CN102233422A - Composite guide plate and preparation process thereof - Google Patents

Composite guide plate and preparation process thereof Download PDF

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Publication number
CN102233422A
CN102233422A CN2011101211006A CN201110121100A CN102233422A CN 102233422 A CN102233422 A CN 102233422A CN 2011101211006 A CN2011101211006 A CN 2011101211006A CN 201110121100 A CN201110121100 A CN 201110121100A CN 102233422 A CN102233422 A CN 102233422A
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China
Prior art keywords
ceramic particles
foreplate
guide plate
composite
hard ceramic
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CN2011101211006A
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Chinese (zh)
Inventor
蒋业华
隋育栋
李祖来
岑启宏
周荣
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN2011101211006A priority Critical patent/CN102233422A/en
Publication of CN102233422A publication Critical patent/CN102233422A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a composite guide plate and a preparation process thereof. A layer of hard ceramic particles is compounded on the abraded surface of the composite guide plate to improve the abrasion resistance. The preparation process comprises the following steps of: adding adhesive and alloy powder into the ceramic particles, stirring uniformly, spreading the mixture into a guide plate casting mold according to the design requirement, pouring a base material metal, cooling, stripping and clearing to obtain the composite guide plate. The composite guide plate has the advantages that: the layer of hard ceramic particles is compounded on the surface of the guide plate to form an abrasion-resistant hard phase, and the base material metal is filled in the gaps of the ceramic particles, so that the compounded surface has the abrasion resistance of the ceramic particles and the plastic toughness and the fatigue resistance of the base material metal, the hard phase does not drop easily, the controllability of process parameters is strong, the defects of slag inclusion and the like do not exist in the tissues, the composite guide plate is convenient for machining operation and convenient for industrialized large-batch production, and the service life of the guide plate is prolonged by 5 to 8 times higher than that of a common guide plate.

