CN102228030A - Germicide composition containing imibenconazole and triazole compound - Google Patents
Germicide composition containing imibenconazole and triazole compound Download PDFInfo
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Abstract
The invention relates to a germicide composition containing imibenconazole and triazole compound. The compound contains the following components in percentage by weight: 1 to 60 percent of active ingredient A and 1 to 60 percent of active ingredient B, wherein the active ingredient A may be imibenconazole; and the active ingredient B is one of triadimenol, propiconazole, bitertanol, ipconazole, metconazole, triticonazole, myclobutanil, flutriafol, triazolone, penconazole and tetraconazole. After being mixed with an auxiliary agent and an excipient, the active ingredients can be prepared into wettable powder, water dispersible granules, a suspending agent, a suspending emulsion, a microemulsion and a water emulsion. The germicide composition is used for controlling powdery mildew, leaf spot, macrophoma musae, rust disease, alternaria leaf spot, bakanae disease and white rot, is rain water wash resistant and has an obvious synergistic effect.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of bactericidal composition on crop pest that contains glyoxalin and triazole class compounds.
Technical background
Glyoxalin, English name: imibenconazole, molecular formula: C
17H
13Cl
3N
4S, chemical name: 4-benzyl chloride base N-(2,4 dichloro benzene base)-2 (1H-1,2,4-triazol-1-yl) thioacetamide ester, structural formula:
Glyoxalin is the broad spectrum activity triazole bactericidal agent.The main mechanism of action is to destroy and stop the biosynthesis of the cell membrane important component part ergosterol of germ, thereby destroys the formation of cell membrane, causes germ death.Glyoxalin has protection and therapeutic action, can rapid osmotic after being sprayed onto on the crop in plant corpus, resistance of rainwater washing against.
No matter be glyoxalin, effective active composition B or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes problems such as dosage increasing, preventive effect reduction, lasting period shortening, is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency, alleviates the pollution to environment.Glyoxalin is different with the effective active composition B mechanism of action, mutually composite have good synergistic effect within the specific limits, and relevant composite about with Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, tetraconazole do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains glyoxalin and effective active composition B.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains glyoxalin and triazole class compounds, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～60%: 1～60%, described active component A is a glyoxalin, and active component B is selected from a kind of in Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, the tetraconazole.
The described glyoxalin bactericidal composition that contains is characterized in that: wherein the percentage by weight of glyoxalin and effective active composition B is 5～50%: 5～50%.
The described bactericidal composition that contains glyoxalin is characterized in that: the percentage by weight of glyoxalin and Triadimenol is 10～30%: 10～40%;
The percentage by weight of glyoxalin and propiconazole is 10～25%: 10～45%;
The percentage by weight of glyoxalin and bitertanol is 10～30%: 10～40%;
Glyoxalin is 10～35%: 10～35% with the percentage by weight of planting the bacterium azoles;
The percentage by weight of glyoxalin and metconazole is 10～35%: 10～35%;
The percentage by weight of glyoxalin and triticonazole is 10～35%: 10～35%;
The percentage by weight of glyoxalin and nitrile bacterium azoles is 10～35%: 10～35%;
The percentage by weight of glyoxalin and Flutriafol is 10～35%: 10～35%;
The percentage by weight of glyoxalin and triazolone is 10～30%: 10～40%;
The percentage by weight of glyoxalin and penconazole is 10～35%: 10～30%;
The percentage by weight of glyoxalin and tetraconazole is 10～35%: 10～30%.
The described bactericidal composition that contains glyoxalin, wherein the effective active component content accounts for 1～95% of gross weight, is preferably 20～80%.
The percentage by weight of A, two kinds of active components of B is 1～60%: 1～60%.Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze, emulsifier, solvent etc. in the preparation.
The described bactericidal composition that contains glyoxalin is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion.
Beneficial effect of the present invention: (1) present composition effective active composition glyoxalin and effective active composition B belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has enlarged fungicidal spectrum, and diseases such as crop powdery mildew, leaf spot, scab, rust, spot defoliation, bakanae disease, white rot are all had special efficacy.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Application Example one
Example 1 60% glyoxalin Triadimenol wetting powder
Glyoxalin 20%, Triadimenol 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, wetting and penetrating agent F 7%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 60% glyoxalin Triadimenol wetting powder.
