Background technology
Agricultural crop straw is the great renewable resources of occurring in nature quantity.The annual agricultural crop straw output of China reaches 700,000,000 tons more than, but these resource long-terms reasonably developed, all the other are all burned as the feed except that minute quantity, this is the severe contamination that the huge waste of natural resource has been caused environment again.According to statistics, present straw utilization rate is 33%, but only accounts for 2.6% through what utilize after certain technical finesse, and all the other major parts just act as a fuel and wait directly utilization.In recent years along with the decline of oil coal reserves, particularly along with the growing interest and the attention of various countries' environmental pollution problem, people will research and develop emphasis gradually and transfer to the application of natural polymer and come up.Agricultural crop straw is wherein a kind of, stalk is fully utilized be meant by physical chemistry or biological method stalk is directly carried out trans-utilization or its biomass is carried out comprehensive complete utilization.
Stalk (bagasse, energy grass, cotton stalk, reed, paddy and wheat, corn etc.) cellulose is about 40%, and Mierocrystalline cellulose is a renewable resources the abundantest on the earth, and has inexpensive, degradability and ecotope do not produced advantages such as pollution.Mierocrystalline cellulose is a poly-hydroxy glucose polymer, through behind the specific physics or chemical modification, have different functional performances, can powdery, multi-form appearance such as sheet, film, fiber and solution, therefore have the popularity of handiness and application with the functional materials of Mierocrystalline cellulose exploitation.Products such as paper pulp, alcohol fuel, degradable dinner set, carboxymethyl cellulose, Microcrystalline Cellulose, cellulose acetate be can produce, paper industry, plastics industry, alcohol fuel, medicine industry, foodstuffs industry, building materials industry, ceramic industry, petroleum industry, textile industry etc. are widely used in.
Past is to use chemical process from the stalk production of cellulose, and adopting chemical process one is to cause serious pollution, the 2nd, and the cost height.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of and prepare cellulosic method from stalk with biological process, this method is not only polluted, and cost reduces (reducing cost 50% than chemical process), is a kind of efficient, cleaning, cheap high-new biotechnology.
Technical scheme of the present invention is: a kind ofly prepare cellulosic method with biological process from stalk, it is characterized in that, with the stalk dedusting, be crushed to the 20-40 order, add in the reaction tank, add stalk weight 4-5 water doubly then, soak 1 hour dense mill defibrination of laggard height; Be added to behind the defibrination in the retort, add the compound bio catalyzer again, after mixing, be warming up to 60-80 ℃, reacted 1-3 hour; Behind the blowing through screening remove behind the impurity slurry slightly, thick slurry advances hang down dense mill defibrination, dewaters through pulp-extruding machine then, discongests with fluffer again, advances roller dryer and carries out drying, pulverize after the drying stalk cellulose; The add-on of described compound bio catalyzer is the compound bio catalyzer that adds the 0.10-0.30 parts by weight in per 100 parts by weight stalks.
Used compound bio catalyzer is mixed by following materials based on weight and forms: laccase 2-5, catalase 3-6, the hydrogen peroxide 1-5 of massfraction 35%, water 5-300.Used stalk is the stalk of farm crop such as sugarcane, energy grass, cotton, reed, paddy and wheat, corn.
This project meets State Council " Office of the State Council sends out file [2008] No. 105: the General Office of the State Council is about accelerating to advance the suggestion of agricultural crop straw comprehensive utilization " requirement, accelerate the agricultural crop straw comprehensive utilization, help promoting growth of agricultural efficiency, increasing peasant income and rural ecological civilization construction, promote resource-conserving and environment-friendly society's construction.
The invention has the beneficial effects as follows: the present invention's stalk is the feedstock production Mierocrystalline cellulose, extracting Mierocrystalline cellulose than traditional technology reduces cost 50% (cost of the present invention is about 1800 yuan/ton, traditional technology is about 3600 yuan/ton) and purity height (the prepared cellulosic purity of the present invention is more than 99%, and the prepared cellulosic purity of traditional technology is about 80%); And biological process is pollution-free, zero release, protection environment.This project is raw material with the stalk, with biological process from the stalk production of cellulose, have prescription rationally, technology is simple, advanced and mature; but the advantage of continuous operation is with reaching zero release constantly, the protection environment; reduce and pollute, energy-saving and emission-reduction meet the requirement of recycling economy.
Embodiment
In conjunction with example the present invention is illustrated further:
Embodiment one:
200 kilograms of straws through dedusting, be crushed to 20 orders, add in the reaction tank, the water that adds 800 kilograms then, soaked 1 hour, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.20 kilogram in the retort again behind the defibrination, after mixing, be warming up to 70 ℃, reacted 2 hours, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 80 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 20 grams, catalase 30 grams, hydrogen peroxide 50 grams of 35% (wt/wt), water 100 grams.
Embodiment two:
100 kilograms of rice bars through dedusting, be crushed to 40 orders, add in the reaction tank, the water that adds 500 kilograms then, soaked 3 hours, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.15 kilogram in the retort again behind the defibrination, after mixing, be warming up to 75 ℃, reacted 1.5 hours, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 43 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 30 grams, catalase 30 grams, hydrogen peroxide 30 grams of 35% (wt/wt), water 60 grams.
Embodiment three:
300 kilograms of bagasse through dedusting, be crushed to 30 orders, add in the reaction tank, the water that adds 1500 kilograms then, soaked 2 hours, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.4 kilogram in the retort again behind the defibrination, after mixing, be warming up to 80 ℃, reacted 3 hours, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 135 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 30 grams, catalase 40 grams, hydrogen peroxide 40 grams of 35% (wt/wt), water 290 grams.
Embodiment four:
200 kilograms of cotton stalks through dedusting, be crushed to 40 orders, add in the reaction tank, the water that adds 1000 kilograms then, soaked 8 hours, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.3 kilogram in the retort again behind the defibrination, after mixing, be warming up to 80 ℃, reacted 3 hours, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 100 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 20 grams, catalase 30 grams, hydrogen peroxide 50 grams of 35% (wt/wt), water 200 grams.
Embodiment five:
400 kilograms of corn stalks through dedusting, be crushed to 30 orders, add in the reaction tank, the water that adds 2000 kilograms then, soaked 5 hours, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.4 kilogram in the retort again behind the defibrination, after mixing, be warming up to 80 ℃, reacted 2 hours, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 180 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 40 grams, catalase 50 grams, hydrogen peroxide 50 grams of 35% (wt/wt), water 260 grams.
Embodiment six:
200 kilograms of energy grass through dedusting, be crushed to 40 orders, add in the reaction tank, the water that adds 800 kilograms then, soaked 6 hours, advance high dense mill defibrination, be added to the compound bio catalyzer that adds 0.2 kilogram in the retort again behind the defibrination, after mixing, be warming up to 75 ℃, reacted 1 hour, starch through getting slightly behind the screening removal impurity behind the blowing, thick slurry advances to hang down dense mill defibrination, through pulp-extruding machine dehydration, discongest with fluffer again, advance roller dryer and carry out drying then, pulverize after the drying 86 kilograms of stalk celluloses.
Used compound bio catalyzer is mixed by mass fraction by following raw material and forms: laccase 40 grams, catalase 60 grams, hydrogen peroxide 20 grams of 35% (wt/wt), water 80 grams.