CN102218545B - Method for preparing nano aluminum by utilizing chemical method - Google Patents
Method for preparing nano aluminum by utilizing chemical method Download PDFInfo
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- CN102218545B CN102218545B CN201110142205XA CN201110142205A CN102218545B CN 102218545 B CN102218545 B CN 102218545B CN 201110142205X A CN201110142205X A CN 201110142205XA CN 201110142205 A CN201110142205 A CN 201110142205A CN 102218545 B CN102218545 B CN 102218545B
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- Prior art keywords
- phosphine
- reaction
- organic solvent
- aluminium
- nano aluminum
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 73
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000000126 substance Substances 0.000 title claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 23
- 238000000634 powder X-ray diffraction Methods 0.000 claims abstract description 3
- 239000004411 aluminium Substances 0.000 claims description 33
- 239000000047 product Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 31
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 26
- 239000003960 organic solvent Substances 0.000 claims description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 19
- 239000012280 lithium aluminium hydride Substances 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 16
- 239000011261 inert gas Substances 0.000 claims description 16
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 229910001387 inorganic aluminate Inorganic materials 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 14
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 230000035484 reaction time Effects 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- 239000008096 xylene Substances 0.000 claims description 8
- 150000003738 xylenes Chemical class 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 claims description 3
- ATJDRVASSJDRKG-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCCCCCCP Chemical compound CCCCCCCCCCCCCCCCCCCCCCCP ATJDRVASSJDRKG-UHFFFAOYSA-N 0.000 claims description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims description 2
- ZRGUXTGDSGGHLR-UHFFFAOYSA-K aluminum;triperchlorate Chemical compound [Al+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O ZRGUXTGDSGGHLR-UHFFFAOYSA-K 0.000 claims description 2
- VQNIOZLNRYKVEF-UHFFFAOYSA-N decylphosphane Chemical class CCCCCCCCCCP VQNIOZLNRYKVEF-UHFFFAOYSA-N 0.000 claims description 2
- HKYQPUQQLCWXDF-UHFFFAOYSA-N docosylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCCCCP HKYQPUQQLCWXDF-UHFFFAOYSA-N 0.000 claims description 2
- AAKDVDDBABPPKC-UHFFFAOYSA-N dodecylphosphane Chemical compound CCCCCCCCCCCCP AAKDVDDBABPPKC-UHFFFAOYSA-N 0.000 claims description 2
- VOMNBNQZXQQBRN-UHFFFAOYSA-N henicosylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCCCP VOMNBNQZXQQBRN-UHFFFAOYSA-N 0.000 claims description 2
- MSAGTGFFCKGEAS-UHFFFAOYSA-N heptadecylphosphane Chemical compound CCCCCCCCCCCCCCCCCP MSAGTGFFCKGEAS-UHFFFAOYSA-N 0.000 claims description 2
- SCCLFGAYCGKMEI-UHFFFAOYSA-N heptylphosphane Chemical class CCCCCCCP SCCLFGAYCGKMEI-UHFFFAOYSA-N 0.000 claims description 2
- QSOFCURVDKCVCM-UHFFFAOYSA-N hexadecylphosphane Chemical compound CCCCCCCCCCCCCCCCP QSOFCURVDKCVCM-UHFFFAOYSA-N 0.000 claims description 2
- CHXARDKIHSVFDK-UHFFFAOYSA-N hexylphosphane Chemical class CCCCCCP CHXARDKIHSVFDK-UHFFFAOYSA-N 0.000 claims description 2
- IGSZBXBKPMIFGE-UHFFFAOYSA-N icosylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCCP IGSZBXBKPMIFGE-UHFFFAOYSA-N 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- DJIMQXSDHCVKRJ-UHFFFAOYSA-N nonadecylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCP DJIMQXSDHCVKRJ-UHFFFAOYSA-N 0.000 claims description 2
- OYFFQMKVQYLFTC-UHFFFAOYSA-N nonylphosphane Chemical class CCCCCCCCCP OYFFQMKVQYLFTC-UHFFFAOYSA-N 0.000 claims description 2
- LYFSPQWNZMXDBG-UHFFFAOYSA-N octadecylphosphane Chemical compound CCCCCCCCCCCCCCCCCCP LYFSPQWNZMXDBG-UHFFFAOYSA-N 0.000 claims description 2
- ZFYSDGKZLKECCX-UHFFFAOYSA-N pentacosylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCP ZFYSDGKZLKECCX-UHFFFAOYSA-N 0.000 claims description 2
- XWCZVYYWOFUDEJ-UHFFFAOYSA-N pentadecylphosphane Chemical compound CCCCCCCCCCCCCCCP XWCZVYYWOFUDEJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000003003 phosphines Chemical class 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- HALMXWXXTMQUCQ-UHFFFAOYSA-N tetracosylphosphane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCP HALMXWXXTMQUCQ-UHFFFAOYSA-N 0.000 claims description 2
- DAUOXRUBCACRRL-UHFFFAOYSA-N tetradecylphosphane Chemical compound CCCCCCCCCCCCCCP DAUOXRUBCACRRL-UHFFFAOYSA-N 0.000 claims description 2
- MOSFSEPBWRXKJZ-UHFFFAOYSA-N tridecylphosphane Chemical compound CCCCCCCCCCCCCP MOSFSEPBWRXKJZ-UHFFFAOYSA-N 0.000 claims description 2
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical group CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 claims description 2
- RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 claims description 2
- KCTAHLRCZMOTKM-UHFFFAOYSA-N tripropylphosphane Chemical compound CCCP(CCC)CCC KCTAHLRCZMOTKM-UHFFFAOYSA-N 0.000 claims description 2