Example 2 65% glyoxalin triadimenol water dispersion granules
Glyoxalin 15%, Triadimenol 50%, lignosulfonates 7%, spaonin powder 6%, bentonite add to 100%, the mixed 65% glyoxalin triadimenol water dispersion granules that gets.
Example 3 25% glyoxalin Triadimenol suspending agents
Glyoxalin 5%, Triadimenol 20%, aryl phenol polyoxyethylene succinate sulfonate 7%, tea are withered 5%, silicone oil 0.2%, methylcellulose 1.4%, glycerine 1.6%, deionized water add to 100%, mixed 25% glyoxalin Triadimenol suspending agent.
Example 4 35% glyoxalin Triadimenol suspension emulsions
Glyoxalin 28%, Triadimenol 7%, alkyl benzene sulfonate calcium salt 8%, silkworm excrement 6%, C
8～10Aliphatic alcohols 0.6%, gelatin 1.2%, agricultural newborn 500#6%, ethylene glycol 1.1%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 35% glyoxalin Triadimenol suspension emulsion.
Example 5 50% glyoxalin propiconazole suspending agents
Glyoxalin 10%, propiconazole 40%, polyoxyethylene carboxylate 6%, lauryl sodium sulfate 5%, C
8～10Aliphatic alcohols 0.1%, sodium phosphate trimer 1.2%, triethylene glycol 1.5%, deionized water add to 100%, the mixed 50% glyoxalin propiconazole suspending agent that gets.
Example 6 40% glyoxalin propiconazole suspension emulsions
Glyoxalin 20%, propiconazole 20%, polycarboxylate 8%, Nekal BX 6%, C
10～20Saturated fat acids 0.3%, xanthans 1.4%, 600# phosphate 6%, ethylene glycol 1.7%, water add to 100%, the mixed 40% glyoxalin propiconazole suspension emulsion that gets.
Example 7 45% glyoxalin propiconazole microemulsions
Glyoxalin 10%, propiconazole 35%, toluene 10%, ethyl acetate 15%, agricultural newborn 1600#6%, glycerin ether 1.2%, sldium lauryl sulfate 1.4%, glycerine 2.6%, sodium sorbate 1.3%, deionized water add to 100%, make 45% glyoxalin propiconazole microemulsion.
Example 8 42% glyoxalin propiconazole emusion in water
Glyoxalin 5%, propiconazole 37%, vegetable oil 13%, acetone 11%, farming breast 500
#5%, OP series 1.4%, diethylene glycol (DEG) 1.8%, ethylene glycol 0.5%, silicone oil 0.2%, deionized water supplies 100%, makes 42% glyoxalin propiconazole emusion in water.
Example 9 60% glyoxalin bitertanol wetting powders
Glyoxalin 15%, bitertanol 45%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, neopelex 6%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make 60% glyoxalin bitertanol wetting powder.
Example 10 50% glyoxalin bitertanol water dispersible granules
Glyoxalin 10%, bitertanol 40%, naphthalene sulfonic acid-formaldehyde condensation product 6%, lauryl sodium sulfate 5%, ammonium sulfate 1.8%, bentonite add to 100%, the mixed 50% glyoxalin bitertanol water dispersible granules that gets.
Example 11 20% glyoxalin bitertanol suspending agents
Glyoxalin 10%, bitertanol 10%, alkylphenol-polyethenoxy are phonetic 7%, soapberry powder 5%, C
10～20Saturated fat acids 0.2%, gum Arabic 1.2%, triethylene glycol 1.8%, deionized water add to 100%, the mixed 20% glyoxalin bitertanol suspending agent that gets.
Example 12 32% glyoxalin bitertanol suspension emulsions
Glyoxalin 24%, bitertanol 8%, aliphatic amine polyoxyethylene are phonetic 8%, spaonin powder 7%, PAA 1.2%, agricultural newborn 34#6%, propane diols 1.6%, silicone oil 0.4%, water add to 100%, through mixed 32% glyoxalin bitertanol suspension emulsion.
