CN101923804A - Anti-counterfeiting fragile self-adhesive paper and preparation method thereof - Google Patents
Anti-counterfeiting fragile self-adhesive paper and preparation method thereof Download PDFInfo
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- CN101923804A CN101923804A CN 200910062657 CN200910062657A CN101923804A CN 101923804 A CN101923804 A CN 101923804A CN 200910062657 CN200910062657 CN 200910062657 CN 200910062657 A CN200910062657 A CN 200910062657A CN 101923804 A CN101923804 A CN 101923804A
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- paper
- counterfeiting
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- adhesive paper
- fragile
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- 239000000853 adhesive Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 25
- 238000007639 printing Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- -1 Acryl Chemical group 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 2
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 2
- 238000003854 Surface Print Methods 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000011425 bamboo Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000004973 liquid crystal related substance Substances 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 239000008159 sesame oil Substances 0.000 claims description 2
- 235000011803 sesame oil Nutrition 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 238000007789 sealing Methods 0.000 abstract description 6
- 230000000007 visual effect Effects 0.000 abstract description 3
- 239000010410 layer Substances 0.000 abstract 6
- 239000012790 adhesive layer Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
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Abstract
The invention discloses anti-counterfeiting fragile self-adhesive paper belonging to self-adhesive paper for sealing products and a preparation method thereof. The anti-counterfeiting fragile self-adhesive paper sequentially comprises a release paper layer, a self-adhesive layer, a base paper layer and a printing layer from bottom to top, wherein the base paper layer is an instant tearing fragile paper layer which is internally provided with dispersedly distributed anti-counterfeiting fiber layers. The invention also discloses a preparation method of the anti-counterfeiting fragile self-adhesive paper. The anti-counterfeiting fragile self-adhesive paper of the invention is extremely fragile paper and is broken into small pieces instead of large pieces if only opened as a seal, is impossible to fully restore, has a visual infrared, ultraviolet and temperature-change obvious anti-counterfeiting mark and therefore is excellent anti-counterfeiting fragile self-adhesive paper.
Description
Technical field
The invention belongs to commodity and seal with self-adhesive paper and preparation method thereof, be specifically related to a kind of multiple anti-fraud functional frangible self-adhesive papers such as infrared, ultraviolet, temperature change and preparation method thereof that have.
Background technology
In the prior art, fragile self-adhesive paper has been important a kind of in the self-adhesive paper.It needing to be widely used in the material of guarantee or the sealing part of article in daily life; can play false proof; the effect of imitative unpacking; the fragile self-adhesive paper that is commercially available is made important source material by wood pulp usually; so often will cut down large quantities of trees during fabrication; like this to environmental protection; the protection ecologic equilibrium is particularly unfavorable; secondly; the broken broken effect of this fragile self-adhesive paper is relatively poor; in use sometimes with fragile paper when the article sealing part is opened; also retaining part adhesion of fragile paper can not be broken into tiny comminution under external force, has so directly had influence on its result of use.The company of present domestic grasp fragile paper production technology is more, and the not good self-adhesive paper antiforge function of crushing effect is relatively poor during Kaifeng of prior art, for reaching real false proof, also needs fragile paper is carried out many-sided improvement.
Summary of the invention
At the above-mentioned deficiency of prior art, one of the technical problem to be solved in the present invention provides a kind of anti-counterfeiting fragile self-adhesive paper, and it has multiple antiforge functions such as infrared, ultraviolet, temperature change, when sealing with it, in case play envelope, seal paper and promptly be broken into fragment, the exhausted possibility of not having recovery.Simultaneously, the present invention also provides the method for the anti-counterfeiting fragile self-adhesive paper for preparing this specific function.
Technical scheme of the present invention is: anti-counterfeiting fragile self-adhesive paper, be followed successively by off-style paper layer, non-drying glue layer, base paper layer, printed layers from the bottom to top, and described base paper layer is a kind of frangible ply of paper crushed after a tearing.
Be provided with the anti-false fiber layer that disperses distribution in the described frangible ply of paper.
Described anti-false fiber layer becomes in the fiber one or more by infrared fibre, ultraviolet fibre, liquid crystal temperature and forms.
Described frangible ply of paper is made up of the material of following component and percent by weight:
Inserts 16%～20%;
Acryl resin 28%～32%;
Organic solvent 45%～55%;
Additive 1%～3%;
In said mixture, add entry and mix, add 0.5～2kg water in the potpourri of every 100kg;
Described inserts is one or more the potpourri in porcelain earth, titanium dioxide, the barium sulphate;
Described organic solvent is the different basic ketone of ethyl acetate or methyl, or their potpourri;
Described additive is auxiliary agent polyglycol ether, wetting agent phosphate ester salt, the potpourri of anti-settling agent hydrogenation thin bamboo strip sesame oil, defoamer siloxane.
