CN102180317A - Antimicrobial cigarette box and preparation method thereof - Google Patents
Antimicrobial cigarette box and preparation method thereof Download PDFInfo
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- CN102180317A CN102180317A CN 201110068165 CN201110068165A CN102180317A CN 102180317 A CN102180317 A CN 102180317A CN 201110068165 CN201110068165 CN 201110068165 CN 201110068165 A CN201110068165 A CN 201110068165A CN 102180317 A CN102180317 A CN 102180317A
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Abstract
The invention discloses an antimicrobial cigarette box which comprises a box body. The antimicrobial cigarette box is characterized in that an antibacterial film is arranged on the surface of the box body. The invention also provides a preparation method of the antimicrobial cigarette box. By arranging the antibacterial film on the surface of the cigarette box, a barrier is formed between a cigarette product and the external environment, so that the pollution to the cigarette product by external bacteria is effectively prevented, the shelf life of the cigarette product is prolonged, the safety and the sensory property of the cigarette product are improved, and the quality of the cigarette product is maintained simultaneously.
Description
Technical field
The present invention relates to packing container, specifically, relate to a kind of antibiotic cigarette case, and the method for making of this antibiotic cigarette case.
Background technology
Cigarette case (being Cigarette pack) is generally the papery box, comprises long box (it is a cigarette that a long box cigarette is commonly called as) and capsule (a little box cigarette is commonly called as a cigarette package), and wherein capsule is divided into hard box and soft box.Be fabricated into the process of packing, accumulating, sale, use of cigarette from cigarette case, pass through a lot of links, cigarette case contacts comparatively frequent as the external packing of cigarette with people's (as the producer, bearer, sellers and customer) hand.Since cigarette case more continually with different people's hand contact, so the surface of cigarette case becomes easily infected by bacterium and virus, and strikes out earlier cigarette case usually with the hand during customer's smoking, directly puts in the mouth after taking out cigarette, is subjected to bacterium and viral infection easily like this.
Summary of the invention
Technical matters to be solved by this invention provides a kind of antibiotic cigarette case, and the method for making of this antibiotic cigarette case, this antibiotic cigarette case can form barrier between tobacco product and external environment, effectively prevent the pollution to tobacco product of extraneous bacterium and virus, keeps the quality of tobacco product.The technical scheme that adopts is as follows:
A kind of antibiotic cigarette case comprises box body, it is characterized in that: the surface of described box body is provided with antibacterial film.
In a kind of concrete scheme, the outside face of above-mentioned box body is provided with antibacterial film.In the concrete scheme of another kind, be equipped with antibacterial film on the outside face of above-mentioned box body and the inside face.Usually, be printed with the picture and text layer on the outside face of above-mentioned box body, antibacterial film covers described picture and text layer.
On the other hand, the invention provides a kind of method for making of above-mentioned antibiotic cigarette case, it is characterized in that comprising the steps: that (1) carry out surface treatment to the paper that is used to make cigarette case; (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, form antimicrobial coating; (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.In the preferred above-mentioned steps (2), the thickness of antimicrobial coating is 3-6 μ m.
When on the outside face that only needs at box body antibacterial film being set, only need the one side of the paper that is used to make cigarette case is carried out surface treatment and form antibacterial film on this face, when making cigarette case, be formed with the outside face of the one side of antibacterial film as cigarette case.Usually, the paper that is used to make cigarette case has one side to be printed with picture and text, is printed with the outside face of the one side of picture and text as cigarette case, like this, general only the need has the one side of picture and text to carry out surface treatment to above-mentioned paper printing, and antibacterial film is formed on above-mentioned paper printing to be had on the one side of picture and text.
In the time need on the outside face of box body and inside face, all antibacterial film being set, need all carrying out surface treatment to the two sides of the paper that is used to make cigarette case, and on the two sides of paper, respectively form an antibacterial film.
Preferred above-mentioned antibiotic paint contains following components in weight percentage: inorganic antibacterial material 0.5～3.5%, aqueous polyurethane 91.5～95%, water 4.5～8%.
Preferred above-mentioned inorganic antibacterial material is made by the following weight proportion raw material: the inorganic porous mineral of the metal ion antibacterial agent of 8-10% (weight), 64-66% (weight) and the emulsifying agent of 25-27% (weight).
In the above-mentioned antibiotic paint, aqueous polyurethane can form the porous rete.Aqueous polyurethane porous rete is as the carrier of inorganic antibacterial material, have softness, flexible, intensity good, the abrasion resistant characteristics.
