CN102174289A - Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof - Google Patents
Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof Download PDFInfo
- Publication number
- CN102174289A CN102174289A CN2011100450565A CN201110045056A CN102174289A CN 102174289 A CN102174289 A CN 102174289A CN 2011100450565 A CN2011100450565 A CN 2011100450565A CN 201110045056 A CN201110045056 A CN 201110045056A CN 102174289 A CN102174289 A CN 102174289A
- Authority
- CN
- China
- Prior art keywords
- group
- aluminum alloy
- alloy material
- radicals
- colloidal sol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses surface anti-corrosion sol for an aeronautic aluminum alloy material and a treatment method thereof in the technical field of aluminum alloy surface treatment. The sol comprises the following components in percentage by weight: 1-15 percent of organosiloxane, 45-93 percent of organic solvent, 0.1-10 percent of additive, 0.5-10 percent of rare earth salt, 5-50 percent of deionized water and 0.1-5 percent of catalyst. In the invention, a coating with a compact netlike crosslinking structure is formed on the surface of an aluminum alloy matrix and has high chemical stability and thermal stability, so that influence of an external acidic and alkaline environment and temperature variation on the coating can be resisted; and the coating has higher mechanical strength, rain washing resistance, friction resistance and scratch resistance. The technical method is simple, is easy and convenient to operate, does not have high requirement on equipment and is environmentally-friendly and pollution-free.
Description
Technical field
What the present invention relates to is a kind of coating and implementation method thereof of aluminum alloy surface processing technology field, specifically is a kind of surface anticorrosion colloidal sol and treatment process thereof that is used for aviation aluminum alloy material.
Background technology
Traditional aluminum alloy surface treatment technology has technology such as anodic oxidation, chemical oxidation, plating and differential arc oxidation.Wherein the chemical oxide film of chemical oxidization method preparation has advantages such as little to the fatigue property influence of aluminum alloy materials, that technology is simple, cost is low, formation speed is fast, tack is good, usually sprays the pre-treating process of priming paint and coating as aluminium alloy.The representative treatment process of chemical oxidization method is a chromic salt chemistry oxidation style at present, aluminium alloy is behind chromate treating, form the high adhesion veneer thing of layer of metal chromic salt on its surface, make its solidity to corrosion be significantly improved, can also strengthen the bonding force of priming paint and matrix surface.But this method has many shortcomings, is the height carcinogenic substance as wherein hexavalent chromate, and is extremely serious to the pollution of environment; And these technologies will be used strong acid, highly basic in steeping vat, this all needs a large amount of water to clean to remain in the excessive treatment soln of article surface, but also need handle again used process waste liquor and Cleaning Wastewater, this treating processes environmental cost is very big, cost is high, and everything has all increased the cost of wet chemical process.
Present the most frequently used chromic salt chemistry oxidation style in the chemical oxidization method is though can make the solidity to corrosion of aluminium alloy be significantly improved.But the shortcoming of this technological method is also very remarkable, is the extremely disagreeableness height carcinogenic substance of a kind of environment as the hexavalent chromate that occurs in its technological process; And the strong acid that uses in these technological processs (comprising fluorine-containing strong acid), highly basic, and a large amount of rinse water of using in the technological process, all produce a large amount of process waste liquors and Cleaning Wastewater in process of production, advocate in the current whole world under the overall background of environmental protection low-carbon (LC), the processing of these waste liquids and waste water all is that this technology has been brought great environmental problem and high environmental treatment cost.It is simple that this just presses for a kind of method of research, and technological operation is easy, and is not high to equipment requirements, environmental friendliness, the pollution-free new technology of top coat cheaply.
Find through retrieval prior art, the colloidal sol of the organo-siloxane that Materials Letters 42 (2000) 326-330 have put down in writing can form the film of one deck build 200 to 1500nm at metal or its alloy surface, this coating can strengthen matrix and priming paint that applies subsequently and the sticking power between coating greatly, because coating itself is thin and have textural defect such as micropore, makes the erosion resistance of itself strong inadequately.
In order to improve the antiseptic property of sol-gel coating, the two polysulfur silanes of document description employing are arranged and add nano aluminium oxide or nanometer silicon dioxide particle, just can make sol-gel coating with better antiseptic property.But compare with the chromate treating layer, this coating does not have self-repair function, and when running into external force collision, scraping, the exposed aluminum alloy surface in coating damage place just begins quick corrosion.Journal of Rare Earths, Vol 28, No.1, Feb.2010 has put down in writing among the 117-122, prepares two coatings that sol-gel coating and rare earth coating combine in aluminum alloy surface, in order to improve the performance of corrosion protection coating.But this method needs twice coating, and twice drying increased operation steps, strengthened technology difficulty and production cost.
Summary of the invention
The present invention is directed to the prior art above shortcomings, a kind of surface anticorrosion colloidal sol and treatment process thereof that is used for aviation aluminum alloy material is provided, can form one deck on the aluminum alloy base material surface and have the coating of fine and close cross-linked network, and this coating has fine chemical stability and thermostability, can resist the influence to coating of extraneous acid or alkali environment and temperature variation; Higher physical strength is arranged, and anti-rainwash also has wear-resisting wiping and scraping and wiping resistance performance.This technological method is simple, easy and simple to handle, and is not high to equipment requirements, and environmental friendliness, pollution-free.
The present invention is achieved by the following technical solutions:
The present invention relates to a kind of surface anticorrosion colloidal sol that is used for aviation aluminum alloy material, its component and content are: 1～15wt% organo-siloxane, 45～93wt% organic solvent, 0.1～10% additive, 0.5～10wt% rare-earth salts, 5～50wt% deionized water and 0.1～5wt% catalyzer.
Described organic solvent is the Fatty Alcohol(C12-C14 and C12-C18) of 1 to 10 carbon atom.
The structural formula of described organo-siloxane is: [Si (R
1) (R
2)
3]
n, wherein: n=1 or 2, promptly contain one or two radicals R on a Siliciumatom
1And 2 or 3 radicals R
2Or on two adjacent Siliciumatoms and each Siliciumatom respectively contain one or two radicals R
1And 2 or 3 radicals R
2, be preferably: a radicals R
1And this group is inseparable and non-hydrolysable and contain 3 radicals R
2And this group hydrolyzable also can be removed.
Described radicals R
1For methyl, ethyl, propyl group, just-butyl, isobutyl-, sec-butyl, the tertiary butyl, propyl disulfide group, vinyl, 1-propenyl, 2-propenyl, butenyl group, ethynyl, proyl group, phenyl, naphthyl group, methacryloyl, methacryloyl oxygen propyl group, glycidyl, glycidoxypropyl group, ammonia aryl or aminoalkyl group.
