CN109401175A - A kind of thermoplastic elastomer (TPE) new material and preparation method thereof - Google Patents
A kind of thermoplastic elastomer (TPE) new material and preparation method thereof Download PDFInfo
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- CN109401175A CN109401175A CN201811175809.2A CN201811175809A CN109401175A CN 109401175 A CN109401175 A CN 109401175A CN 201811175809 A CN201811175809 A CN 201811175809A CN 109401175 A CN109401175 A CN 109401175A
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- tpe
- thermoplastic elastomer
- copolymer
- new material
- lavender
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L99/00—Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of thermoplastic elastomer (TPE) new materials and preparation method thereof, component including following mass percent: copolymer 20%~80%, plasticiser 10%~30%, plant raw material 5%~50%, the copolymer is SEBS or SBS, the plant raw material is wormwood or lavender, lavender and wormwood is utilized as base-material, cooperate SEBS and SBS, with environmental protection, it is nontoxic, comfortable feel, exquisite appearance, facilitate processing, the advantages that resource is renewable, the thermoplastic elastomer (TPE) new material produced has deodorization, taste removal, it is ventilative, absorbing sweat, the functions such as health care, suitable for sporting goods, consumer goods industries.
Description
Technical field
The present invention relates to thermoplastic elastic material fields, and in particular to a kind of thermoplastic elastomer (TPE) new material and its preparation
Method.
Background technique
Thermoplastic elastomer (TPE) TPE/TPR, also known as artificial rubber or synthetic rubber, the entitled TPE(Thermoplastic of English
Elastomer).Its product had both had the high resiliency of traditional cross-linking vulcanized rubber, ageing-resistant, the every excellent properties of oil resistivity, together
When, feature that processing method wide easy to process but also with common plastics.The production of the processing methods such as injection molding, extrusion, blow molding can be used,
100% direct secondary use after mouth of a river corner crushes.Not only simplify process, but also reduce processing cost, therefore thermoplastic elastomer (TPE)
TPE/TPR material has become the Latest Materials for replacing traditional rubber, and environmentally friendly, nontoxic, comfortable feel, exquisite appearance make product
More intention.
Since thermoplastic elastomer (TPE) has the above advantages, so it is widely used in sporting goods, in consumer goods industries,
Such as cushion, cushion, rubber mat, medical supplies etc., these product utilizations characteristic of thermoplastic elastomer (TPE) can be produced
The advantages that speed is fast, nontoxic, good hand touch, beautiful appearance, but there is no from smell pharmacology for existing thermoplastic elastic material
Aspect brings preferably comfortable experience to user, thus, it is necessary to research and develop a kind of thermoplastic elastomer (TPE) new material to obtain more
Good using effect.
Summary of the invention
In view of the problems of the existing technology, the present invention provides a kind of thermoplastic elastomer (TPE) new material and its preparations
Method, specific technical solution are as follows:
A kind of thermoplastic elastomer (TPE) new material, the component including following mass percent: copolymer 20%~80%, plasticiser 10%
~30%, plant raw material 5%~50%, the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender.
As a kind of preferred embodiment of material of the present invention, the component including following mass percent: SEBS50%, plasticiser
20%, wormwood 30%.
As a kind of preferred embodiment of material of the present invention, the component including following mass percent: SEBS40%, plasticiser
30%, lavender 30%.
As a kind of preferred embodiment of material of the present invention, the component including following mass percent: SBS50%, plasticiser
25%, wormwood 25%.
As a kind of preferred embodiment of material of the present invention, the component including following mass percent: SBS60%, plasticiser
20%, lavender 20%.
A kind of thermoplastic elastomer (TPE) green wood preparation method for material, comprising the following steps:
1. copolymer 20%~80%, plasticiser 10%~30%, plant raw material 5%~50% by mass percentage is put into mixing
In machine or screw machine, wherein the copolymer is SEBS or SBS, the plant raw material is wormwood or lavender, in work temperature
Preliminary thermoplastic elastomer (TPE) is obtained within hybrid process 3~15 minutes at 110 DEG C~200 DEG C of degree;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
A kind of preferred embodiment as preparation method of the present invention, comprising the following steps:
1. copolymer 60%, plasticiser 25%, plant raw material 15% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 150 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 10 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
A kind of preferred embodiment as preparation method of the present invention, comprising the following steps:
1. copolymer 30%, plasticiser 25%, plant raw material 45% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 170 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 15 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
Beneficial effects of the present invention:
1. using SEBS or SBS 20%~80%, the present invention is made in plasticiser 10%~30%, wormwood or lavender 5%~50%
Thermoplastic elastomer (TPE) new material have that environmentally friendly, nontoxic, comfortable feel, exquisite appearance, to facilitate processing, resource renewable etc. excellent
Point is suitable for sporting goods, consumer goods industries;
2. using lavender is used as base-material, the fragrance for taking full advantage of lavender itself is carefree and leisurely, tranquilizing soporific, spasmolysis, resists
The characteristics such as bacterium, neuroprotection, lipid-loweringing, treatment neurosis, the thermoplastic elastomer (TPE) new material produced have taste removal, ventilative, suction
Sweat, the advantages that keeping fit and healthy, and lavender is aftergrowth, it is environmentally protective, there is certain promotion to conservation of nature environment
Effect;
3. using wormwood as base-material, the antibacterial promoting blood circulation, clearing damp cold dispelling, band fragrance, anti-mistake of wormwood itself are taken full advantage of
Quick, nontoxic, antimycotic, rationale blood, temperature through etc. characteristics, the thermoplastic elastomer (TPE) new material produced have deodorization, taste removal, thoroughly
The advantages that gas, absorbing sweat, the equipment especially suitable for contacting with people use, and help to treat rheumatic arthritis etc., have health care
Function.
