CN102227207B - Hair cosmetic - Google Patents
Hair cosmetic Download PDFInfo
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- CN102227207B CN102227207B CN2009801481913A CN200980148191A CN102227207B CN 102227207 B CN102227207 B CN 102227207B CN 2009801481913 A CN2009801481913 A CN 2009801481913A CN 200980148191 A CN200980148191 A CN 200980148191A CN 102227207 B CN102227207 B CN 102227207B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Abstract
The present invention relates to a hair cosmetic characterized by comprising 0.1 to 2 mass% of an acrylic polymer (A), 0.1 to 3 mass% of a nonionic surfactant having an HLB value of 14 to 18 (B), 0.5 to 5 mass% of a cationic surfactant (C), and 0.5 to 10 mass% of a linear saturated aliphatic alcohol (D), wherein the mass ratio represented by the formula (A)/(B) is 0.05 to 18.00. An acrylic polymer (A) comprising 70 to 95 mol% of a monomer unit represented by general formula (1) and 5 to 30 mol% of a monomer unit represented by general formula (2) [in the formulae, R1 represents a hydrogen atom or a methyl group; R2 represents a hydrogen atom or a group -CH2OH; A represents an oxygen atom or -NH-; R3 represents a hydrogen atom or a methyl group; and M represents a hydrogen atom, an alkali metal atom, an ammonium or an amine].
Description
Technical field
The present invention relates to give the hair cosmetics of hair moist feeling smooth feeling.
Background technology
Tackle a kind of of hair cosmetics (patent documentation 1: the Japan Patent spy opens the 2007-137830 communique) who develops in damaged hair and can enumerate conditioning polymer.This polymer not only has the effect of maintenance hair, but also demonstrates the effect of giving hair gloss and smooth feeling.Yet, indispensable cationic composition in this anionic property polymer and the present hair conditioner, owing to formed complex, viscosity degradation, so the extension when having coating is poor, the problem points of storage stability variation.Therefore, needs are a kind of when keeping hair maintenance effect (the moist feeling smooth feeling of hair), again the technology that can address the above problem.
Patent documentation 1: the Japan Patent spy opens the 2007-137830 communique
Patent documentation 2: the Japan Patent spy opens the 2007-161986 communique
Summary of the invention
The present invention In view of the foregoing, it is a kind of when keeping hair maintenance effect (the moist feeling smooth feeling of hair) that its purpose is to provide, even also with acrylic acid series polymeric compounds and cationic composition, also can have the hair cosmetics of extension good when applying and good storage stability.
The inventor is in order to reach above-mentioned purpose, through concentrating on studies discovery, by containing specific (A) acrylic acid series polymeric compounds and (C) in the hair cosmetics of cationic surfactant, in company with (A), (B) composition, (B) HLB that remixes specified quantitative respectively is 14～18 nonionic surfactant and (D) straight chain saturated fatty alcohol, making (A) composition shown in (A)/(B) and (B) mass ratio of composition is 0.05～18.00, can provide a kind of when keeping hair maintenance effect (the moist feeling smooth feeling of hair), even also with acrylic acid series polymeric compounds and cationic composition, also can have good reagent extension and the hair cosmetics of good storage stability, finally finish the present invention.
Therefore, the invention provides following hair cosmetics.
[1]. a kind of hair cosmetics, it is characterized in that, contain following (A) acrylic acid series polymeric compounds 0.1～2 quality %, (B) HLB and be 14～18 nonionic surfactant 0.1～3 quality %, (C) cationic surfactant 0.5～5 quality % and (D) straight chain saturated fatty alcohol 0.5～10 quality %, (A)/(B) (A) composition shown in is 0.05～18.00 with (B) mass ratio of composition.
(A) for containing 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the following general formula (1) and the following general formula (2) as the acrylic acid series polymeric compounds that constitutes the unit.
(in the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-.)
(in the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, alkali metal atom, ammonium or amine.)
[2]. 12～150) or polyoxyethylene hardened castor oil (the average addition molal quantity of oxirane: 60～100) according to [1] described hair cosmetics, (B) composition is mono fatty acid macrogol ester (the average addition molal quantity of oxirane:.
The effect of invention
According to the present invention, can provide a kind of when keeping hair maintenance effect (the moist feeling smooth feeling of hair), even also with acrylic acid series polymeric compounds and cationic composition, also can have good reagent extension and the hair cosmetics of good storage stability.
The specific embodiment
Below, the present invention is described in detail.