Example 13 60% glyoxalin kind bacterium azoles wetting powders
Glyoxalin 10%, kind bacterium azoles 50%, aryl phenol polyoxyethylene succinate sulfonate 6%, wetting and penetrating agent F 5%, precipitated calcium carbonate add to 100%, and mixture carries out comminution by gas stream, makes 60% glyoxalin kind bacterium azoles wetting powder.
Example 14 48% glyoxalin kind bacterium azoles water dispersible granules
Glyoxalin 12%, kind bacterium azoles 36%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 5%, urea 1.2%, bentonite add to 100%, the mixed 48% glyoxalin kind bacterium azoles water dispersible granules that gets.
Example 15 40% glyoxalin kind bacterium azole suspending agents
Glyoxalin 20%, kind bacterium azoles 20%, lignosulfonates 8%, Nekal BX 6%, C8～10 aliphatic alcohols 0.3%, polyvinylpyrrolidone 1.4%, ethylene glycol 1.6%, deionized water add to 100%, the mixed 40% glyoxalin kind bacterium azole suspending agent that gets.
Example 16 36% glyoxalin kind bacterium azoles suspension emulsions
Glyoxalin 26%, plant that bacterium azoles 10%, polycarboxylate 7%, tea are withered 6%, silicone compound 0.5%, methylcellulose 1.1%, tween series 6%, propane diols 1.3%, water add to 100%, the aforementioned formula material is mixed, promptly make 36% glyoxalin kind bacterium azoles suspension emulsion.
Example 17 55% glyoxalin metconazole wetting powders
Glyoxalin 42%, metconazole 13%, octylphenol polyethylene oxyethylene group ether sulfate 8%, neopelex 7%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 55% glyoxalin metconazole wetting powder.
Example 18 45% glyoxalin metconazole water dispersible granules
Glyoxalin 10%, metconazole 35%, naphthalene sulfonic acid-formaldehyde condensation product 6%, wetting and penetrating agent F 5%, bentonite add to 100%, the mixed 45% glyoxalin metconazole water dispersible granules that gets.
Example 19 48% glyoxalin metconazole suspending agents
Glyoxalin 24%, metconazole 24%, alkylphenol-polyethenoxy are phonetic 7%, soapberry powder 6%, silicone compound 0.4%, polyvinyl alcohol 1.5%, triethylene glycol 1.7%, deionized water add to 100%, mixed 48% glyoxalin metconazole suspending agent.
Example 20 34% glyoxalin metconazole suspension emulsions
Glyoxalin 10%, metconazole 24%, ester polyoxyethylene are phonetic 6%, spaonin powder 4%, silicone oil 0.2%, xanthans 1.5%, By series 6%, glycerine 1.9%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 34% glyoxalin metconazole suspension emulsion.
Example 21 55% glyoxalin triticonazole wetting powders
Glyoxalin 20%, triticonazole 35%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, wetting and penetrating agent F 6%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 55% glyoxalin triticonazole wetting powder.
Example 22 50% glyoxalin triticonazole water dispersible granules
Glyoxalin 35%, triticonazole 15%, alkyl benzene sulfonate calcium salt 8%, lauryl sodium sulfate 6%, aluminium chloride 1.8%, starch add to 100%, the mixed 50% glyoxalin triticonazole water dispersible granules that gets.
Example 23 40% glyoxalin triticonazole suspending agents
Glyoxalin 10%, triticonazole 30%, lignosulfonates 6%, neopelex 6%, C
8～10Aliphatic alcohols 0.4%, methylcellulose 1.5%, glycerine 1.7%, deionized water adds to 100%, the mixed 40% glyoxalin triticonazole suspending agent that gets.
Example 24 32% glyoxalin triticonazole suspension emulsions
Glyoxalin 16%, triticonazole 16%, alkylphenol-polyethenoxy are phonetic 8%, spaonin powder 6%, sodium phosphate trimer 1.2%, propane diols 1.5%, C
10～20Saturated fat acids 0.5%, agricultural newborn 1600#7%, water add to 100%, the mixed 32% glyoxalin triticonazole suspension emulsion that gets.
