CN102219975A - Modified high impact polystyrene composite material and preparation process thereof - Google Patents
Modified high impact polystyrene composite material and preparation process thereof Download PDFInfo
- Publication number
- CN102219975A CN102219975A CN 201110158865 CN201110158865A CN102219975A CN 102219975 A CN102219975 A CN 102219975A CN 201110158865 CN201110158865 CN 201110158865 CN 201110158865 A CN201110158865 A CN 201110158865A CN 102219975 A CN102219975 A CN 102219975A
- Authority
- CN
- China
- Prior art keywords
- high impact
- gum
- modified high
- impact polystyrene
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005669 high impact polystyrene Polymers 0.000 title claims abstract description 23
- 239000004797 high-impact polystyrene Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002131 composite material Substances 0.000 title abstract description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 24
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004793 Polystyrene Substances 0.000 claims abstract description 11
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 11
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 11
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 claims abstract description 11
- 239000008117 stearic acid Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000011159 matrix material Substances 0.000 claims description 11
- 238000005516 engineering process Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000005034 decoration Methods 0.000 abstract description 2
- 229920002261 Corn starch Polymers 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000008120 corn starch Substances 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 206010020675 Hypermetropia Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- CCTYIJIKDVBOTE-UHFFFAOYSA-L calcium;octadecanoic acid;sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O.CCCCCCCCCCCCCCCCCC(O)=O CCTYIJIKDVBOTE-UHFFFAOYSA-L 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a modified high impact polystyrene composite material and a preparation process thereof. The composite material is prepared from the following raw materials in percentage by weight: 10-50wt% of calcium sulfate, 10-40wt% of corn starch, 20-60wt% of high impact resistant polystyrene, 1-10wt% of antioxidant 1010 and 1-20wt% of stearic acid. The invention also provides the preparation process of the modified high impact polystyrene composite material. The modified high impact polystyrene composite material has the advantages of good mechanical property, small formation shrinkage and low cost and can be used for replacing natural wood in the fields of indoor and outdoor decoration, building industry and the like.
Description
Technical field
The present invention relates to a kind of high-impact polystyrene (HIPS) composite material and preparation technology thereof, especially relate to a kind of modified high impact resistant polystyrene matrix material and preparation technology thereof.
Background technology
In recent years, high-impact polystyrene (HIPS) resin demand keeps increasing fast, particularly aspect building materials, is in rapid growth period in recent years; Along with the international paces of Chinese market strengthen, HIPS package resin material and tubing all will have wide development space in fields such as cement, chemical fertilizer, grain, food, beverage, medicine, washing composition, makeup, and its demand is corresponding to increase substantially; In addition, automobile, communication, field of traffic also are rapid growth to the demand of HIPS resin.But the high-impact polystyrene price is higher, and impact strength is lower in engineering plastics, and range of application is very limited.
Summary of the invention
The technical problem to be solved in the present invention is, overcomes the deficiencies in the prior art, provides a kind of mechanical property good, and shaping shrinkage rate is little, modified high impact resistant polystyrene matrix material and preparation technology thereof that cost is low.
The present invention solve the technical problem the technical scheme that is adopted:
The present invention's modified high impact resistant polystyrene matrix material is made by following raw materials by weight percent: calcium sulfate 10-50 wt%, W-Gum 10-40wt%, high-impact polystyrene (HIPS) 20-60 wt%, antioxidant 1010 1-10 wt%, stearic acid 1-20wt%.
Preferred weight percent is: calcium sulfate 15wt%, W-Gum 15wt%, high-impact polystyrene (HIPS) 60 wt%, antioxidant 1010 5wt%, stearic acid 5wt%.
The preparation technology of the present invention's modified high impact resistant polystyrene matrix material may further comprise the steps:
(1) calcium sulfate is pulverized, crossed 100 mesh sieves, place the dry 23-25 of baking oven hour (preferred 24 hours) of 90-110 ℃ (preferred 100 ℃); Dry back adds in the high-speed mixer, adds antioxidant 1010 and stearic acid, mixes 12-18 minute (preferred 15 minutes) down at 45-55 ℃ (preferred 50 ℃);
(2) W-Gum is placed the dry 2-3 of baking oven hour (preferred 2 hours) of 60-80 ℃ (preferred 70 ℃);
(3) the dried W-Gum of high-impact polystyrene, step (1) gained mixture and step (2) is added 15-25 minute (preferred 20 minutes) of physical agitation mixing in the high-speed mixer;
(4) place forcing machine to extrude in step (3) gained mixture, granulation.
