CN102174784B - Light storage and emission counterfeiting paper and manufacturing method and application thereof - Google Patents
Light storage and emission counterfeiting paper and manufacturing method and application thereof Download PDFInfo
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- CN102174784B CN102174784B CN 201110059765 CN201110059765A CN102174784B CN 102174784 B CN102174784 B CN 102174784B CN 201110059765 CN201110059765 CN 201110059765 CN 201110059765 A CN201110059765 A CN 201110059765A CN 102174784 B CN102174784 B CN 102174784B
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- light
- accumulated luminous
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- light storage
- printing ink
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Abstract
The invention relates to light storage and emission material products, in particular to light storage and emission counterfeiting paper and a manufacturing method and application thereof. The paper is made by uniformly coating light storage and emission ink on common paper in a printing mode. The light storage and emission ink consists of the following components in percentage by weight: 20 percent of white ink, 10 percent of polyamide resin, 25 percent of titanium white, 5 percent of acetic ether, 10 percent of isopropyl alcohol, 10 percent of edible alcohol and 20 percent of light storage liquid, wherein the light storage liquid is a light storage coating which is prepared by mixing a light storage pigment and varnish in the weight ratio of 1:1; and the light storage pigment is phosphorescence zinc sulfide ZnS:Cu. In the invention, the technical problem of light emission failure of the light storage material phosphorescence zinc sulfide due to deterioration because the phosphorescence zinc sulfide is chemically reacted with heavy metal substances in the air easily is mainly solved; a light storage and emission material can be further coated on the common paper, so that the common paper can have light storage and emission effects; and the special paper with light storage and emission performance is used in the field of counterfeiting.
Description
Technical field
The present invention relates to the light-accumulating luminous material product, particularly a kind of light-accumulated luminous cheque paper and manufacturing approach and application.
Background technology
Light-accumulating luminous material is to have to absorb and storage sunshine or light, and discharges the pigment of the characteristic of visible light in the dark slowly.Its absorption--storage---luminous cyclic process can go round and begin again heap of times.Therefore, it usually is used to the occasion that need to indicate and decorate, comprises that noctilucence indicates, holds that cursor shows and ornament.
Employed in the market light-storing paint is normally mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint mainly is phosphorescent zinc sulphide (ZnS:Cu).Because this body colour of this light-storing paint is faint yellow, so light-storing paint also is to be faint yellow.Above-mentioned this light-storing paint can be kept visible state 1-2 hours after fully holding light; And under normal operating position; This light-storing paint can keep its light-accumulated luminous functional 3-5; And usually after using 5 years, the light-accumulated luminous characteristic of material is progressively lost, and causes the main cause of light-storing paint loss of function to be: the chemical reaction of heavy metal substance can make its rotten and luminous inefficacy in light-storing paint and the air.
Summary of the invention
The object of the present invention is to provide a kind of light-accumulated luminous cheque paper and manufacturing approach and application; The chemical reaction of heavy metal substance easily and in the air that mainly solves light-storing material phosphorescent zinc sulphide can make the technical problem of its rotten and luminous inefficacy; Further can be coated in this light-accumulating luminous material on the common paper; Make common paper also can have light-accumulated luminous effect, and this special paper with light-accumulated luminous performance is used in false proof field.
For realizing above-mentioned purpose, the present invention realizes like this.
A kind of light-accumulated luminous cheque paper is characterized in that: it is on common paper, evenly to apply light-accumulated luminous printing ink with mode of printing; Described light-accumulated luminous printing ink according to the composition of percentage by weight is: chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% and hold light liquid 20%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
A kind of manufacturing approach of light-accumulated luminous cheque paper is characterized in that: it comprises the steps that (1) prepares light-accumulated luminous printing ink, and the light-accumulated luminous printing ink that (2) will prepare passes through press printing on common paper.
Described manufacturing approach; It is characterized in that: in the light-accumulated luminous printing ink of described preparation; Earlier chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stir, mixing time is 1 hour, temperature 10-20 ° C; And then will hold the miniature jackhammer that light liquid 20% adds in the container gradually and helical blade is installed in use additional simultaneously and stir, mixing time is 1 hour, temperature 10-20 ° C; Promptly accomplished the preparation of light-accumulated luminous printing ink.
Described manufacturing approach; It is characterized in that: behind the light-accumulated luminous printing ink of preparation in 1-5 hour; Add this printing ink and add in the ink printer, and under the operating environment of temperature 10-20 ° C, the speed of printing ink with 300 meters/minute is printed on the common paper through ink printer.
Described manufacturing approach is characterized in that: the thickness of described common paper is the 0.5-55 silk, and the thickness of described light-accumulated luminous ink printing on common paper is the 1-2 silk.
Described light-accumulated luminous cheque paper is characterized in that: this light-accumulated luminous cheque paper republishes other pattern or literal to be used as the commodity labeling.