Specific embodiment
A specific embodiment of the invention is described further below:
SEBS is using polystyrene as end segment in text, and the ethylene-butene copolymer obtained with polybutadiene plus hydrogen is intermediate bullet
Property block linear tri-block copolymer, the entitled hydrogenated styrene-butadiene block copolymer of Chinese;SBS, Chinese name styrene-
Butadiene-styrene block copolymer.
A kind of thermoplastic elastomer (TPE) new material, the component including following mass percent: copolymer 20%~80%, plasticiser
10%~30%, plant raw material 5%~50%, the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender.
New material embodiment 1, thermoplastic elastomer (TPE) new material include the component of following mass percent: SEBS50%, plasticizing
Agent 20%, wormwood 30%.
New material embodiment 2, thermoplastic elastomer (TPE) new material include the component of following mass percent: SEBS40%, plasticizing
Agent 30%, lavender 30%.
New material embodiment 3, thermoplastic elastomer (TPE) new material include the component of following mass percent: SBS50%, plasticizing
Agent 25%, wormwood 25%.
New material embodiment 4, thermoplastic elastomer (TPE) new material include the component of following mass percent: SBS60%, plasticizing
Agent 20%, lavender 20%.
New material embodiment 5, thermoplastic elastomer (TPE) new material include the component of following mass percent: SEBS45%, plasticizing
Agent 25%, wormwood 30%.
New material embodiment 6, thermoplastic elastomer (TPE) new material include the component of following mass percent: SEBS20%, plasticizing
Agent 30%, lavender 50%.
New material embodiment 7, thermoplastic elastomer (TPE) new material include the component of following mass percent: SBS50%, plasticizing
Agent 30%, wormwood 20%.
New material embodiment 8, thermoplastic elastomer (TPE) new material include the component of following mass percent: SBS40%, plasticizing
Agent 15%, lavender 45%.
A kind of thermoplastic elastomer (TPE) green wood preparation method for material, comprising the following steps:
1. copolymer 20%~80%, plasticiser 10%~30%, plant raw material 5%~50% by mass percentage is put into mixing
In machine or screw machine, wherein the copolymer is SEBS or SBS, the plant raw material is wormwood or lavender, in work temperature
Preliminary thermoplastic elastomer (TPE) is obtained within hybrid process 3~15 minutes at 110 DEG C~200 DEG C of degree;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
Preparation method embodiment 1, a kind of thermoplastic elastomer (TPE) green wood preparation method for material, comprising the following steps:
1. copolymer 60%, plasticiser 25%, plant raw material 15% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 150 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 10 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
Preparation method embodiment 2, a kind of thermoplastic elastomer (TPE) green wood preparation method for material, comprising the following steps:
1. copolymer 30%, plasticiser 25%, plant raw material 45% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 170 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 15 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
In conclusion thermoplastic elastomer (TPE) new material component of the present invention is reasonable, effectively combine lavender, wormwood and SEBS,
Such new material is made in the characteristic of SBS, has the advantages that
1, facilitate processing, processing cost is low, and the thermoplastics processing equipment and technique of available standards carry out machine-shaping.
2, it being not required to vulcanize, production rubber product can be prepared, reduce vulcanization process, investment reduction, low energy consumption, simple process,
Process-cycle shortens, and production efficiency improves, and processing charges is low.
3, leftover bits are recyclable, save resource, also advantageous to environmental protection.
