CN102276103B - Integrated in-situ denitrification aquaculture wastewater biological treatment device and treatment method - Google Patents
Integrated in-situ denitrification aquaculture wastewater biological treatment device and treatment method Download PDFInfo
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技术领域technical field
本发明涉及一种污水处理装置和处理方法,特别是涉及一种一体化原位脱氮养殖废水生物处理装置及处理方法。The invention relates to a sewage treatment device and a treatment method, in particular to an integrated in-situ denitrification aquaculture wastewater biological treatment device and a treatment method.
背景技术Background technique
虽然我国城市规模化畜禽养殖业的发展起步晚,但其发展势头十分迅猛,短短十多年己达到相当大的规模,并继续呈高速发展趋势。由于畜禽业污染的防治和管理大大落后于该产业的迅速发展,并缺乏畜禽业污染系统的基础资料与数据。养殖业的飞速发展给社会带来巨大经济效益的同时,其排放的养殖废水带来的环境问题也日趋严重,养殖废水污染主要是氨氮污染,已经成为城市生活、工业废水之后的第三大污染源。Although the development of my country's large-scale urban livestock and poultry breeding industry started late, its development momentum is very rapid, and it has reached a considerable scale in just over ten years, and continues to develop at a high speed. As the prevention and management of livestock and poultry pollution is far behind the rapid development of the industry, there is a lack of basic information and data on the pollution system of the livestock and poultry industry. While the rapid development of the aquaculture industry has brought huge economic benefits to the society, the environmental problems caused by the aquaculture wastewater discharged by it have become increasingly serious. The pollution of aquaculture wastewater is mainly ammonia nitrogen pollution, which has become the third largest pollution source after urban life and industrial wastewater. .
由于一直以来对于畜禽养殖业的污染问题重视程度不够,加之畜禽养殖业低利润的特点,大部分养殖场都未对畜禽废水进行有效处理就直接排放。随着水体富营养化的加剧,人们越来越重视废水中氮、磷的达标排放问题,富营养化问题是当今世界面临的最主要的水污染问题之一。而畜禽废水具有悬浮固体高、有机物浓度高、氨氮浓度高的特点,尽管国内外学者对畜禽废水处理进行了大量试验研究,但就现行技术应用方面还存在很多问题。如:采用自然处理系统进行处理,其处理效果易受季节、温度及土地面积的影响,对于我国人多地少的实际情况而言,生物处理技术将是土地受限地区养殖废水处理的最优选择。但是,厌氧处理后的水中污染物浓度仍然很高,特别是氨氮基本没有去除,排入水体后,诱发水体“富营养化”,造成水生生态系统的紊乱,而且还能消耗溶解氧,造成水体缺氧,需要做进一步进行脱氮除磷的处理。Due to the lack of attention paid to the pollution of livestock and poultry farming, coupled with the low profit of livestock and poultry farming, most farms directly discharge livestock and poultry wastewater without effective treatment. With the intensification of eutrophication in water bodies, people pay more and more attention to the discharge of nitrogen and phosphorus in wastewater. Eutrophication is one of the most important water pollution problems facing the world today. The livestock and poultry wastewater has the characteristics of high suspended solids, high organic matter concentration, and high ammonia nitrogen concentration. Although domestic and foreign scholars have conducted a lot of experimental research on the treatment of livestock and poultry wastewater, there are still many problems in the application of current technologies. For example, the natural treatment system is used for treatment, and its treatment effect is easily affected by seasons, temperature and land area. For the actual situation in my country where there are many people and little land, biological treatment technology will be the best for the treatment of aquaculture wastewater in land-limited areas. choose. However, the concentration of pollutants in the water after anaerobic treatment is still high, especially the ammonia nitrogen is basically not removed. After being discharged into the water body, it will induce "eutrophication" of the water body, causing the disorder of the aquatic ecosystem, and can also consume dissolved oxygen, resulting in The water body is hypoxic and needs to be further treated to remove nitrogen and phosphorus.