Hair cosmetics of the present invention is 14～18 nonionic surfactant 0.1～3 quality %, (C) cationic surfactant 0.5～5 quality % and (D) straight chain saturated fatty alcohol 0.5～10 quality % for containing following (A) acrylic acid series polymeric compounds 0.1～2 quality %, (B) HLB, and (A)/(B) (A) composition shown in and (B) mass ratio of composition are 0.05～18.00 hair cosmetics.
(A) acrylic acid series polymeric compounds
Be a kind of by containing 70～95 moles of % of the monomeric unit shown in the following general formula (1), with the acrylic acid series polymeric compounds that 5～30 moles of % of monomeric unit shown in the following general formula (2) constitute as the copolymer that constitutes the unit, a kind of or appropriate combination use more than 2 kinds separately.
(in the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-.)
(in the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, alkali metal atom, ammonium or amine.)
Alkali metal atom can be enumerated sodium atom, potassium atom, and amine can be enumerated monoethanolamine, diethanolamine, triethanolamine etc., and in addition, when M was alkali metal atom, ammonium or amine ,-COOM formed salt.
As the monomeric unit shown in the general formula (1), R
1Be preferably hydrogen atom, R
2Be preferably hydrogen atom, A is preferably-NH-, as the monomeric unit shown in the following general formula (2), R
3Preferred hydrogen atom, the preferred hydrogen atom of M and/or sodium atom.
Ratio about the monomeric unit shown in the general formula (1), (all among 100 moles of % of monomeric unit) are 70～95 moles of % in acrylic acid series polymeric compounds, preferred 75～90 moles of %, ratio as for the monomeric unit shown in the general formula (2), (all among 100 moles of % of monomeric unit) are 5～30 moles of % in acrylic acid series polymeric compounds, preferred 10～25 moles of %.When the ratio of the monomeric unit shown in the general formula (1) surpassed 95 moles of %, hair smoothness such as finger mediation sense variation can descend, and during 70 moles of % of less than, and not only hair smoothness such as finger mediation sense variation can descend, and storage stability also can variation.
Acrylic acid series polymeric compounds can also contain the monomeric unit except the monomeric unit shown in general formula (1) or (2) in the scope of not damaging effect of the present invention.As other monomeric unit, for example can enumerate, be equivalent to outside the monomeric unit shown in general formula (1) or (2) nonionic monomers, ampholytic monomer, semi-polarity monomer, cationic monomer, contain the monomeric unit of polysiloxane group monomer.The ratio of the monomeric unit except the monomeric unit shown in general formula (1) or (2) preferably accounts for 0～25 mole of % in acrylic acid series polymeric compounds.Acrylic acid series polymeric compounds of the present invention can be random copolymer or block copolymer, is preferably with the monomeric unit shown in general formula (1) and (2) as the acrylic acid series polymeric compounds that copolymer was constituted that constitutes the unit as acrylic acid series polymeric compounds of the present invention.
As nonionic monomers, can enumerate for example alcohol and (methyl) acrylic acid ester of carbon number 1～22, the alkylamine of carbon number 1～22 and (methyl) acrylic acid amide, ethylene glycol, 1, ammediol etc. and (methyl) acrylic acid monoesters, the ester that the hydroxyl of further this monoesters forms by etherificates such as methanol or ethanol, (methyl) acryloyl morpholine etc.; As ampholytic monomer, can enumerate (methyl) acrylate that for example contains the Radix Betae base, (methyl) acrylamide that contains the Radix Betae base etc.; As the semi-polarity monomer, can enumerate (methyl) acrylate that for example contains azyloxy, (methyl) acrylamide that contains azyloxy etc.; As cationic monomer, can enumerate (methyl) acrylate that for example contains quaternary ammonium group, (methyl) acrylamide that contains quaternary ammonium group etc.
Contain the monomer of polysiloxane group for having polysiloxane structure, have the chemical compound of the structure that can be connected by covalent bond with acrylic acid series polymeric compounds.Usually and between the silicone oil of usefulness has high affinity in this kind formation unit and the cosmetic combination, can think that it has connects the effect that in the acrylic acid series polymeric compounds other constitute unit and silicone oil, plays a part raising silicone oil to the absorption affinity of epidermis or hair, especially damaged hair etc.
In addition, the IR that the ratio of each monomeric unit in the acrylic acid series polymeric compounds can be passed through carbonyl, amido link, polysiloxane structure or various functional groups etc. absorbs, or the methyl of polydimethylsiloxane or amido link position and with their adjacent methyl, methylene etc.
