CN102304785A - Nano bamboo-tea brush wire and manufacturing method thereof - Google Patents
Nano bamboo-tea brush wire and manufacturing method thereof Download PDFInfo
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- CN102304785A CN102304785A CN201110207303A CN201110207303A CN102304785A CN 102304785 A CN102304785 A CN 102304785A CN 201110207303 A CN201110207303 A CN 201110207303A CN 201110207303 A CN201110207303 A CN 201110207303A CN 102304785 A CN102304785 A CN 102304785A
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Abstract
The invention relates to a nano bamboo-tea brush wire and a manufacturing method thereof. The nano bamboo-tea brush wire comprises polyamide nylon yarn core and a nano bamboo-tea powder layer, wherein the nano bamboo-tea powder layer covers the surface of the yarn core and consists of a mixture of nano bamboo powder and tea polyphenol. The nano bamboo-tea brush wire provided by the invention has biologic degradability and environmental compatibility to solve the technical problems that the current toothbrush has high manufacturing method, wastes an energy source, can not be recycled and is harmful to human bodies.
Description
Technical field
The present invention relates to a kind of nanometer bamboo tea brush silk and preparation method thereof.
Background technology
According to relevant newpapers and periodicals: present " toothbrush ", no matter tooth handle and Ya Mao (packing that comprises " toothbrush ") use plastic production (or plastics+rubber mix making), therefore, existence three big serious problems:
A, raw material refine from oil, and petroleum resources are non-renewable, and meeting fewer and feweri (calculate with 7,000,000,000 " toothbrush ", need 5,000,000 tons of oil of loss, increase by 8,000,000 tons of carbon dioxide) therefore, causes the cost of manufacture height, wastes energy.
B, use the back not reclaim, can only abandon, cause environmental pollution (with 7,000,000,000 " toothbrush " calculate, will cause 2,800 ten thousand square metres environmental pollution every year).If recycle (extruding becomes once through pulverizing, secondary or tertiary recycling raw material), not only continue to reduce raw materials quality, increase toxicity, and can cause bigger pollution to environment.
C, raw material itself poisonous (containing compositions such as bisphenol-A and hydrogen chloride); After being absorbed by the body; Not only unhealthful; And increase the weight of the state of an illness (in odontopathy and the various stomatopathy; There is 47% patient to be difficult to cure; Wherein 17% conditions of patients increases the weight of), and can cause the generation of heart disease, hyperactivity, diabetes, obesity and multiple cancer etc.
Summary of the invention
For solve the current toothbrushes cost of manufacture high, waste energy, can't recycle, the technical problem of harmful to human, the invention provides a kind of nanometer bamboo tea brush silk and preparation method thereof.
Technical solution of the present invention is:
A kind of nanometer bamboo tea brush silk, its special character is: the nanometer bamboo tea bisque that comprises polyamide nylon silk core and be coated in a wicking surface, said nanometer bamboo tea bisque is made up of the mixture of nanometer bamboo powder and Tea Polyphenols.
A kind of preparation method of nanometer bamboo tea brush silk may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] nanometer bamboo powder, the Tea Polyphenols of 0.5～2 weight portion, 88～99 weight parts of polyamide nylon particles of getting 0.5～10 weight portion are mixed into material;
7] nanometer bamboo tea brush silk is processed in material wire drawing under 210～250 ℃ temperature.
A kind of preparation method of nanometer bamboo tea brush silk may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] particulate material is mediated in preparation: get the nanometer bamboo powder of 0.5～10 weight portion, the Tea Polyphenols of 0.5～2 weight portion, the mixed material of 88～99 weight parts of polyamide nylon particles and put into the high speed kneader; Be heated to 95 ℃-100 ℃, 10～15 minutes kneading time; Cool off kneading, temperature of charge is dropped to below 50 ℃, go out particulate material and store subsequent use;
7] get particulate material wire drawing under 210～250 ℃ temperature, process nanometer bamboo tea brush silk.
A kind of preparation method of nanometer bamboo tea brush silk may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] get the polyamide nylon particle, be pulled to the core silk that diameter is 0.05～0.2mm at wire drawing machine;
7] immediately with core silk secondary through wire drawing machine, the mixture of Tea Polyphenols of getting nanometer bamboo powder and 0.5～2 weight portion of 0.5～10 weight portion is sprayed on core silk surface, processes nanometer bamboo tea brush silk.
The advantage that the present invention had:
1, nanometer bamboo powder, Tea Polyphenols is actual is a kind of string, is one of the abundantest natural macromolecular material of occurring in nature.Add nanometer bamboo powder and Tea Polyphenols at nylon such as polyamide, it is compound to allow nylon such as polyamide and nanometer bamboo powder, Tea Polyphenols carry out, and processes nanometer bamboo matter tea silk, makes its nanometer bamboo tea brush silk have effects such as bacteriostasis antibiosis, absorption peculiar smell, preventing decayed tooth permanent tooth, removing halitosis.And soft and smoothly softly warm up, have suede brocade sense, color gloss is beautiful, drapability is good, resilience is arranged, cool and comfortable, suction (wetting) property is good and gas permeability is strong, ABRASION RESISTANCE is high.