Described radicals R
2For methoxyl group, oxyethyl group, just-propoxy-, different-propoxy-, just-butoxy, different-butoxy, the second month in a season-butoxy, uncle-butoxy, just-pentyloxy, just-hexyloxy group, ring propoxy-, cyclohexyloxy, phenoxy group, acyloxy, acetoxyl group, propionyloxy or ethanoyl;
Described organo-siloxane is selected from and is vinyltriethoxysilane, the propenyl triethoxyl silane, the 3-aminopropyltriethoxywerene werene, 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE, 3-Racemic glycidol propyl-triethoxysilicane, 3-sulfydryl propyl-triethoxysilicane, N-(2-amino-ethyl)-3-aminopropyltriethoxywerene werene, N-[N '-(2 '-amino-ethyl)-2-amino-ethyl]-3-aminopropyl-triethoxyl silane, N-phenyl amino propyl-triethoxysilicane, two-(the silica-based propyl group of 3-(triethoxy)) tetrasulfide or two-(the silica-based propyl group of 3-(triethoxy)) ethane are preferably two-(the silica-based propyl group of 3-(triethoxy)) tetrasulfide.
Described catalyzer is aliphatics monocarboxylic acid such as acetate, di-carboxylic acid and tribasic carboxylic acid such as citric acid, nitric acid, hydrochloric acid, thanomin, triethylamine or its mixing.
Described additive is nanometer SiO
2Particle, its particle diameter are the 50-100 nanometer.
Described rare-earth salts is the hydrate of cerous nitrate, the hydrate of cerium oxide, the hydrate or the cerium stearate of cerous acetate.
The present invention relates to the surface anticorrosive treatment method of above-mentioned surface anticorrosion colloidal sol, by carrying out maturation process after organo-siloxane, organic solvent, additive, rare-earth salts, deionized water and the catalyst mix, spray, brush or be immersed in matrix surface after again the mixture after the slaking being filtered, the deposition back forms coating at matrix surface, realizes the surface anticorrosion processing.
Spraying, brush or dipping after deposition process in heat, Heating temperature is to heat 1 second to 2 hour under 50 to 150 ℃ of temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush.
Described filtration is meant: the elimination size is from the impurity particle of hundreds of nanometer to 20 micron.
Described matrix is selected from aluminium alloy, preferred aerolite 2024 and 7075.
The method of sol-gel coating technology disclosed by the invention is simple, easy and simple to handle, quick, reliable, and required cost is low, this method can be simply with lower cost, in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of body material, and need not to carry out other adjustment on the equipment substantially.This method does not almost have other loss to the utilization ratio height of sol solutions except that the small molecules product (for example water and ethanol etc.) of condensation gained, be the Eco-power production technique of a kind of height.
Description of drawings
Fig. 1 is the embodiment design sketch;
Among the figure: be (a) without the aluminium alloy 2024 of any processing figure as a result behind 168 hours neutral salt spray tests; (b) be aluminium alloy 2024 figure as a result after the sol-gel coating in embodiment 1; (c) be that aluminium alloy 2024 is in embodiment 1 after the sol-gel coating, again through the figure as a result behind 168 hours neutral salt spray tests.
Embodiment
Below embodiments of the invention are elaborated, present embodiment is being to implement under the prerequisite with the technical solution of the present invention, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1:
1. the preparation of sol-gel solution
With the catalyzer of the additive of 30 milliliters of organo-siloxanes and 750 milliliters of organic solvents and 1wt%, 0.5wt% rare-earth salts, 1wt% and appropriate amount of deionized water totally 1000 milliliters mix and stir, churning time is 5 minutes to 1 hour;
For accelerating hydrolysis rate, also can be heated to 40 to 60 ℃;
As preparation (18 ℃ to 25 ℃) at normal temperatures, after stirring, also need to leave standstill 48 hours to 60 hours and carry out slaking; Filter sol solutions in the laboratory with quantitative paper at a slow speed, move into airtight preservation in the clean container, stand-by.
2. colloidal sol is applied to (following description is with the example that is embodied as on aluminium alloy 2024 prints) on the body material
2.1 the cleaning surfaces of body material and activation:
Clean the surface of print with tap water, sanitising agent; At room temperature flood print 10 minutes with alkaline cleansing agent, remove the grease on print surface, and with tap water and washed with de-ionized water print; With the nitration mixture treatment solution room temperature dipping print 10 minutes with deoxidation, with tap water and washed with de-ionized water print; Under 50 ℃ of temperature, flooded print 10 to 15 minutes with alkali lye, with the surface of activation print, with tap water and washed with de-ionized water print; With the hot-air dry print, standby (print needs coating in a hour)
2.2 the coating of sol solutions:
The print of handling well is placed on spray chamber's inner support, the sol solutions for preparing is coated to the surface of print, adjust spray distance and spray gun setting, make colloidal sol cover the surface of print equably, and make sol solutions be no less than 30 seconds to be advisable in the print surface residence time; Place print temperature to be arranged on 110 ℃ baking oven, dry one hour; Take out the print naturally cooling.
3. the shape and the detection of sol-gel liquid coating back print
As shown in Figure 1, the present embodiment preparation forms the print surfacing of sol-gel coating, smooth, even, flawless, nothing depression, and coating is transparent complete; Tack to the alloy matrix aluminum material is good, the smooth no perk of coating; The priming paint that is applied on the sol-gel coating there is good bonding force, the bonding force of itself and priming paint is tested, all reach very good effect (detect and all obtain best test result) with dry method and wet method; Erosion resistance: this coating is not observed corrosion phenomenon by behind 168 hours neutral salt spray tests, and anti-neutral salt spray and filiform corrosion are good;
Embodiment 2:
1. the preparation of sol-gel solution
With the catalyzer of the additive of 60 milliliters of organo-siloxanes and 850 milliliters of organic solvents and 1wt%, 1wt% rare-earth salts, 0.5wt% and appropriate amount of deionized water totally 1000 milliliters mix and stir, churning time is 5 minutes to 1 hour;
During preparation (18 ℃ to 25 ℃) at normal temperatures, after stirring, also need to leave standstill 48 hours to 60 hours and carry out slaking; Filter sol solutions in the laboratory with quantitative paper at a slow speed, move into airtight preservation in the clean container, stand-by.
