CN102173165A - Light-storing luminous anti-counterfeiting film, and manufacturing method and application thereof - Google Patents
Light-storing luminous anti-counterfeiting film, and manufacturing method and application thereof Download PDFInfo
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- CN102173165A CN102173165A CN2011100597767A CN201110059776A CN102173165A CN 102173165 A CN102173165 A CN 102173165A CN 2011100597767 A CN2011100597767 A CN 2011100597767A CN 201110059776 A CN201110059776 A CN 201110059776A CN 102173165 A CN102173165 A CN 102173165A
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Abstract
The invention relates to a light-storing luminous material product, particularly a light-storing luminous anti-counterfeiting film, and a manufacturing method and application thereof. The light-storing luminous anti-counterfeiting film is formed by evenly applying a light-storing luminous ink on a film substrate in a printing mode. The light-storing luminous ink is prepared from the following components in percentage by weight: 20% of white ink, 15% of polyamide resin, 10% of ethyl acetate, 15% of isopropanol, 10% of edible alcohol and 30% of light-storing liquid. The light-storing liquid is a light-storing paint formed by mixing a light-storing pigment and varnish in a weight ratio of 1:1, wherein the light-storing pigment is phosphorescent zinc sulfide ZnS:Cu. The invention mainly solves the problem that the light-storing material phosphorescent zinc sulfide can easily chemically react with heavy metal substances in air, causing deterioration and luminous failure; the light-storing luminous material can be applied on a film substrate, so that the film substrate also has the light-storing luminous effect; and the special film with light-storing luminous performance can be used in the field of anti-counterfeiting.
Description
Technical field
The present invention relates to the light-accumulating luminous material product, particularly a kind of light-accumulated luminous anti false film and manufacture method and application.
Background technology
Light-accumulating luminous material is to have to absorb and storage sunshine or light, and discharges the pigment of the feature of visible light in the dark slowly.Its absorption--storage---luminous cyclic process can go round and begin again heap of times.Therefore, it usually is used to the occasion that need to indicate and decorate, comprises that noctilucence indicates, holds that cursor shows and ornament.
Employed in the market light-storing paint is normally mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint mainly is phosphorescent zinc sulphide (ZnS:Cu).Because this body colour of this light-storing paint is faint yellow, so light-storing paint also is to be faint yellow.Above-mentioned this light-storing paint can be kept visible state 1-2 hours after fully holding light, and under normal operating position, this light-storing paint can keep its light-accumulated luminous functional 3-5, and usually after using 5 years, the light-accumulated luminous characteristic of material is progressively lost, and causes the main cause of light-storing paint loss of function to be: the chemical reaction of heavy metal substance can make its rotten and luminous inefficacy in light-storing paint and the air.
Summary of the invention
The object of the present invention is to provide a kind of light-accumulated luminous anti false film and manufacture method and application, the chemical reaction of heavy metal substance easily and in the air that mainly solves light-storing material phosphorescent zinc sulphide can make the technical problem of its rotten and luminous inefficacy, further can be coated in this light-accumulating luminous material on the film base material, make it also have light-accumulated luminous effect, and this special film with light-accumulated luminous performance is used in false proof field.
For achieving the above object, the present invention realizes like this.
A kind of light-accumulated luminous anti false film is characterized in that: it is evenly to apply light-accumulated luminous printing ink with mode of printing on film base material; Described light-accumulated luminous printing ink according to the composition of percentage by weight is: chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% and hold light liquid 30%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
A kind of manufacture method of light-accumulated luminous anti false film is characterized in that: it comprises the steps that (1) prepares light-accumulated luminous printing ink, the light-accumulated luminous printing ink that (2) will prepare by press printing on film base material.
Described manufacture method, it is characterized in that: in the light-accumulated luminous printing ink of described preparation, earlier chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stir, mixing time is 1 hour, temperature 10-20 ° C; And then will hold the miniature jackhammer that light liquid 30% adds in the container gradually and helical blade is installed in use additional simultaneously and stir, mixing time is 1 hour, temperature 10-20 ° C; Promptly finished the preparation of light-accumulated luminous printing ink.