近年来,虽然我国污水处理率不断提高,但是由氮磷污染引起的水体富营养问题不仅没有解决,而且有日益严重的趋势。可见,污水处理的主要矛盾已逐渐由有机污染物的去除转变为氮、磷污染物的去除。这就促使人们对传统活性污泥法进行改造,以提高氮、磷的去除率。氮化合物(NH4 +-N和NO3-N)的分子量比较小,无法通过投加药剂来去除。另外,如果采用物理化学法,如利用膜分离技术来去除氮化合物,仅有反渗透膜技术是最有效的,但工程造价及运行成本也是十分高的。因此氮的去除是污水处理的难点和重点,只有利用生物脱氮技术才是最合理可行的。另一方面,污水中的磷化合物利用生物处理方法有时不易去除,但通过投药混凝可实现满意的除磷效果。因此,生物脱氮技术是污水深度处理的关键所在。In recent years, although my country's sewage treatment rate has continued to increase, the eutrophication problem caused by nitrogen and phosphorus pollution has not only not been resolved, but has become increasingly serious. It can be seen that the main contradiction of sewage treatment has gradually changed from the removal of organic pollutants to the removal of nitrogen and phosphorus pollutants. This prompts people to transform the traditional activated sludge process to improve the removal rate of nitrogen and phosphorus. Nitrogen compounds (NH 4 + -N and NO 3 -N) have relatively small molecular weights and cannot be removed by adding chemicals. In addition, if physical and chemical methods are used, such as using membrane separation technology to remove nitrogen compounds, only reverse osmosis membrane technology is the most effective, but the engineering cost and operating cost are also very high. Therefore, the removal of nitrogen is the difficulty and focus of sewage treatment, and only the use of biological denitrification technology is the most reasonable and feasible. On the other hand, the phosphorus compounds in sewage are sometimes difficult to remove by biological treatment methods, but satisfactory phosphorus removal effects can be achieved by coagulation with drugs. Therefore, biological denitrification technology is the key to the advanced treatment of sewage.
当前实现脱氮的工艺很多,最具有代表性的工艺主要有SBR法、A/0法、氧化沟工艺,然而SBR法只能应用在小型污水处理厂,具有池容闲置期长、运行管理复杂等缺点,在城市污水处理厂的应用很少。而氧化沟工艺属于延时曝气工艺,具有基建费用和运行费用高的缺点。AA/0生物脱氮工艺是厌氧/缺氧/好氧生物脱氮除磷工艺的简称,是我国目前城市污水处理厂应用最多的一种脱氮工艺,反硝化在缺氧条件下运行,含碳有机物的去除和氨氮的硝化在好氧条件下运行,与传统的多级生物脱氮工艺相比具有很多优点,但也只是将氨氮转化为硝态氮,并没有对氮素污染实现真正的去除。但许多研究仅利用养殖废水的A/A/O空间环境,单独考虑脱氮作用,缺少碳氮比对硝化和反硝化作用的研究,过高的COD不利于硝化和反硝化细菌的生长,进而影响脱氮效果。如要去除,需要大量的回流动力,通过出水回流将处理条件由厌氧到好氧再到缺氧的转变来实现脱氮,因此污水处理负荷高,运行成本太大,这是目前我国污水处理厂生物脱氮普遍存在的能耗高、效率低以及运行不稳定的缺点。如果能有效减少回流,减少污泥产率,增加反硝化反应池的碳源和碱度,将可以保证AA/0生物脱氮的顺利实现。At present, there are many technologies for denitrification, the most representative ones are SBR method, A/0 method, and oxidation ditch process. However, SBR method can only be applied to small sewage treatment plants, which has the advantages of long idle period of pool capacity and complicated operation management. And other shortcomings, there are few applications in urban sewage treatment plants. The oxidation ditch process is a delayed aeration process, which has the disadvantages of high infrastructure and operating costs. AA/0 biological nitrogen removal process is the abbreviation of anaerobic/anoxic/aerobic biological nitrogen and phosphorus removal process. It is the most widely used nitrogen removal process in urban sewage treatment plants in my country. Denitrification operates under anoxic conditions. The removal of carbon-containing organic matter and the nitrification of ammonia nitrogen operate under aerobic conditions. Compared with the traditional multi-stage biological denitrification process, it has many advantages, but it only converts ammonia nitrogen into nitrate nitrogen, and does not really realize the nitrogen pollution. removal. However, many studies only use the A/A/O space environment of aquaculture wastewater, consider the denitrification effect alone, and lack the research on the effect of carbon-nitrogen ratio on nitrification and denitrification. Excessive COD is not conducive to the growth of nitrification and denitrification bacteria. affect the denitrification effect. If it is to be removed, a large amount of reflux power is required, and the treatment conditions are changed from anaerobic to aerobic to anoxic through effluent reflux to achieve denitrification. Therefore, the sewage treatment load is high and the operating cost is too high. This is the current sewage treatment in my country. The shortcomings of high energy consumption, low efficiency and unstable operation of plant biological denitrification are common. If the backflow can be effectively reduced, the sludge yield can be reduced, and the carbon source and alkalinity in the denitrification tank can be increased, the smooth realization of AA/0 biological denitrification can be guaranteed.