1H-NMR, or they
13C-NMR etc. measure.
The weight average molecular weight of acrylic acid series polymeric compounds is preferably 3,000～100, and 000.When less than 3,000 o'clock, the situation that exists moist feeling, smooth feeling and the conditioning effect of hair to die down in addition, surpassed at 100,000 o'clock, had the situation of the easness deterioration that reagent extends again.For the moist feeling that improves hair, reagent extend the smooth feeling of easness and hair, more preferably 10,000～30,000, more preferably 10,000～20,000, further preferred 12,000～17,000.
Weight average molecular weight can adopt gel permeation chromatography to measure, the concrete use, the device: East ソ SC8010 processed of one Co., Ltd., SD8022, RI8020, CO8011, PS8010, post: the Wakopak of Wako Pure Chemical Industries, Ltd. (Wakobeads G-50), launch solvent: water/methanol/acetic acid/sodium acetate=6/4/0.3/0.41 (Capacity Ratio) is that standard substance is tried to achieve with the Polyethylene Glycol.
The molecular-weight adjusting of acrylic acid series polymeric compounds can be undertaken by the degree of polymerization of for example controlling polymer.In addition, also can control molecular weight and viscosity by the addition of cross-linking agent such as increase and decrease polyfunctional acrylic ester.But, even exist like this cross-linking agent add excessive little by little, molecular weight and viscosity also can increase etc. suddenly, in the one side of commercial production control difficulty.Therefore, preferably do not contain cross-linking agent.
The method that acrylic acid series polymeric compounds can be opened records such as 2007-161986 communique according to the Japan Patent spy obtains.For example, that can mix that each constitutes the unit comes source monomer or its presoma, makes it copolymerization by methods such as polymerisation in solution, suspension polymerisation, emulsion polymerisations and obtains.In addition, counter ion counterionsl gegenions in the general formula (2) can be replaced by the thing outside the hydrion its part or all by neutralization reaction before polymerization, are supplied to polymerization again, also can after polymerization or other reactions, be replaced by the thing outside the hydrion its part or all by neutralization reaction.These can carry out suitable selection by synthetic easness.Polyreaction is preferably carried out in hydrophilic solvents such as ethanol, as polymerization initiator, can use dimethyl-2,2 '-azo two known polymerization initiators such as (2 Methylpropionic acid esters).In addition, mixing each monomer makes it reach specific mole with respect to whole monomer total amounts (100 moles of %).The ratio that constitutes the unit that is constituted by each monomer in the copolymer of the present invention during with copolymerization the combined amount of each monomer identical.
Polyreaction is preferably carried out in hydrophilic solvent.As hydrophilic solvent, can enumerate ketone series solvents such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), pure series solvents such as methanol, ethanol, normal propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutanol, sec-butyl alcohol, water etc.They may be used alone, used in two or more.Wherein, preferably use pure series solvent.
As polymerization initiator, be not particularly limited, can use 2,2 '-azodiisobutyronitrile, 2,2 '-azo two (2, the 4-methyl pentane nitrile), 2,2 '-azo two (4-methoxyl group-2, the 4-methyl pentane nitrile), dimethyl-2,2 '-azo dibutyrate, 2,2 '-azo two (2-methylbutyronitrile), 1,1 '-azo two (1-cyclohexene formonitrile HCN), 2,2 '-azo two (2-methyl-N-(2-hydroxyethyl)-propionic acid amide .), 2,2 '-azo two (2-amidine propane) dihydrochloride, dimethyl-2,2 '-azo two azo-compounds such as (2 Methylpropionic acid esters), benzoyl peroxide, cumyl peroxide, di-tert-butyl peroxide, peroxide such as lauroyl peroxide, persulfate or its redox system etc.Polymerization initiator preferably uses in 0.01～5 quality % scope with respect to whole monomers.
Polyreaction can be under inert gas atmosphere such as nitrogen or argon for example, and preferred 30～120 ℃, more preferably to carry out under 40～100 ℃, the time is generally 1～30 hour.After polymerization finishes, the copolymer that generates is removed, added suitable method such as poor solvent by the solvent distillation and from reactant liquor, emanate and get final product.This copolymer can be directly or further refining after, the production of the material that is used for for example making up.Making with extra care can be as required, and suitable methods such as combination precipitates again, solvent is cleaned, membrance separation are carried out.