Above-mentioned metal ion antibacterial agent plays antibacterial action.Preferred above-mentioned metal ion antibacterial agent is a kind of or wherein multiple combination in silver ion antimicrobial agent, copper ion antiseptic and the zinc ion antiseptic.Above-mentioned silver ion antimicrobial agent can be the inorganic salts of argent or silver; The copper ion antiseptic can be the inorganic salts of metallic copper or copper; The zinc ion antiseptic can be the inorganic salts of metallic zinc or zinc.Antimicrobial component in the above-mentioned inorganic antibacterial material is silver, copper, zinc, and metals such as silver, copper, zinc are that the state with ion exists, and metals (or its ion) such as silver, copper, zinc are attached to the surface of inorganic porous mineral.Metallic ions such as silver, copper, zinc have the strong binding ability in organized enzyme center with bacterium or mould, can make protein coagulating, destroy the activity of cell synzyme, make thalline forfeiture schizogamy ability and death, therefore have the ability of inhibition or kill bacteria; After thalline lost activity, metallic ion can dissociate out from thalline again, repeats fungicidal property, so its antibacterial effect is lasting.
Above-mentioned inorganic porous mineral can be a kind of in zeolite and the calcium carbonate or both combinations.
Mentioned emulsifier can adopt common various emulsifying agents at present, as a kind of or wherein multiple compound in lecithin, monoglyceride acid glyceride, sucrose fatty acid ester, APES, benzylphenol polyoxyethylene ether, phenethyl phenol polyethenoxy ether, AEO, phenethyl phenol polyethenoxy ether polyethenoxy ether, aliphatic amine polyoxyethylene ether, polyoxyethylene oleic acid ester, polyoxyethylene stearic acid ester, abietic acid polyoxyethylene ester, sapn, tween, trimerization glycerol monosterate, rosin glycerine and the Foral glycerine.
Preferred above-mentioned inorganic antibacterial material is a nano-scale particle.Inorganic antibacterial material is adopted nanotechnology treatments, obtain nanometer grade inorganic antibacterial material, make it have more extensive, remarkable antibiotic and sterilizing function, and, improved antibiotic long-lasting by slow releasing function.
The invention provides a kind of preparation method of above-mentioned antibiotic paint, it is characterized in that comprising the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water (by weight ratio promptly in proportion, inorganic antibacterial material 0.5～3.5%, aqueous polyurethane 91.5～95%, water 4.5～8%); (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.In the preferred steps (2), stirring rate is 50-200 rev/min; Usually in whipping process, stirring rate is accelerated gradually.
The preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion (is metal ion antibacterial agent 8-10% (weight) in the preferred above-mentioned steps (1), inorganic porous mineral 64-66% (weight), emulsifying agent 25-27% (weight)), wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder (being the surface that metal ion antibacterial agent is fixed on the inorganic porous mineral hole); (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.
Usually, after with inorganic antibacterial material and aqueous polyurethane, in 24 hours, antibiotic paint is used for coating, best results.
The present invention is by being provided with antibacterial film on the cigarette case surface, between tobacco product and external environment, form barrier, effectively prevent of the pollution of extraneous bacterium, thereby prolong the shelf life of tobacco product tobacco product, improve the safety and the organoleptic properties of tobacco product, keep the quality of tobacco product simultaneously.Among the present invention, antibiotic paint is after coating and oven dry, form antibacterial film, aqueous polyurethane forms the porous rete, inorganic antibacterial material is attached to the surface of porous rete, make antibacterial film have following advantage: antibacterial ability is strong, broad spectrum antibacterial is arranged, MIC (minimal inhibitory concentration) to hay bacillus is 16ppm, to colibacillary MIC is 250ppm, to Escherichia coli with staphylococcus aureus is efficient reaches 99%, moulds such as aspergillus niger, Aspergillus terreus, Aureobasidium pullulans, paecilomyces varioti, penicillium funiculosum are also had obviously strangle the extinction effect; Resistance to effect of heat height (reaching 800 ℃), resistance to acids reaches pH=3, and resistance to alkalis reaches pH=13, and the antibiotic paint coating is permanently effective; Nontoxic, tasteless, nonirritant meets the standard of food additives, reaches the requirement of high standard safety.In addition, antibiotic paint of the present invention also can be used for the packing of other products.
The specific embodiment
Embodiment 1
This antibiotic cigarette case comprises box body, and the surface of box body is provided with antibacterial film.In the present embodiment, be equipped with antibacterial film on the outside face of box body and the inside face; Be printed with the picture and text layer on the outside face of box body, antibacterial film covers described picture and text layer.