Example 25 52% glyoxalin nitrile bacterium azoles wetting powders
Glyoxalin 13%, nitrile bacterium azoles 39%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, wetting and penetrating agent F 6%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make 52% glyoxalin nitrile bacterium azoles wetting powder.
Example 26 56% glyoxalin nitrile bacterium azoles water dispersible granules
Glyoxalin 28%, nitrile bacterium azoles 28%, lignosulfonates 6%, soapberry powder 5%, bentonite add to 100%, the mixed 56% glyoxalin nitrile bacterium azoles water dispersible granules that gets.
Example 27 48% glyoxalin nitrile bacterium azole suspending agents
Glyoxalin 36%, nitrile bacterium azoles 12%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, Nekal BX 7%, C
10～20Saturated fat acids 0.3%, polyvinylpyrrolidone 1.6%, triethylene glycol 1.8%, deionized water add to 100%, the mixed 48% glyoxalin nitrile bacterium azole suspending agent that gets.
Example 28 30% glyoxalin nitrile bacterium azoles suspension emulsions
Glyoxalin 15%, nitrile bacterium azoles 15%, naphthalene sulfonic acid-formaldehyde condensation product 6%, tea are withered 4%, silicone oil 0.2%, PAA 1.4%, Nongru-700 #6%, ethylene glycol 1.5%, water add to 100%, the aforementioned formula material is mixed, promptly make 30% glyoxalin nitrile bacterium azoles suspension emulsion.
Example 29 50% glyoxalin Flutriafol wetting powders
Glyoxalin 10%, Flutriafol 40%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, wetting and penetrating agent F 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 50% glyoxalin Flutriafol wetting powder.
Example 30 56% glyoxalin Flutriafol water dispersible granules
Glyoxalin 14%, Flutriafol 42%, polyoxyethylene carboxylate 8%, neopelex 6%, sodium carbonate 1.3%, bentonite add to 100%, the mixed 56% glyoxalin Flutriafol water dispersible granules that gets.
Example 31 46% glyoxalin Flutriafol suspending agents
Glyoxalin 23%, Flutriafol 23%, alkyl benzene sulfonate calcium salt 6%, lauryl sodium sulfate 5%, C
8～10Aliphatic alcohols 0.6%, gum Arabic 1.2%, propane diols 1.2%, deionized water add to 100%, the mixed 46% glyoxalin Flutriafol suspending agent that gets.
Example 32 40% glyoxalin Flutriafol suspension emulsions
Glyoxalin 30%, Flutriafol 10%, alkylnaphthalene sulfonate 8%, spaonin powder 7%, silicone compound 0.5%, sodium phosphate trimer 1.4%, agricultural newborn 33#6%, triethylene glycol 1.7%, water add to 100%, the aforementioned formula material is mixed, promptly make 40% glyoxalin Flutriafol suspension emulsion.
Example 33 60% glyoxalin trazodone wettable powders
Glyoxalin 10%, triazolone 50%, octylphenol polyethylene oxyethylene group ether sulfate 7%, wetting and penetrating agent F 5%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 60% glyoxalin trazodone wettable powder.
Example 34 55% glyoxalin triazolone water dispersible granules
Glyoxalin 15%, triazolone 40%, polycarboxylate 6%, lauryl sodium sulfate 4%, urea 1.2%, bentonite add to 100%, the mixed 55% glyoxalin triazolone water dispersible granules that gets.
Example 35 20% glyoxalin triazolone suspending agents
Glyoxalin 10%, triazolone 10%, lignosulfonates 7%, soapberry powder 5%, C
8～10Aliphatic alcohols 0.3%, sodium alginate 1.7%, ethylene glycol 1.5%, deionized water add to 100%, the mixed 20% glyoxalin triazolone suspending agent that gets.
Example 36 33% glyoxalin triazolone suspension emulsions
Glyoxalin 25%, triazolone 8%, alkyl benzene sulfonate calcium salt 8%, silkworm excrement 7%, silicone oil 0.1%, xanthans 1.2%, tween series 5%, diethylene glycol (DEG) 1.3%, water add to 100%, the aforementioned formula material is mixed, promptly make 33% glyoxalin triazolone suspension emulsion.