Description

A kind of composite foreplate and preparation technology thereof
Technical field
The present invention relates to the plant equipment and the preparation technology in general fragmentation, grinding, conveying, flotation, pulverizing field, particularly foreplate and the preparation technology thereof under the impact wear operating mode.
Background technology
Foreplate has the blank of importing and escorts effect in processes such as rolled steel, its working face bears impact, friction and the extruding of hot steel billet simultaneously, and the Quench of cooling water, and working condition is more abominable, and the working position wearing and tearing are very serious.So it is foreplate is changed more frequent, also bigger to producing influence.This shows,, need the comprehensive mechanical property under the normal temperature, also need the mechanical property under the high temperature simultaneously for foreplate.Therefore, select scientific and rational material and manufacturing process for use, produce higher foreplate in service life, important meaning is all arranged enhancing productivity, reducing production costs.
Past, the foreplate that domestic many steel rolling mills use white cast-iron, spheroidal graphite cast-iron, low-alloy steel to produce more, the foreplate of these materials weares and teares easily, and service life is shorter, and maintenance is changed frequent, directly influences production efficiency and production cost.In recent years, many producers adopt Gao Ge, nickel alloy to produce foreplate and obtained than obvious effects, also the overall economic efficiency of Ti Gaoing.But, Gao Ge, nickel alloy prices of raw and semifnished materials costliness.As every heavy 16kg of finishing mill foreplate, and the more serious less part of having only of wearing and tearing, waste of material is comparatively serious.Therefore have only by combination process the material of different qualities is combined, and the comparatively serious position of local synergic wear, make the composite foreplate and take into account the each side mechanical mechanics property, could satisfy the needs of various operating modes.China utility model patent CN2495390Y discloses a kind of composite alloy material guide and guard board, it be with low-alloy steel such as 40Cr as body, the working face part is made with unit or binary and multicomponent alloy layer.CN101195156A discloses a kind of preparation method of casting and seeping foreplate of rolling mill, and this foreplate is to reach wear-resisting purpose at the compound alloy powder with the ball mill refinement of working face.China utility model patent CN200998736Y discloses a kind of foreplate that working face is designed to waveform.CN1706635A has invented compound foreplate of a kind of bimetallic and preparation method thereof.CN101412095A discloses a kind of preparation method of composite wear-resistant foreplate, and what it adopted is that the alloyed powder plug is prefabricated in the die cavity of foreplate casting mold, melts bar by the heat effect of substrate metal then, thereby obtains having the foreplate of complex abrasion-proof layer.What above foreplate and preparation method thereof had can't satisfy actual use needs, the complicated process of preparation that has, and production cost is high, can't carry out industrialized large-scale production.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, provide a kind of and can satisfy high-performance foreplate and the preparation technology thereof who uses under the complex working conditions such as various wearing and tearing, impact.Adopt polyvinyl alcohol as binding agent, alloy powder as penetration-assisting agent, with simple manufacturing process extremely, hard ceramic particles be compounded in foreplate frayed with the working face that impacts on form wear-resistant hard mutually, make the foreplate working face both have the intensity and the toughness of substrate metal, the high rigidity of ceramic hard phase is arranged again and do wearability, power, high frequency cyclic loading and strong wear simultaneously can withstand shocks, has very high cost performance, also be fit to large-scale industrialization production, improve 5 ~ 8 times than common foreplate the service life of foreplate.
Composite machine of the present invention is defended plate, a base material (1) that adopts any one making in potassium steel, steel alloy, high chrome and the high-carbon steel is arranged, it is characterized in that, partly be compounded with the hard ceramic particles layer (2) of one deck by hard ceramic particles and metal powder metallurgy combination at the working face of said foreplate; Said hard ceramic particles is 1 ~ 4 kind in carborundum, tungsten carbide, silicon nitride, the titanium nitride, and when hard ceramic particles was made up of two or more ceramic particles, the ratio between its constituent element was arbitrarily; Said metal dust is any one in nickel powder, cobalt powder, molybdenum-iron powder, the ferrotungsten powder, and its adding proportion is 5 ~ 25% of a hard ceramic particles weight.
The grain diameter of said hard ceramic particles layer (2) is-40 ~+80 orders, and the thickness of hard ceramic particles layer (2) is 2 ~ 6mm.
The preparation technology of composite foreplate is characterized in that, preparation section is as follows:
A,Binding agent polyvinyl alcohol, metal dust and hard ceramic particles are mixed, after stirring, be routed in the foreplate bubbles model (3) by designing requirement, its THICKNESS CONTROL is at 2 ~ 6mm; The adding proportion of metal dust is 5 ~ 25% of a hard ceramic particles weight, and the adding proportion of binding agent polyvinyl alcohol is 2 ~ 5% of a hard ceramic particles weight;
B, smelt the fusing substrate metal, come out of the stove after reaching base materials employed metal tapping temperature, pour in the model (3), till filling with intermediate frequency furnace; Under the heat effect of substrate metal, the binding agent gasification is discharged, and ceramic particle is full of substrate metal in the gap, and the dissolving and the diffusion of trace take place between ceramic particle and substrate metal, make to form the excellent metallurgical combination between the two, constituted the composite foreplate of wearability and obdurability matched well;
C, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make the base steel composite material foreplate that working surface is strengthened by hard particles.
Compare with prior art, the present invention has following beneficial effect:
1, because ceramic particles such as carborundum, tungsten carbide, silicon nitride, titanium nitride has very high hardness, generally be 8 ~ 10 times of conventional metals high-abrasive material hardness, therefore after being compound to the foreplate surface, can become good wear-resistant hard phase, the cutting and the cutter of foreplate are cut when the foreplate apparent motion to resist material, improve the service life of foreplate, improve 5 ~ 8 times than common foreplate.
2, the binding agent polyvinyl alcohol is cast moment at substrate metal, can prevent that hard ceramic particles is defeated and dispersed, and after casting is finished, polyvinyl alcohol gasifies under the high temperature action of substrate metal and discharges from casting mold, can not stay genetic defects such as slag inclusion, hard ceramic particles is full of substrate metal in the gap, ceramic particle is realized the good supporting effect, because ceramic grain surface generation oligodynamical and atom diffusion under the high temperature, therefore have very strong adhesion with substrate metal, avoided foreplate in use under high-frequency percussion load ceramic particle come off.
3, the hard ceramic particles composite thickness can carry out freely designing in 2 ~ 6mm scope according to the actual working conditions needs, realizes the control to the foreplate production cost, obtains very high cost performance.
4, compound preparation technology's controllability of the present invention is strong, the yield rate height, and the quality of production is stable, is convenient to large-scale industrialization production.
Description of drawings
Fig. 1 is a composite foreplate schematic three dimensional views; Fig. 2 is a composite foreplate preparation technology schematic diagram; Fig. 3 is a composite foreplate structure cutaway view; Fig. 4 is a composite foreplate preparation technology flow chart.
The specific embodiment
Also in conjunction with the accompanying drawings the present invention is described in further detail below by embodiment.
Embodiment 1
Shown in Fig. 2,3, the preparation tungsten carbide particle is that hard phase, Cr15 high chrome are the composite foreplate of base material, and its preparation process is as follows:
A, select the tungsten carbide particle of-40 ~+60 order particle size range for use,, add 3% polyvinyl alcohol and 10% nickel powder, stir by the weight of ceramic particle;
B, require to make foreplate model (3) according to casting technique;
C, the mixture that steps A is made are routed on the working face of foreplate model (3), and appropriate compacting, and its thickness is 3mm;
D, select for use the Cr15 high chrome as substrate metal (1), smelt fusing with intermediate frequency furnace after, reach 1580 ℃ and come out of the stove, the Cr15 high chrome is poured in the model (3), till filling with;
E, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make the working surface tungsten carbide particle and strengthen Cr15 high chrome based composites foreplate.
Embodiment 2
Shown in Fig. 2,3, preparation tungsten carbide, silicon-carbide particle are that hard phase, high-carbon steel are the composite foreplate of base material, and its preparation process is as follows:
A, the tungsten carbide particle of selecting-40 ~+60 order particle size range for use and silicon-carbide particle (2), the ratio of tungsten carbide particle and silicon-carbide particle is 1:1, by the weight of ceramic particle, adds 3% polyvinyl alcohol and 5% cobalt powder, stirs;
B, require to make foreplate model (3) according to casting technique;
C, the mixture that steps A is made are routed on the working face of foreplate model (3), and appropriate compacting, and its thickness is 2mm;
D, select for use high-carbon steel as substrate metal (1), smelt fusing with intermediate frequency furnace after, reach 1580 ℃ and come out of the stove, high-carbon steel is poured in the die cavity of model (3), till filling with;
E, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make the working surface tungsten carbide, silicon-carbide particle strengthens high-carbon steel based composites foreplate.
Embodiment 3
Shown in Fig. 2,3, preparation tungsten carbide, carborundum, silicon nitride particle are that hard phase, 40Cr low-alloy steel are the composite foreplate of base material, and its preparation process is as follows:
A, the tungsten carbide particle of selecting-60 ~+80 order particle size range for use, silicon-carbide particle and silicon nitride particle (2), tungsten carbide particle: silicon-carbide particle: the ratio of silicon nitride particle is 2:1:1, by the weight of ceramic particle, add 2% polyvinyl alcohol and 15% ferrotungsten powder, stir;
B, require to make foreplate model (3) according to casting technique;
C, the mixture that steps A is made are routed on the working face of foreplate model (3), and appropriate compacting, and its thickness is 6mm;
D, select for use 40Cr low-alloy steel as substrate metal (1), smelt fusing with intermediate frequency furnace after, reach 1500 ℃ and come out of the stove, 40Cr low-alloy steel is poured in the die cavity of model (3), till filling with;
E, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make working surface tungsten carbide, carborundum, silicon nitride particle and strengthen 40Cr low-alloy steel based composites foreplate.
Embodiment 4
Shown in Fig. 2,3, preparation tungsten carbide, carborundum, silicon nitride, titanium nitride particles are that hard phase, potassium steel are the composite foreplate of base material, and its preparation process is as follows:
A, the tungsten carbide particle of selecting-60 ~+80 order particle size range for use, silicon-carbide particle, silicon nitride particle and titanium nitride particles (2), tungsten carbide particle: silicon-carbide particle: silicon nitride particle: the ratio of titanium nitride particles is 1:1:1:1, weight by ceramic particle, add 5% polyvinyl alcohol and 25% molybdenum-iron powder, stir;
B, require to make foreplate model (3) according to casting technique;
C, the mixture that steps A is made are routed on the working face of foreplate model (3), and appropriate compacting, and its thickness is 4mm;
D, select for use potassium steel as substrate metal (1), smelt fusing with intermediate frequency furnace after, reach 1580 ℃ and come out of the stove, potassium steel is poured in the die cavity of model (3), till filling with;
E, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make working surface tungsten carbide, carborundum, silicon nitride and titanium nitride particles and strengthen the high manganese steel base composite material foreplate.