Described light-accumulated luminous cheque paper is characterized in that: this light-accumulated luminous cheque paper republishes other pattern or literal to be used as commercial tissue.
Described light-accumulated luminous cheque paper is characterized in that: this light-accumulated luminous cheque paper is as the printing paper of invoice and currency.
The specific embodiment
The invention discloses a kind of light-accumulated luminous cheque paper and manufacturing approach and application.Wherein, described light-accumulated luminous cheque paper is on common paper, evenly to apply light-accumulated luminous printing ink with mode of printing.To hold light liquid be light-storing paint and contain in the light-accumulated luminous printing ink, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.This light-storing paint is the material of present commonplace employing, and therefore, its advantage repeats no more.But when being used to prepare light-accumulated luminous printing ink, we mainly need consider following some.
1, in order to be that product has long year in service life (30-50), the chemical reaction that just need overcome heavy metal substance in light-storing paint and the air through the improvement of ink formulations can make the problem of its rotten and luminous inefficacy.
2, because the base material of product is a common paper, and after printing applies printing ink, do not change the color (white) of base material, therefore need in ink formulations, consider how to improve the faint yellow color of light-storing paint.
In addition, in order further to enhance productivity, we also need consider the fast dry characteristic of printing ink simultaneously when the light-accumulated luminous printing ink of configuration.In order further to guarantee the environmental protection problem in the printing ink production use, we also will consider in configuration printing ink, to avoid the use of noxious material as far as possible.
In view of above-mentioned purpose, light-accumulated luminous printing ink of the present invention according to the composition of percentage by weight is: chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% and hold light liquid 20%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
In the above-mentioned recipe ingredient; Chalk 20% and titanium white powder 25% that we use help to improve color of ink, printing ink are white in color, after being printed on the base material common paper; Its ink printing face and non-printing surface color basically identical, and yellowish color can not appear certainly.
In the above-mentioned recipe ingredient, polyamide 10%, isopropyl alcohol 10% be mainly as the adhesive of printing ink, helps the printing ink can firm sticking on the base material.Wherein: polyamide presents white usually, grease resistance, mineral oil and water, water imbibition is big, and has electrical insulating property preferably after the drying, these characteristics all be paper need especially help to prolong the paper characteristic in service life.
During above-mentioned prescription was formed, ethyl acetate 5%, isopropyl alcohol 10% all were environmentally friendly solvents, are particularly suitable for ink product.
During above-mentioned prescription was formed, edible alcohol 10% had non-toxic nature, and it adds and helps in the ink formulations to do soon behind the ink printing, helps to promote production efficiency.
During above-mentioned prescription is formed; Be very beneficial for prolonging the function retention time of light-accumulated luminous printing ink after the adding of polyamide 10%; Reason is: have electrical insulating property preferably after the polyamide drying; Therefore be easy to the micronic dust in the absorbed air behind the last static, as the ink material that contains polyamide that is coated on the base material, its suction-operated helps on the ink printing face, forming one deck natural containment through the absorption micronic dust; This protective layer helps phosphorescent zinc sulphide ZnS:Cu and the airborne heavy metal material in the isolated printing ink to produce chemical reaction, and then has prolonged the service life of light-accumulating luminous material.
The manufacturing approach of a kind of light-accumulated luminous cheque paper of the present invention comprises the steps, (1) prepares light-accumulated luminous printing ink, and the light-accumulated luminous printing ink that (2) will prepare passes through press printing on common paper.
In the light-accumulated luminous printing ink of described preparation; Earlier chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stir, mixing time is 1 hour, temperature 10-20 ° C; And then will hold the miniature jackhammer that light liquid 20% adds in the container gradually and helical blade is installed in use additional simultaneously and stir, mixing time is 1 hour, temperature 10-20 ° C; Promptly accomplished the preparation of light-accumulated luminous printing ink.
Because the light-accumulated luminous printing ink of the present invention has fast dry characteristic, therefore be preferably in behind the light-accumulated luminous printing ink of preparation and print use in 1-5 hour, and before printing is used, printing ink is stored in the low temperature environment of vacuum environment, 5-10 ° C.In the concrete operations, add this printing ink add in ink printer (such as: Heidelberg printing machine model DCC450), and under the operating environment of temperature 10-20 ° C, the speed of printing ink with 300 meters/minute is printed on the common paper through ink printer.The common ink print speed printing speed is 500 meters/minute, because printing ink of the present invention has fast dry characteristic, so print speed printing speed can promote one times nearly.The thickness of described common paper is the 0.5-55 silk, and the thickness of described light-accumulated luminous ink printing on common paper is the 1-2 silk.
Through detecting, through the light-accumulated luminous cheque paper that said method is made, its luminous brightness of holding behind the light can reach 1Min1.6*10
2MCD/m
2, 2Min0.5*10
2MCD/m
2, 5Min0.2*10
2MCD/m
2, 10Min0.1*10
2MCD/m
2, be higher than the 1Min > of correlation technique standard code far away; 120MCD/m
2, 2Min>40MCD/m
2, 5Min>15MCD/m
2, 10Min>8MCD/m
2The shelf-life of this product can reach 30-50.