The preparation method of anti-counterfeiting fragile self-adhesive paper carries out according to the following steps successively:
(1), following material is pressed its percent by weight mixing and stirring:
Inserts 16%～20%;
Acryl resin 28%～32%;
Organic solvent 45%～55%;
Additive 1%～3%;
In said mixture, add entry and mix, add 0.5～2kg water in the potpourri of every 100kg;
(2) in said mixture, add 0.5%～2% anti-false fiber, and mixing and stirring, this potpourri is the pulpous state raw material of false proof fragile paper;
(3) the pulpous state raw material with above-mentioned false proof fragile paper evenly is applied on the middle release liners, and coating thickness 0.25mm～0.35mm after the drying moulding, presses the rewinding rolling through the shape-moulding wand volume again;
(4) the surface printing printed layers of the paper roll that obtains in step (3);
(5) the above-mentioned paper roll that has printed layers that step (4) is obtained separates with middle release liners, at the bottom surface of paper roll coating adhesive sticker, and makes its bottom surface and another release liners compound; Gained is anti-counterfeiting fragile self-adhesive paper.
The anti-false fiber of described step (2) becomes in the fiber one or more by infrared fibre, ultraviolet fibre, temperature and forms.
The printing of described step (4) is with semiarid UV (ultraviolet) printing ink the literal of appointment and pattern to be imprinted on the transfer membrane earlier, and the literal and the graphics of transfer being moved on the film are incorporated into the paper roll surface again, carries out UV (ultraviolet) lamp again and solidifies.
Anti-counterfeiting fragile self-adhesive paper of the present invention is a kind of very frangible paper, when sealing with it, this paper will be ground into very little sheet in case break seal, never have large stretch of possibility that exists, there is not restorable possibility fully yet, and have the obvious anti-counterfeiting mark that visual infrared, ultraviolet, temperature become, be a kind of very good anti-counterfeiting fragile self-adhesive paper.
Description of drawings
Accompanying drawing 2 is anti-counterfeiting fragile self-adhesive paper one embodiment sectional structure synoptic diagram.
Mark division in the accompanying drawing is as follows: the frangible ply of paper of 1-; The 2-off-style paper layer; The 3-printed layers; The 4-non-drying glue layer; 5-anti-false fiber layer.
Embodiment
Below in conjunction with accompanying drawing relevant technologies problem of the present invention and embodiment are described in further detail.As shown in Figure 2, the base paper layer of anti-counterfeiting fragile self-adhesive paper of the present invention is frangible ply of paper 1, and the less anti-false fiber layer 5 of area that disperses distribution is arranged in frangible ply of paper 1.When using anti-counterfeiting fragile self-adhesive paper of the present invention, its off-style paper layer 2 is peeled off, non-drying glue layer 4 is bonded at sealing part, seal when slightly acting force being arranged on the paper at this, this fragile paper will be broken for tiny tablet soon, and this anti-counterfeiting fragile self-adhesive paper can not be torn and answer sticking.This fragile paper is made raw material without wood pulp, has saved natural resources.And, owing in frangible ply of paper 1, be provided with anti-false fiber layer 5, make this anti-counterfeiting fragile self-adhesive paper when infrared light, ultraviolet light or temperature variation, present corresponding color, have very strong antiforge function.The printed layers 3 of this anti-counterfeiting fragile self-adhesive paper is one or more layers, and printed layers 3 is common printed layer or laser hologram and text printout layer.
Be technological process signal of the present invention as shown in Figure 1.Inserts, organic solvent, additive, acryl resin in proportion after the mixing and stirring, are added anti-false fiber, mixing and stirring again, treat that it becomes pulpous state after, add an amount of water again, stir once more, obtain the pulpous state raw material.The oven temperature of coating machine is adjusted to 65 ℃-75 ℃, shape-moulding wand speed is transferred to the rotating speed about 350m/h, with the poor position that rises to energy dip coating rod of glue, to be coated with the rod coating thickness according to the thickness requirement of paper then and be transferred to 0.25mm-0.35mm, release liners is loaded onto coating machine, the pulpous state raw material is evenly coated on the release liners, after the oven for drying moulding, press through the shape-moulding wand volume again, the rewinding rolling, at this moment promptly become the package fragile paper, last layer release liners peelled off, the package fragile paper of making is coated adhesive sticker through coating machine at opposite side again, and the compound release liners that goes up, promptly be made for described fragile self-adhesive paper.The anti-counterfeiting fragile self-adhesive paper that method of the present invention is produced has outside the frangible characteristics, also has the variation that the energy visual observations arrives color when infrared, ultraviolet, temperature variation, is easy to identification.And its manufacturing process is special, prevents emitting fraud all relatively more difficult, thereby for manufacturer has created a relatively external environment condition of safety, helps enterprise development.