2. colloidal sol is applied to (following description is with the example that is embodied as on aluminium alloy 2024 prints) on the body material
2.1 the cleaning surfaces of body material and activation:
Clean the surface of print with tap water, sanitising agent; At room temperature flood print 10 minutes with alkaline cleansing agent, remove the grease on print surface, and with tap water and washed with de-ionized water print; With the nitration mixture treatment solution room temperature dipping print 10 minutes with deoxidation, with tap water and washed with de-ionized water print; Under 55 ℃ of temperature, flooded print 10 to 15 minutes with alkali lye, with the surface of activation print, with tap water and washed with de-ionized water print; With the hot-air dry print, standby (print of processing needs coating in a hour)
2.2 the coating of sol solutions:
The print of handling well is placed on spray chamber's inner support; The sol solutions for preparing is coated to the surface of print, adjusts spray distance and spray gun setting, make colloidal sol cover the surface of print equably, and sol solutions was no less than in the print surface residence time be advisable for 30 seconds; Place print temperature to be arranged on 110 ℃ baking oven, dry 30 minutes; Take out the print naturally cooling.
3. the proterties and the detection of sol-gel liquid coating back print
Print surfacing behind the naturally cooling, smooth, even, flawless, nothing depression, coating is transparent smooth; Tack to the alloy matrix aluminum material is good, the smooth no perk of coating; The priming paint that is applied on the sol-gel coating there is good bonding force, the bonding force of itself and priming paint is tested, all reach very good effect (detect and all obtain best test result) with dry method and wet method;
Erosion resistance: this coating is not observed corrosion phenomenon by behind 168 hours neutral salt spray tests, and anti-neutral salt spray and filiform corrosion are good.
Claims (10)
1. surface anticorrosion colloidal sol that is used for aviation aluminum alloy material, it is characterized in that its component and content are: the additive of 1～15wt% organo-siloxane, 45～93wt% organic solvent, 0.1-10%, 0.5～10wt% rare-earth salts, 5～50wt% deionized water and 0.1～5wt% catalyzer.
2. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 1 is characterized in that, described organic solvent is the Fatty Alcohol(C12-C14 and C12-C18) of 1 to 10 carbon atom.
3. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 1 is characterized in that the structural formula of described organo-siloxane is: [Si (R
1) (R
2)
3]
n, wherein: n=1 or 2, promptly contain one or two radicals R on a Siliciumatom
1And 2 or 3 radicals R
2Or on two adjacent Siliciumatoms and each Siliciumatom respectively contain one or two radicals R
1And 2 or 3 radicals R
2
4. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 3 is characterized in that, contains in the described organo-siloxane: a radicals R
1And this group is inseparable and non-hydrolysable and contain 3 radicals R
2And this group hydrolyzable also can be removed; Described radicals R
2For methoxyl group, oxyethyl group, just-propoxy-, different-propoxy-, just-butoxy, different-butoxy, the second month in a season-butoxy, uncle-butoxy, just-pentyloxy, just-hexyloxy group, ring propoxy-, cyclohexyloxy, phenoxy group, acyloxy, acetoxyl group, propionyloxy or ethanoyl; Described radicals R
1For methyl, ethyl, propyl group, just-butyl, isobutyl-, sec-butyl, the tertiary butyl, propyl disulfide group, vinyl, 1-propenyl, 2-propenyl, butenyl group, ethynyl, proyl group, phenyl, naphthyl group, methacryloyl, methacryloyl oxygen propyl group, glycidyl, glycidoxypropyl group, ammonia aryl or aminoalkyl group.
5. according to claim 1 or the 3 or 4 described surface anticorrosion colloidal sols that are used for aviation aluminum alloy material, it is characterized in that described organo-siloxane is a vinyltriethoxysilane, the propenyl triethoxyl silane, the 3-aminopropyltriethoxywerene werene, 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE, 3-Racemic glycidol propyl-triethoxysilicane, 3-sulfydryl propyl-triethoxysilicane, N-(2-amino-ethyl)-3-aminopropyltriethoxywerene werene, N-[N '-(2 '-amino-ethyl)-2-amino-ethyl]-3-aminopropyl-triethoxyl silane, N-phenyl amino propyl-triethoxysilicane, two-(the silica-based propyl group of 3-(triethoxy)) tetrasulfide or two-(the silica-based propyl group of 3-(triethoxy)) ethane.
6. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 1, it is characterized in that described catalyzer is aliphatics monocarboxylic acid such as acetate, di-carboxylic acid and tribasic carboxylic acid such as citric acid, nitric acid, hydrochloric acid, thanomin, triethylamine or its mixing.
7. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 1 is characterized in that described additive is nanometer SiO
2Particle, its particle diameter are the 50-100 nanometer.
8. the surface anticorrosion colloidal sol that is used for aviation aluminum alloy material according to claim 1 is characterized in that, described rare-earth salts is the hydrate of cerous nitrate, the hydrate of cerium oxide, the hydrate or the cerium stearate of cerous acetate.
9. surface anticorrosive treatment method according to the described surface anticorrosion colloidal sol of above-mentioned arbitrary claim, it is characterized in that, by carrying out maturation process after organo-siloxane, organic solvent, additive, rare-earth salts, deionized water and the catalyst mix, spray, brush or be immersed in matrix surface after again the mixture after the slaking being filtered, the deposition back forms coating at matrix surface, realizes the surface anticorrosion processing.