2, nanometer bamboo powder and Tea Polyphenols have been added in Ben Nami bamboo tea brush silk the inside, and nanometer bamboo tea brush silk has biodegradability and Environmental compatibility.
3, the brush holder of toothbrush of the present invention, bristle, packing have all adopted recyclable materials, with after can dissolve naturally after abandoning, can not cause any pollution to environment.
4, the plastics bristle contains the maximum chemical substance to the human influence, bisphenol-A (both BPA was used for the production of Merlon and synthetic resin) and O-phthalic hydrochloric acid (a kind of plastics softness that is used for, the anti-chemical substance of drawing).Nanometer bamboo tea bristle replaces the plastics bristle can make the consumer reduce the risk of suffering from diabetes, heart disease, hyperactivity and cancer.
5, State Council proposes the seven big industries first develop and support; Wherein energy-conserving and environment-protective; New material is all relevant with our " bamboo toothbrush " with new forms of energy (because can alleviate oil pressure and reduce emission of carbon-dioxide) three big industries; Therefore, nanometer bamboo tea bristle of the present invention meets the industrial policy of present country.
6, nanometer bamboo tea of the present invention brush silk have good ABRASION RESISTANCE, antidusting, elastic recovery, etc. effect.
Description of drawings
Fig. 1 is the structural representation of a kind of bristle of the present invention;
Wherein Reference numeral is: 1-silk core, 2-nanometer bamboo tea bisque.
The specific embodiment
Structural representation of the present invention as shown in Figure 1, a kind of nanometer bamboo tea brush silk, the nanometer bamboo tea bisque that comprises polyamide nylon silk core and be coated in a wicking surface, said nanometer bamboo tea bisque is made up of the mixture of nanometer bamboo powder and Tea Polyphenols.
The present invention provides three kinds of methods that prepare nanometer bamboo tea brush silk:
One, a kind of preparation method of nanometer bamboo tea brush silk may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] nanometer bamboo powder, the Tea Polyphenols of 0.5～2 weight portion, 88～99 weight parts of polyamide nylon particles of getting 0.5～10 weight portion are mixed into material;
7] nanometer bamboo tea brush silk is processed in material wire drawing under 210～250 ℃ temperature.
Two, a kind of preparation method of nanometer bamboo tea brush silk is characterized in that: may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] particulate material is mediated in preparation: get the nanometer bamboo powder of 0.5～10 weight portion, the Tea Polyphenols of 0.5～2 weight portion, the mixed material of 88～99 weight parts of polyamide nylon particles and put into the high speed kneader; Be heated to 95 ℃-100 ℃, 10～15 minutes kneading time; Cool off kneading, temperature of charge is dropped to below 50 ℃, go out particulate material and store subsequent use;
7] get particulate material wire drawing under 210～250 ℃ temperature, process nanometer bamboo tea brush silk.
Three, a kind of preparation method of nanometer bamboo tea brush silk: it is characterized in that: may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] get the polyamide nylon particle, be pulled to the core silk that diameter is 0.05～0.2mm at wire drawing machine;
7] immediately with core silk secondary through wire drawing machine, the mixture of Tea Polyphenols of getting nanometer bamboo powder and 0.5～2 weight portion of 0.5～10 weight portion is sprayed on core silk surface, processes nanometer bamboo tea brush silk.
Carry out quantitative, vacuum-packed to above-mentioned bamboo powder finished product.
The nanometer bamboo flour producing process:
One, multidimensional swing type high energy nano ball grinding technique.Multidimensional swing type high energy nanometer ball crusher is through tank body multidimensional swing type motion fast; Be that mill Jie produces huge impact power in jar; Prolong the movement locus that mill is situated between, improve impact energy, reduce the busy point of bump; Its operating efficiency is tens times of traditional ball crusher; Can significantly improve jar an impact energy and a times of exercise that interior mill is situated between, make pulverized material grains reach nanoscale, improve the uniformity of nanometer bamboo powder granule simultaneously greatly; The powder particle diameter minimum is 10nm, belongs to sealing high energy abrading-ball.The nanometer bamboo powder of the new abrading-ball technology of multidimensional swing type and multilayer classifying formula preparation is that pure physical method processes, and bamboo itself is not had destruction, does not also introduce other compositions, relative assurance the natural sex and the integrality of bamboo composition.Two, multilayer classifying nano ball grinding technique.The multilayer classifying nano ball grinding machine adopts bartender's arm action principle; Two-way fast turn-around repeatedly; Strengthened the probability of mill Jie track conversion; Produce high energy impact, make 300 order bamboo powder clash into ball milling at the volley, micron-sized powder is at multi-machine cavities; At many levels; Bump pulverizing constantly during many diameter mill Jie (by diminishing greatly gradually) streams send produces the classification crushing effect, and final powder is broken into the above nanometer bamboo powder of 10nm.
Claims (4)
1. a nanometer bamboo tea is brushed silk, and it is characterized in that: the nanometer bamboo tea bisque that comprises polyamide nylon silk core and be coated in a wicking surface, said nanometer bamboo tea bisque is made up of the mixture of nanometer bamboo powder and Tea Polyphenols.