Described manufacture method, it is characterized in that: behind the light-accumulated luminous printing ink of preparation in 1-5 hour, add this printing ink and add in the ink printer, and under the operating environment of temperature 10-20 ° C, the speed of printing ink with 300 meters/minute is printed on the film base material by ink printer.
Described manufacture method is characterized in that: the thickness of described film base material is the 0.5-60 silk, and the thickness of described light-accumulated luminous ink printing on film base material is the 1-2 silk.
Described light-accumulated luminous anti false film is characterized in that: this light-accumulated luminous anti false film republishes other pattern or literal to be used as the commodity labeling.
Described light-accumulated luminous anti false film is characterized in that: this light-accumulated luminous anti false film republishes other pattern or literal to be used as the commodity packaging film.
The specific embodiment
The invention discloses a kind of light-accumulated luminous anti false film and manufacture method and application.Wherein, described a kind of light-accumulated luminous anti false film is to go up with mode of printing at film base material (as: as polypropylene, or polystyrene) evenly to apply light-accumulated luminous printing ink.To hold light liquid be light-storing paint and contain in the light-accumulated luminous printing ink, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.This light-storing paint is the material of present commonplace employing, therefore, repeats no more its advantage.But when being used to prepare light-accumulated luminous printing ink, we mainly need to consider following some.
1, in order to be that product has long year in service life (30-50), the chemical reaction that just need overcome heavy metal substance in light-storing paint and the air by the improvement of ink formulations can make the problem of its rotten and luminous inefficacy.
2, need in ink formulations, consider how to improve the faint yellow color of light-storing paint.
In addition, in order further to enhance productivity, we also need to consider simultaneously the fast dry characteristic of printing ink when the light-accumulated luminous printing ink of configuration.In order further to guarantee the environmental protection problem in the printing ink production use, we also will consider to avoid using noxious material in configuration printing ink as far as possible.
In view of above-mentioned purpose, light-accumulated luminous printing ink of the present invention according to the composition of percentage by weight is: chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% and hold light liquid 30%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
In the above-mentioned recipe ingredient, the chalk 20% that we use helps to improve color of ink, and printing ink is white in color, and yellowish color can not occur certainly after being printed on the base material.
In the above-mentioned recipe ingredient, polyamide 15%, isopropyl alcohol 15% be mainly as the adhesive of printing ink, helps the printing ink can firm sticking on the base material.Wherein: polyamide presents white usually, grease resistance, and mineral oil and water, water imbibition is big, and has electrical insulating property preferably after the drying.
During above-mentioned prescription was formed, ethyl acetate 10%, isopropyl alcohol 15% all were environmentally friendly solvents, are particularly suitable for ink product.
During above-mentioned prescription was formed, edible alcohol 10% had non-toxic nature, and it adds and helps in the ink formulations to do soon behind the ink printing, helps to promote production efficiency.
During above-mentioned prescription is formed; be very beneficial for prolonging the function retention time of light-accumulated luminous printing ink after the adding of polyamide 15%; reason is: have electrical insulating property preferably after the polyamide drying; therefore be easy to the micronic dust in the absorbed air behind the last static; as the ink material that contains polyamide that is coated on the base material; its suction-operated helps forming one deck natural containment by the absorption micronic dust on the ink printing face; this protective layer helps phosphorescent zinc sulphide ZnS:Cu and the airborne heavy metal material in the isolated printing ink to produce chemical reaction, and then has prolonged the service life of light-accumulating luminous material.
The manufacture method of a kind of light-accumulated luminous anti false film of the present invention, it comprises the steps that (1) prepares light-accumulated luminous printing ink, the light-accumulated luminous printing ink that (2) will prepare by press printing on film base material.