发明内容Contents of the invention
本发明要解决的技术问题是提供一种污泥产率小、无需回流,氨氮处理效果好的一体化原位脱氮养殖废水生物处理装置及处理方法。The technical problem to be solved by the present invention is to provide an integrated in-situ denitrification aquaculture wastewater biological treatment device and treatment method with low sludge yield, no need for reflux, and good ammonia nitrogen treatment effect.
本发明一体化原位脱氮养殖废水生物处理装置,包括池体,所述池体内由若干隔板分隔为厌氧除碳区、好氧硝化及沉淀区和缺氧脱氮区,其中所述厌氧除碳区纵向设有若干上向流折流板和下向流折流板,所述上向流折流板和下向流折流板将厌氧除碳区分隔成至少一组下降隔室和上升隔室,所述第一下降隔室、第二下降隔室与第一上升隔室、第二上升隔室交叉排布,每组中的第一下降隔室与第一上升隔室、第二下降隔室与第二上升隔室通过设置在其间下向流折流板下方的通道相连通,相邻组间的第一上升隔室与第二下降隔室通过设置在其间上向流折流板上方的通道相连通,所述第一上升隔室、第二上升隔室的宽度是所述第一下降隔室、第二下降隔室的3-5倍,第一组中的第一下降隔室的上部与主进水管相连通,所述主进水管上装有进水阀门;The integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention comprises a pool body, and the pool body is divided into an anaerobic carbon removal area, an aerobic nitrification and precipitation area, and an anoxic denitrification area by several partitions, wherein the The anaerobic carbon removal zone is longitudinally provided with several upward flow baffles and downward flow baffles, and the upward flow baffles and downward flow baffles divide the anaerobic carbon removal zone into at least one group of descending Compartments and ascending compartments, the first descending compartment, the second descending compartment and the first ascending compartment, the second ascending compartment are arranged crosswise, the first descending compartment and the first ascending compartment in each group chamber, the second descending compartment and the second ascending compartment are communicated through the channel arranged under the downward flow baffle between them, and the first ascending compartment and the second descending compartment between adjacent groups are communicated through the passage disposed between them It communicates with the channel above the flow baffle, and the width of the first ascending compartment and the second ascending compartment is 3-5 times that of the first descending compartment and the second descending compartment. In the first group The upper part of the first descending compartment communicates with the main water inlet pipe, and the water inlet valve is installed on the main water inlet pipe;
所述好氧硝化及沉淀区包括好氧曝气室、沉淀室和第四下降隔室,所述厌氧除碳区中第二上升隔室的上部与第四下降隔室的上部相连通,所述第四下降隔室的底部与好氧曝气室的底部相连通,所述好氧曝气室的底部设有曝气装置,好氧曝气室的底部与沉淀室的底部相连通,好氧曝气室的中部靠近沉淀室一侧纵向设置有隔流板,所述隔流板在好氧曝气室与沉淀室之间分隔出分流通道,所述分流通道的上端与好氧曝气室相连通,下端与沉淀室相连通;The aerobic nitrification and precipitation zone includes an aerobic aeration chamber, a sedimentation chamber and a fourth descending compartment, the upper part of the second ascending compartment in the anaerobic carbon removal zone communicates with the upper part of the fourth descending compartment, The bottom of the fourth descending compartment communicates with the bottom of the aerobic aeration chamber, the bottom of the aerobic aeration chamber is provided with an aeration device, and the bottom of the aerobic aeration chamber communicates with the bottom of the sedimentation chamber, The middle part of the aerobic aeration chamber near the sedimentation chamber is longitudinally provided with a divider, and the divider separates a shunt channel between the aerobic aeration chamber and the sedimentation chamber. The upper end of the shunt passage is connected to the aerobic aeration The air chamber is connected, and the lower end is connected with the precipitation chamber;