2. the preparation method of nanometer bamboo tea brush silk is characterized in that: may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] nanometer bamboo powder, the Tea Polyphenols of 0.5～2 weight portion, 88～99 weight parts of polyamide nylon particles of getting 0.5～10 weight portion are mixed into material;
7] nanometer bamboo tea brush silk is processed in material wire drawing under 210～250 ℃ temperature.
3. the preparation method of nanometer bamboo tea brush silk is characterized in that: may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] particulate material is mediated in preparation: get the nanometer bamboo powder of 0.5～10 weight portion, the Tea Polyphenols of 0.5～2 weight portion, the mixed material of 88～99 weight parts of polyamide nylon particles and put into the high speed kneader; Be heated to 95 ℃-100 ℃, 10～15 minutes kneading time; Cool off kneading, temperature of charge is dropped to below 50 ℃, go out particulate material and store subsequent use;
7] get particulate material wire drawing under 210～250 ℃ temperature, process nanometer bamboo tea brush silk.
4. the preparation method of nanometer bamboo tea brush silk is characterized in that: may further comprise the steps:
1] gets clean sheet bamboo piece, remove surperficial rascal and inner chamber film;
2] boiling infusion:
Above-mentioned sheet bamboo piece, put into water and heat, when water temperature reaches 60～70 ℃, add formula solution, continue to be heated to boiling point, and kept boiling temperature 5～7 minutes, take out the bamboo piece then, with pure water the bamboo piece is rinsed well, drain away the water;
Said formula solution comprises the inferior sodium pyrosulfate of alimentary acetic acid, ammonium hydrogencarbonate and food-grade; After this formula solution adds in the entry; The weight ratio of alimentary acetic acid and water is 1: 10000～15000; The weight ratio of ammonium hydrogencarbonate and water is 1: 4000～6000, and the weight ratio of inferior sodium pyrosulfate of food-grade and water is 1: 6000～10000;
3] the sheet bamboo piece that drains away the water is dry, sterilization;
4] the sheet bamboo piece after the sterilization is ground, obtain being not more than 300 purpose bamboo powder after the screening;
5] the bamboo powder is ground into the nanometer bamboo powder of 10～50nm;
6] get the polyamide nylon particle, be pulled to the core silk that diameter is 0.05～0.2mm at wire drawing machine;
7] immediately with core silk secondary through wire drawing machine, the mixture of Tea Polyphenols of getting nanometer bamboo powder and 0.5～2 weight portion of 0.5～10 weight portion is sprayed on core silk surface, processes nanometer bamboo tea brush silk.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110207303 CN102304785B (en) | 2011-07-22 | 2011-07-22 | Nano bamboo-tea brush wire and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110207303 CN102304785B (en) | 2011-07-22 | 2011-07-22 | Nano bamboo-tea brush wire and manufacturing method thereof |
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| Publication Number | Publication Date |
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| CN102304785A true CN102304785A (en) | 2012-01-04 |
| CN102304785B CN102304785B (en) | 2013-02-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110207303 Expired - Fee Related CN102304785B (en) | 2011-07-22 | 2011-07-22 | Nano bamboo-tea brush wire and manufacturing method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899737A (en) * | 2012-11-01 | 2013-01-30 | 西安纵横纺织科技有限公司 | Production technology for degradable nylon fiber material |
| USD754442S1 (en) | 2013-07-17 | 2016-04-26 | Colgate-Palmolive Company | Toothbrush |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1113973A (en) * | 1994-06-24 | 1995-12-27 | 温一林 | Producing method for antibiotic health tooth-brush |
| CN1145209A (en) * | 1995-09-12 | 1997-03-19 | 田树霖 | Method for prodn. of long-effect antibiotic toothbrush nylon yarn |
| CN1475183A (en) * | 2002-08-13 | 2004-02-18 | 梅嘉贸易株式会社 | Toothbrush containing natural jade powder |
| US20060037160A1 (en) * | 2004-08-18 | 2006-02-23 | Kayser Steven L | Toothbrush and methods of making and using same |
-
2011
- 2011-07-22 CN CN 201110207303 patent/CN102304785B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1113973A (en) * | 1994-06-24 | 1995-12-27 | 温一林 | Producing method for antibiotic health tooth-brush |
| CN1145209A (en) * | 1995-09-12 | 1997-03-19 | 田树霖 | Method for prodn. of long-effect antibiotic toothbrush nylon yarn |
| CN1475183A (en) * | 2002-08-13 | 2004-02-18 | 梅嘉贸易株式会社 | Toothbrush containing natural jade powder |
| US20060037160A1 (en) * | 2004-08-18 | 2006-02-23 | Kayser Steven L | Toothbrush and methods of making and using same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899737A (en) * | 2012-11-01 | 2013-01-30 | 西安纵横纺织科技有限公司 | Production technology for degradable nylon fiber material |
| USD754442S1 (en) | 2013-07-17 | 2016-04-26 | Colgate-Palmolive Company | Toothbrush |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102304785B (en) | 2013-02-20 |
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