10. surface anticorrosive treatment method according to claim 9 is characterized in that, spraying, brush or dipping after deposition process in heat, Heating temperature is to heat 1 second to 2 hour under 50 to 150 ℃ of temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100450565A CN102174289A (en) | 2011-02-25 | 2011-02-25 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100450565A CN102174289A (en) | 2011-02-25 | 2011-02-25 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102174289A true CN102174289A (en) | 2011-09-07 |
Family
ID=44517555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100450565A Pending CN102174289A (en) | 2011-02-25 | 2011-02-25 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102174289A (en) |
Cited By (117)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102586775A (en) * | 2012-01-18 | 2012-07-18 | 上海交通大学 | Surface preservative treatment method for aviation aluminium alloy material |
| CN102936459A (en) * | 2012-12-10 | 2013-02-20 | 青岛中科英泰商用系统有限公司 | Coating process of environmentally friendly paint on metal surface |
| CN102942862A (en) * | 2012-12-10 | 2013-02-27 | 青岛菲特电器科技有限公司 | Corrosion prevention technology for metal structure |
| CN102942867A (en) * | 2012-12-10 | 2013-02-27 | 青岛中科英泰商用系统有限公司 | Non-aromatic corrosion prevention technology for metal structure |
| CN102942860A (en) * | 2012-12-14 | 2013-02-27 | 青岛中科英泰商用系统有限公司 | Non-aromatic anti-corrosive paint coating process |
| CN102942854A (en) * | 2012-12-14 | 2013-02-27 | 青岛中科润美润滑材料技术有限公司 | Coating scheme of non-aromatic anti-corrosion paint |
| CN102942870A (en) * | 2012-12-13 | 2013-02-27 | 青岛华电高压电气有限公司 | Non-aromatic corrosion prevention scheme for metal surface |
| CN102942846A (en) * | 2012-12-13 | 2013-02-27 | 青岛菲特电器科技有限公司 | Coating scheme of anti-corrosion paint |
| CN102942852A (en) * | 2012-12-13 | 2013-02-27 | 青岛汉河药业有限公司 | Corrosion prevention scheme of metal surface |
| CN102965005A (en) * | 2012-12-13 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion scheme for metal structure |
| CN102964997A (en) * | 2012-12-10 | 2013-03-13 | 青岛博益特生物材料有限公司 | Anticorrosion method of metal structure |
| CN102964987A (en) * | 2012-12-13 | 2013-03-13 | 青岛蔚蓝生物集团有限公司 | Coating flow of arene-free anticorrosive paint |
| CN102965007A (en) * | 2012-12-13 | 2013-03-13 | 青岛华电高压电气有限公司 | Anti-corrosion scheme of metal surface |
| CN102964991A (en) * | 2012-12-13 | 2013-03-13 | 青岛菲特电器科技有限公司 | Aromatic-hydrocarbon-free anti-corrosion flow of metal surface |
| CN102964990A (en) * | 2012-12-10 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion method of metal structure |
| CN102964995A (en) * | 2012-12-13 | 2013-03-13 | 青岛森淼实业有限公司 | Anti-corrosion scheme of metal structure |
| CN102964989A (en) * | 2012-12-10 | 2013-03-13 | 青岛博益特生物材料有限公司 | Anticorrosion method of metal structure |
| CN102965003A (en) * | 2012-12-13 | 2013-03-13 | 青岛蔚蓝生物集团有限公司 | Coating scheme of arene-free anticorrosive paint |
| CN102965006A (en) * | 2012-12-13 | 2013-03-13 | 青岛天人环境股份有限公司 | Anticorrosion scheme for metal structure |
| CN102965001A (en) * | 2012-12-13 | 2013-03-13 | 青岛海洋新材料科技有限公司 | Anti-corrosion flow of metal surface |
| CN102964998A (en) * | 2012-12-13 | 2013-03-13 | 青岛博益特生物材料有限公司 | Aromatic-hydrocarbon-free anti-corrosion scheme of metal surface |
| CN102965000A (en) * | 2012-12-13 | 2013-03-13 | 青岛汉河药业有限公司 | Aromatic-hydrocarbon-free anti-corrosion flow of metal surface |
| CN102977780A (en) * | 2012-12-13 | 2013-03-20 | 青岛海诺水务科技股份有限公司 | Coating scheme for anticorrosive paint |
| CN102977779A (en) * | 2012-12-10 | 2013-03-20 | 青岛菲特电器科技有限公司 | Method for coating anticorrosive paint without aromatic hydrocarbon |
| CN102977778A (en) * | 2012-12-10 | 2013-03-20 | 青岛菲特电器科技有限公司 | Coating technology for anticorrosive paint without aromatic hydrocarbon |
| CN102977777A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic-free corrosion prevention process for metal surface |
| CN102977776A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic-free corrosion prevention technology for metal surface |
| CN102977781A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free anti-corrosion technology of metal structure |
| CN102993954A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Metal surface aromatic hydrocarbon-free corrosion prevention technology |
| CN102993956A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free corrosion prevention technology for metal structure |
| CN102993963A (en) * | 2012-12-19 | 2013-03-27 | 青岛汉河药业有限公司 | Non-arene anticorrosion method for metal surfaces |
| CN102993947A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth anticorrosive paint coating process |
| CN102993949A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth anticorrosive paint coating technology |
| CN102993950A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth corrosion prevention method of metal surface |
| CN102993958A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Aromatic hydrocarbon-free anticorrosive paint coating technology |
| CN102993960A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare-earth anticorrosion process for metal surfaces |
| CN102993951A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare-earth anticorrosion method for metal surfaces |
| CN102993955A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Non-arene anticorrosion process for metal structures |
| CN102993962A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Metal surface aromatic hydrocarbon-free corrosion prevention process |
| CN102993959A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Aromatic hydrocarbon-free anticorrosive paint coating process |
| CN102993952A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free corrosion prevention process for metal structure |
| CN102993948A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Coating process of rare earth anticorrosive paint |
| CN102993953A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Non-arene anticorrosion process for metal surfaces |
| CN102993961A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Coating process of arene-free anticorrosive paint |
| CN103013332A (en) * | 2012-12-17 | 2013-04-03 | 青岛华电高压电气有限公司 | Metal surface non arene anticorrosion technology |
| CN103045084A (en) * | 2012-12-17 | 2013-04-17 | 青岛天人环境股份有限公司 | Coating method of anticorrosive paint |
| CN103045089A (en) * | 2012-12-17 | 2013-04-17 | 青岛研博电子有限公司 | Metal surface aseptic technology |
| CN103045081A (en) * | 2012-12-13 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Anticorrosion flow for metal structure |
| CN103045088A (en) * | 2012-12-17 | 2013-04-17 | 青岛研博电子有限公司 | Environment-friendly paint coating flow for metal surface |
| CN103045076A (en) * | 2012-12-17 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Coating process of environmental-friendly coating on metal surface |