Example 37 60% glyoxalin penconazole wetting powders
Glyoxalin 40%, penconazole 20%, alkylphenol-polyethenoxy are phonetic 6%, neopelex 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, makes 60% glyoxalin penconazole wetting powder.
Example 38 50% glyoxalin penconazole water dispersible granules
Glyoxalin 15%, penconazole 35%, aryl phenol polyoxyethylene succinate sulfonate 8%, Nekal BX 7%, sodium bicarbonate 1.9%, diatomite add to 100%, the mixed 50% glyoxalin penconazole water dispersible granules that gets.
Example 39 45% glyoxalin penconazole suspending agents
Glyoxalin 30%, penconazole 15%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 5%, silicone oil 0.4%, polyvinylpyrrolidone 1.7%, propane diols 1.8%, deionized water add to 100%, the mixed 45% glyoxalin penconazole suspending agent that gets.
Example 40 35% glyoxalin penconazole suspension emulsions
Glyoxalin 7%, penconazole 28%, polycarboxylate 6%, spaonin powder 5%, C
10～20Saturated fat acids 0.6%, gelatin 1.4%, agricultural newborn 500#6%, ethylene glycol 1.2%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 35% glyoxalin penconazole suspension emulsion.
Example 41 45% glyoxalin tetraconazole suspension emulsions
Glyoxalin 35%, tetraconazole 10%, aliphatic amine polyoxyethylene are phonetic 8%, tea is withered 6%, diethylene glycol (DEG) 1.6%, methylcellulose 1.8%, C
8～10Aliphatic alcohols 0.3%, sapn series 7%, water add to 100%, the mixed 45% glyoxalin tetraconazole suspension emulsion that gets.
Example 42 48% glyoxalin tetraconazole microemulsions
Glyoxalin 32%, tetraconazole 16%, N, dinethylformamide 17%, methyl alcohol 8%, agricultural newborn 36#9%, tributyl phosphate 2%, diethylene glycol (DEG) 1.8%, silicone oil 0.1%, deionized water supplies 100%, makes 48% glyoxalin tetraconazole microemulsion.
Example 43 45% glyoxalin tetraconazole aqueous emulsions
Glyoxalin 40%, tetraconazole 5%, acetone 16%, toluene 5%, 600# phosphate 8%, glycerine 1.6%, polyethylene glycol 1.1%, silicone 0.5%, deionized water supplies 100%, makes 45% glyoxalin tetraconazole aqueous emulsion.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
Glyoxalin and active component B (B be selected from Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, the tetraconazole a kind of) are composite to the crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the crop germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component glyoxalin and active component B (Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, tetraconazole) shared ratio in combination;
A is a glyoxalin;
B is a kind of in Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, the tetraconazole.
Implementation of an application example two: glyoxalin and Triadimenol are composite to the wheat powdery mildew Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of Triadimenol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 1 glyoxalin, Triadimenol and composite toxicity test analysis of results table thereof to wheat powdery mildew
As shown in Table 1, glyoxalin, Triadimenol are to the EC of wheat powdery mildew
50Be respectively 0.75mg/L and 1.58mg/L.Glyoxalin and Triadimenol proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and Triadimenol were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and Triadimenol percentage by weight are 1: 2 wherein, synergistic effect is the most obvious.
Implementation of an application example three: glyoxalin and propiconazole compound are to the sigatoka Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, propiconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 glyoxalin, propiconazole and composite toxicity test analysis of results table thereof to sigatoka
As shown in Table 2, glyoxalin, propiconazole are to the EC of sigatoka
50Be respectively 0.71mg/L and 3.07mg/L.Glyoxalin and propiconazole proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and propiconazole were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and propiconazole percentage by weight are 1: 4 wherein, synergistic effect is the most obvious.
Implementation of an application example four: glyoxalin and bitertanol are composite to the leaf spot of peanut Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of bitertanol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 3 glyoxalin, bitertanol and composite toxicity test analysis of results table thereof to leaf spot of peanut
As shown in Table 3, glyoxalin, bitertanol are to the EC of leaf spot of peanut
50Be respectively 0.82mg/L and 2.59mg/L.Glyoxalin and bitertanol proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and bitertanol were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and bitertanol percentage by weight are 1: 3 wherein, synergistic effect is the most obvious.