The method for making of above-mentioned antibiotic cigarette case comprises the steps: that (1) carry out surface treatment (surface treatment is all carried out on the two sides to the paper that is used to make cigarette case) to the paper that is used to make cigarette case; (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, form antimicrobial coating (in the present embodiment, respectively form an antimicrobial coating on the two sides of paper, the thickness of two antimicrobial coatings is 5 μ m); (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.
Above-mentioned antibiotic paint contains following components in weight percentage: inorganic antibacterial material 2%, and aqueous polyurethane 91.5%, water 6.5%, wherein inorganic antibacterial material is a nano-scale particle.Inorganic antibacterial material is made by the following weight proportion raw material: the emulsifying agent (being the monoglyceride acid glyceride) of the inorganic porous mineral (being zeolite) of the metal ion antibacterial agent of 9% (weight) (being silver ion antimicrobial agent), 65% (weight) and 26% (weight).
The preparation method of above-mentioned antibiotic paint comprises the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water in proportion; (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.In the step (2), the scope of stirring rate is 50-200 rev/min, and stirring rate is accelerated gradually in whipping process.In the above-mentioned steps (1), the preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion, and wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder; (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.In the above-mentioned steps (1-3), the particle diameter of the inorganic antibacterial material that obtains after the pulverizing reaches nanoscale.
Usually, after with inorganic antibacterial material and aqueous polyurethane, in 24 hours, antibiotic paint is used for coating, best results.
Embodiment 2
This antibiotic cigarette case comprises box body, and the surface of box body is provided with antibacterial film.In the present embodiment, be equipped with antibacterial film on the outside face of box body and the inside face; Be printed with the picture and text layer on the outside face of box body, antibacterial film covers described picture and text layer.
The method for making of above-mentioned antibiotic cigarette case comprises the steps: that (1) carry out surface treatment (surface treatment is all carried out on the two sides to the paper that is used to make cigarette case) to the paper that is used to make cigarette case; (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, form antimicrobial coating (in the present embodiment, respectively form an antimicrobial coating on the two sides of paper, paper is 6 μ m as the thickness of antimicrobial coating on the one side of cartridge outer surface, and paper is 3 μ m as the thickness of antimicrobial coating on the one side of cartridge inner surface); (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.
Above-mentioned antibiotic paint contains following components in weight percentage: inorganic antibacterial material 3.5%, and aqueous polyurethane 92%, water 4.5%, wherein inorganic antibacterial material is a nano-scale particle.Inorganic antibacterial material is made by the following weight proportion raw material: the emulsifying agent (wherein 8% (weight) is polyoxyethylene oleic acid ester, and 18% (weight) is tween) of the inorganic porous mineral (being calcium carbonate) of the metal ion antibacterial agent of 10% (weight) (wherein 6% (weight) is that silver ion antimicrobial agent, 4% (weight) is the zinc ion antiseptic), 64% (weight) and 26% (weight).
The preparation method of above-mentioned antibiotic paint comprises the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water in proportion; (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.In the step (2), the scope of stirring rate is 50-200 rev/min, and stirring rate is accelerated gradually in whipping process.In the above-mentioned steps (1), the preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion, and wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder; (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.In the above-mentioned steps (1-3), the particle diameter of the inorganic antibacterial material that obtains after the pulverizing reaches nanoscale.
Usually, after with inorganic antibacterial material and aqueous polyurethane, in 24 hours, antibiotic paint is used for coating, best results.
Embodiment 3
This antibiotic cigarette case comprises box body, and the surface of box body is provided with antibacterial film.In the present embodiment, the outside face of box body is provided with antibacterial film; Be printed with the picture and text layer on the outside face of box body, antibacterial film covers described picture and text layer.
The method for making of above-mentioned antibiotic cigarette case comprises the steps: (1) paper that is used to make cigarette case to be carried out surface treatment, and (paper that is used to make cigarette case has one side to be printed with picture and text, be printed with the outside face of the one side of picture and text as cigarette case, like this, general only the need has the one side of picture and text to carry out surface treatment to above-mentioned paper printing); (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, (antimicrobial coating is formed on above-mentioned paper printing to be had on the one side of picture and text, and the thickness of antimicrobial coating is 4 μ m to form antimicrobial coating.); (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.
Above-mentioned antibiotic paint contains following components in weight percentage: inorganic antibacterial material 0.5%, aqueous polyurethane 95%, water 4.5%.Wherein inorganic antibacterial material is made by the following weight proportion raw material: (wherein 6% (weight) is silver ion antimicrobial agent to the metal ion antibacterial agent of 8% (weight), 2% (weight) is the copper ion antiseptic), the inorganic porous mineral (wherein 35% (weight) is zeolite, and 30% (weight) is calcium carbonate) of 65% (weight) and the emulsifying agent (being rosin glycerine) of 27% (weight).