| CN103045077A (en) * | 2012-12-17 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Coating method of rare earth anti-corrosion coating |
| CN103102805A (en) * | 2012-12-10 | 2013-05-15 | 青岛盛瀚色谱技术有限公司 | Aromatic hydrocarbon-free anticorrosive method of metal surface |
| CN103102806A (en) * | 2012-12-13 | 2013-05-15 | 青岛研博电子有限公司 | Coating process of arene-free anticorrosive paint |
| CN103205145A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Coating method of anticorrosive paint |
| CN103205200A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103205195A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion technology for metal surface |
| CN103205199A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103205196A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103214935A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Coating process of anticorrosion coating material |
| CN103214930A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Rare earth anticorrosion process of metal surface |
| CN103214960A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Coating technology of anticorrosion coating material |
| CN103214958A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion technology for metal structure |
| CN103214929A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion technology of metal structure |
| CN103214925A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion coating material coating process |
| CN103214938A (en) * | 2012-12-18 | 2013-07-24 | 青岛蔚蓝生物集团有限公司 | Coating method of anticorrosion coating material |
| CN103214936A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion process for metal surface |
| CN103214926A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion coating material coating technology |
| CN103214932A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Aromatic hydrocarbon-free anticorrosion process for metal surface |
| CN103214931A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Aromatic hydrocarbon-free anticorrosion technology for metal surface |
| CN103214955A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion technology of metal surface |
| CN103214950A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Coating technology of aromatic hydrocarbon-free anticorrosion coating material |
| CN103214952A (en) * | 2012-12-17 | 2013-07-24 | 青岛研博电子有限公司 | Metal surface anticorrosion technology |
| CN103214937A (en) * | 2012-12-18 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion technology for metal structure |
| CN103214928A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion process for metal structure |
| CN103214927A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Metal structure anticorrosion process |
| CN103214953A (en) * | 2012-12-18 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion method for metal structure |
| CN103232811A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of titanium-magnesium alloy foil explosion-proof material |
| CN103232805A (en) * | 2013-04-22 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating process for nickel-aluminium alloy foil explosion-proof material |
| CN103232808A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of martensitic stainless steel strip explosion-proof material |
| CN103232810A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of austenitic stainless steel strip explosion-proof material |
| CN103242744A (en) * | 2013-04-27 | 2013-08-14 | 上海华篷防爆科技有限公司 | Coating process for anti-explosion material of ferrite stainless steel belt |
| CN103254775A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of zinc-copper alloy foil explosion-proof material |
| CN103254774A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of silicon-copper alloy foil explosion-proof material |
| CN103254766A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of manganese-copper alloy foil explosion-proof material |
| CN103254776A (en) * | 2013-04-27 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of duplex stainless steel band explosion-proof material |
| CN103254773A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of tin-copper alloy foil explosion-proof material |
| CN103254772A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of aluminium-copper alloy foil explosion-proof material |
| CN103265886A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Anticorrosion process for metal surface |
| CN103265890A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating process of rare earth anticorrosive paint |
| CN103265887A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating method of rare earth anti-corrosion coating |
| CN103265889A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating method of rare earth anti-corrosion coating |
| CN103265888A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Rare earth anticorrosive paint coating technology |
| CN103726058A (en) * | 2014-01-19 | 2014-04-16 | 黑龙江慧田知识产权服务有限公司 | Preservative treatment process for aluminum alloy |
| CN103865384A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating process for metal surfaces |
| CN103865385A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating scheme for metal surfaces |
| CN103865387A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Anticorrosion process for metal surfaces |
| CN103865388A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating scheme for metal surfaces |
| CN103865382A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Metal surface anticorrosion process |
| CN103865383A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Anti-corrosion technology for metal surfaces |
| CN104099010A (en) * | 2014-06-19 | 2014-10-15 | 锐展(铜陵)科技有限公司 | Vulcanized silane aluminium alloy surface treating agent |
| CN105274510A (en) * | 2015-09-29 | 2016-01-27 | 安徽岳塑汽车工业股份有限公司 | Hard aluminum alloy curing film forming liquid and preparation method thereof |
| CN105274511A (en) * | 2015-09-29 | 2016-01-27 | 安徽瑞林汽配有限公司 | Aluminum alloy curing film forming liquid and preparation method thereof |
| CN105274537A (en) * | 2015-09-29 | 2016-01-27 | 安徽岳塑汽车工业股份有限公司 | Aluminum alloy corrosion inhibition curing film forming liquid and preparation method thereof |
| CN105295722A (en) * | 2015-10-28 | 2016-02-03 | 天长市润达金属防锈助剂有限公司 | Corrosion-preventive lifting composite aluminum-titanium sol for aluminum alloy and preparation method thereof |
| CN105331965A (en) * | 2015-09-29 | 2016-02-17 | 安徽岳塑汽车工业股份有限公司 | Forming liquid for antifriction aluminum alloy curing film and preparation method of forming liquid |
| CN105463549A (en) * | 2015-12-03 | 2016-04-06 | 中国航空工业集团公司北京航空材料研究院 | Anodizing method improving protection performance of aluminum and aluminum alloy |
| CN105860826A (en) * | 2015-01-19 | 2016-08-17 | 深圳市堃琦鑫华股份有限公司 | Surface conditioning agent and adhesive membrane |