所述缺氧脱氮区包括第三下降隔室和第三上升隔室,所述第三下降隔室的上部与沉淀室的上部相连通,第三下降隔室的底部与第三上升隔室的底部相连通,所述第三上升隔室的上部的侧壁上设置有溢流堰,所述溢流堰内设置有出水管,所述第三下降隔室的上部与分进水管相连通,所述分进水管通过分水阀门与主进水管相连通;The anoxic denitrification zone includes a third descending compartment and a third ascending compartment, the upper part of the third descending compartment communicates with the upper part of the precipitation chamber, and the bottom of the third descending compartment communicates with the third ascending compartment The bottom of the third ascending compartment is connected, the upper side wall of the third rising compartment is provided with an overflow weir, the overflow weir is provided with a water outlet pipe, and the upper part of the third descending compartment is connected with the water inlet pipe , the water inlet pipe communicates with the main water inlet pipe through a water diversion valve;
所述池体顶部设有若干工作口,所述工作口分别与厌氧除碳区和缺氧脱氮区相对应,工作口上设置有盖板,所述盖板设有排气孔,所述第一上升隔室、第二上升隔室、好氧曝气区和第三上升隔室内设置有适于微生物附着的填料。The top of the pool body is provided with a number of working ports, which correspond to the anaerobic carbon removal zone and the anoxic denitrification zone respectively, and a cover plate is provided on the working port, and the cover plate is provided with an exhaust hole. Fillers suitable for microbial attachment are arranged in the first ascending compartment, the second ascending compartment, the aerobic aeration zone and the third ascending compartment.
本发明一体化原位脱氮养殖废水生物处理装置,其中所述池体为纵向设置的圆柱体,所述沉淀室设置在池体中心,所述厌氧除碳区的第一组第一下降隔室与缺氧脱氮区的第三下降隔室相邻。The integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention, wherein the pool body is a cylinder arranged vertically, the settling chamber is set in the center of the pool body, and the first group of the first drop in the anaerobic carbon removal zone The compartment is adjacent to the third descending compartment of the anoxic denitrification zone.
本发明一体化原位脱氮养殖废水生物处理装置,其中所述沉淀室的内壁上设有若干向下倾斜的斜板。The integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention, wherein the inner wall of the sedimentation chamber is provided with several inclined plates inclined downward.
本发明一体化原位脱氮养殖废水生物处理装置,其中所述隔流板的上端设有向好氧曝气室倾斜的上导流板,隔流板的下端设有向沉淀室倾斜的下导流板。The integrated in-situ denitrification breeding wastewater biological treatment device of the present invention, wherein the upper end of the flow partition is provided with an upper deflector inclined to the aerobic aeration chamber, and the lower end of the flow partition is provided with a lower deflector inclined to the sedimentation chamber. deflector.
本发明一体化原位脱氮养殖废水生物处理装置,其中所述填料为方形颗粒改性聚氨酯塑料泡沫。The integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention, wherein the filler is square particle modified polyurethane plastic foam.
本发明一体化原位脱氮养殖废水生物处理装置,其中所述厌氧除碳区内设有两组上升隔室和下降隔室。The integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention, wherein two sets of ascending compartments and descending compartments are arranged in the anaerobic carbon removal area.
本发明养殖废水生物处理方法,包括如下步骤:The biological treatment method of aquaculture wastewater of the present invention comprises the following steps:
【1】将经过干清粪分离和液-液分离装置分离后的养殖废水接入上述处理装置的主进水管,废水进入厌氧除碳区,通过在第一下降隔室、第二下降隔室与第一上升隔室、第二上升隔室的流动进入好氧曝气及沉淀区的第四下降隔室;[1] Connect the aquaculture wastewater that has been separated by the dry-clear feces separation and the liquid-liquid separation device into the main water inlet pipe of the above-mentioned treatment device, and the wastewater enters the anaerobic carbon removal area, and passes through the first descending compartment and the second descending compartment. The flow of the chamber and the first rising compartment and the second rising compartment enters the fourth descending compartment of the aerobic aeration and sedimentation zone;
【2】废水从第四下降隔室的底部进入好氧曝气室进行好氧微曝气,其中好氧微曝气供氧强度的上限为液相溶解氧水平低于2mgO2/L;【2】Wastewater enters the aerobic aeration chamber from the bottom of the fourth descending compartment for aerobic micro-aeration, wherein the upper limit of the oxygen supply intensity of the aerobic micro-aeration is that the liquid-phase dissolved oxygen level is lower than 2mgO 2 /L;