Claims (10)
1. an anti-counterfeiting fragile self-adhesive paper is followed successively by off-style paper layer, non-drying glue layer, base paper layer, printed layers from the bottom to top, it is characterized in that: described base paper layer is a kind of frangible ply of paper crushed after a tearing (1).
2. anti-counterfeiting fragile self-adhesive paper according to claim 1 is characterized in that: be provided with the anti-false fiber layer (5) that disperses distribution in the described frangible ply of paper (1).
3. anti-counterfeiting fragile self-adhesive paper according to claim 2 is characterized in that: described anti-false fiber layer (5) becomes in the fiber one or more by infrared fibre, ultraviolet fibre, liquid crystal temperature and forms.
4. anti-counterfeiting fragile self-adhesive paper according to claim 1 is characterized in that: described frangible ply of paper (1) is made up of the material of following component and percent by weight:
Inserts 16%～20%;
Acryl resin 28%～32%;
Organic solvent 45%～55%;
Additive 1%～3%;
In said mixture, add entry and mix, add 0.5kg～2kg water in the potpourri of every 100kg.
5. anti-counterfeiting fragile self-adhesive paper according to claim 4 is characterized in that: described inserts is one or more the potpourri in porcelain earth, titanium dioxide, the barium sulphate.
6. anti-counterfeiting fragile self-adhesive paper according to claim 4 is characterized in that: described organic solvent is the different basic ketone of ethyl acetate or methyl, or their potpourri.
7. anti-counterfeiting fragile self-adhesive paper according to claim 4 is characterized in that: described additive is auxiliary agent polyglycol ether, wetting agent phosphate ester salt, the potpourri of anti-settling agent hydrogenation thin bamboo strip sesame oil, defoamer siloxane.
8. the preparation method of an anti-counterfeiting fragile self-adhesive paper is characterized in that described method carries out according to the following steps successively:
(1), following material is pressed its percent by weight mixing and stirring:
Inserts 16%～20%;
Acryl resin 28%～32%;
Organic solvent 45%～55%;
Additive 1%～3%;
In said mixture, add entry and mix, add 0.5～2kg water in the potpourri of every 100kg;
(2) in said mixture, add 0.5%～2% anti-false fiber, and mixing and stirring, this potpourri is the pulpous state raw material of false proof fragile paper;
(3) the pulpous state raw material with above-mentioned false proof fragile paper evenly is applied on the middle release liners, and coating thickness 0.25mm～0.35mm after the drying moulding, presses the rewinding rolling through the shape-moulding wand volume again;
(4) the surface printing printed layers of the paper roll that obtains in step (3);
(5) the above-mentioned paper roll that has printed layers that step (4) is obtained separates with middle release liners, at the bottom surface of paper roll coating adhesive sticker, and makes its bottom surface and another release liners compound; Gained is anti-counterfeiting fragile self-adhesive paper.
9. the preparation method of anti-counterfeiting fragile self-adhesive paper according to claim 6, the anti-false fiber that it is characterized in that described step (2) becomes in the fiber one or more by infrared fibre, ultraviolet fibre, temperature and forms.