| WO2017092675A1 (en) * | 2015-11-30 | 2017-06-08 | Dazzeon Technology Co., Ltd. | Nano-shielded article and method for making the same |
| CN106867398A (en) * | 2017-02-17 | 2017-06-20 | 哈尔滨工程大学 | A kind of preparation method with self-repair function polysiloxane coating |
| CN108727930A (en) * | 2018-06-08 | 2018-11-02 | 安徽工业大学 | A kind of aluminum alloy surface Coating Pretreatment liquid |
| CN108948805A (en) * | 2018-07-23 | 2018-12-07 | 芜湖彰鸿工程技术有限公司 | A kind of plane aluminium alloy material surface treatment method |
| CN109082144A (en) * | 2018-07-23 | 2018-12-25 | 芜湖彰鸿工程技术有限公司 | A kind of plane aluminium alloy material surface preservative and its application method |
| CN109777290A (en) * | 2018-12-24 | 2019-05-21 | 苏州市智永亿精密五金有限公司 | A kind of process for treating surface of the ultralight corrosion-resistant aviation aluminum alloy material of high-performance |
| CN110945087A (en) * | 2017-07-31 | 2020-03-31 | 诺维尔里斯公司 | Pretreatment composition, coated aluminum alloy and method of making the same |
| CN112226752A (en) * | 2020-10-16 | 2021-01-15 | 台州青源精细化工有限公司 | Formula of silane coupling pre-film agent before metal coating and preparation method thereof |
| CN113684511A (en) * | 2021-09-23 | 2021-11-23 | 中国计量大学 | Electrochemical preparation method of high-temperature self-repairing coating and product thereof |
| CN113845843A (en) * | 2021-11-04 | 2021-12-28 | 福建三钢闽光股份有限公司 | Silane composite water-based treating agent for pretreatment before metal surface coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007901A (en) * | 2006-01-26 | 2007-08-01 | 德古萨公司 | Water dilutable sol-gel composite |
| CN101184866A (en) * | 2005-05-31 | 2008-05-21 | 法国空中客车公司 | Sol for sol-gel process coating of a surface and coating method by sol-gel process using same |
-
2011
- 2011-02-25 CN CN2011100450565A patent/CN102174289A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101184866A (en) * | 2005-05-31 | 2008-05-21 | 法国空中客车公司 | Sol for sol-gel process coating of a surface and coating method by sol-gel process using same |
| CN101007901A (en) * | 2006-01-26 | 2007-08-01 | 德古萨公司 | Water dilutable sol-gel composite |
Non-Patent Citations (3)
| Title |
|---|
| 《物理化学学报》 20060831 陈明安等 2Al2-T6铝合金表面双-(gamma-三乙氧基硅丙基)四硫化物薄膜的特性 第22卷, 第8期 * |
| 钟显康: "《西南大学硕士学位论文-镁合金表面耐蚀性溶胶-凝胶膜层的制备与修复研究》", 31 December 2010, article "镁合金表面耐蚀性溶胶-凝胶膜层的制备与修复研究" * |
| 陈明安等: "2Al2-T6铝合金表面双-(γ-三乙氧基硅丙基)四硫化物薄膜的特性", 《物理化学学报》, vol. 22, no. 8, 31 August 2006 (2006-08-31) * |
Cited By (121)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102586775A (en) * | 2012-01-18 | 2012-07-18 | 上海交通大学 | Surface preservative treatment method for aviation aluminium alloy material |
| CN102586775B (en) * | 2012-01-18 | 2014-05-21 | 上海交通大学 | Surface preservative treatment method for aviation aluminium alloy material |
| CN102964990A (en) * | 2012-12-10 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion method of metal structure |
| CN102936459A (en) * | 2012-12-10 | 2013-02-20 | 青岛中科英泰商用系统有限公司 | Coating process of environmentally friendly paint on metal surface |
| CN102942862A (en) * | 2012-12-10 | 2013-02-27 | 青岛菲特电器科技有限公司 | Corrosion prevention technology for metal structure |
| CN102942867A (en) * | 2012-12-10 | 2013-02-27 | 青岛中科英泰商用系统有限公司 | Non-aromatic corrosion prevention technology for metal structure |
| CN103102805A (en) * | 2012-12-10 | 2013-05-15 | 青岛盛瀚色谱技术有限公司 | Aromatic hydrocarbon-free anticorrosive method of metal surface |
| CN102977778A (en) * | 2012-12-10 | 2013-03-20 | 青岛菲特电器科技有限公司 | Coating technology for anticorrosive paint without aromatic hydrocarbon |
| CN102977779A (en) * | 2012-12-10 | 2013-03-20 | 青岛菲特电器科技有限公司 | Method for coating anticorrosive paint without aromatic hydrocarbon |
| CN102964989A (en) * | 2012-12-10 | 2013-03-13 | 青岛博益特生物材料有限公司 | Anticorrosion method of metal structure |
| CN102964997A (en) * | 2012-12-10 | 2013-03-13 | 青岛博益特生物材料有限公司 | Anticorrosion method of metal structure |
| CN102942846A (en) * | 2012-12-13 | 2013-02-27 | 青岛菲特电器科技有限公司 | Coating scheme of anti-corrosion paint |
| CN102964998A (en) * | 2012-12-13 | 2013-03-13 | 青岛博益特生物材料有限公司 | Aromatic-hydrocarbon-free anti-corrosion scheme of metal surface |
| CN102964991A (en) * | 2012-12-13 | 2013-03-13 | 青岛菲特电器科技有限公司 | Aromatic-hydrocarbon-free anti-corrosion flow of metal surface |
| CN102964987A (en) * | 2012-12-13 | 2013-03-13 | 青岛蔚蓝生物集团有限公司 | Coating flow of arene-free anticorrosive paint |
| CN102964995A (en) * | 2012-12-13 | 2013-03-13 | 青岛森淼实业有限公司 | Anti-corrosion scheme of metal structure |
| CN102965005A (en) * | 2012-12-13 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion scheme for metal structure |
| CN102965003A (en) * | 2012-12-13 | 2013-03-13 | 青岛蔚蓝生物集团有限公司 | Coating scheme of arene-free anticorrosive paint |
| CN102965006A (en) * | 2012-12-13 | 2013-03-13 | 青岛天人环境股份有限公司 | Anticorrosion scheme for metal structure |
| CN102965001A (en) * | 2012-12-13 | 2013-03-13 | 青岛海洋新材料科技有限公司 | Anti-corrosion flow of metal surface |
| CN102965007A (en) * | 2012-12-13 | 2013-03-13 | 青岛华电高压电气有限公司 | Anti-corrosion scheme of metal surface |
| CN102965000A (en) * | 2012-12-13 | 2013-03-13 | 青岛汉河药业有限公司 | Aromatic-hydrocarbon-free anti-corrosion flow of metal surface |
| CN102977780A (en) * | 2012-12-13 | 2013-03-20 | 青岛海诺水务科技股份有限公司 | Coating scheme for anticorrosive paint |
| CN102942852A (en) * | 2012-12-13 | 2013-02-27 | 青岛汉河药业有限公司 | Corrosion prevention scheme of metal surface |
| CN103045081A (en) * | 2012-12-13 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Anticorrosion flow for metal structure |
| CN102942870A (en) * | 2012-12-13 | 2013-02-27 | 青岛华电高压电气有限公司 | Non-aromatic corrosion prevention scheme for metal surface |
| CN103102806A (en) * | 2012-12-13 | 2013-05-15 | 青岛研博电子有限公司 | Coating process of arene-free anticorrosive paint |
| CN102942854A (en) * | 2012-12-14 | 2013-02-27 | 青岛中科润美润滑材料技术有限公司 | Coating scheme of non-aromatic anti-corrosion paint |
| CN102942860A (en) * | 2012-12-14 | 2013-02-27 | 青岛中科英泰商用系统有限公司 | Non-aromatic anti-corrosive paint coating process |
| CN103214960A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Coating technology of anticorrosion coating material |
| CN103214927A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Metal structure anticorrosion process |
| CN102993947A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth anticorrosive paint coating process |
| CN102993949A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth anticorrosive paint coating technology |
| CN102993950A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare earth corrosion prevention method of metal surface |
| CN102993958A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Aromatic hydrocarbon-free anticorrosive paint coating technology |
| CN102993960A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare-earth anticorrosion process for metal surfaces |
