorrisive agent 0.01%~0.03%;
Binding agent 0.8%~1.2%;
Wetting agent 0.5%~1.0%;
Sintering aid 5%~10%;
Surplus is a refractory aggregate, and refractory aggregate is three kinds of 200~320 purpose silica flours, pyrophyllite powder, graphite powder; Wherein silica flour account for surplus 50~65%, pyrophyllite powder account for surplus 20~35%, graphite powder accounts for 10~20% of surplus.
Lithium bentonite according to the invention, palygorskite soil, hydroxyethylcellulose granularity are 270~320 orders.Levelling agent according to the invention is any one among organosilicon levelling agent BD3033, BD3037, polyurethane rheology modifier WL-728, the Wl-730.
Antifoaming agent according to the invention is any one among the high sticking system antifoaming agent WX-67 of water-based, AR34, A60, silicone defoaming agent BD3030, BD0068, the BD3029HL.
Anticorrisive agent according to the invention is any one in OIT CH-801, potassium sorbate, the Sodium Benzoate.
Binding agent according to the invention is any one of α starch, dextrin.
Wetting agent according to the invention is any one among WR-300, WR-311, the efficient wetting agent WF-216 of anionic, the DISP-5041.
Sintering aid according to the invention is any one in iron oxide, the talcum powder.
It is base-material that water-based dip applicating paint refractory aggregate of the present invention is selected the moderate material of two or more refractoriness for use, has screened multiple high-performance powder material and fluent material, is mixed with a kind of water-based dip applicating paint that is used for the cast iron cold-box.Coating of the present invention is pulverulence before using, and is easy to use, processing performance good, transportation is convenient.When using coating, only need take by weighing a certain amount of powdery paints, take by weighing an amount of water more by a certain percentage and put into stirred vessel and prepare.Advantages such as the coating for preparing has that suspension is good, intensity is high, coating is even, good leveling property, any surface finish, still, flawless.The dope viscosity variation is looked the user and need and be decided different foundry goods employing different coatings thickness.Coating of the present invention can improve the surface quality of foundry goods greatly, improves cast(ing) surface fineness.
[specific embodiment]
The following stated is embodiments of the invention, can explain the present invention in more detail through following embodiment, but the present invention should not be confined to the disclosed content of this embodiment.
Embodiment 1:
The cast iron cold-box core with the powdery water-based dip applicating paint by weight organosilicon levelling agent BD3033 0.2% (0.2kg), lithium bentonite 1.5% (1.5kg), palygorskite soil 3.0% (3.0kg); Silicone defoaming agent BD3030 0.8% (0.8kg), anticorrisive agent OIT CH-801 0.02% (0.02kg), dextrin 1.2% (1.2kg); Hydroxyethylcellulose 0.2% (0.2kg), the efficient wetting agent WF-216 0.8% of anionic (0.8kg), iron oxide 10% (10.0kg); Surplus is 200 order refractory materials; Wherein pyrophillite is 50%, silica flour 35%, graphite 15%.
The preparation process of said coating:
1, with binding agent, suspending agent, levelling agent, anticorrisive agent etc. weigh up in proportion, put into that high speed dispersor stirs, about time 15min, the powder after mixed is referred to as the powder auxiliary agent.
2, off-the-shelf refractory material, sintering aid, powder auxiliary agent are put into roller successively and rolled; Reinforced order rolls about time 15min for adding the graphite powder of light specific gravity, add silica flour, pyrophyllite powder, iron oxide, powder auxiliary agent etc. successively more earlier.
3, after rolling 15min, will dilute good antifoaming agent and wetting agent in proportion and add successively in the roller, go out stone roller after fully rolling and pack for use.
Coating of the present invention in use, with powder and water in 1: the ratio of (1.3 ~ 1.6) is disperseed in high speed dispersor, obtains colloidal coating behind about 30min, and barrelling is used.
 