The preparation method of above-mentioned antibiotic paint comprises the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water in proportion; (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.In the step (2), the scope of stirring rate is 50-200 rev/min, and stirring rate is accelerated gradually in whipping process.In the above-mentioned steps (1), the preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion, and wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder; (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.
Usually, after with inorganic antibacterial material and aqueous polyurethane, in 24 hours, antibiotic paint is used for coating, best results.
Embodiment 4
This antibiotic cigarette case comprises box body, and the surface of box body is provided with antibacterial film.In the present embodiment, the outside face of box body is provided with antibacterial film; Be printed with the picture and text layer on the outside face of box body, antibacterial film covers described picture and text layer.
The method for making of above-mentioned antibiotic cigarette case comprises the steps: (1) paper that is used to make cigarette case to be carried out surface treatment, and (paper that is used to make cigarette case has one side to be printed with picture and text, be printed with the outside face of the one side of picture and text as cigarette case, like this, general only the need has the one side of picture and text to carry out surface treatment to above-mentioned paper printing); (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, (antimicrobial coating is formed on above-mentioned paper printing to be had on the one side of picture and text, and the thickness of antimicrobial coating is 6 μ m to form antimicrobial coating.); (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.
Above-mentioned antibiotic paint contains following components in weight percentage: inorganic antibacterial material 0.5%, aqueous polyurethane 91.5%, water 8%.Wherein inorganic antibacterial material is made by the following weight proportion raw material: the inorganic porous mineral (being zeolite) of the metal ion antibacterial agent of 9% (weight) (being the zinc ion antiseptic), 66% (weight) and the emulsifying agent (being sapn) of 25% (weight).
The preparation method of above-mentioned antibiotic paint comprises the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water in proportion; (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.In the step (2), the scope of stirring rate is 50-200 rev/min, and stirring rate is accelerated gradually in whipping process.In the above-mentioned steps (1), the preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion, and wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder; (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.
Usually, after with inorganic antibacterial material and aqueous polyurethane, in 24 hours, antibiotic paint is used for coating, best results.
More than by four embodiment the present invention is elaborated.Those skilled in the art are according to the prompting of the foregoing description and summary of the invention part, can select other ratiometric inorganic antibacterial material, aqueous polyurethane and water, and other kind and ratiometric metal ion antibacterial agent, inorganic porous mineral and emulsifying agent, realize purpose of the present invention.
Claims (10)
1. an antibiotic cigarette case comprises box body, it is characterized in that: the surface of described box body is provided with antibacterial film.
2. the method for making of an antibiotic cigarette case is characterized in that comprising the steps: that (1) carry out surface treatment to the paper that is used to make cigarette case; (2) use coating apparatus antibiotic paint to be coated on the surface of above-mentioned paper, form antimicrobial coating; (3) antimicrobial coating is dried, make the crosslinked film forming of antimicrobial coating, obtain having the cigarette case package paper of antibacterial film; (4) the cigarette case package paper that utilizes step (3) to obtain cut, moulding, obtain cigarette case.
3. the method for making of the described antibiotic cigarette case of claim 2, it is characterized in that: in the described step (2), the thickness of antimicrobial coating is 3-6 μ m.
4. the method for making of the described antibiotic cigarette case of claim 2, it is characterized in that: described antibiotic paint contains following components in weight percentage: inorganic antibacterial material 0.5～3.5%, aqueous polyurethane 91.5～95%, water 4.5～8%.
5. the method for making of the described antibiotic cigarette case of claim 4, it is characterized in that: described inorganic antibacterial material is made by the following weight proportion raw material: the inorganic porous mineral of the metal ion antibacterial agent of 8-10% (weight), 64-66% (weight) and the emulsifying agent of 25-27% (weight).
6. the method for making of the described antibiotic cigarette case of claim 5, it is characterized in that: described metal ion antibacterial agent is a kind of or wherein multiple combination in silver ion antimicrobial agent, copper ion antiseptic and the zinc ion antiseptic.
7. the method for making of the described antibiotic cigarette case of claim 5 is characterized in that: described inorganic porous mineral is a kind of in zeolite and the calcium carbonate or both combinations.
8. the method for making of the described antibiotic cigarette case of claim 5, it is characterized in that: described emulsifying agent is a lecithin, the monoglyceride acid glyceride, sucrose fatty acid ester, APES, the benzylphenol polyoxyethylene ether, the phenethyl phenol polyethenoxy ether, AEO, phenethyl phenol polyethenoxy ether polyethenoxy ether, aliphatic amine polyoxyethylene ether, polyoxyethylene oleic acid ester, polyoxyethylene stearic acid ester, the abietic acid polyoxyethylene ester, sapn, tween, the trimerization glycerol monosterate, a kind of or wherein multiple compound in rosin glycerine and the Foral glycerine.