| CN102993951A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Rare-earth anticorrosion method for metal surfaces |
| CN102993955A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Non-arene anticorrosion process for metal structures |
| CN102993962A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Metal surface aromatic hydrocarbon-free corrosion prevention process |
| CN102993959A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Aromatic hydrocarbon-free anticorrosive paint coating process |
| CN102993952A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free corrosion prevention process for metal structure |
| CN102993948A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Coating process of rare earth anticorrosive paint |
| CN102993953A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Non-arene anticorrosion process for metal surfaces |
| CN102993961A (en) * | 2012-12-17 | 2013-03-27 | 青岛汉河药业有限公司 | Coating process of arene-free anticorrosive paint |
| CN103013332A (en) * | 2012-12-17 | 2013-04-03 | 青岛华电高压电气有限公司 | Metal surface non arene anticorrosion technology |
| CN103045084A (en) * | 2012-12-17 | 2013-04-17 | 青岛天人环境股份有限公司 | Coating method of anticorrosive paint |
| CN103045089A (en) * | 2012-12-17 | 2013-04-17 | 青岛研博电子有限公司 | Metal surface aseptic technology |
| CN102993956A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free corrosion prevention technology for metal structure |
| CN103045088A (en) * | 2012-12-17 | 2013-04-17 | 青岛研博电子有限公司 | Environment-friendly paint coating flow for metal surface |
| CN103045076A (en) * | 2012-12-17 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Coating process of environmental-friendly coating on metal surface |
| CN103045077A (en) * | 2012-12-17 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Coating method of rare earth anti-corrosion coating |
| CN102993954A (en) * | 2012-12-17 | 2013-03-27 | 青岛华电高压电气有限公司 | Metal surface aromatic hydrocarbon-free corrosion prevention technology |
| CN102977781A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic hydrocarbon-free anti-corrosion technology of metal structure |
| CN103865383A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Anti-corrosion technology for metal surfaces |
| CN103865382A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Metal surface anticorrosion process |
| CN103865388A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating scheme for metal surfaces |
| CN103865387A (en) * | 2012-12-17 | 2014-06-18 | 青岛中科英泰商用系统有限公司 | Anticorrosion process for metal surfaces |
| CN103865385A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating scheme for metal surfaces |
| CN103214935A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Coating process of anticorrosion coating material |
| CN103214930A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Rare earth anticorrosion process of metal surface |
| CN102977776A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic-free corrosion prevention technology for metal surface |
| CN103214958A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion technology for metal structure |
| CN103214929A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion technology of metal structure |
| CN103214925A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion coating material coating process |
| CN103865384A (en) * | 2012-12-17 | 2014-06-18 | 青岛天鹅针织有限公司 | Environment-friendly paint coating process for metal surfaces |
| CN103214936A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion process for metal surface |
| CN103214926A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion coating material coating technology |
| CN103214932A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Aromatic hydrocarbon-free anticorrosion process for metal surface |
| CN103214931A (en) * | 2012-12-17 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Aromatic hydrocarbon-free anticorrosion technology for metal surface |
| CN103214955A (en) * | 2012-12-17 | 2013-07-24 | 青岛中科英泰商用系统有限公司 | Anticorrosion technology of metal surface |
| CN103214950A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Coating technology of aromatic hydrocarbon-free anticorrosion coating material |
| CN103214952A (en) * | 2012-12-17 | 2013-07-24 | 青岛研博电子有限公司 | Metal surface anticorrosion technology |
| CN102977777A (en) * | 2012-12-17 | 2013-03-20 | 青岛华电高压电气有限公司 | Aromatic-free corrosion prevention process for metal surface |
| CN103214928A (en) * | 2012-12-17 | 2013-07-24 | 青岛天人环境股份有限公司 | Anticorrosion process for metal structure |
| CN103265888A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Rare earth anticorrosive paint coating technology |
| CN103265889A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating method of rare earth anti-corrosion coating |
| CN103265887A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating method of rare earth anti-corrosion coating |
| CN103265890A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Coating process of rare earth anticorrosive paint |
| CN103265886A (en) * | 2012-12-17 | 2013-08-28 | 青岛菲特电器科技有限公司 | Anticorrosion process for metal surface |
| CN103205199A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103205145A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Coating method of anticorrosive paint |
| CN103214937A (en) * | 2012-12-18 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion technology for metal structure |
| CN103214938A (en) * | 2012-12-18 | 2013-07-24 | 青岛蔚蓝生物集团有限公司 | Coating method of anticorrosion coating material |
| CN103205196A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103205200A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion method for metal surface |
| CN103214953A (en) * | 2012-12-18 | 2013-07-24 | 青岛海洋新材料科技有限公司 | Anticorrosion method for metal structure |
| CN103205195A (en) * | 2012-12-18 | 2013-07-17 | 青岛蔚蓝生物集团有限公司 | Anticorrosion technology for metal surface |
| CN102993963A (en) * | 2012-12-19 | 2013-03-27 | 青岛汉河药业有限公司 | Non-arene anticorrosion method for metal surfaces |
| CN103232805A (en) * | 2013-04-22 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating process for nickel-aluminium alloy foil explosion-proof material |
| CN103254774A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of silicon-copper alloy foil explosion-proof material |
| CN103254772A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of aluminium-copper alloy foil explosion-proof material |
| CN103254773A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of tin-copper alloy foil explosion-proof material |
| CN103254766A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of manganese-copper alloy foil explosion-proof material |
| CN103254775A (en) * | 2013-04-26 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of zinc-copper alloy foil explosion-proof material |
| CN103232811A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of titanium-magnesium alloy foil explosion-proof material |
