CN105598471A - Preparation method of super thermite with core-shell structure - Google Patents
Preparation method of super thermite with core-shell structure Download PDFInfo
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- CN105598471A CN105598471A CN201610164482.3A CN201610164482A CN105598471A CN 105598471 A CN105598471 A CN 105598471A CN 201610164482 A CN201610164482 A CN 201610164482A CN 105598471 A CN105598471 A CN 105598471A
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- aluminium powder
- thermite
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- super thermite
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- 239000003832 thermite Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000011258 core-shell material Substances 0.000 title abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 28
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims description 23
- 239000004411 aluminium Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- WTDRDQBEARUVNC-LURJTMIESA-N L-DOPA Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-LURJTMIESA-N 0.000 claims description 16
- WTDRDQBEARUVNC-UHFFFAOYSA-N L-Dopa Natural products OC(=O)C(N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-UHFFFAOYSA-N 0.000 claims description 16
- 229960004502 levodopa Drugs 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 10
- 239000012153 distilled water Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000001291 vacuum drying Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 13
- 238000000034 method Methods 0.000 abstract description 13
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 230000008569 process Effects 0.000 abstract description 6
- 239000007800 oxidant agent Substances 0.000 abstract description 4
- 230000001590 oxidative effect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000010949 copper Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- -1 metal oxide compound Chemical class 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/102—Metallic powder coated with organic material
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemically Coating (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
The invention discloses a preparation method of super thermite with a core-shell structure. The preparation method comprises the following steps: (1) covering the surface of nano aluminum powder; (2) and preparing the super thermite nAl@DOPA-M. Compared with a traditional method, the super thermite prepared by the method disclosed by the invention avoids the problem that the distribution of an oxidant and the aluminum powder is not uniform; a complete shell layer is formed on the surface of nano aluminum through a biomolecule oxidant; and the conduction speed of reaction heat can be remarkably reduced, the mass transferring efficiency is improved and the energy releasing efficiency of materials is greatly improved. The method has the advantages of moderate reaction conditions, simple process, and convenience for preparation in batch, and popularization and application of the method are facilitated.
Description
Technical field
The present invention relates to a kind of super thermite, this material can be used as key component or the combustion catalyst of solid propellant.
Technical background
In modern science and techniques of defence field, energetic material and the exploitation in weaponry system thereof are light in occupation of lifting foot with applicationHeavy status is that weapons and ammunitions possess high performance important foundation. Pursuing high energy characteristics is the target that energetic material is eternally immutable;Aspect the energy release (dynamics) of energetic material, need the essence spy of its efficacy exertion/energy release process of exploration discovery simultaneouslyProperty, and understand and utilize these characteristics to regulate and control the performance of energetic material.
Energetic Nanomaterials (NanoEnergeticmaterials, nEMs) refers to the energetic material of particle diameter in 1～100nm, bothCan be simple substance energetic material nanocrystal, can be also that nanoscale contains can compound, be generally by metal/metal oxide and (or)The nano particle of inorganic/organic energetic material component and matrix composition. After energetic material nanometer, except thering is common size containing energy materialOutside the excellent properties of material, also have many potential performance advantages, as the release of explosion energy more completely, detonation is closer to idealDetonation, very high energyreleaserate and burning (Conversion of Energy) efficiency, relative sensitivity preferably, good mechanical property etc. Various countriesLaunch one after another the research to Energetic Nanomaterials, while mainly concentrating on technical barrier in material preparation process and its for fiery explosivePotential and effectiveness.
Super thermite (SuperThermite), is called again metastable state intermolecular complex (MIC), is nanoscale aluminium powder and oxidationProperty the stronger metal/non-metal oxide compound that forms, show the high exothermal nature of thermite, with traditional simple substance containing can materialMaterial is compared, and maximum its reactivity that is not both is based on intermolecular interaction instead of intramolecular reaction. Because its aluminothermy is anti-Answer the reaction rate that is exceedingly fast in process and higher thermal discharge, the application of chemical industry, the energy, military affairs, environmental protection etc. become one non-Normal challenging research field.
But, utilize current preparation method as sol-gel process, ultrasonic dispersion composite algorithm, reaction inhibition polishings etc. are preparedSuper thermite even mix or compound of being often merely able to realize nanometer aluminium powder and oxide, and can not meet metal and oxidantBetween effective contact of molecular scale. And ALD (ald) although etc. method can prepare and there is complete nucleocapsid structureSuper aluminothermy material, but its complex process equipment, technical requirement is high, and its output is less, is difficult to meet application requirements.