【3】经过好氧曝气后的废水进入分流通道,从分流通道下端进入沉淀室底部,调整隔流板的位置,改变分流通道的宽度,使分流通道内水力下降流速为0.2-1.0m/s;【3】After aerobic aeration, the waste water enters the diversion channel, and enters the bottom of the sedimentation chamber from the lower end of the diversion channel. Adjust the position of the partition plate and change the width of the diversion channel so that the hydraulic flow rate in the diversion channel is 0.2-1.0m/ s;
【4】废水从沉淀室底部向上流动,废水中的泥污沉降回到好氧曝气室底部,再次和废水混合曝气;【4】Wastewater flows upward from the bottom of the sedimentation chamber, and the sludge in the wastewater settles back to the bottom of the aerobic aeration chamber, where it is mixed and aerated with the wastewater again;
【5】沉淀后的废水从沉淀室的上部进入缺氧脱氮区的第三下降隔室,打开分水阀门,使部分养殖废水直接进入第三下降隔室,废水混合后从第三下降隔室底部进入第三上升隔室并和改性聚氨酯塑料泡沫附着的微生物充分接触,然后进入第三上升隔室上部的溢流堰内,再从出水管流出。[5] The wastewater after precipitation enters the third descending compartment of the anoxic denitrification zone from the upper part of the sedimentation chamber, and the water diversion valve is opened to allow part of the aquaculture wastewater to directly enter the third descending compartment. After the wastewater is mixed, it flows from the third descending compartment The bottom of the chamber enters the third rising compartment and fully contacts with the microorganisms attached to the modified polyurethane plastic foam, then enters the overflow weir on the upper part of the third rising compartment, and then flows out from the outlet pipe.
本发明养殖废水生物处理方法,其中所述厌氧除碳区水力停留时间为22h,好氧微曝气水力停留时间为7.5h,沉淀室水力停留时间为0.5h,缺氧脱氮区水力停留时间为6h,将循环一次后从出水管流出的废水再次引入进水管中,循环两次为一个完整反应周期。The biological treatment method for aquaculture wastewater of the present invention, wherein the hydraulic retention time in the anaerobic decarbonization zone is 22h, the hydraulic retention time in the aerobic micro-aeration zone is 7.5h, the hydraulic retention time in the sedimentation chamber is 0.5h, and the hydraulic retention time in the anoxic denitrification zone The time is 6 hours, and the waste water flowing out from the outlet pipe after one cycle is reintroduced into the water inlet pipe, and two cycles are a complete reaction cycle.
本发明养殖废水生物处理方法,其中所述主进水管进水量与分进水管进水量的比值为4-5:1。The biological treatment method for aquaculture wastewater of the present invention, wherein the ratio of the water intake of the main water inlet pipe to the water inlet amount of the sub-water inlet pipes is 4-5:1.
本发明养殖废水生物处理方法,其中所述缺氧脱氮区进水COD:NH4 +-N小于4:1。In the biological treatment method for aquaculture wastewater of the present invention, the COD:NH 4 + -N of the influent water in the anoxic denitrification zone is less than 4:1.
本发明一体化原位脱氮养殖废水生物处理装置及处理方法将传统脱氮工艺AA/O中从时间上实现厌氧—好氧—缺氧环境顺序的转变转化为在空间上实现厌氧—好氧—缺氧环境顺序的转变,通过在水流方向上不停出现厌氧、好氧、缺氧环境来实现脱氮,同时用分进水管向缺氧脱氮区补充反硝化所需的碳源,并不需回流,好氧产生的污泥自然回流到好氧曝气室中,实现生物量的有效截留,使污泥浓度大幅度下降,节省了大量的回流动力费用及污泥处置费用,对污水的碳素污染和氮素污染有很好的去除效果,同时提高了反应器的处理效率。The integrated in-situ denitrification aquaculture wastewater biological treatment device and treatment method of the present invention converts the transformation of the sequence of anaerobic-aerobic-anoxic environment realized in time from the traditional denitrification process AA/O into anaerobic-anoxic environment realized in space. The transformation of the sequence of aerobic-anoxic environment, denitrification is realized by continuously appearing anaerobic, aerobic, and anoxic environments in the direction of water flow, and at the same time, the carbon required for denitrification is supplemented to the anoxic denitrification area by using separate water inlet pipes The sludge produced by aerobic flow back into the aerobic aeration chamber naturally, so as to achieve the effective interception of biomass, greatly reduce the sludge concentration, and save a lot of return flow power costs and sludge disposal costs , It has a good removal effect on carbon pollution and nitrogen pollution of sewage, and at the same time improves the treatment efficiency of the reactor.