The amount of (A) composition is 0.1～2 quality % in the hair cosmetics, preferred 0.2～1.5 quality %.During less than 0.1 quality %, be difficult to the effect of moist feeling, smooth feeling and the reagent extension easness of hair, and after surpassing 2 quality %, the smooth feeling of hair can variation.
(B) HLB is 14～18 nonionic surfactant
The HLB of nonionic surfactant of the present invention is 14～18, preferably uses 15～18 surfactant.During the situation of the nonionic surfactant of HLB less than 14, the smooth feeling variation of hair can't be brought into play the effect that improves storage stability.In addition, the HLB value is the value that expression constitutes the strength of force balance of the hydrophilic group of surfactant and hydrophobic group, calculates according to following river following formula.In addition, in the present invention, HLB is the value of 1 of arithmetic point of rounding up.
HLB value=7+11.7log (M
W/ M
O)
Mw: the molecular weight of surfactant hydrophilic segment
Mo: the molecular weight of surfactant oleophilic moiety
Above-mentioned HLB and during with the situation of two or more nonionic surfactant, represent weighted mean.Weighted mean is in 14～18 scope the time, and the HLB of each nonionic surfactant can not be 14～18, is 14～18 nonionic surfactant but preferably contain a kind of HLB.In addition, weighted average HLB value refers to, for whole nonionic surfactant, calculate the product of the operating weight of the HLB value of nonionic surfactant and this nonionic surfactant, again with total service property (quality) of whole nonionic surfactant value divided by the summation of this value of calculating.
It is 14～18 nonionic surfactant as HLB, can enumerate the polyoxyethylene fatty acid glyceride, polyglyceryl fatty acid ester, polyoxyethylene sorbitan fatty acid ester, the polyoxyethylene sorbitol sorbitan fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hardened castor oil (the average addition molal quantity of oxirane: 60～100), glycol fatty acid ester, 12～150) Polyethylene Glycol mono fatty acid ester (the average addition molal quantity of oxirane: cithrol such as, alkyl glycerylether, polyoxyethylene alkyl ether, polyoxyethylene alkyl ether fatty acid ester etc.These can be used alone or appropriate combination is two or more uses.
Particularly, HLB14 can enumerate, polyethyleneglycol dodecyl acid esters (12EO), polyethylene glycol mono stearate (20EO), four oleic acid POE (60) sorbitol, POE (60) hardened castor oil, single myristic acid ten glyceride, POE (25) stearyl ether etc.As HLB15, polyglycol distearate (30EO), POE (80) hardened castor oil, POE (100) hardened castor oil, POE (20) sorbitan list isostearate, POE (20) sorbitan monooleate, POE (25) isocetyl ether, POE (20) lauryl ether, POE (30) octadecyl ether, polyoxyethylene iso stearic acid of glycerine ester (30EO) etc.As HLB16, can enumerate polyethylene glycol mono stearate (40EO), the oily ether of POE (15), POE (40) octadecyl ether, polyoxyethylene glycerol isostearic acid (50EO) etc.HLB18 can enumerate polyethylene glycol mono stearate (150EO) etc.Wherein, from the smoothness of more effectively bringing into play hair, the point of storage stability, the above nonionic surfactant of preferred HLB15, the more preferably polyethylene glycol mono stearate of HLB18 (150EO).In addition, EO is the omission of oxirane, and POE is polyoxyethylated omission.
The content of (B) composition is 0.1～3 quality % in the hair cosmetics, preferred 0.3～1 quality %.During less than 0.1 quality %, the storage stability variation, when surpassing 3 quality %, the smoothness variation of the wettability of hair, hair is not easy to be dissolved in other raw materials, makes to cooperate the difficulty that becomes.
In addition, (A)/(B) (A) composition shown in is 0.05～18.00 with (B) mass ratio of composition, preferred 0.60～5.00.During this mass ratio less than 0.05, the smoothness variation of hair surpasses at 18.00 o'clock, and the extension easness of storage stability, reagent, the smoothness of hair are produced bad influence.In addition, above-mentioned ratio is the value of the 3rd of arithmetic point of rounding up.