Claims (3)

1. composite foreplate, a base material (1) that adopts any one making in potassium steel, steel alloy, high chrome and the high-carbon steel is arranged, it is characterized in that, partly be compounded with the hard ceramic particles layer (2) of one deck by hard ceramic particles and metal powder metallurgy combination at the working face of said foreplate; Said hard ceramic particles is 1 ~ 4 kind in carborundum, tungsten carbide, silicon nitride, the titanium nitride, and when hard ceramic particles was made up of two or more ceramic particles, the ratio between its constituent element was arbitrarily; Said metal dust is any one in nickel powder, cobalt powder, molybdenum-iron powder, the ferrotungsten powder, and its adding proportion is 5 ~ 25% of a hard ceramic particles weight.
2. according to the foreplate of claim 1, it is characterized in that the grain diameter of said hard ceramic particles layer (2) is-40 ~+80 orders, the thickness of hard ceramic particles layer (2) is 2 ~ 6mm.
3. the preparation technology of claim 1 and 2 composite foreplate is characterized in that preparation section is as follows:
A,Binding agent polyvinyl alcohol, metal dust and hard ceramic particles are mixed, after stirring, be routed in the foreplate bubbles model (3) by designing requirement, its THICKNESS CONTROL is at 2 ~ 6mm; The adding proportion of metal dust is 5 ~ 25% of a hard ceramic particles weight, and the adding proportion of binding agent polyvinyl alcohol is 2 ~ 5% of a hard ceramic particles weight;
B, smelt the fusing substrate metal, come out of the stove after reaching base materials employed metal tapping temperature, pour in the model (3), till filling with intermediate frequency furnace; Under the heat effect of substrate metal, the binding agent gasification is discharged, and ceramic particle is full of substrate metal in the gap, and the dissolving and the diffusion of trace take place between ceramic particle and substrate metal, make to form the excellent metallurgical combination between the two, constituted the composite foreplate of wearability and obdurability matched well;
C, treat that the substrate metal liquid cooling is but solidified after, take out casting cleaning, promptly make the base steel composite material foreplate that working surface is strengthened by hard particles.
CN2011101211006A 2011-05-11 2011-05-11 Composite guide plate and preparation process thereof Pending CN102233422A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102554236A (en) * 2011-12-29 2012-07-11 中联重科股份有限公司 Composite material piece and manufacturing method thereof
CN103252474A (en) * 2013-05-28 2013-08-21 肖振桥 Base steel alloy composite part and production method thereof
CN104674108A (en) * 2015-02-06 2015-06-03 中国兵器工业第五二研究所烟台分所 Tungsten carbide ceramic particle/high-chromium cast iron composite wear-resistant lining plate and manufacturing method thereof
CN106392061A (en) * 2016-10-13 2017-02-15 广州番禺职业技术学院 Ceramic particle reinforced wear-resisting insert and manufacturing method thereof
CN108453243A (en) * 2018-04-10 2018-08-28 昆明理工大学 A kind of ceramic-metal composites preparation method
CN113714487A (en) * 2021-08-23 2021-11-30 昆明理工大学 Preparation method of high-wear-resistance WC particle reinforced steel-based surface layer composite guide plate
CN114378261A (en) * 2022-02-24 2022-04-22 德清县东旭合金钢铸造有限公司 Casting process of bimetal alloy steel plate