10. the preparation method of anti-counterfeiting fragile self-adhesive paper according to claim 6, the printing that it is characterized in that described step (4) is with semiarid UV printing ink the literal of appointment and pattern to be imprinted on the transfer membrane earlier, the literal and the graphics of transfer being moved on the film are incorporated into the paper roll surface again, carry out the UV lamp again and solidify.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910062657 CN101923804A (en) | 2009-06-11 | 2009-06-11 | Anti-counterfeiting fragile self-adhesive paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910062657 CN101923804A (en) | 2009-06-11 | 2009-06-11 | Anti-counterfeiting fragile self-adhesive paper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101923804A true CN101923804A (en) | 2010-12-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910062657 Pending CN101923804A (en) | 2009-06-11 | 2009-06-11 | Anti-counterfeiting fragile self-adhesive paper and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN101923804A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102248731A (en) * | 2011-05-11 | 2011-11-23 | 深圳市摩码科技有限公司 | Preparation method and device of fragile paper |
| CN102321999A (en) * | 2011-05-11 | 2012-01-18 | 深圳市摩码科技有限公司 | Improved easy-to-tear paper |
| CN102529273A (en) * | 2012-01-06 | 2012-07-04 | 佛山市塑兴母料有限公司 | Brittle film |
| CN102945641A (en) * | 2012-11-27 | 2013-02-27 | 武汉华工图像技术开发有限公司 | Fragile scrapable holographic digital anti-counterfeiting label and manufacturing method thereof |
| CN102941724A (en) * | 2012-11-27 | 2013-02-27 | 卫辉市凌锋特种纸有限公司 | Production process of packaging composite base material |
| CN104050492A (en) * | 2013-03-13 | 2014-09-17 | 深圳市华阳微电子股份有限公司 | Fragile paper anti-fake RFID label and preparation method thereof |
| CN105568749A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Frangible non-setting adhesive paper and preparation method thereof |
| CN105568738A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Pearl decorative paper and preparation method thereof |
| CN105788447A (en) * | 2014-12-15 | 2016-07-20 | 竹林伟业科技发展（天津）股份有限公司 | Fragile anti-counterfeit label |
| CN106221547A (en) * | 2016-08-19 | 2016-12-14 | 汕头市龙湖昌丰化工有限公司 | Random distribution has the transferable coating of fiber and the antifalsification label containing this coating |
| CN106835838A (en) * | 2017-02-13 | 2017-06-13 | 深圳市冠宝胶粘制品有限公司 | Shielding fragile paper high and preparation method thereof |
| CN107867100A (en) * | 2017-11-28 | 2018-04-03 | 任福海 | Position flower pattern transfer membrane and its manufacture craft |
| CN107901649A (en) * | 2017-11-28 | 2018-04-13 | 任福海 | Lines transfer membrane and its manufacture craft |
| CN109377863A (en) * | 2018-12-25 | 2019-02-22 | 广州山木新材料科技有限公司 | A kind of frangible antifalsification label and preparation method thereof that polychrome is random |
| CN109461366A (en) * | 2018-12-25 | 2019-03-12 | 广州山木新材料科技有限公司 | A kind of frangible antifalsification label and preparation method thereof orienting random fibre |
-
2009
- 2009-06-11 CN CN 200910062657 patent/CN101923804A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102248731A (en) * | 2011-05-11 | 2011-11-23 | 深圳市摩码科技有限公司 | Preparation method and device of fragile paper |
| CN102321999A (en) * | 2011-05-11 | 2012-01-18 | 深圳市摩码科技有限公司 | Improved easy-to-tear paper |
| CN102248731B (en) * | 2011-05-11 | 2014-10-29 | 深圳市摩码科技有限公司 | Preparation method and device of fragile paper |
| CN102529273A (en) * | 2012-01-06 | 2012-07-04 | 佛山市塑兴母料有限公司 | Brittle film |
| CN102945641A (en) * | 2012-11-27 | 2013-02-27 | 武汉华工图像技术开发有限公司 | Fragile scrapable holographic digital anti-counterfeiting label and manufacturing method thereof |
| CN102941724A (en) * | 2012-11-27 | 2013-02-27 | 卫辉市凌锋特种纸有限公司 | Production process of packaging composite base material |
| CN104050492A (en) * | 2013-03-13 | 2014-09-17 | 深圳市华阳微电子股份有限公司 | Fragile paper anti-fake RFID label and preparation method thereof |
| CN105788447A (en) * | 2014-12-15 | 2016-07-20 | 竹林伟业科技发展（天津）股份有限公司 | Fragile anti-counterfeit label |
| CN105568738A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Pearl decorative paper and preparation method thereof |
| CN105568749A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Frangible non-setting adhesive paper and preparation method thereof |
| CN106221547A (en) * | 2016-08-19 | 2016-12-14 | 汕头市龙湖昌丰化工有限公司 | Random distribution has the transferable coating of fiber and the antifalsification label containing this coating |
| CN106835838A (en) * | 2017-02-13 | 2017-06-13 | 深圳市冠宝胶粘制品有限公司 | Shielding fragile paper high and preparation method thereof |
| CN107867100A (en) * | 2017-11-28 | 2018-04-03 | 任福海 | Position flower pattern transfer membrane and its manufacture craft |
| CN107901649A (en) * | 2017-11-28 | 2018-04-13 | 任福海 | Lines transfer membrane and its manufacture craft |
| CN109377863A (en) * | 2018-12-25 | 2019-02-22 | 广州山木新材料科技有限公司 | A kind of frangible antifalsification label and preparation method thereof that polychrome is random |
| CN109461366A (en) * | 2018-12-25 | 2019-03-12 | 广州山木新材料科技有限公司 | A kind of frangible antifalsification label and preparation method thereof orienting random fibre |
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Application publication date: 20101222 |