Summary of the invention
In order to solve shortcomings and deficiencies of the prior art, the invention provides one and utilize biomolecule levodopa (DOPA) to regulate and controlThe super thermite preparation method of nAlDOPA-M nucleocapsid structure. The present invention adopts solution manufacturing method, and technological process is simple, syntheticEquipment is traditional mixing plant, and raw material is common chemical reagent, can meet the needs of extensive preparation completely.
The preparation method of above-mentioned super thermite, comprises the following steps:
(1) surface of nanometer aluminium powder is coated
Take raw material aluminium powder and put into beaker, under condition of ice bath, add distilled water, then add levodopa (DOPA), regulate pHValue disperses to stir 1～2h in 8.5～12 scope, can realize levodopa being evenly coated on nanometer aluminium powder surface;
(2) preparation of super thermite nAlDOPA-M
To the aqueous solution that adds soluble metallic salt in the prepared nanometer aluminium powder suspension of step 1, ice bath stirs 2～4 hours, fromThe heart, washing, puts into vacuum drying chamber and dries the super thermite obtaining based on biomolecule.
Described aluminium powder average grain diameter is 80～200nm. Levodopa quality is 1%～50% of aluminium powder, and distilled water quality is aluminium powder10～20 times. Soluble metallic salt is selected from Fe, Cu, Mg, Ni, the soluble metallic salt of Mn etc.
Advantage of the present invention: synthesis technique of the present invention is simple, the synthetic super thermite obtaining is complete nucleocapsid structure, realize metal withEffective contact of molecular scale between oxidant, has avoided oxidant and metal powder skewness and mass transfer distance in traditional preparation methodFrom excessive problem, biomolecule can transport by directed control metal ion simultaneously, significantly reduces mass transfer distance, improves exothermal efficiency.
Brief description of the drawings
Fig. 1 is the TEM photo of super thermite nAlDOPA-Cu;
Fig. 2 is SEM and the EDS spectrogram of super thermite nAlDOPA-Cu;
Fig. 3 is the thermal decomposition characteristic spectrogram of super thermite nAlDOPA-Cu and common nano aluminum thermit powder.
Detailed description of the invention
Below by embodiment, the present invention is further explained to explanation.
The preparation of embodiment 1nAlDOPA-Cu
(1) will under 5g nanometer aluminium powder condition of ice bath, be scattered in 100mL distilled water, add 2g levodopa (DOPA), adjustJoint pH value stirs 1～2h in 8.5～12 scope; Take 4.84g (0.02mol) copper nitrate and be dissolved in above-mentioned suspension, stirMix;
(2) ice bath stirring reaction 4h, then leaves standstill;
(3) precipitate with deionized water is repeatedly washed, dry can make black gray expandable product.
The preparation of embodiment 2nAlDOPA-Fe
(1) take the nanometer aluminium powder of 5g, under condition of ice bath, be scattered in 100mL distilled water, add 2g levodopa (DOPA),Regulate pH value in 8.5～12 scope, to disperse to stir 1～2h; Take 8.08g (0.02mol) ferric nitrate and be dissolved in above-mentioned suspension,Be uniformly mixed;
(2) ice bath stirring reaction 3h, then leaves standstill;
(3) precipitate with deionized water is repeatedly washed, dry can make black gray expandable product.
The preparation of embodiment 3nAlDOPA-Mg
(1) take the nanometer aluminium powder of 5g, under condition of ice bath, be scattered in 100mL distilled water, add 2g levodopa (DOPA),Regulate pH value in 8.5～12 scope, to disperse to stir 1～2h; Take 5.12g (0.02mol) magnesium nitrate and be dissolved in above-mentioned suspension,Be uniformly mixed;
(2) ice bath stirring reaction 4h, then leaves standstill;
(3) precipitate with deionized water is repeatedly washed, dry can make black gray expandable product.
The sign of the super thermite of nAlDOPA-M and performance test
1. structural characterization
Taking nAlDOPA-Cu sample as example, Fig. 1 is the transmission electron microscope photo of sample. From figure, can know and see,Prepared sample is complete nucleocapsid structure. Particle size is about 100nm, and shell thickness is in 10nm left and right, due to sample preparationIn process, do not add other compounds, known surface crust should be the clad of DOPA molecule formation. Fig. 1 right side is sampleHRTEM photo, the lattice fringe spacing that can measure sample from figure is about 0.23nm, meets the spacing of (111) face of aluminium,The core that has proved nucleocapsid structure is nano aluminum particle.