9. the method for making of the described antibiotic cigarette case of claim 5, it is characterized in that: the preparation method of described antibiotic paint comprises the steps: that (1) is equipped with inorganic antibacterial material, aqueous polyurethane and water in proportion; (2) inorganic antibacterial material, aqueous polyurethane and water are mixed, and stir, make antibiotic paint.
10. the method for making of the described antibiotic cigarette case of claim 9, it is characterized in that: among the preparation method of described antibiotic paint, the preparation method of inorganic antibacterial material comprises the steps: that successively (1-1) is equipped with metal ion antibacterial agent, inorganic porous mineral and emulsifying agent in proportion in the step (1), and wherein inorganic porous mineral is a powder; (1-2) metal ion antibacterial agent is added in the inorganic porous mineral powder, and stir, metal ion antibacterial agent is implanted in the hole of inorganic porous mineral powder; (1-3) emulsifying agent is joined in the material that step (1-2) obtains, and stir, and then dry, pulverize, obtain inorganic antibacterial material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110068165 CN102180317B (en) | 2011-03-21 | 2011-03-21 | Antimicrobial cigarette box and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110068165 CN102180317B (en) | 2011-03-21 | 2011-03-21 | Antimicrobial cigarette box and preparation method thereof |
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| CN102180317A true CN102180317A (en) | 2011-09-14 |
| CN102180317B CN102180317B (en) | 2012-12-26 |
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| CN 201110068165 Active CN102180317B (en) | 2011-03-21 | 2011-03-21 | Antimicrobial cigarette box and preparation method thereof |
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Cited By (5)
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| CN102517993A (en) * | 2011-12-20 | 2012-06-27 | 广东壮丽彩印股份有限公司 | Packaging and printing paper substrate with antibacterial property, and preparation method thereof |
| CN102550604A (en) * | 2011-12-22 | 2012-07-11 | 广东壮丽彩印股份有限公司 | Antibacterial agent, antibacterial gloss oil with antibacterial agent and preparation method and using method for antibacterial gloss oil |
| CN103304986A (en) * | 2012-03-13 | 2013-09-18 | 合肥杰事杰新材料股份有限公司 | Mildewproof flame retardant polyamide and preparation method thereof |
| CN107082190A (en) * | 2017-06-14 | 2017-08-22 | 广东中烟工业有限责任公司 | A kind of cigarette packaging structure |
| WO2024115402A1 (en) * | 2022-11-28 | 2024-06-06 | Jt International Sa | Packaging for smoking or aerosol generating articles |
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| CN1800253A (en) * | 2005-10-14 | 2006-07-12 | 深圳清华大学研究院 | Atibiotic cigarette package film and its method for making same |
| CN2844049Y (en) * | 2005-08-17 | 2006-12-06 | 温雨杰 | Antibacterial and preservative cigarette case |
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| US4934524A (en) * | 1988-09-19 | 1990-06-19 | Brown & Williamson Tobacco Corporation | Package for storing moisture laden articles |
| CN1245770A (en) * | 1999-07-29 | 2000-03-01 | 谢建平 | Food packaging container/material with antibiotic action, bacteriostatic action and fresh-keeping function |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102517993A (en) * | 2011-12-20 | 2012-06-27 | 广东壮丽彩印股份有限公司 | Packaging and printing paper substrate with antibacterial property, and preparation method thereof |
| CN102517993B (en) * | 2011-12-20 | 2014-06-11 | 广东壮丽彩印股份有限公司 | Packaging and printing paper substrate with antibacterial property, and preparation method thereof |
| CN102550604A (en) * | 2011-12-22 | 2012-07-11 | 广东壮丽彩印股份有限公司 | Antibacterial agent, antibacterial gloss oil with antibacterial agent and preparation method and using method for antibacterial gloss oil |
| CN103304986A (en) * | 2012-03-13 | 2013-09-18 | 合肥杰事杰新材料股份有限公司 | Mildewproof flame retardant polyamide and preparation method thereof |
| CN107082190A (en) * | 2017-06-14 | 2017-08-22 | 广东中烟工业有限责任公司 | A kind of cigarette packaging structure |
| WO2024115402A1 (en) * | 2022-11-28 | 2024-06-06 | Jt International Sa | Packaging for smoking or aerosol generating articles |
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| Publication number | Publication date |
|---|---|
| CN102180317B (en) | 2012-12-26 |
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