| CN103232810A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of austenitic stainless steel strip explosion-proof material |
| CN103232808A (en) * | 2013-04-27 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating technique of martensitic stainless steel strip explosion-proof material |
| CN103254776A (en) * | 2013-04-27 | 2013-08-21 | 上海华篷防爆科技有限公司 | Coating process of duplex stainless steel band explosion-proof material |
| CN103242744A (en) * | 2013-04-27 | 2013-08-14 | 上海华篷防爆科技有限公司 | Coating process for anti-explosion material of ferrite stainless steel belt |
| CN103726058A (en) * | 2014-01-19 | 2014-04-16 | 黑龙江慧田知识产权服务有限公司 | Preservative treatment process for aluminum alloy |
| CN104099010A (en) * | 2014-06-19 | 2014-10-15 | 锐展(铜陵)科技有限公司 | Vulcanized silane aluminium alloy surface treating agent |
| CN105860826A (en) * | 2015-01-19 | 2016-08-17 | 深圳市堃琦鑫华股份有限公司 | Surface conditioning agent and adhesive membrane |
| CN105274510A (en) * | 2015-09-29 | 2016-01-27 | 安徽岳塑汽车工业股份有限公司 | Hard aluminum alloy curing film forming liquid and preparation method thereof |
| CN105274537A (en) * | 2015-09-29 | 2016-01-27 | 安徽岳塑汽车工业股份有限公司 | Aluminum alloy corrosion inhibition curing film forming liquid and preparation method thereof |
| CN105331965A (en) * | 2015-09-29 | 2016-02-17 | 安徽岳塑汽车工业股份有限公司 | Forming liquid for antifriction aluminum alloy curing film and preparation method of forming liquid |
| CN105274511A (en) * | 2015-09-29 | 2016-01-27 | 安徽瑞林汽配有限公司 | Aluminum alloy curing film forming liquid and preparation method thereof |
| CN105295722A (en) * | 2015-10-28 | 2016-02-03 | 天长市润达金属防锈助剂有限公司 | Corrosion-preventive lifting composite aluminum-titanium sol for aluminum alloy and preparation method thereof |
| WO2017092675A1 (en) * | 2015-11-30 | 2017-06-08 | Dazzeon Technology Co., Ltd. | Nano-shielded article and method for making the same |
| CN105463549A (en) * | 2015-12-03 | 2016-04-06 | 中国航空工业集团公司北京航空材料研究院 | Anodizing method improving protection performance of aluminum and aluminum alloy |
| CN105463549B (en) * | 2015-12-03 | 2018-06-26 | 中国航空工业集团公司北京航空材料研究院 | A kind of anodization process for improving aluminium and aluminium alloy barrier propterty |
| CN106867398A (en) * | 2017-02-17 | 2017-06-20 | 哈尔滨工程大学 | A kind of preparation method with self-repair function polysiloxane coating |
| CN110945087A (en) * | 2017-07-31 | 2020-03-31 | 诺维尔里斯公司 | Pretreatment composition, coated aluminum alloy and method of making the same |
| US11519076B2 (en) | 2017-07-31 | 2022-12-06 | Novelis Inc. | Pretreatment compositions, coated aluminum alloys, and methods of making the same |
| CN108727930A (en) * | 2018-06-08 | 2018-11-02 | 安徽工业大学 | A kind of aluminum alloy surface Coating Pretreatment liquid |
| CN108727930B (en) * | 2018-06-08 | 2020-07-28 | 安徽工业大学 | Aluminum alloy surface coating pretreatment liquid |
| CN108948805A (en) * | 2018-07-23 | 2018-12-07 | 芜湖彰鸿工程技术有限公司 | A kind of plane aluminium alloy material surface treatment method |
| CN109082144A (en) * | 2018-07-23 | 2018-12-25 | 芜湖彰鸿工程技术有限公司 | A kind of plane aluminium alloy material surface preservative and its application method |
| CN109777290A (en) * | 2018-12-24 | 2019-05-21 | 苏州市智永亿精密五金有限公司 | A kind of process for treating surface of the ultralight corrosion-resistant aviation aluminum alloy material of high-performance |
| CN112226752A (en) * | 2020-10-16 | 2021-01-15 | 台州青源精细化工有限公司 | Formula of silane coupling pre-film agent before metal coating and preparation method thereof |
| CN113684511A (en) * | 2021-09-23 | 2021-11-23 | 中国计量大学 | Electrochemical preparation method of high-temperature self-repairing coating and product thereof |
| CN113845843A (en) * | 2021-11-04 | 2021-12-28 | 福建三钢闽光股份有限公司 | Silane composite water-based treating agent for pretreatment before metal surface coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102174289A (en) | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof | |
| CN102586775B (en) | Surface preservative treatment method for aviation aluminium alloy material | |
| RU2415169C2 (en) | Sol for applying sol-gel coating on surface, method of applying sol-gel coating, preparation method thereof and use | |
| CN101434802B (en) | Water system super-hydrophobic surface coating agent and preparation thereof | |
| JP7381173B2 (en) | Superhydrophobic coating layer and its preparation method and use | |
| CN110359044B (en) | Preparation method of steel matrix surface super-hydrophobic film | |
| CN109401373A (en) | A kind of preparation method of super-hydrophobic oleophobic silica solution | |
| CN105694715A (en) | Preparation method of SiO2/PDMS composite transparent super hydrophobic coating | |
| CN102795786A (en) | Super hydrophobic self-cleaning coating and preparation method thereof | |
| CN109439042A (en) | A kind of hydrophilic surface layer coating, relevant stainless steel sink and preparation method | |
| CN105038440A (en) | Polytetrafluoroethylene modified chromium-free Dacromet paint and preparation method of composite coating thereof | |
| CN108841211A (en) | A kind of inorganic zinc coating of modified graphene and preparation method thereof | |
| CN105148563A (en) | Superhydrophilic and superoleophobic oil-water separation membrane with humidity responsiveness as well as preparation method and application of oil-water separation membrane | |
| CN107353701A (en) | It is a kind of corrosion-free without scuffing metal paint remover and its preparation method and application | |
| CN109777290A (en) | A kind of process for treating surface of the ultralight corrosion-resistant aviation aluminum alloy material of high-performance | |
| CN107287903A (en) | A kind of preparation method of the resistant to boiling water superhydrophobic fabric available for water-oil separating | |
| CN102373448B (en) | Pre-treatment sol solution used for surface of aviation titanium alloy material and sol-gel coating formed by pre-treatment sol solution | |
| CN101713069B (en) | Method for preparing additive homogeneous phase modified solution of silane and application thereof | |
| CN101914344B (en) | Non-chrome water-based organic fingerprint-resistant coating and preparation method thereof | |
| CN113462207A (en) | Photocatalytic self-cleaning composite coating and preparation method thereof | |
| CN109679423B (en) | Water-based wood wax oil and preparation method thereof | |
| CN107325699A (en) | A kind of resistance and fingerprint resistance coated steel sheet and its production method | |
| JP2021080157A (en) | Manufacturing method of structure having super water repellent surface | |
| CN108165963B (en) | Preparation method of surface with lyophobic property on high-viscosity complex liquid phase | |
| CN111822306B (en) | Stainless steel nano self-cleaning coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110907 |