(C) cationic surfactant
Cationic surfactant can be enumerated; aliphatic amine salt such as mountain Yu amido propyl dimethylamine and fatty acid amide amine salt such as quaternary ammonium salt, stearic acid dimethylamino-propyl amide thereof, alkyl three aklylene glycol ammonium salts, Acylguanidine derivative, list-aminoacid cation surfacants such as N-long acyl basic amino acid lower alkyl esters salt; alkylbenzene is pricked ammonium salt; the alkyl pyridine quaternary amine; imidazoline salts etc. can independent suitably collocation use more than a kind or 2 kinds.Wherein preferred aliphat amine quaternary ammonium salt, the more preferably quaternary ammonium salt of carbon number 18～22.Mountain Yu base trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride (ア one カ one De T-800: ラ イ オ Application (strain)) etc. have been enumerated particularly.
The content of (C) composition is 0.5～5 quality % in the hair cosmetics, preferred 1～3 quality %.When containing quantity not sufficient 0.5 quality %, the extension easness of reagent, the smoothness variation of hair when surpassing 5 quality %, have bad influence to aridity, the storage stability of hair.
(D) straight chain representative examples of saturated aliphatic alcohol
Straight chain representative examples of saturated aliphatic alcohol can use alkyl to be the alcohol of carbon number 12～24, and preferred carbon number is 16～22.Cetyl alcohol, stearyl alcohol, hexadeca-octadecyl alcohol, behenyl alcohol etc. are arranged particularly for example, wherein preferred cetyl alcohol, stearyl alcohol.
The content of (D) composition is 0.5～10 quality % in the hair cosmetics, preferred 2～6 quality %.When containing quantity not sufficient 0.5 quality %, the extension easness of reagent, the smoothness variation of hair when surpassing 10 quality %, have bad influence to smoothness, the storage stability of hair.
Hair cosmetics of the present invention in the scope of not damaging effect of the present invention, can also mix general various adding ingredients in the hair cosmetics according to expectation except mentioned component.These adding ingredients can be enumerated, silicone compounds such as dimethyl polysiloxane or amino modified silicone for example, alkyl sulfate salt, anionic surfactants such as polyoxyethylene alkyl ether sodium sulfate, the coco-nut oil fatty acid amido propyl betaine, betanins such as lauryl dimethyl aminoacetic acid betanin are amphoteric surfactant, the hydrogenation soybean phospholipid, salt dialkylaminobenzoic acid diamino ethyl glycine, amphoteric surfactantes such as lauryl alanine sodium, rice germ oil, Testa oryzae oil, Camellia oil, almond oil, hydrogenation Jojoba wet goods oils and fats wax class, myristic acid, Palmic acid, stearic acid, behenic acid, oleic acid, pantothenic acid, gallic acid-3, the 5-bioside, gallic acid-3, the 4-bioside, gallic acid methyl-3, the 5-bioside, ethylenediaminetetraacetic acid, hyaluronic acid, aminoacid, lactic acid, malic acid, the 2-pyrrolidone-5-carboxylic acid, organic acid and salt thereof such as glycolic, ethylene glycol, propylene glycol, glycerol, Polyethylene Glycol, polyhydric alcohol such as dipropylene glycol, erithritol, sugar alcohols such as Sorbitol, liquid paraffin, hydrocarbon such as squalane, ester oil, remove the anionic property polymer of (A) composition, Poise C-80M, cation property copolymers such as cationization guar gum, polyvinylpyrrolidone, non-ionic polyalcohols such as PVP/VA (vinylpyrrolidone/vinylacetate) copolymer, amphiphilic polymers, cellulosic cpds such as hydroxy ethyl cellulose, crude drug, plant extract, the range protein hydrolysate, vitamin, antibacterial, UV absorbent, antioxidant, coloring agent, the pH buffer agent, spice, solvent (ethanol etc.), fine-particle powder etc.These adding ingredients can be independent a kind or suitable more than 2 kinds collocation use, in addition, can also cooperate in the suitable stage when preparation hair cosmetics compositions.
Hair cosmetics of the present invention can adopt the well-established law preparation to get final product according to above-mentioned necessary, necessary mix any composition, water remainder.Hair cosmetics of the present invention has shampoo, shampoo, hair conditioner, nursing agent, modeling agent etc. for example.After being coated with, shampoo, hair conditioner, nursing agent branch wash type, leave off.Wherein preferred shampoo, hair conditioner, nursing agent are especially preferably washed type off.
Embodiment
Below, by embodiment and comparative example, more be described in detail the present invention, but the present invention is not limited by following embodiment.In addition, do not specify in the following example, " % " expression quality % of composition, ratio is represented mass ratio, the amount of each composition in the table is the amount that converts through purity.