- UNONUKLLXITFPT-UHFFFAOYSA-N undecylphosphane Chemical compound CCCCCCCCCCCP UNONUKLLXITFPT-UHFFFAOYSA-N 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 7
- 238000005979 thermal decomposition reaction Methods 0.000 abstract description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000010586 diagram Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 210000004027 cell Anatomy 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000000654 additive Substances 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 239000003814 drug Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000003380 propellant Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229910010082 LiAlH Inorganic materials 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000002360 explosive Substances 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- 206010028980 Neoplasm Diseases 0.000 description 4
- 238000001132 ultrasonic dispersion Methods 0.000 description 4
- 150000001399 aluminium compounds Chemical class 0.000 description 3
- -1 aluminium salt compounds Chemical class 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000004449 solid propellant Substances 0.000 description 2
- 208000030507 AIDS Diseases 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920002121 Hydroxyl-terminated polybutadiene Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000002512 chemotherapy Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003721 gunpowder Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003832 thermite Substances 0.000 description 1
- 210000004881 tumor cell Anatomy 0.000 description 1
Images
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- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Luminescent Compositions (AREA)
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CN201110142205XA CN102218545B (en) | 2011-05-30 | 2011-05-30 | Method for preparing nano aluminum by utilizing chemical method |
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CN201110142205XA CN102218545B (en) | 2011-05-30 | 2011-05-30 | Method for preparing nano aluminum by utilizing chemical method |
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CN102218545B true CN102218545B (en) | 2012-11-28 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103042228B (en) * | 2012-12-21 | 2014-12-03 | 江苏大学 | Liquid-phase preparation method for high-quality nano-aluminum particles |
CN106623901B (en) * | 2016-12-19 | 2021-01-19 | 北京化工大学 | Aluminum nanosheet, and preparation method and application thereof |
CN107225254A (en) * | 2017-04-01 | 2017-10-03 | 北京化工大学 | A kind of aluminum nanoparticles and preparation method thereof |
CN109834288B (en) * | 2017-11-24 | 2022-04-29 | 阜阳师范学院 | Preparation method of nano aluminum powder with uniform particle size distribution |
CN109834289B (en) * | 2017-11-24 | 2022-06-10 | 阜阳师范学院 | Preparation method of nano aluminum powder |
CN110860696A (en) * | 2018-08-27 | 2020-03-06 | 阜阳师范学院 | Method for preparing nano aluminum powder |
CN110860697A (en) * | 2018-08-28 | 2020-03-06 | 阜阳师范学院 | Method for preparing nano aluminum powder by using protective agent |
CN113564382B (en) * | 2021-07-09 | 2022-08-30 | 中南大学 | Method for preparing metal aluminum by reduction at room temperature |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1568285A (en) * | 2001-10-12 | 2005-01-19 | 韩国Nano技术株式会社 | Synthesis of mono-disperse and highly crystalline nano-particles of metals, alloys, metal-oxides, and multi-metallic oxides without a size-selection process |
CN1894043A (en) * | 2003-10-15 | 2007-01-10 | 托尔萨公司 | Method of preparing metallic nanoparticles and materials thus obtained |
CN101100002A (en) * | 2006-07-06 | 2008-01-09 | 三星电机株式会社 | Method for producing metal nano granule |
CN101259539A (en) * | 2008-04-18 | 2008-09-10 | 北京化工大学 | High dispersion metal nano granule and preparation thereof |
Family Cites Families (1)
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JP2002294312A (en) * | 2001-03-29 | 2002-10-09 | Toda Kogyo Corp | Method for manufacturing metal particle powder |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1568285A (en) * | 2001-10-12 | 2005-01-19 | 韩国Nano技术株式会社 | Synthesis of mono-disperse and highly crystalline nano-particles of metals, alloys, metal-oxides, and multi-metallic oxides without a size-selection process |
CN1894043A (en) * | 2003-10-15 | 2007-01-10 | 托尔萨公司 | Method of preparing metallic nanoparticles and materials thus obtained |
CN101100002A (en) * | 2006-07-06 | 2008-01-09 | 三星电机株式会社 | Method for producing metal nano granule |
CN101259539A (en) * | 2008-04-18 | 2008-09-10 | 北京化工大学 | High dispersion metal nano granule and preparation thereof |
Non-Patent Citations (1)
Title |
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JP特开2002-294312A 2002.10.09 |
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Address after: 453499 No. 3, Pubei pilot industrial park, Changyuan City, Xinxiang City, Henan Province Patentee after: Henan Soton New Material Co.,Ltd. Address before: 453499 No. 3, Pubei pilot industrial park, Changheng County, Xinxiang, Henan Province Patentee before: Henan Soton New Material Co.,Ltd. |
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