In the light-accumulated luminous printing ink of described preparation, earlier chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stir, mixing time is 1 hour, temperature 10-20 ° C; And then will hold the miniature jackhammer that light liquid 30% adds in the container gradually and helical blade is installed in use additional simultaneously and stir, mixing time is 1 hour, temperature 10-20 ° C; Promptly finished the preparation of light-accumulated luminous printing ink.
Because the light-accumulated luminous printing ink of the present invention has fast dry characteristic, therefore be preferably in behind the light-accumulated luminous printing ink of preparation and print use in 1-5 hour, and before printing is used, printing ink is stored in the low temperature environment of vacuum environment, 5-10 ° C.In the concrete operations, add this printing ink add in ink printer (such as: Heidelberg printing machine model DCC450), and under the operating environment of temperature 10-20 ° C, the speed of printing ink with 300 meters/minute is printed on the film base material by ink printer.The common ink print speed printing speed is 500 meters/minute, because printing ink of the present invention has fast dry characteristic, so print speed printing speed can promote one times nearly.The thickness of described film base material is the 0.5-60 silk, and the thickness of described light-accumulated luminous ink printing on film base material is the 1-2 silk.
Through detecting, by the film base material that said method is made, its luminous brightness of holding behind the light can reach 1Min1.6*10
2MCD/m
2, 2Min0.5*10
2MCD/m
2, 5Min0.2*10
2MCD/m
2, 10Min0.1*10
2MCD/m
2, be higher than the 1Min of correlation technique standard code far away〉and 120MCD/m
2, 2Min〉and 40MCD/m
2, 5Min〉and 15MCD/m
2, 10Min〉and 8MCD/m
2The shelf-life of this product can reach 30-50.
This light-accumulated luminous anti false film republishes other pattern or literal being used as the commodity labeling, and this light-accumulated luminous anti false film republishes other pattern or literal to be used as the commodity packaging film.
In sum, be preferred embodiment of the present invention only, be not to be used for limiting practical range of the present invention, promptly all equivalences of doing according to the content of the present patent application claim change and modify, and all should be technology category of the present invention.
Claims (7)
1. light-accumulated luminous anti false film is characterized in that: it is evenly to apply light-accumulated luminous printing ink with mode of printing on film base material; Described light-accumulated luminous printing ink according to the composition of percentage by weight is: chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% and hold light liquid 30%; The described light liquid that holds is light-storing paint, and it is mixed by the part by weight according to 1:1 of light-storing paint and varnish, and wherein, described light-storing paint is phosphorescent zinc sulphide ZnS:Cu.
2. the manufacture method of a light-accumulated luminous anti false film, it is characterized in that: it comprises the steps that (1) prepares light-accumulated luminous printing ink, the light-accumulated luminous printing ink that (2) will prepare by press printing on film base material.
3. manufacture method according to claim 2, it is characterized in that: in the light-accumulated luminous printing ink of described preparation, earlier chalk 20%, polyamide 15%, ethyl acetate 10%, isopropyl alcohol 15%, edible alcohol 10% are added in the container and with the miniature jackhammer that installs helical blade additional and stir, mixing time is 1 hour, temperature 10-20 ° C; And then will hold the miniature jackhammer that light liquid 30% adds in the container gradually and helical blade is installed in use additional simultaneously and stir, mixing time is 1 hour, temperature 10-20 ° C; Promptly finished the preparation of light-accumulated luminous printing ink.
4. manufacture method according to claim 3, it is characterized in that: behind the light-accumulated luminous printing ink of preparation in 1-5 hour, adding this printing ink adds in the ink printer, and under the operating environment of temperature 10-20 ° C, the speed of printing ink with 300 meters/minute is printed on the film base material by ink printer.
5. manufacture method according to claim 4 is characterized in that: the thickness of described film base material is the 0.5-60 silk, and the thickness of described light-accumulated luminous ink printing on film base material is the 1-2 silk.