[formulation example 1]
The 100 mass parts ethanol of in the reactor that possesses reflux cooler, Dropping funnel, thermometer, nitrogen ingress pipe and agitating device, packing into, the monomer mixed solution of packing in Dropping funnel and being made of 2-hydroxyethyl acrylamide 88.6 mass parts, acrylic acid 11.4 mass parts and ethanol 80 mass parts is heated 80 ℃ after being replaced as nitrogen in the reactor.The dimethyl-2 of 1 mass parts of in reactor, packing into, 2 '-azo two (2 Methylpropionic acid ester) (V-601: and the pure pharmaceutical worker's industry of light (strain) system) after, last 2 hours and drip monomer mixed solution.After drip finishing, make it to react 6 hours after cooling, use sodium hydroxide to neutralize, obtain acrylic acid series polymeric compounds (A-1).2-hydroxyethyl acrylamide/sodium acrylate=83 moles of %/17 mole %
[formulation example 2]
The 100 mass parts ethanol of in the reactor that possesses reflux cooler, Dropping funnel, thermometer, nitrogen ingress pipe and agitating device, packing into, in Dropping funnel, pack into by 2, the monomer mixed solution that 3-dihydroxypropyl acrylamide 82.5 mass parts, acrylic acid 17.5 mass parts and ethanol 80 mass parts constitute is heated 80 ℃ after being replaced as nitrogen in the reactor.The dimethyl-2 of 1 mass parts of in reactor, packing into, 2 '-azo two (2 Methylpropionic acid ester) (V-601: and the pure pharmaceutical worker's industry of light (strain) system) after, last 2 hours and drip monomer mixed solution.After drip finishing, make it to react 6 hours after cooling, add the sodium hydroxide that is equivalent to acrylic acid mol ratio half amount and neutralize, obtain acrylic acid series polymeric compounds (A-2).2,3-dihydroxypropyl acrylamide/acrylic acid (sodium)=70 mole %/30 moles of %
[formulation example 3]
The 100 mass parts ethanol of in the reactor that possesses reflux cooler, Dropping funnel, thermometer, nitrogen ingress pipe and agitating device, packing into, in Dropping funnel, pack into by 2, the monomer mixed solution that 3-dihydroxypropyl acrylamide 97.5 mass parts, acrylic acid 2.5 mass parts and ethanol 80 mass parts constitute is heated 80 ℃ after being replaced as nitrogen in the reactor.The dimethyl-2 of 1 mass parts of in reactor, packing into, 2 '-azo two (2 Methylpropionic acid ester) (V-601: and the pure pharmaceutical worker's industry of light (strain) system) after, last 2 hours and drip monomer mixed solution.After drip finishing, make it to react 6 hours after cooling, add the sodium hydroxide that is equivalent to acrylic acid mol ratio half amount and neutralize, obtain acrylic acid series polymeric compounds (A-3).2,3-dihydroxypropyl acrylamide/acrylic acid (sodium)=95 mole %/5 moles of %
[formulation example 4]
Adjust combined amount according to the formation unit of following table 1, adopt the method identical with above-mentioned formulation example 1, acquisition acrylic acid series polymeric compounds (A-4).
[formulation example 5]
Adjust combined amount according to the formation unit of following table 1, adopt the method identical with above-mentioned formulation example 1, acquisition acrylic acid series polymeric compounds (A-5).
[relatively formulation example 6]
Adjust combined amount according to the formation unit of following table 1, adopt the method identical with above-mentioned formulation example 1, acquisition acrylic acid series polymeric compounds (A '-6).
Ratio (mol ratio), the weight average molecular weight of the general formula (1) of aforesaid propylene acid polymer (A-1～A-5, A '-6) or functional group, general formula (1) or (2) monomeric unit of (2) see Table 1.In addition, weight average molecular weight can be used, the device: East ソ SC8010 processed of one Co., Ltd., SD8022, RI8020, CO8011, PS8010, post: the Wakopak of Wako Pure Chemical Industries, Ltd. (Wakobeads G-50), launch solvent: water/methanol/acetic acid/sodium acetate=6/4/0.3/0.41 (Capacity Ratio) is that standard substance is tried to achieve with the Polyethylene Glycol.