The present invention adds stearic acid calcium sulfate is carried out the surface active modification, can improve the consistency of calcium sulfate and starch, can improve the flowability of melt and the surface flatness of matrix material as lubricant simultaneously.
The present invention's modified high impact resistant polystyrene matrix material, mechanical property is good, and shaping shrinkage rate is little, and cost is low, can replace natural timber to be used for fields such as indoor and outdoor decoration, construction industry.
Embodiment
Below in conjunction with specific embodiment the present invention is described in further detail.
Each embodiment raw material weight proportioning sees Table 1.
Starting material provider is as follows:
The calcium sulfate powder, Hebei Xingtai Shuanghua Plaster Products Co., Ltd.;
W-Gum, the farsighted development in science and technology company limited that reaches of Wuhan dragon;
HIPS/HP8250, the permanent trade Co., Ltd in Qidong;
Antioxidant 1010, Nanjing Jia Yin Science and Technology Ltd.;
Stearic acid, the Shanghai card is won industry and trade company limited.
The preparation method:
(1) calcium sulfate is pulverized, crossed 100 mesh sieves, place 100 ℃ dry 24 hours of baking oven; Dry back adds in the high-speed mixer, adds antioxidant 1010 and stearic acid, mixes 15 minutes down at 50 ℃;
(2) W-Gum is placed 70 ℃ dry 2 hours of baking oven;
(3) physical agitation in the dried W-Gum adding of high-impact polystyrene, step (1) gained mixture and step (2) high-speed mixer was mixed 20 minutes;
(4) place forcing machine to extrude in step (3) gained mixture, granulation.
Each embodiment product performance detects, and tensile strength is pressed the test of GB/T 1040-92 prescriptive procedure; Flexural strength is pressed the test of GB/T 1936.1-1991 prescriptive procedure, and shock strength is pressed the test of GB/T 1043-93 prescriptive procedure, and elongation at break is pressed the test of GB/T17200-1997 prescriptive procedure, and shrinking percentage is pressed the standard testing of GB/T 15585-1995 prescriptive procedure.
Table 1 embodiment 1-3 raw material weight proportioning
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Calcium sulfate (kg) | 15 | 15 | 20 |
| W-Gum (kg) | 15 | 20 | 15 |
| HIPS（kg） | 60 | 55 | 55 |
| Antioxidant 1010 (kg) | 5 | 2 | 2 |
| Stearic acid (kg) | 5 | 8 | 8 |
Table 2 embodiment 1-3 product performance detected result relatively
| ? | Tensile strength (MPa) | Flexural strength (MPa) | Shock strength (KJ/m 2） | Elongation at break/% | Shrinking percentage/% |
| Embodiment 1 | 57.6 | 100.4 | 16.7 | 3.8 | 0.5 |
| Embodiment 2 | 56.4 | 99.7 | 16.3 | 3.6 | 0.9 |
| Embodiment 3 | 55.3 | 98.3 | 15.9 | 3.7 | 0.7 |
Claims (4)
1. a modified high impact resistant polystyrene matrix material is characterized in that, is made by following raw materials by weight percent: calcium sulfate 10-50 wt%, W-Gum 10-40wt%, high-impact polystyrene 20-60 wt%, antioxidant 1010 1-10 wt%, stearic acid 1-20wt%.
2. modified high impact resistant polystyrene matrix material according to claim 1 is characterized in that, is made by following raw materials by weight percent: calcium sulfate 15wt%, W-Gum 15wt%, high-impact polystyrene 60 wt%, antioxidant 1010 5wt%, stearic acid 5wt%.
3. the preparation technology of a modified high impact resistant polystyrene matrix material as claimed in claim 1 or 2 is characterized in that, may further comprise the steps:
(1) calcium sulfate is pulverized, crossed 100 mesh sieves, place 90-110 ℃ the dry 23-25 of baking oven hour; Dry back adds in the high-speed mixer, adds antioxidant 1010 and stearic acid, mixes 12-18 minute down at 45-55 ℃;
(2) W-Gum is placed 60-80 ℃ the dry 2-3 of baking oven hour;
(3) physical agitation in the dried W-Gum adding of high-impact polystyrene, step (1) gained mixture and step (2) high-speed mixer was mixed 15-25 minute;
(4) place forcing machine to extrude in step (3) gained mixture, granulation.