6. light-accumulated luminous anti false film according to claim 1 is characterized in that: this light-accumulated luminous anti false film republishes other pattern or literal to be used as the commodity labeling.
7. light-accumulated luminous anti false film according to claim 1 is characterized in that: this light-accumulated luminous anti false film republishes other pattern or literal to be used as the commodity packaging film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100597767A CN102173165A (en) | 2011-03-14 | 2011-03-14 | Light-storing luminous anti-counterfeiting film, and manufacturing method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100597767A CN102173165A (en) | 2011-03-14 | 2011-03-14 | Light-storing luminous anti-counterfeiting film, and manufacturing method and application thereof |
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|---|---|
| CN102173165A true CN102173165A (en) | 2011-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100597767A Pending CN102173165A (en) | 2011-03-14 | 2011-03-14 | Light-storing luminous anti-counterfeiting film, and manufacturing method and application thereof |
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| CN (1) | CN102173165A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106847071A (en) * | 2017-03-22 | 2017-06-13 | 北京康得新功能材料有限公司 | A kind of false-proof film of random grain |
| CN110246436A (en) * | 2018-03-09 | 2019-09-17 | 东莞市锐泽创艺新材料有限公司 | A kind of light storage paper and preparation method thereof |
| CN111511541A (en) * | 2017-12-19 | 2020-08-07 | 鹤卷京彦 | Sheet member |
| CN112080213A (en) * | 2020-08-31 | 2020-12-15 | 晋江联兴反光材料有限公司 | Preparation method of flame-retardant light-storing film |
| CN112838169A (en) * | 2020-12-31 | 2021-05-25 | 湖南鼎一致远科技发展有限公司 | Electroluminescent device of metal base material and preparation method |
| CN113990219A (en) * | 2021-10-25 | 2022-01-28 | 苏州赛维智能科技有限公司 | Method for manufacturing ink transfer light storage label |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1402204A (en) * | 2002-09-25 | 2003-03-12 | 张振东 | Method for mfg. energy-storage luminous antiforging sign number plate |
| CN2797027Y (en) * | 2005-04-29 | 2006-07-19 | 曹其焕 | Light storage luminous antiforge fransfer film |
| CN2856114Y (en) * | 2005-11-18 | 2007-01-10 | 曹凡 | Light storage luminous anti-fraud paper |
-
2011
- 2011-03-14 CN CN2011100597767A patent/CN102173165A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1402204A (en) * | 2002-09-25 | 2003-03-12 | 张振东 | Method for mfg. energy-storage luminous antiforging sign number plate |
| CN2797027Y (en) * | 2005-04-29 | 2006-07-19 | 曹其焕 | Light storage luminous antiforge fransfer film |
| CN2856114Y (en) * | 2005-11-18 | 2007-01-10 | 曹凡 | Light storage luminous anti-fraud paper |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106847071A (en) * | 2017-03-22 | 2017-06-13 | 北京康得新功能材料有限公司 | A kind of false-proof film of random grain |
| CN106847071B (en) * | 2017-03-22 | 2024-06-07 | 张家港保税区康得菲尔实业有限公司 | Random texture anti-counterfeiting film |
| CN111511541A (en) * | 2017-12-19 | 2020-08-07 | 鹤卷京彦 | Sheet member |
| CN110246436A (en) * | 2018-03-09 | 2019-09-17 | 东莞市锐泽创艺新材料有限公司 | A kind of light storage paper and preparation method thereof |
| CN112080213A (en) * | 2020-08-31 | 2020-12-15 | 晋江联兴反光材料有限公司 | Preparation method of flame-retardant light-storing film |
| CN112838169A (en) * | 2020-12-31 | 2021-05-25 | 湖南鼎一致远科技发展有限公司 | Electroluminescent device of metal base material and preparation method |
| CN113990219A (en) * | 2021-10-25 | 2022-01-28 | 苏州赛维智能科技有限公司 | Method for manufacturing ink transfer light storage label |
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Application publication date: 20110907 |