[table 1]
[embodiment 1～29, comparative example 1～12]
[compound method]
According to the composition shown in table 2～9, wash type hair conditioner off according to following method preparation.Particularly, dissolving mixes the oiliness composition, adds polyalcohols (polyhydric alcohol or sugar alcohol) and mixes, and homogenization makes it to form the gel liquid crystal.Add (A) acrylic acid series polymeric compounds in the gel liquid crystal, further homogeneous mixes.Then, add the water that is dissolved with organic acid and water soluble ingredient, make it phase transfer emulsifying.Further be cooled to room temperature while stirring.By sodium hydroxide pH is adjusted into 3.7.
In addition, pH, viscosity measurement are as follows, and the hair conditioner that obtains is carried out following evaluation.
Condition determination
The PH:pH quantifier: East Ami デ イ one ケ one ケ HM-30G processed of one Co., Ltd. measures temperature: 25 ℃
Viscosity: viscometer: the BM type processed viscometer No.4 of TOKIMEC society rotor 30rpm measured temperature: 25 ℃ after 20 seconds
[evaluation methodology]
(1) [wettability of hair], [smoothness of hair], [the extension easness of reagent]
Make nearly 2 months with interior carry out 50 years old～60 years old of the overstain poliosis feel dry or 30 the impaired women of hair, use separately and washed the type hair conditioner composition off 7 days (ラ イ オ Application (strain) [plant story Rhizoma et radix valerianae mixes salubrious dry-touch type] is used in shampoo).[wettability of hair], [smoothness of hair], [the extension easness of reagent] these several projects are estimated.The result shows based on following benchmark to answer good number.
＜metewand 〉
◎: answer good people account in 30 more than 25
Zero: answer good people and account in 30 15～24
△: answer good people and account in 30 5～14
*: answer 5 of good people's less thaies
(2) storage stability
To wash PET (polyethylene terephthalate) sample bottle that type hair hair conditioner is filled in 50mL off, preserve after 6 months in 40 ℃ temperature chamber, naked eyes are observed, and estimate based on following metewand.
＜metewand 〉
◎: do not see separation, separate out
Zero: can see and a bit separate or separate out, not have the problem on the commodity value
*: be separated into two layers fully
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
Among the embodiment 28, be that 15.7, embodiment 29 is 14.7 with the weighted average HLB value that (B) compares composition (B).
[table 8]
[table 9]
According to above-mentioned method for making, prepare following hair conditioner, hair-care medicament.Be the aridity of hair, the smoothness of hair, extension easness and the outstanding hair cosmetics of storage stability of reagent.
[embodiment 30] hair conditioner
PH3.5, viscosity 8.0Pas (25 ℃)
(A)/(B)＝2.00
The wettability ◎ of hair
The smoothness ◎ of hair
Reagent extends easness ◎
Storage stability (40 ℃ 6 months) ◎
[embodiment 31] hair nursing agent
PH3.3, viscosity 15.0Pas (25 ℃)
(A)/(B)＝1.20
The wettability ◎ of hair
The smoothness ◎ of hair
Reagent extends easness ◎
Storage stability (40 ℃ 6 months) ◎
[embodiment 32] hair conditioner
PH3.5, viscosity 8.0Pas (25 ℃)
The weighted average HLB value 15.7 of nonionic surfactant (the 2nd 4 house 5 of arithmetic point gone into)
(A)/(B)＝2
The wettability ◎ of hair
The smoothness ◎ of hair
Reagent extends easness ◎
Storage stability (40 ℃ 6 months) ◎
[embodiment 33] nursing agent
PH3.3, viscosity 15.0Pas (25 ℃)
The weighted average HLB value 14.6 of nonionic surfactant (the 2nd 4 house 5 of arithmetic point gone into)
(A)/(B)＝1.2
The wettability ◎ of hair
The smoothness ◎ of hair
Reagent extends easness ◎
Storage stability (40 ℃ 6 months) ◎
Employed raw material shows below when preparation embodiment and comparative example.
[table 10]
Claims (5)
1. hair cosmetics, it is characterized in that, contain following (A) acrylic acid series polymeric compounds 0.1～2 quality %, (B) HLB and be cationic surfactant 0.5～5 quality % of the quaternary ammonium salt of 14～18 nonionic surfactant 0.1～3 quality %, aliphatic amine that (C) is selected from carbon number 18～22 and mountain Yu amido propyl dimethylamine and (D) straight chain saturated fatty alcohol 0.5～10 quality % of carbon number 16～22, (A)/(B) represented (A) composition is 0.05～18.00 with (B) mass ratio of composition;
(A) for contain 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the following general formula (1) and the following general formula (2) as the formation unit, weight average molecular weight is 3,000～100,000 acrylic acid series polymeric compounds;
(B) composition is selected from mono fatty acid macrogol ester and polyoxyethylene hardened castor oil, the average addition molal quantity of the oxirane of described mono fatty acid macrogol ester is 12～150, and the average addition molal quantity of the oxirane of described polyoxyethylene hardened castor oil is 60～100;
[changing 1]
In the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-;
[changing 2]
In the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, sodium atom, potassium atom, ammonium or amine.