Embodiment 2:
The cast iron cold-box core with the powdery water-based dip applicating paint by weight organosilicon levelling agent BD3037 0.4% (0.4kg), lithium bentonite 1.8% (1.8kg) palygorskite soil 2.8% (2.8kg), the high sticking system antifoaming agent AR34 0.7% (0.7kg) of water-based; Preservative sodium benzoate 0.03% (0.03kg), dextrin 1.0% (1.0kg), hydroxyethylcellulose 0.1% (0.1kg); The general wetting agent WR-300 0.5% of water paint (0.5kg); Talcum powder 5% (5.0kg), surplus are 200 order refractory materials, and wherein pyrophillite is 65% of a surplus; Silica flour is 25% of surplus, and graphite is 10% of surplus.
The coating preparation process is ditto said.
Embodiment 3:
The cast iron cold-box core with the powdery water-based dip applicating paint by weight polyurethane rheology modifier WL-728 0.3% (0.3kg); Lithium bentonite 2.0% (2.0kg), palygorskite soil 2.5% (2.5kg), silicone defoaming agent BD3030 1.0% (1.0kg); Potassium sorbate anticorrisive agent 0.01% aStarch 0.8% (0.8kg); Hydroxyethylcellulose 0.3% (0.3kg), the efficient wetting agent 1.0% of anionic (1.0kg), iron oxide 8% (8.0kg); Surplus is 200 order refractory materials; Wherein pyrophyllite powder is 53% of a surplus, and silica flour is 27% of surplus, and graphite powder is 20% of a surplus.
Embodiment 4
The cast iron cold-box core with the powdery water-based dip applicating paint by weight polyurethane rheology modifier Wl-730 0.2% (0.2kg); Lithium bentonite 2.0% (2.0kg), palygorskite soil 2.5% (2.5kg), silicone defoaming agent BD0068 1.0% (1.0kg); Potassium sorbate anticorrisive agent 0.01% aStarch 0.8% (0.8kg); Hydroxyethylcellulose 0.3% (0.3kg), the efficient wetting agent 1.0% of anionic (1.0kg), talcum powder 8% (8.0kg); Surplus is 200 order refractory materials; Wherein pyrophyllite powder is 53% of a surplus, and silica flour is 27% of surplus, and graphite powder is 20% of a surplus.
The coating preparation process is ditto said.

Claims (1)

1. cast iron cold-box core water original washing powder shape dip-coating paint, it is characterized in that: the compositions in weight percentage of said coating is: lithium bentonite 1.5%~2.0%; Palygorskite soil 2.5%~3.0%; Hydroxyethylcellulose 0.1%~0.3%; Levelling agent 0.2%~0.4%; Antifoaming agent 0.7%~1.0%; Anticorrisive agent 0.01%~0.03%; Binding agent 0.8%~1.2%; Wetting agent 0.5%~1.0%; Sintering aid 5%~10%; Surplus is a refractory aggregate, and refractory aggregate is three kinds of 200~320 purpose silica flours, pyrophyllite powder, graphite powder; Wherein silica flour account for surplus 50~65%, pyrophyllite powder account for surplus 20~35%, graphite powder accounts for 10~20% of surplus; Wherein, said lithium bentonite, palygorskite soil, hydroxyethylcellulose granularity are 270~320 orders; Said levelling agent is any one among organosilicon levelling agent BD3033, BD3037, polyurethane rheology modifier WL-728, the Wl-730; Said antifoaming agent is any one among the high sticking system antifoaming agent WX-67 of water-based, AR34, A60, silicone defoaming agent BD3030, BD0068, the BD3029HL; Said anticorrisive agent is any one in OIT CH-801, potassium sorbate, the Sodium Benzoate; Said binding agent is any one of α starch, dextrin; Said wetting agent is any one among WR-300, WR-311, the efficient wetting agent WF-216 of anionic, the DISP-5041; Said sintering aid is any one in iron oxide, the talcum powder.
CN 201010583092 2010-12-11 2010-12-11 Water-based powder-type dip-coating coating for cast iron cold-box core Expired - Fee Related CN102310159B (en)

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Application Number Priority Date Filing Date Title
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CN102310159B CN102310159B (en) 2013-05-29