4. the preparation technology of modified high impact resistant polystyrene matrix material according to claim 3 is characterized in that, may further comprise the steps:
(1) calcium sulfate is pulverized, crossed 100 mesh sieves, place 100 ℃ dry 24 hours of baking oven; Dry back adds in the high-speed mixer, adds antioxidant 1010 and stearic acid, mixes 15 minutes down at 50 ℃;
(2) W-Gum is placed 70 ℃ dry 2 hours of baking oven;
(3) physical agitation in the dried W-Gum adding of high-impact polystyrene, step (1) gained mixture and step (2) high-speed mixer was mixed 20 minutes;
(4) place forcing machine to extrude in step (3) gained mixture, granulation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110158865 CN102219975B (en) | 2011-06-14 | 2011-06-14 | Modified high impact polystyrene composite material and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110158865 CN102219975B (en) | 2011-06-14 | 2011-06-14 | Modified high impact polystyrene composite material and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102219975A true CN102219975A (en) | 2011-10-19 |
| CN102219975B CN102219975B (en) | 2013-06-05 |
Family
ID=44776693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110158865 Expired - Fee Related CN102219975B (en) | 2011-06-14 | 2011-06-14 | Modified high impact polystyrene composite material and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102219975B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727761A (en) * | 2018-06-06 | 2018-11-02 | 全椒祥瑞塑胶有限公司 | A method of improving high impact polystyrene dimensional stability |
-
2011
- 2011-06-14 CN CN 201110158865 patent/CN102219975B/en not_active Expired - Fee Related
Non-Patent Citations (4)
| Title |
|---|
| 《Plastics Technology》 20091231 无 HIPS/Starch Blends Add Renewable Content 27 1-2 第55卷, 第12期 * |
| 《Plastics Technology》 20091231 无 HIPS/Starch Blends Add Renewable Content 27 3-4 第55卷, 第12期 * |
| 《现代塑料加工应用》 20090831 周超等 硫酸钙晶须在HIPS中的应用 45-48 1-2 第21卷, 第4期 * |
| 《现代塑料加工应用》 20090831 周超等 硫酸钙晶须在HIPS中的应用 45-48 3-4 第21卷, 第4期 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727761A (en) * | 2018-06-06 | 2018-11-02 | 全椒祥瑞塑胶有限公司 | A method of improving high impact polystyrene dimensional stability |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102219975B (en) | 2013-06-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105111671B (en) | A kind of table tennis and preparation method thereof | |
| CN106589650A (en) | Fine-performance plastic material and preparation method thereof | |
| CN104356978B (en) | A kind of preparation method of binding agent | |
| CN107640921B (en) | Preparation method of high-adaptability alkali-free accelerator auxiliary material | |
| CN102219967B (en) | Modified polyvinyl chloride composite material and preparation process of modified polyvinyl chloride composite material | |
| CN104803604A (en) | Wear-resistant and high-hardness ceramic formula and production technology of ceramic | |
| CN103570259A (en) | Geopolymer dry powder material as well as preparation method thereof | |
| CN101580372A (en) | Method for producing high-strength environment-friendly whitewash gypsum by using desulfurization gypsum | |
| CN102161797B (en) | Modified linear low-density polyethylene composite material and preparation method thereof | |
| CN106006696A (en) | Fabrication method and application of gypsum micro powder | |
| CN102219975B (en) | Modified high impact polystyrene composite material and preparation process thereof | |
| CN103568104A (en) | Preparation method for novel rice straw fiber board | |
| CN102557529A (en) | Vermiculite composite thermal insulation material | |
| CN102219963A (en) | Modified polystyrene composite material and preparation process thereof | |
| CN104059391A (en) | Surface-treated modified calcium carbonate and preparation method thereof | |
| CN106047192A (en) | Computer advertising art design packing bag binder | |
| CN102276906A (en) | Modified ethane-vinyl alcohol copolymer composite material and preparation technology thereof | |
| CN107099159A (en) | A kind of imitative porcelain fiber chopsticks spoon and preparation method thereof | |
| CN102219981B (en) | Modified acrylonitrile-butadiene-styrene copolymer and preparation method of modified acrylonitrile-butadiene-styrene copolymer | |
| CN113214575B (en) | PVC sole and preparation process thereof | |
| CN105419130A (en) | Molecular sieve impact modification flexibilizer for polyvinyl chloride and preparing method thereof | |
| CN111793322A (en) | High-impact degradable amino molding plastic and preparation method thereof | |
| CN105907315A (en) | Home wood-plastic board binding agent for interior decoration | |
| CN105860858A (en) | Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive | |
| CN102226036B (en) | Calcium sulfate maize starch nylon 66 composite and preparation technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160823 Address after: An Industrial Park Economic Development Zone, Changde City, Hunan province Linli County 415200 Patentee after: Hunan Fu Xiang new type building material Co.,Ltd. Address before: 410005, 12 floor, Haidong mansion, Furong Road, Changsha, Hunan Patentee before: Liu Liwen |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130605 |