Implementation of an application example five: glyoxalin is composite to the bakanae disease of rice Toxicity Determination with kind bacterium azoles.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the kind former medicine of bacterium azoles and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 4 glyoxalin, kind bacterium azoles and composite toxicity test analysis of results table thereof to bakanae disease of rice
As shown in Table 4, glyoxalin, plant the EC of bacterium azoles to bakanae disease of rice
50Be respectively 0.79mg/L and 0.72mg/L.Glyoxalin and kind bacterium azoles proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, glyoxalin is described and plants the bacterium azoles and be mixed in the scope at 60: 1 to 1: 60 and all show synergistic effect, wherein when glyoxalin with plant bacterium azoles percentage by weight synergy ratio SR maximum when being 1: 1, synergistic effect is the most obvious.
Implementation of an application example six: glyoxalin and metconazole are composite to the stripe rust of wheat Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of metconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 5 glyoxalin, metconazole and composite toxicity test analysis of results table thereof to stripe rust of wheat
As shown in Table 5, glyoxalin, metconazole are to the EC of stripe rust of wheat
50Be respectively 0.73mg/L and 0.67mg/L.Glyoxalin and metconazole proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and metconazole were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and metconazole percentage by weight are 1: 1 wherein, synergistic effect is the most obvious.
Implementation of an application example seven: glyoxalin and triticonazole are composite to the wheat powdery mildew Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of triticonazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 6 glyoxalin, triticonazole and composite toxicity test analysis of results table thereof to wheat powdery mildew
As shown in Table 6, glyoxalin, triticonazole are to the EC of wheat powdery mildew
50Be respectively 0.78mg/L and 0.65mg/L.Glyoxalin and triticonazole proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and triticonazole were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and triticonazole percentage by weight are 1: 1 wherein, synergistic effect is the most obvious.
Implementation of an application example eight: glyoxalin and myclobutanil compositional are to the pear scab Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, bulk myclobutanil and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 7 glyoxalin, nitrile bacterium azoles and composite toxicity test analysis of results table thereof to pear scab
As shown in Table 7, glyoxalin, nitrile bacterium azoles are to the EC of pear scab
50Be respectively 0.69mg/L and 0.57mg/L.Glyoxalin and nitrile bacterium azoles proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and nitrile bacterium azoles were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and nitrile bacterium azoles percentage by weight are 1: 1 wherein, synergistic effect is the most obvious.
Implementation of an application example nine: glyoxalin and Flutriafol are composite to toxicity test in the stripe rust of wheat.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of Flutriafol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 8 glyoxalin, Flutriafol and composite toxicity test analysis of results table thereof to stripe rust of wheat
As shown in Table 8, glyoxalin, Flutriafol are to the EC of stripe rust of wheat
50Be respectively 0.86mg/L and 1.05mg/L.Glyoxalin and Flutriafol proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and Flutriafol were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and Flutriafol percentage by weight are 1: 1 wherein, synergistic effect is the most obvious.
Implementation of an application example ten: glyoxalin and triazolone are composite to the wheat powdery mildew Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of triazolone and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 9 glyoxalin, triazolone and composite toxicity test analysis of results table thereof to wheat powdery mildew
As shown in Table 9, glyoxalin, triazolone are to the EC of wheat powdery mildew
50Be respectively 0.83mg/L and 1.92mg/L.Glyoxalin and triazolone proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and triazolone were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and triazolone percentage by weight are 1: 2 wherein, synergistic effect is the most obvious.
Implementation of an application example 11: glyoxalin and penconazole are composite to the fruit white rot of grape Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of penconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 glyoxalin, penconazole and composite toxicity test analysis of results table thereof to fruit white rot of grape
As shown in Table 10, glyoxalin, penconazole are to the EC of fruit white rot of grape
50Be respectively 0.85mg/L and 0.43mg/L.Glyoxalin and penconazole proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and penconazole were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and penconazole percentage by weight are 2: 1 wherein, synergistic effect is the most obvious.
