CN102257016B - 使用酯溶剂混合物溴化丁二烯聚合物的方法 - Google Patents

使用酯溶剂混合物溴化丁二烯聚合物的方法 Download PDF

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Publication number
CN102257016B
CN102257016B CN200980150882.7A CN200980150882A CN102257016B CN 102257016 B CN102257016 B CN 102257016B CN 200980150882 A CN200980150882 A CN 200980150882A CN 102257016 B CN102257016 B CN 102257016B
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Prior art keywords
tribromide
quaternary ammonium
butadiene
brominated
polymer
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Chinese (zh)
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CN102257016A (zh
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戴维·布鲁斯·戈尔曼
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American Special Electronic Materials Co ltd
Special Electronic Materials Inc
Dow Chemical Co
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/12—Incorporating halogen atoms into the molecule
    • C08C19/14—Incorporating halogen atoms into the molecule by reaction with halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/12—Incorporating halogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/14—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
    • C08F36/16—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN200980150882.7A 2008-12-19 2009-12-07 使用酯溶剂混合物溴化丁二烯聚合物的方法 Active CN102257016B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13908508P 2008-12-19 2008-12-19
US61/139,085 2008-12-19
PCT/US2009/067036 WO2010080286A1 (en) 2008-12-19 2009-12-07 Process for brominating butadiene polymers using ester solvent mixtures

Publications (2)

Publication Number Publication Date
CN102257016A CN102257016A (zh) 2011-11-23
CN102257016B true CN102257016B (zh) 2014-04-09

Family

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Family Applications (1)

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CN200980150882.7A Active CN102257016B (zh) 2008-12-19 2009-12-07 使用酯溶剂混合物溴化丁二烯聚合物的方法

Country Status (6)

Country Link
US (1) US8779066B2 (cg-RX-API-DMAC7.html)
EP (1) EP2379605B1 (cg-RX-API-DMAC7.html)
JP (1) JP5612599B2 (cg-RX-API-DMAC7.html)
CN (1) CN102257016B (cg-RX-API-DMAC7.html)
IL (1) IL213552A (cg-RX-API-DMAC7.html)
WO (1) WO2010080286A1 (cg-RX-API-DMAC7.html)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012044483A1 (en) * 2010-09-30 2012-04-05 Dow Global Technologies Llc Process for recovering brominated styrene-butadiene copolymers from a bromination reaction solution
US9062133B2 (en) 2010-09-30 2015-06-23 Dow Global Technologies Llc Process for brominating butadiene polymers using mixed solvents
CN107207631B (zh) 2015-01-30 2019-04-12 陶氏环球技术有限责任公司 生成溴化并卤化水合聚合物的方法
CN109942730B (zh) * 2019-03-07 2021-06-25 天津市建筑材料科学研究院有限公司 一种非均相氧化制备溴化苯乙烯-丁二烯共聚物的方法
EP3938316A1 (en) * 2019-03-13 2022-01-19 Eastman Chemical Company Processes useful in the manufacture of cyclododecasulfur
CN115010857B (zh) * 2022-07-25 2023-09-29 北京工商大学 一种高热稳定性溴化丁二烯-苯乙烯共聚物的制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1567568A1 (ru) * 1988-04-08 1990-05-30 Киевский Государственный Университет Им.Т.Г.Шевченко Способ получени 1,3-дибромацетона
EP0565075A1 (en) * 1992-04-07 1993-10-13 Teijin Chemicals, Ltd. Emulsion polymerization method for a brominated styrene
WO2008021418A1 (en) * 2006-08-16 2008-02-21 Dow Global Technologies, Inc. Process for brominating butadiene/vinyl aromatic copolymers
WO2008021417A3 (en) * 2006-08-16 2008-04-10 Dow Global Technologies Inc Process for brominating butadiene/vinyl aromatic copolymers
CN101305022A (zh) * 2005-11-12 2008-11-12 陶氏环球技术公司 溴化丁二烯/乙烯基芳族共聚物、该共聚物与乙烯基芳族聚合物的掺合物和由该掺合物形成的聚合物泡沫

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3306208B2 (ja) * 1994-01-10 2002-07-24 ダイセル化学工業株式会社 熱可塑性重合体組成物
AUPP909499A0 (en) * 1999-03-10 1999-04-01 Commonwealth Scientific And Industrial Research Organisation Surface modification of rubber objects
JP4819616B2 (ja) * 2006-08-11 2011-11-24 三井化学株式会社 オレフィン系重合体
US20080064774A1 (en) 2006-09-07 2008-03-13 Stobby William G Stabilized extruded alkenyl aromatic polymer foams and processes for extruding stabilized alkenyl aromatic polymer foams
EP2170962B1 (en) * 2007-07-03 2012-05-16 Dow Global Technologies LLC Process for recovering brominated butadiene polymers from solution
CN101959954B (zh) 2008-02-26 2013-03-27 陶氏环球技术公司 作为阻燃添加剂的溴化聚合物及含有该溴化聚合物的聚合物体系

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1567568A1 (ru) * 1988-04-08 1990-05-30 Киевский Государственный Университет Им.Т.Г.Шевченко Способ получени 1,3-дибромацетона
EP0565075A1 (en) * 1992-04-07 1993-10-13 Teijin Chemicals, Ltd. Emulsion polymerization method for a brominated styrene
CN101305022A (zh) * 2005-11-12 2008-11-12 陶氏环球技术公司 溴化丁二烯/乙烯基芳族共聚物、该共聚物与乙烯基芳族聚合物的掺合物和由该掺合物形成的聚合物泡沫
WO2008021418A1 (en) * 2006-08-16 2008-02-21 Dow Global Technologies, Inc. Process for brominating butadiene/vinyl aromatic copolymers
WO2008021417A3 (en) * 2006-08-16 2008-04-10 Dow Global Technologies Inc Process for brominating butadiene/vinyl aromatic copolymers

Also Published As

Publication number Publication date
EP2379605A1 (en) 2011-10-26
CN102257016A (zh) 2011-11-23
WO2010080286A1 (en) 2010-07-15
IL213552A0 (en) 2011-07-31
IL213552A (en) 2016-12-29
EP2379605B1 (en) 2014-03-12
US20140121330A1 (en) 2014-05-01
US8779066B2 (en) 2014-07-15
JP5612599B2 (ja) 2014-10-22
JP2012512943A (ja) 2012-06-07

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