4, use lavender as base-material, the fragrance for taking full advantage of lavender itself is carefree and leisurely, tranquilizing soporific, spasmolysis,
Antibacterial, neuroprotection, lipid-loweringing, the treatment characteristics such as neurosis, the thermoplastic elastomer (TPE) new material produced have taste removal, it is ventilative,
Absorbing sweat, the advantages that keeping fit and healthy, and lavender is aftergrowth, it is environmentally protective, there is certain rush to conservation of nature environment
Into effect;
5, use wormwood and be used as base-material, take full advantage of the antibacterial promoting blood circulation of wormwood itself, clearing damp cold dispelling, with fragrance, antiallergy,
Nontoxic, antimycotic, rationale blood, temperature through etc. characteristics, the thermoplastic elastomer (TPE) new material produced have deodorization, taste removal, it is ventilative, inhale
The advantages that sweat, the equipment especially suitable for contacting with people use, and help to treat rheumatic arthritis etc., have healthcare function.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions, for those of ordinary skill in the art to which the present invention belongs,
Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention
Protection scope.
Claims (8)
1. a kind of thermoplastic elastomer (TPE) new material, which is characterized in that the component including following mass percent: copolymer 20%~
80%, plasticiser 10%~30%, plant raw material 5%~50%, the copolymer is SEBS or SBS, and the plant raw material is wormwood
Or lavender.
2. a kind of thermoplastic elastomer (TPE) new material according to claim 1, which is characterized in that including following mass percent
Component: SEBS50%, plasticiser 20%, wormwood 30%.
3. a kind of thermoplastic elastomer (TPE) new material according to claim 1, which is characterized in that including following mass percent
Component: SEBS40%, plasticiser 30%, lavender 30%.
4. a kind of thermoplastic elastomer (TPE) new material according to claim 1, which is characterized in that including following mass percent
Component: SBS50%, plasticiser 25%, wormwood 25%.
5. a kind of thermoplastic elastomer (TPE) new material according to claim 1, which is characterized in that including following mass percent
Component: SBS60%, plasticiser 20%, lavender 20%.
6. a kind of thermoplastic elastomer (TPE) green wood preparation method for material, which comprises the following steps:
1. copolymer 20%~80%, plasticiser 10%~30%, plant raw material 5%~50% by mass percentage is put into mixing
In machine or screw machine, wherein the copolymer is SEBS or SBS, the plant raw material is wormwood or lavender, in work temperature
Preliminary thermoplastic elastomer (TPE) is obtained within hybrid process 3~15 minutes at 110 DEG C~200 DEG C of degree;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
7. a kind of thermoplastic elastomer (TPE) green wood preparation method for material according to claim 6, which is characterized in that including following step
It is rapid:
1. copolymer 60%, plasticiser 25%, plant raw material 15% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 150 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 10 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
8. a kind of thermoplastic elastomer (TPE) green wood preparation method for material according to claim 6, which is characterized in that including following step
It is rapid:
1. copolymer 30%, plasticiser 25%, plant raw material 45% by mass percentage is put into mixer or screw machine,
Wherein the copolymer is SEBS or SBS, and the plant raw material is wormwood or lavender, is mixed at 170 DEG C of operating temperature
Processing obtains preliminary thermoplastic elastomer (TPE) in 15 minutes;
2. preliminary thermoplastic elastomer (TPE) is put into pelletizer, pelletizer cutting produces thermoplastic elastomer (TPE) new material particle.
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Cited By (1)
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CN115181390A (en) * | 2022-08-04 | 2022-10-14 | 深圳艾眠高分子科技有限公司 | Preparation method of TPE material containing herbaceous plants and pillow applying TPE material |
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CN105566738A (en) * | 2016-02-04 | 2016-05-11 | 湖北顶铭环保材料有限公司 | TPE foaming pad containing Chinese traditional medicine ingredients and preparation method thereof |
CN107760052A (en) * | 2017-10-17 | 2018-03-06 | 广东腾克体育发展有限公司 | A kind of wormwood polymer composite and preparation method thereof |
CN108587533A (en) * | 2018-04-21 | 2018-09-28 | 浙江精华科技有限公司 | Disposable medical articles for use structure glue and preparation method thereof |
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2018
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Patent Citations (3)
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CN105566738A (en) * | 2016-02-04 | 2016-05-11 | 湖北顶铭环保材料有限公司 | TPE foaming pad containing Chinese traditional medicine ingredients and preparation method thereof |
CN107760052A (en) * | 2017-10-17 | 2018-03-06 | 广东腾克体育发展有限公司 | A kind of wormwood polymer composite and preparation method thereof |
CN108587533A (en) * | 2018-04-21 | 2018-09-28 | 浙江精华科技有限公司 | Disposable medical articles for use structure glue and preparation method thereof |
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CN115181390A (en) * | 2022-08-04 | 2022-10-14 | 深圳艾眠高分子科技有限公司 | Preparation method of TPE material containing herbaceous plants and pillow applying TPE material |
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Application publication date: 20190301 |