Implementation of an application example 12: glyoxalin and tetraconazole are composite to the alternaria leaf spot of apple Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining glyoxalin, the former medicine of tetraconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 11 glyoxalin, tetraconazole and composite toxicity test analysis of results table thereof to alternaria leaf spot of apple
As shown in Table 11, glyoxalin, tetraconazole are to the EC of alternaria leaf spot of apple
50Be respectively 0.88mg/L and 0.52mg/L.Glyoxalin and tetraconazole proportioning were at 60: 1 to 1: 60 o'clock, synergy ratio SR is all greater than 1.5, illustrating that glyoxalin and tetraconazole were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, synergy ratio SR maximum when glyoxalin and tetraconazole percentage by weight are 2: 1 wherein, synergistic effect is the most obvious.
Application Example 13 glyoxalins and Triadimenol and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Fengxiang County, Baoji, Shaanxi province city, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 15% Triadimenol wetting powder (commercial).
The investigation wheat powdery mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 12 glyoxalin, Triadimenol and the composite control wheat powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 12, can effectively prevent and treat wheat powdery mildew after glyoxalin and Triadimenol are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 14 glyoxalins and propiconazole and the composite sigatoka test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at Zhanjiang City, Guangdong Province Xuwen County, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 25% propiconazole emulsifiable concentrate (commercial).
The preceding investigation of medicine sigatoka disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 13 glyoxalin, propiconazole and the composite sigatoka test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 13, can effectively prevent and treat sigatoka behind glyoxalin and the propiconazole compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 15 glyoxalins and bitertanol and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Daming County, Handan City, Hebei province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 25% bitertanol wetting powder (commercial).
The investigation leaf spot of peanut state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 14 glyoxalin, bitertanol and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 14, can effectively prevent and treat leaf spot of peanut after glyoxalin and bitertanol are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 16 glyoxalins and the kind bacterium azoles and the composite bakanae disease of rice test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in suburb, Guangxi province Liuzhou City, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 10% kind of bacterium azole suspending agent (commercial).
The preceding investigation of medicine bakanae disease of rice disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 15 glyoxalin, kind bacterium azoles and the composite bakanae disease of rice test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 15, can effectively prevent and treat bakanae disease of rice after glyoxalin and kind bacterium azoles are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 17 glyoxalins and metconazole and the composite stripe rust of wheat test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Fuyang City Linquan County, Anhui Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 60 grams per liter metconazole aqueous emulsions (commercial).
The investigation stripe rust of wheat state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 16 glyoxalin, metconazole and the composite stripe rust of wheat test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 16, can effectively prevent and treat stripe rust of wheat after glyoxalin and metconazole are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 18 glyoxalins and triticonazole and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Mengcheng County, city, Haozhou, Anhui Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 25 grams per liter triticonazole suspension seed-coating agents (commercial).
The preceding investigation of medicine wheat powdery mildew disease index, in the their early stage dispenser, dispenser for the second time after 7 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 17 glyoxalin, the composite control wheat powdery mildew of the triticonazole test of pesticide effectiveness
As can be seen from Table 17, can effectively prevent and treat wheat powdery mildew after glyoxalin and triticonazole are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 19 glyoxalins and nitrile bacterium azoles and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 40% nitrile bacterium azoles wetting powder (commercial).
The investigation pear scab state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 18 glyoxalin, nitrile bacterium azoles and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 18, can effectively prevent and treat pear scab behind glyoxalin and the myclobutanil compositional, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 20 glyoxalins and Flutriafol and the composite stripe rust of wheat test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at Kaifeng, Henan Province Lankao County, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 12.5% Flutriafol suspending agent (commercial).
The investigation stripe rust of wheat state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 19 glyoxalin, Flutriafol and the composite stripe rust of wheat test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 19, can effectively prevent and treat stripe rust of wheat after glyoxalin and Flutriafol are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 21 glyoxalins and triazolone and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Jingyang County, Xianyang, Shanxi province city, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 25% trazodone wettable powder (commercial).