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013044904A1 (en) * 2011-09-30 2013-04-04 Ask Chemicals Gmbh Coating compositions for inorganic casting moulds and cores and use thereof and method for sizing
CN103586407A (en) * 2013-11-27 2014-02-19 吴江市液铸液压件铸造有限公司 Casting coating
CN103990764A (en) * 2014-05-20 2014-08-20 朝阳佳诚耐火材料有限公司 Casting sand core repairing paste and preparation method thereof
CN105170889A (en) * 2015-09-21 2015-12-23 蚌埠冠宜型材科技有限公司 Sudden-heating-resistant casting coating
CN106944590A (en) * 2017-04-28 2017-07-14 河北新兴铸管有限公司 A kind of high-temperature resistant coating and preparation method
CN107866520A (en) * 2017-11-15 2018-04-03 宁夏共享模具有限公司 A kind of anhydrous water-soluble powder foundry facing and preparation method thereof
CN114769503A (en) * 2022-04-06 2022-07-22 中国第一汽车股份有限公司 Coating for sand core of gray iron cylinder body of automobile engine and preparation method of coating

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108971419A (en) * 2018-08-17 2018-12-11 贵阳灵峰铸造材料有限公司 Water-based dip-coating paint for 3D printing sand mold and preparation method thereof

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US4106945A (en) * 1976-05-24 1978-08-15 Precision Metalsmiths, Inc. Investment material
CN1880281A (en) * 2005-06-16 2006-12-20 章浩龙 Composite investment casting refractory material and its production method
CN1911556A (en) * 2006-08-25 2007-02-14 蒋文兰 Water base casting coating material powder for concave convex rod
EP1841556B1 (en) * 2004-12-16 2009-03-11 Ashland-Südchemie-Kernfest GmbH Highly insulating and fireproof coating materials for casting moulds

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US4106945A (en) * 1976-05-24 1978-08-15 Precision Metalsmiths, Inc. Investment material
EP1841556B1 (en) * 2004-12-16 2009-03-11 Ashland-Südchemie-Kernfest GmbH Highly insulating and fireproof coating materials for casting moulds
CN1880281A (en) * 2005-06-16 2006-12-20 章浩龙 Composite investment casting refractory material and its production method
CN1911556A (en) * 2006-08-25 2007-02-14 蒋文兰 Water base casting coating material powder for concave convex rod

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013044904A1 (en) * 2011-09-30 2013-04-04 Ask Chemicals Gmbh Coating compositions for inorganic casting moulds and cores and use thereof and method for sizing
CN103586407A (en) * 2013-11-27 2014-02-19 吴江市液铸液压件铸造有限公司 Casting coating
CN103586407B (en) * 2013-11-27 2016-08-17 吴江市液铸液压件铸造有限公司 A kind of cast paint
CN103990764A (en) * 2014-05-20 2014-08-20 朝阳佳诚耐火材料有限公司 Casting sand core repairing paste and preparation method thereof
CN103990764B (en) * 2014-05-20 2016-03-30 朝阳佳诚耐火材料有限公司 A kind of casting sand core mending paste and preparation method thereof
CN105170889A (en) * 2015-09-21 2015-12-23 蚌埠冠宜型材科技有限公司 Sudden-heating-resistant casting coating
CN106944590A (en) * 2017-04-28 2017-07-14 河北新兴铸管有限公司 A kind of high-temperature resistant coating and preparation method
CN107866520A (en) * 2017-11-15 2018-04-03 宁夏共享模具有限公司 A kind of anhydrous water-soluble powder foundry facing and preparation method thereof
CN107866520B (en) * 2017-11-15 2020-04-07 共享智能装备有限公司 Anhydrous water-soluble powder casting coating and preparation method thereof
CN114769503A (en) * 2022-04-06 2022-07-22 中国第一汽车股份有限公司 Coating for sand core of gray iron cylinder body of automobile engine and preparation method of coating
CN114769503B (en) * 2022-04-06 2023-11-14 中国第一汽车股份有限公司 Coating for gray iron cylinder sand core of automobile engine and preparation method thereof

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