CN102304852B - Antibacterial coating finishing liquid and antibacterial finishing process of casement - Google Patents

Antibacterial coating finishing liquid and antibacterial finishing process of casement Download PDF

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Publication number
CN102304852B
CN102304852B CN2011102637557A CN201110263755A CN102304852B CN 102304852 B CN102304852 B CN 102304852B CN 2011102637557 A CN2011102637557 A CN 2011102637557A CN 201110263755 A CN201110263755 A CN 201110263755A CN 102304852 B CN102304852 B CN 102304852B
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parts
coating
softener
bamboo vinegar
liquid
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CN2011102637557A
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CN102304852A (en
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丁水法
张声诚
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Anhui Wanfang weaving & Dyeing Co. Ltd
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Zhejiang Sanzhi Textile Co Ltd
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Abstract

The invention discloses antibacterial coating finishing liquid and an antibacterial finishing process of casement. The process comprises the following steps: preparing the antibacterial coating finishing liquid, wherein the antibacterial coating finishing liquid comprises the following components in parts by mass: 10-40 parts of bamboo vinegar liquid, 80-120 parts of coating agent and 3-4 parts of additive; blade-coating the antibacterial coating finishing liquid on fabric, and drying at 75-95 DEG C for 3-5 minutes for forming; and performing baking and crosslinking at 120-180 DEG C for 3-5 minutes. The antibacterial coating finishing liquid disclosed by the invention has a durable antibacterial coating effect, is harmless to human body and environment, and improves the durable antibacterial performance and washing resistance of casement. The bamboo vinegar liquid has good bacterial effect and is applied to textiles so as to obtain a natural, green and environment-friendly antibacterial finishing agent with broad market prospect for sure. The bamboo vinegar liquid has a wide source and low cost, and the economical values brought by the bamboo vinegar liquid are remarkable.