The investigation wheat powdery mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 20 glyoxalin, triazolone and the composite control wheat powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 20, can effectively prevent and treat wheat powdery mildew after glyoxalin and triazolone are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 20 diimine azoles and penconazole and the composite fruit white rot of grape test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at Baoding, Hebei province Mancheng County, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 10% penconazole missible oil (commercial).
The investigation fruit white rot of grape state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 21 glyoxalin, penconazole and the composite fruit white rot of grape test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 21, can effectively prevent and treat fruit white rot of grape after glyoxalin and penconazole are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 23 glyoxalins and tetraconazole and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dengcheng County, Shaanxi Province, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 5% glyoxalin wetting powder (commercial), 4% tetraconazole aqueous emulsion (commercial).
The investigation alternaria leaf spot of apple state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 22 glyoxalin, tetraconazole and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 22, can effectively prevent and treat alternaria leaf spot of apple after glyoxalin and tetraconazole are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Claims (5)
1. bactericidal composition that contains glyoxalin and triazole class compounds, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～60%: 1～60%, described active component A is a glyoxalin, and active component B is selected from a kind of in Triadimenol, propiconazole, bitertanol, kind bacterium azoles, metconazole, triticonazole, nitrile bacterium azoles, Flutriafol, triazolone, penconazole, the tetraconazole.
2. the glyoxalin bactericidal composition that contains according to claim 1 is characterized in that: wherein the percentage by weight of glyoxalin and effective active composition B is 5～50%: 5～50%.
3. the bactericidal composition that contains glyoxalin according to claim 2 is characterized in that: the percentage by weight of glyoxalin and Triadimenol is 10～30%: 10～40%;
The percentage by weight of glyoxalin and propiconazole is 10～25%: 10～45%;
The percentage by weight of glyoxalin and bitertanol is 10～30%: 10～40%;
Glyoxalin is 10～35%: 10～35% with the percentage by weight of planting the bacterium azoles;
The percentage by weight of glyoxalin and metconazole is 10～35%: 10～35%;
The percentage by weight of glyoxalin and triticonazole is 10～35%: 10～35%;
The percentage by weight of glyoxalin and nitrile bacterium azoles is 10～35%: 10～35%;
The percentage by weight of glyoxalin and Flutriafol is 10～35%: 10～35%;
The percentage by weight of glyoxalin and triazolone is 10～30%: 10～40%;
The percentage by weight of glyoxalin and penconazole is 10～35%: 10～30%;
The percentage by weight of glyoxalin and tetraconazole is 10～35%: 10～30%;
4. the bactericidal composition that contains glyoxalin according to claim 1 is characterized in that: the formulation of microbicide compositions is selected from: wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion.
5. the bactericidal composition that contains glyoxalin according to claim 1 is used to prevent and treat disease common on fruit tree, vegetables and the cereal crop.
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Citations (4)
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| EP0306413A1 (en) * | 1987-09-03 | 1989-03-08 | Hokko Chemical Industry Co., Ltd | A synergistic fungicidal composition of agricultural and horticultural utilities, and methods for controlling fungal diseases on plants |
| CN101416631A (en) * | 2008-09-24 | 2009-04-29 | 中国农业科学院植物保护研究所 | Functional slow-release suspension seed-coating agents |
| CN101779676A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing epoxiconazole |
| CN102113489A (en) * | 2010-12-30 | 2011-07-06 | 陕西美邦农药有限公司 | Bactericidal composition containing metconazole |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0306413A1 (en) * | 1987-09-03 | 1989-03-08 | Hokko Chemical Industry Co., Ltd | A synergistic fungicidal composition of agricultural and horticultural utilities, and methods for controlling fungal diseases on plants |
| CN101416631A (en) * | 2008-09-24 | 2009-04-29 | 中国农业科学院植物保护研究所 | Functional slow-release suspension seed-coating agents |
| CN101779676A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing epoxiconazole |
| CN102113489A (en) * | 2010-12-30 | 2011-07-06 | 陕西美邦农药有限公司 | Bactericidal composition containing metconazole |
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Address after: 715500 Weinan City, Shaanxi province Pucheng County agricultural base industrial park Applicant after: Shaanxi Meibang Pesticide Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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