Fig. 2 is respectively SEM photo and the corresponding constituency EDS power spectrum of nAlDOPA and nAlDOPA-Cu sample.As we can see from the figure, in the EDS power spectrum of left side sample, only contain Al and C, N, O element, in sample preparation processDo not add other compounds, illustrate Al coated with uniform DOPA molecule. And in right sample except Al, C, N, OThe outer appearance that also has Cu element, illustrates and in sample, adds after soluble copper salt, has formed DOPA-Cuization on nanometer aluminium powder surfaceThe clad of compound. The super thermite known in conjunction with Fig. 1 and Fig. 2, prepared sample is nucleocapsid structure, and surface is coatedLayer is DOPA-Cu compound.
2. performance test
Fig. 3 is the Pyrogram of nAlDOPA-Cu and common nano aluminum thermit powder nAl/CuO, as we can see from the figure, and with generalLogical nano aluminum thermit powder is compared, and in advance, thermal discharge increases decomposition peak's temperature of nAlDOPA-Cu sample, and nAlDOPA-Cu is describedHigher than common nano aluminum thermit powder exothermal efficiency, releasing can be more complete.
Claims (4)
1. a preparation method for the super thermite of nucleocapsid structure, is characterized in that comprising the following steps:
(1) under condition of ice bath, aluminium powder is reacted with distilled water, levodopa, regulate pH value in 8.5～12 scope, stir 1～2hObtain nanometer aluminium powder suspension;
(2) in nanometer aluminium powder suspension, add soluble metallic salt ice bath to stir 2～4 hours, centrifugal, washing, vacuum drying obtainsSuper thermite.
2. the preparation method of super thermite according to claim 1, is characterized in that described aluminium powder average grain diameter is 80～200nm.
3. the preparation method of super thermite according to claim 1, is characterized in that levodopa quality is 1%～50% of aluminium powder,Distilled water quality is 10～20 times of aluminium powder.
4. the preparation method of super thermite according to claim 1, it is characterized in that soluble metallic salt be selected from Fe, Cu, Mg,Ni or Mn.
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| CN201610164482.3A CN105598471B (en) | 2016-03-22 | 2016-03-22 | A kind of preparation method of the super thermite of core shell structure |
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| CN105598471A true CN105598471A (en) | 2016-05-25 |
| CN105598471B CN105598471B (en) | 2017-09-08 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106083499A (en) * | 2016-06-03 | 2016-11-09 | 上海交通大学 | Super thermite that different size graphene oxide is compound and preparation method thereof |
| CN107297496A (en) * | 2017-06-23 | 2017-10-27 | 西安近代化学研究所 | A kind of preparation method of the micro-nano zirconium powder of hud typed carbon coating |
| CN112626635A (en) * | 2020-12-15 | 2021-04-09 | 西南科技大学 | Method for preparing high-burning-rate micro-pipeline based on nano thermite ink |
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2016
- 2016-03-22 CN CN201610164482.3A patent/CN105598471B/en not_active Expired - Fee Related
Patent Citations (5)
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| CN102581272A (en) * | 2012-02-06 | 2012-07-18 | 西安近代化学研究所 | Method for preparing nanometer aluminum composite powder coated with nitro-cotton |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106083499A (en) * | 2016-06-03 | 2016-11-09 | 上海交通大学 | Super thermite that different size graphene oxide is compound and preparation method thereof |
| CN106083499B (en) * | 2016-06-03 | 2018-03-06 | 上海交通大学 | Compound super thermite of different size graphene oxides and preparation method thereof |
| CN107297496A (en) * | 2017-06-23 | 2017-10-27 | 西安近代化学研究所 | A kind of preparation method of the micro-nano zirconium powder of hud typed carbon coating |
| CN112626635A (en) * | 2020-12-15 | 2021-04-09 | 西南科技大学 | Method for preparing high-burning-rate micro-pipeline based on nano thermite ink |
| CN112626635B (en) * | 2020-12-15 | 2022-01-28 | 西南科技大学 | A method for preparing high burning rate micro-pipes based on nano-thermite ink |
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