Description

A kind of antimicrobial coating dressing liquid and antibacterial finishing process of Curtains Fabrics
[technical field]
The present invention relates to the antibacterial finishing process of antimicrobial coating dressing liquid and Curtains Fabrics, the technology that especially adopts the antimicrobial coating dressing liquid contain Bamboo vinegar solution to carry out the Curtains Fabrics antibiotic finish.
[background technology]
So-called fabric coating promptly applies one or more layers macromolecule filming thing at fabric face uniformly, and promptly coating agent makes lining have a kind of Surface-micromachining process of difference in functionality through certain process optimization.Coating agent commonly used at present has: Corvic, polyacrylate coating agent, polyurethane coating agent; In addition, also have natural rubber and synthetic rubber coating agent etc.Coating process commonly used has: direct dry-coated method, wet-process coating, transfer method coating, lamination are sent out coating, in addition, also have spraying process and Vacuum Coating method.
Bamboo vinegar solution is to produce in the bamboo charcoal manufacturing process, and the bluish yellow look that the process condensing and recycling obtains or the liquid of yellowish-brown are multicomponent mixtures.
In the textile garment product, also there is not at present the application of Bamboo vinegar solution antiseptic top finish; So the research Bamboo vinegar solution is of great importance as antiseptic on textiles, moreover also contains carboxylic-acid substance how far in the Bamboo vinegar solution and also can increase the wrinkle resistance of textiles.In addition, big in recent years quantity research shows, many chemical antiseptics all have in various degree toxicity, to abnormal property, cause variability and carcinogenic.Therefore; The Oeko-Tex Standard 100 that announces in January, 2003 clearly is defined in and should can detect bio-active products on all textiless except that ornament materials and promptly can not contain antiseptic, only if harmless through this antiseptic of abundant evaluation certificate.Like this; Antiseptic commonly used is as 2; 4; 4 ' three chloro-2 '-two ethers of hydroxyl (THDE), 2-(4 '-thiazolyl) benzimidazole TBII, only a bromo cinnamic acid (BCA), 2-(3 ', 5 one dimethyl pyrazole base)-4-hydroxyl-6-phenyl pyrimidine, 1,2-two bromo-, 3 chloropropanes (DBCP) etc. are all disabled.Become a kind of exigence so seek a kind of novel and natural antiseptic.
The at present common technology of padding makes the washing resistance of antimicrobial fluid and endurance quality poor.
[summary of the invention]
The object of the invention solves the problems of the prior art exactly, proposes the antibacterial finishing process of a kind of antimicrobial coating dressing liquid and Curtains Fabrics, can improve the durable anti-microbial property and the washing resistance of Curtains Fabrics, and can be to environment and body harmless.
For realizing above-mentioned purpose, the present invention proposes a kind of antimicrobial coating dressing liquid, composed of the following components and each constituent mass ratio is: Bamboo vinegar solution: 10~40 parts; Coating agent: 80~120 parts; Additive: 3~4 parts; Said Bamboo vinegar solution is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic, and the bluish yellow look that this gas is obtained through condensing and recycling at normal temperatures or the liquid of yellowish-brown; Said coating agent adopts polyurethane binder; Said additive comprises softener and thickener, and the mass ratio of softener and thickener is 1:1.
As preferably, each constituent mass ratio is: Bamboo vinegar solution: 15 parts; Coating agent: 100 parts; Additive: 3.5 parts, best results.
As preferably, said softener adopts the Y-17238 softener, and thickener adopts carboxymethyl cellulose.
For realizing above-mentioned purpose; The invention allows for a kind of antibacterial finishing process of Curtains Fabrics, be ready to the antimicrobial coating dressing liquid earlier, composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 10~40 parts; Coating agent: 80~120 parts, additive: 3~4 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 75~95 ℃ temperature to dry shaping, drying time is 3~5 minutes; It is crosslinked to adopt 120~180 ℃ temperature to train baking again, and the training baking time is 3~5 minutes; Adopt the tentering dryer when said oven dry is shaped, bake and adopt heat setting machine when crosslinked; Said Bamboo vinegar solution is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic, and the bluish yellow look that this gas is obtained through condensing and recycling at normal temperatures or the liquid of yellowish-brown; Coating agent adopts polyurethane binder; Additive comprises softener and thickener, and the mass ratio of softener and thickener is 1:1; Softener adopts the Y-17238 softener, and thickener adopts carboxymethyl cellulose.
As preferably, each constituent mass ratio is in the said antimicrobial coating dressing liquid: Bamboo vinegar solution: 15 parts; Coating agent: 100 parts; Additive: 3.5 parts.
Beneficial effect of the present invention: antimicrobial coating dressing liquid of the present invention has durable antibiotic coating result, and to human body and environmentally friendly, has improved the durable anti-microbial property and the washing resistance of Curtains Fabrics.What the present invention adopted is the finishing agent of natural nontoxic, has well solved ecological problem of the prior art, has reached effect in energy saving and environmental protection.Bamboo vinegar solution has the good sterilization effect, is applied on the textiles, becomes antibacterial finishing agent natural, green, environmental protection, and vast market prospect will be arranged.And the Bamboo vinegar solution source is wide, and cost is low, and the economic worth of being created is considerable.
Characteristic of the present invention and advantage will be elaborated through embodiment.
[specific embodiment]
The antimicrobial coating dressing liquid, composed of the following components and each constituent mass ratio is: Bamboo vinegar solution: 10~40 parts; Coating agent: 80~120 parts; Additive: 3~4 parts.Be added with Bamboo vinegar solution in the prescription as antibiotic effective ingredient, and adopt the coating agent of polyurethane type can produce bonding, set effect, improved the antibiotic washability of Bamboo vinegar solution, an amount of additive has played the effect of regulating coating quality.
Said Bamboo vinegar solution is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic, and the bluish yellow look that this gas is obtained through condensing and recycling at normal temperatures or the liquid of yellowish-brown.Bamboo vinegar solution contains nearly 300 kinds of natural polymer organic compounds, and the alkaline components of organic acid, alcohols, ketone, aldehydes, ester class and trace etc. is arranged.The collection of Bamboo vinegar solution should be to carry out between 80 ℃~150 ℃ in the throat temperature of charcoal kiln.In order to obtain pure Bamboo vinegar solution, in the process that bamboo wood is made charcoal, be not suitable for using and also should do not use wood fuel.
Said coating agent adopts polyurethane binder.
Additive can only adopt thickener, also can adopt softener and thickener, and the mass ratio of softener and thickener is 1:1.Soft dose is adopted the Y-17238 softener, and thickener adopts carboxymethyl cellulose.Softener commonly used at present has the special-purpose soft finishing agent of RF-terylene, soft finishing agent SRS, high dense fluffy soft finishing agent JR-702B etc., and we adopt effect Y-17238 softener preferably.Thickener commonly used has BJ-100 thickener, hydroxyethylcellulose (HEC), carboxymethyl cellulose (CMC), ASE – 60, and we select carboxymethyl cellulose for use.Adopt softener further to improve the feel of fabric.
The antibacterial finishing process of Curtains Fabrics is ready to the antimicrobial coating dressing liquid earlier, and composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 10~40 parts, and coating agent: 80~120 parts, additive: 3~4 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 75~95 ℃ temperature to dry shaping, drying time is 3~5 minutes; It is crosslinked to adopt 120~180 ℃ temperature to bake again, and the time of baking is 3~5 minutes.The present invention adopts polyurethane coating agent and adopts direct dry coating (blade coating) mode to carry out coating.
Embodiment one:
The antibacterial finishing process of Curtains Fabrics is ready to the antimicrobial coating dressing liquid earlier, and composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 15 parts, and coating agent: 100 parts, additive: 3.5 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 80 ℃ temperature to dry shaping, drying time is 4 minutes; It is crosslinked to adopt 160 ℃ temperature to bake again, and the time of baking is 5 minutes.
Embodiment two:
The antibacterial finishing process of Curtains Fabrics is ready to the antimicrobial coating dressing liquid earlier, and composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 18 parts, and coating agent: 107 parts, additive: 3.8 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 85 ℃ temperature to dry shaping, drying time is 3 minutes; It is crosslinked to adopt 170 ℃ temperature to bake again, and the time of baking is 4 minutes.
Embodiment three:
The antibacterial finishing process of Curtains Fabrics is ready to the antimicrobial coating dressing liquid earlier, and composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 13 parts, and coating agent: 86 parts, additive: 3.2 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 75 ℃ temperature to dry shaping, drying time is 5 minutes; It is crosslinked to adopt 170 ℃ temperature to bake again, and the time of baking is 4 minutes.
The foregoing description is to explanation of the present invention, is not to qualification of the present invention, any scheme after the simple transformation of the present invention is all belonged to protection scope of the present invention.