This light-accumulated luminous cheque paper republishes other pattern or literal to be used as the commodity labeling; This light-accumulated luminous cheque paper republishes other pattern or literal to be used as commercial tissue; Can also be used as the paper of invoice, currency, have very strong and very hidden false proof result of use.
In sum, being merely preferred embodiment of the present invention, is not to be used for limiting practical range of the present invention, and promptly all equivalences of doing according to the content of claim of the present invention change and modify, and all should be technological category of the present invention.
Claims (7)
1. light-accumulated luminous cheque paper is characterized in that: it is on common paper, evenly to apply light-accumulated luminous printing ink with mode of printing; Described light-accumulated luminous printing ink according to the composition of percentage by weight is: chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% and hold light liquid 20%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
2. the manufacturing approach of a light-accumulated luminous cheque paper, it is characterized in that: it comprises the steps that (1) prepares light-accumulated luminous printing ink, the light-accumulated luminous printing ink that (2) will prepare through press printing on common paper; In the light-accumulated luminous printing ink of described preparation; Earlier chalk 20%, polyamide 10%, titanium white powder 25%, ethyl acetate 5%, isopropyl alcohol 10%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stirs, mixing time is 1 hour, temperature 10-20 ℃; And then will hold that light liquid 20% adds in the container gradually and use the miniature jackhammer that installs helical blade additional to stir simultaneously, mixing time is 1 hour, temperature 10-20 ℃; Promptly accomplished the preparation of light-accumulated luminous printing ink.
3. manufacturing approach according to claim 2; It is characterized in that: behind the light-accumulated luminous printing ink of preparation in 1-5 hour; This printing ink adds in the ink printer, and under temperature 10-20 ℃ operating environment, through ink printer the speed of printing ink with 300 meters/minute is printed on the common paper.
4. manufacturing approach according to claim 3 is characterized in that: the thickness of described common paper is the 0.5-55 silk, and the thickness of described light-accumulated luminous ink printing on common paper is the 1-2 silk.
5. light-accumulated luminous cheque paper according to claim 1 is characterized in that: this light-accumulated luminous cheque paper republishes other pattern or literal to be used as the commodity labeling.
6. light-accumulated luminous cheque paper according to claim 1 is characterized in that: this light-accumulated luminous cheque paper republishes other pattern or literal to be used as commercial tissue.
7. light-accumulated luminous cheque paper according to claim 1 is characterized in that: this light-accumulated luminous cheque paper is as the printing paper of invoice and currency.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110059765 CN102174784B (en) | 2011-03-14 | 2011-03-14 | Light storage and emission counterfeiting paper and manufacturing method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110059765 CN102174784B (en) | 2011-03-14 | 2011-03-14 | Light storage and emission counterfeiting paper and manufacturing method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102174784A CN102174784A (en) | 2011-09-07 |
| CN102174784B true CN102174784B (en) | 2012-11-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110059765 Expired - Fee Related CN102174784B (en) | 2011-03-14 | 2011-03-14 | Light storage and emission counterfeiting paper and manufacturing method and application thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839574A (en) * | 2012-08-30 | 2012-12-26 | 上海欣旺壁纸有限公司 | Light-storing wallpaper and preparation method thereof |
| CN103643597A (en) * | 2013-12-11 | 2014-03-19 | 周靖云 | Light-storing environment-friendly wallpaper and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221505A (en) * | 1996-04-15 | 1999-06-30 | 德拉鲁国际有限公司 | Document of value |
| CN1301900A (en) * | 1999-12-28 | 2001-07-04 | 迪尼克株式会社 | Anti-fake paper |
| CN2856114Y (en) * | 2005-11-18 | 2007-01-10 | 曹凡 | Light storage luminous anti-fraud paper |
| CN200967918Y (en) * | 2006-11-13 | 2007-10-31 | 佛山市长盛兴隆装饰材料有限公司 | False proof decorative laminate |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2808540B1 (en) * | 2000-05-04 | 2008-11-28 | Thibierge 2 Comar S A | TRANSPARENT AND / OR TRANSLUCENT PAPER OF FLUORESCENT COLOR |
-
2011
- 2011-03-14 CN CN 201110059765 patent/CN102174784B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1221505A (en) * | 1996-04-15 | 1999-06-30 | 德拉鲁国际有限公司 | Document of value |
| CN1301900A (en) * | 1999-12-28 | 2001-07-04 | 迪尼克株式会社 | Anti-fake paper |
| CN2856114Y (en) * | 2005-11-18 | 2007-01-10 | 曹凡 | Light storage luminous anti-fraud paper |
| CN200967918Y (en) * | 2006-11-13 | 2007-10-31 | 佛山市长盛兴隆装饰材料有限公司 | False proof decorative laminate |
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| CN102174784A (en) | 2011-09-07 |
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