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JPS5982154A (en) * 1982-10-30 1984-05-12 Kubota Ltd Production of composite casting
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CN101195156A (en) * 2007-12-04 2008-06-11 北京工业大学 Process for producing casting and seeping foreplate of rolling mill
CN101412095A (en) * 2008-11-28 2009-04-22 西安建筑科技大学 Method for preparing composite wear-resistant foreplate
CN101412102A (en) * 2008-12-03 2009-04-22 西安建筑科技大学 Method for preparing primary column/ribbon shaped horniness phase composite wear-resistant steel rolling guide roller

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5982154A (en) * 1982-10-30 1984-05-12 Kubota Ltd Production of composite casting
CN2495390Y (en) * 2000-11-09 2002-06-19 毛立仁 Guiding and positioning plate made of composite alloy material
CN101195156A (en) * 2007-12-04 2008-06-11 北京工业大学 Process for producing casting and seeping foreplate of rolling mill
CN101412095A (en) * 2008-11-28 2009-04-22 西安建筑科技大学 Method for preparing composite wear-resistant foreplate
CN101412102A (en) * 2008-12-03 2009-04-22 西安建筑科技大学 Method for preparing primary column/ribbon shaped horniness phase composite wear-resistant steel rolling guide roller

Non-Patent Citations (1)

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Title
张玉勤: "碳化钨颗粒增强铁基表面复合材料及其冲蚀磨损性能研究", 《中国优秀硕士学位论文全文数据库》 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102554236A (en) * 2011-12-29 2012-07-11 中联重科股份有限公司 Composite material piece and manufacturing method thereof
CN102554236B (en) * 2011-12-29 2013-06-05 中联重科股份有限公司 Composite material piece and manufacturing method thereof
CN103252474A (en) * 2013-05-28 2013-08-21 肖振桥 Base steel alloy composite part and production method thereof
CN104674108A (en) * 2015-02-06 2015-06-03 中国兵器工业第五二研究所烟台分所 Tungsten carbide ceramic particle/high-chromium cast iron composite wear-resistant lining plate and manufacturing method thereof
CN104674108B (en) * 2015-02-06 2016-09-21 中国兵器工业第五二研究所烟台分所 Tungsten carbide ceramics particles/rich chromium cast iron composite abrasion-proof inner plate and preparation method thereof
CN106392061A (en) * 2016-10-13 2017-02-15 广州番禺职业技术学院 Ceramic particle reinforced wear-resisting insert and manufacturing method thereof
CN106392061B (en) * 2016-10-13 2018-06-19 广州番禺职业技术学院 A kind of ceramic particle enhancing wear insert and preparation method thereof
CN108453243A (en) * 2018-04-10 2018-08-28 昆明理工大学 A kind of ceramic-metal composites preparation method
CN113714487A (en) * 2021-08-23 2021-11-30 昆明理工大学 Preparation method of high-wear-resistance WC particle reinforced steel-based surface layer composite guide plate
CN113714487B (en) * 2021-08-23 2023-02-03 昆明理工大学 Preparation method of high-wear-resistance WC particle reinforced steel-based surface layer composite guide plate
CN114378261A (en) * 2022-02-24 2022-04-22 德清县东旭合金钢铸造有限公司 Casting process of bimetal alloy steel plate
CN114378261B (en) * 2022-02-24 2023-12-05 德清县东旭合金钢铸造有限公司 Casting process of bimetal alloy steel plate

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Application publication date: 20111109