2. hair cosmetics according to claim 1, in the described general formula (1), R
1Be hydrogen atom, R
2Be hydrogen atom, A is-NH-.
3. hair cosmetics according to claim 1 and 2, in the described general formula (2), R
3Be hydrogen atom, M is hydrogen atom and/or sodium atom.
4. hair cosmetics according to claim 1 and 2, (D) composition is cetyl alcohol or stearyl alcohol.
5. hair cosmetics according to claim 1 and 2, it is for washing type off.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008-260262 | 2008-10-07 | ||
| JP2008260262 | 2008-10-07 | ||
| PCT/JP2009/065570 WO2010041530A1 (en) | 2008-10-07 | 2009-09-07 | Hair cosmetic |
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| Publication Number | Publication Date |
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| CN102227207A CN102227207A (en) | 2011-10-26 |
| CN102227207B true CN102227207B (en) | 2013-07-10 |
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| JP (1) | JP5459218B2 (en) |
| KR (1) | KR101705913B1 (en) |
| CN (1) | CN102227207B (en) |
| HK (1) | HK1161679A1 (en) |
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| WO2015161199A1 (en) * | 2014-04-18 | 2015-10-22 | Benz Research And Development Corp. | (meth)acrylamide polymers for contact lens and intraocular lens |
| KR101947681B1 (en) * | 2014-06-04 | 2019-02-13 | 가부시키가이샤 만다무 | Cleansing cosmetic and sheet product |
| US11359156B2 (en) | 2019-10-21 | 2022-06-14 | Biocoat, Inc. | UV cure basecoatings for medical devices |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006347973A (en) * | 2005-06-17 | 2006-12-28 | Lion Corp | Shampoo composition |
| JP2007031615A (en) * | 2005-07-28 | 2007-02-08 | Lion Corp | Liquid detergent composition |
| JP2007063546A (en) * | 2005-08-04 | 2007-03-15 | Mitsubishi Chemicals Corp | Detergent composition |
| JP2007522092A (en) * | 2004-02-09 | 2007-08-09 | 三菱化学株式会社 | Hair cosmetics |
| JP2008517021A (en) * | 2004-10-22 | 2008-05-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Cosmetic formulation comprising a copolymer of ethyl methacrylate and at least one monoethylenically unsaturated carboxylic acid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5167601B2 (en) | 2005-11-18 | 2013-03-21 | 三菱化学株式会社 | Hair cosmetics |
| JP4736741B2 (en) | 2005-11-18 | 2011-07-27 | 三菱化学株式会社 | Cosmetic composition |
-
2009
- 2009-09-07 CN CN2009801481913A patent/CN102227207B/en not_active Expired - Fee Related
- 2009-09-07 KR KR1020117008893A patent/KR101705913B1/en active IP Right Grant
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007522092A (en) * | 2004-02-09 | 2007-08-09 | 三菱化学株式会社 | Hair cosmetics |
| JP2008517021A (en) * | 2004-10-22 | 2008-05-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Cosmetic formulation comprising a copolymer of ethyl methacrylate and at least one monoethylenically unsaturated carboxylic acid |
| JP2006347973A (en) * | 2005-06-17 | 2006-12-28 | Lion Corp | Shampoo composition |
| JP2007031615A (en) * | 2005-07-28 | 2007-02-08 | Lion Corp | Liquid detergent composition |
| JP2007063546A (en) * | 2005-08-04 | 2007-03-15 | Mitsubishi Chemicals Corp | Detergent composition |
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| Publication number | Publication date |
|---|---|
| KR101705913B1 (en) | 2017-02-10 |
| HK1161679A1 (en) | 2012-08-03 |
| KR20110081986A (en) | 2011-07-15 |
| CN102227207A (en) | 2011-10-26 |
| WO2010041530A1 (en) | 2010-04-15 |
| MY160099A (en) | 2017-02-28 |
| JPWO2010041530A1 (en) | 2012-03-08 |
| JP5459218B2 (en) | 2014-04-02 |
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