Claims (4)

1. the antimicrobial coating dressing liquid of a Curtains Fabrics, it is characterized in that: composed of the following components and each constituent mass ratio is: Bamboo vinegar solution: 10~40 parts; Coating agent: 80~120 parts; Additive: 3~4 parts; Said Bamboo vinegar solution is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic, and the bluish yellow look that this gas is obtained through condensing and recycling at normal temperatures or the liquid of yellowish-brown; Said coating agent adopts polyurethane binder; Said additive comprises softener and thickener, and the mass ratio of softener and thickener is 1:1; Said softener adopts the Y-17238 softener, and thickener adopts carboxymethyl cellulose.
2. the antimicrobial coating dressing liquid of a kind of Curtains Fabrics as claimed in claim 1, it is characterized in that: each constituent mass ratio is: Bamboo vinegar solution: 15 parts; Coating agent: 100 parts; Additive: 3.5 parts.
3. the antibacterial finishing process of a Curtains Fabrics is characterized in that: be ready to the antimicrobial coating dressing liquid earlier, composed of the following components and each the constituent mass ratio of antimicrobial coating dressing liquid is: Bamboo vinegar solution: 10~40 parts, and coating agent: 80~120 parts, additive: 3~4 parts; Then with antimicrobial coating dressing liquid blade coating after on the fabric, adopt 75~95 ℃ temperature to dry shaping, drying time is 3~5 minutes; It is crosslinked to adopt 120~180 ℃ temperature to bake again, and the time of baking is 3~5 minutes; Adopt the tentering dryer when said oven dry is shaped, bake and adopt heat setting machine when crosslinked; Said Bamboo vinegar solution is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic, and the bluish yellow look that this gas is obtained through condensing and recycling at normal temperatures or the liquid of yellowish-brown; Coating agent adopts polyurethane binder; Additive comprises softener and thickener, and the mass ratio of softener and thickener is 1:1; Softener adopts the Y-17238 softener, and thickener adopts carboxymethyl cellulose.
4. the antibacterial finishing process of a kind of Curtains Fabrics as claimed in claim 3, it is characterized in that: each constituent mass ratio is in the said antimicrobial coating dressing liquid: Bamboo vinegar solution: 15 parts; Coating agent: 100 parts; Additive: 3.5 parts.
CN2011102637557A 2011-09-07 2011-09-07 Antibacterial coating finishing liquid and antibacterial finishing process of casement Active CN102304852B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105671976A (en) * 2016-03-30 2016-06-15 江阴芗菲服饰有限公司 Scrape coating type antimicrobial acrylic fabric
CN107197668B (en) * 2017-05-27 2020-04-28 贵州省德均农特产品开发有限公司 Gastrodia elata planting method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101053482A (en) * 2006-04-10 2007-10-17 梁玉珍 Bamboo charcoal blanket and manufacturing technology thereof
CN101671953A (en) * 2008-10-27 2010-03-17 浙江纺织服装科技有限公司 Method for producing antibacterial fabric finished by bamboo vinegar liquor
CN102061619A (en) * 2010-11-26 2011-05-18 安吉谈竹庄竹纤维有限公司 Process for dyeing and finishing by using bamboo vinegar

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3819973B2 (en) * 1996-10-21 2006-09-13 株式会社ツーウイン Textile manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101053482A (en) * 2006-04-10 2007-10-17 梁玉珍 Bamboo charcoal blanket and manufacturing technology thereof
CN101671953A (en) * 2008-10-27 2010-03-17 浙江纺织服装科技有限公司 Method for producing antibacterial fabric finished by bamboo vinegar liquor
CN102061619A (en) * 2010-11-26 2011-05-18 安吉谈竹庄竹纤维有限公司 Process for dyeing and finishing by using bamboo vinegar

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Effective date of registration: 20190307

Address after: 313100 1st Floor, 66 Luhui Road, Taihu Street Economic Development Zone, Changxing County, Huzhou City, Zhejiang Province

Patentee after: Zhejiang Changxing Yike Textile Co., Ltd.

Address before: 313100 Luhui Road, Changxing County Economic Development Zone, Huzhou City, Zhejiang Province

Patentee before: Zhejiang Sanzhi Textile Co., Ltd.

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Effective date of registration: 20190613

Address after: 242131 Cross Town Economic Development Zone, Langxi County, Xuancheng City, Anhui Province

Patentee after: Anhui Wanfang weaving & Dyeing Co. Ltd

Address before: 313100 1st Floor, 66 Luhui Road, Taihu Street Economic Development Zone, Changxing County, Huzhou City, Zhejiang Province

Patentee before: Zhejiang Changxing Yike Textile Co., Ltd.

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