下面结合附图对本发明的一体化原位脱氮养殖废水生物处理装置及处理方法作进一步说明。The integrated in-situ denitrification aquaculture wastewater biological treatment device and treatment method of the present invention will be further described below in conjunction with the accompanying drawings.
附图说明Description of drawings
图1为本发明一体化原位脱氮养殖废水生物处理装置的结构示意图;Fig. 1 is the structural representation of the present invention's integrated in-situ denitrification aquaculture wastewater biological treatment device;
图2为图1中Ⅰ-Ⅰ方向剖面图;Fig. 2 is a sectional view in the direction of I-I in Fig. 1;
图3为图1中Ⅱ-Ⅱ方向剖面图;Fig. 3 is a sectional view in the direction of II-II in Fig. 1;
图4为图1中Ⅲ-Ⅲ方向剖面图。Fig. 4 is a sectional view along III-III direction in Fig. 1 .
具体实施方式Detailed ways
如图1所示,本发明一体化原位脱氮养殖废水生物处理装置包括池体23,池体23为纵向设置的圆柱体,池体23内由若干隔板分隔为厌氧除碳区、好氧硝化及沉淀区和缺氧脱氮区,厌氧除碳区纵向安装有若干上向流折流板24和下向流折流板25,上向流折流板24和下向流折流板25将厌氧除碳区分隔成两组下降隔室和上升隔室,第一下降隔室1、第二下降隔室3与第一上升隔室2、第二上升隔室4交叉排布,每组中的第一下降隔室1与第一上升隔室2、第二下降隔室3与第二上升隔室4通过设置在其间下向流折流板25下方的通道相连通,相邻组间的第一上升隔室2与第二下降隔室3通过设置在其间上向流折流板24上方的通道相连通,第一上升隔室2、第二上升隔室4的宽度是第一下降隔室1、第二下降隔室3的4倍,第一上升隔室2、第二上升隔室4内填充有适于微生物附着的方形颗粒改性聚氨酯塑料泡沫填料19,采用上向流折流板24和下向流折流板25,延长水流路径,改变水流速度,增强污水与附着在方形颗粒改性聚氨酯塑料泡沫填料19上的微生物充分接触性。第一组中的第一下降隔室1的上部与主进水管12相连通,主进水管12上装有进水阀门21。As shown in Figure 1, the integrated in-situ denitrification aquaculture wastewater biological treatment device of the present invention comprises a
结合图2和图3所示,好氧硝化及沉淀区包括好氧曝气室6、沉淀室7和第四下降隔室5,厌氧除碳区中第二上升隔室4的上部与第四下降隔室5的上部相连通,第四下降隔室5的底部与好氧曝气室6的底部相连通,好氧曝气室6的底部安装有曝气装置20,好氧曝气室6的底部与沉淀室7的底部相连通,沉淀室7设置在池体23中心,沉淀室7的内壁上安装有若干向下倾斜的斜板22。好氧曝气室6的中部靠近沉淀室7一侧纵向设置有隔流板16,隔流板16在好氧曝气室6与沉淀室7之间分隔出分流通道10,分流通道10的上端与好氧曝气室6相连通,下端与沉淀室7相连通,隔流板16的上端安装有向好氧曝气室6倾斜的上导流板27,隔流板16的下端安装有向沉淀室7倾斜的下导流板28。好氧曝气室6内填充有适于微生物附着的方形颗粒改性聚氨酯塑料泡沫填料19。Shown in conjunction with Fig. 2 and Fig. 3, aerobic nitrification and sedimentation area comprise aerobic aeration chamber 6,
结合图4所示,缺氧脱氮区包括第三下降隔室8和第三上升隔室9,厌氧除碳区的第一组第一下降隔室1与缺氧脱氮区的第三下降隔室8相邻,第三下降隔室8的上部与沉淀室7的上部相连通,第三下降隔室8的底部与第三上升隔室9的底部相连通,第三上升隔室9内填充有适于微生物附着的方形颗粒改性聚氨酯塑料泡沫填料19。第三上升隔室9的上部的侧壁上设置有溢流堰15,溢流堰15内设置有出水管11,第三下降隔室8的上部与分进水管12’相连通,分进水管12’通过分水阀门21’与主进水管12相连通。As shown in Figure 4, the anoxic denitrification zone includes the third descending compartment 8 and the third ascending compartment 9, the first group of the first descending compartment 1 of the anaerobic carbon removal zone and the third compartment 1 of the anoxic denitrification zone. The descending compartment 8 is adjacent, the upper part of the third descending compartment 8 communicates with the upper part of the settling
池体23顶部安装有若干工作口26,工作口26分别与厌氧除碳区和缺氧脱氮区相对应,工作口26上设置有盖板14,盖板14安装有排气孔13。A number of working
本发明养殖废水生物处理方法,包括如下步骤:The biological treatment method of aquaculture wastewater of the present invention comprises the following steps:
【1】将经过干清粪分离和液-液分离装置分离后的养殖废水接入上述处理装置的主进水管12,废水水质为COD为6000mg/L,NH4 +-N为500mg/L,TN为18mg/L,打开进水阀门21,使80%的废水进入厌氧除碳区,通过在第一下降隔室1、第二下降隔室3与第一上升隔室2、第二上升隔室4的流动进入好氧曝气及沉淀区的第四下降隔室5;[1] Connect the aquaculture wastewater after dry-clear feces separation and liquid-liquid separation device to the main water inlet pipe 12 of the above-mentioned treatment device, the wastewater quality is 6000 mg/L for COD, and 500 mg/L for NH 4 + -N, TN is 18mg/L, open the water inlet valve 21, so that 80% of the waste water enters the anaerobic carbon removal zone, and passes through the first descending compartment 1, the second descending compartment 3 and the first ascending compartment 2, the second ascending compartment The flow from compartment 4 enters the fourth descending compartment 5 of the aerobic aeration and sedimentation zone;
【2】废水从第四下降隔室5的底部进入好氧曝气室6进行好氧微曝气,其中好氧微曝气供氧强度的上限为液相溶解氧水平低于2mgO2/L;[2] Wastewater enters the aerobic aeration chamber 6 from the bottom of the fourth descending compartment 5 for aerobic micro-aeration, wherein the upper limit of the oxygen supply intensity of the aerobic micro-aeration is that the liquid-phase dissolved oxygen level is lower than 2mgO 2 /L ;
【3】经过好氧曝气后的废水进入分流通道10,从分流通道10下端进入沉淀室7底部,调整隔流板16的位置,改变分流通道10的宽度,使分流通道10内水力下降流速为0.2-1.0m/s;[3] The waste water after aerobic aeration enters the diversion channel 10, enters the bottom of the
【4】废水从沉淀室7底部向上流动,废水中的泥污沉降自动回流到好氧曝气室6底部,再次和废水混合曝气,实现污泥减量化的目的;[4] The waste water flows upward from the bottom of the
【5】沉淀后的废水从沉淀室7的上部进入缺氧脱氮区的第三下降隔室8,打开分水阀门21’,使20%的养殖废水直接进入第三下降隔室8,第三下降隔室8进水COD:NH4 +-N小于4:1,补充反硝化所需的碳源。废水混合后从第三下降隔室8底部进入第三上升隔室9并和改性聚氨酯塑料泡沫附着的微生物充分接触,然后进入第三上升隔室9上部的溢流堰15内,再从出水管11流出。设计厌氧除碳区水力停留时间为22h,好氧微曝气水力停留时间为7.5h,沉淀室水力停留时间为0.5h,缺氧脱氮区水力停留时间为6h,将循环一次后从出水管11流出的废水再次引入主进水管12中,循环两次为一个完整反应周期。【5】Wastewater after precipitation enters the third descending compartment 8 of the anoxic denitrification zone from the upper part of the
经过一个反应周期处理后的废水COD为270mg/L,NH4 +-N为180mg/L,处理效果得到明显的提高,运行成本也得到有效的降低。After one reaction cycle, the COD of wastewater is 270mg/L, and the NH 4 + -N is 180mg/L. The treatment effect is significantly improved, and the operating cost is also effectively reduced.
以上所述的实施例仅仅是对本发明的优选实施方式进行描述,并非对本发明的范围进行限定,在不脱离本发明设计精神的前提下,本领域普通技术人员对本发明的技术方案作出的各种变形和改进,均应落入本发明权利要求书确定的保护范围内。The above-mentioned embodiments are only descriptions of preferred implementations of the present invention, and are not intended to limit the scope of the present invention. Variations and improvements should fall within the scope of protection defined by the claims of the present invention.
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