CN102170000A - Composite layer paper battery and preparation method - Google Patents
Composite layer paper battery and preparation method Download PDFInfo
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- CN102170000A CN102170000A CN2011100834207A CN201110083420A CN102170000A CN 102170000 A CN102170000 A CN 102170000A CN 2011100834207 A CN2011100834207 A CN 2011100834207A CN 201110083420 A CN201110083420 A CN 201110083420A CN 102170000 A CN102170000 A CN 102170000A
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Abstract
The invention relates to a composite layer paper battery and a preparation method thereof, wherein a fiber paper material is used as a carrier; both sides of an electroactive material layer are respectively connected with a positive electrode and a negative electrode; the composite layer paper battery is characterized in that the electroactive material layer consists of two different electroactive material layers which are overlapped, wherein the first layer of electroactive material layer consists of manganese dioxide, conductive agent and electrolyte according to the ratio of 1: 0.01-0.2: 0.01-0.2 by weight; and the second layer of electroactive material layer consists of metal nanometer material, conductive agent and electrolyte according to a ratio of 1: 0.01-0.2: 0.01-0.2 by weight. The main performances of the composite layer paper battery prepared by the invention are as follows: the single voltage is 1.2-1.5 V; the multi-body voltage is 2-5 V or higher; the thickness is 1.0-1.2 mm; the capacitor is 2-8 mA/cm2; the multi-body battery with an effective area of 2-4 cm2 can illume various types of LED (Light Emitting Diode) tubes; and a vibrator of a mobile phone further can be started.
Description
Technical field
The invention belongs to the battery technology field, specially refer to the paper mold battery.
Background technology
Battery has become the indispensable commodity of the modern life as electric energy storage device.Little of household electrical appliance, arrive electric automobile greatly, all to use battery.And cell types is very various, but has occurred a kind of novel paper battery in recent years, and this paper battery can be described as a new recruit in the green energy resource.Its principal character be with fibrous paper as support, utilize cellulosic network configuration, be used for doing collection (holding) electrical equipment and electrode.Be with the conventional dry cell batteries difference: paper battery is that both positive and negative polarity, electrolyte and electroactive material layering are stamped on the paper, constitutes a thick about 1mm flat paper battery card.Its feature be lightweight, efficient, flexible, plastic, bendable, stackable, can provide power supply for various devices, can also make secondary rechargeable battery.Therefore its application prospect is very wide.
Conclude paper battery and can be used in the following aspects: the source that 1, is the power of music card, New Year card and various miniature toys; 2, be a kind of desirable drive unit for small household appliance (as mobile phone, digital camera, pocket diary computer, hair-dryer, electric shaver etc.) provides power supply, paper battery; 3, be used for intelligent electronic label, in particular for RF Reader (RFID) discern automatically in safe antitheft, food security, target data obtain and discern the energy that provides required; 4, the strong assistant of health care.For example " battery-efficient facial mask " is used in the facial mask aspect with paper battery, will the vigor of the nutrient in the facial mask be activated greatly, and rapid permeability is to the internal layer of skin, and human body cell to the absorption of nutritional labeling more quickly and effectively.And for example " battery kinetic energy plaster ", because electrocaloric effect, the usefulness of plaster can obviously improve; 5, sociable newspaper.If paper battery and newspaper are printed on a piece of paper simultaneously, newspaper has had kinetic energy, and newspaper may become sound newspaper; If paper battery and map printing are in the same place, battery provides the energy, and map can be located automatically; 6, further improve when the efficiency and the life-span of paper battery, might provide power for motor.
Paper battery can become a kind of super power supply device from now in a word.
The whole world only has a few countries such as the U.S., Israel, Finland to succeed in developing the paper battery product at present.The scientist of Stanford Univ USA forms the conductive nano ink with carbon nano-tube and nano silver wire, and it is penetrated in the paper, makes efficient conductive energy storage device---paper battery or paper super capacitor.This super capacitor has and deposits in faster and discharge the electric charge ability.The paper super capacitor can keep the charge and discharge cycle ten million time, than the high order of magnitude of lithium ion battery." printing technology " 2010,07 " young science " 2010.03.
The paper battery that Israel power company produces is to make on the basis of zinc/manganese dioxide.Its main performance: monomer voltage: 1.5V; Many bodies battery: 3V(or higher); Thickness: 0.5-0.7mm; Continuous current density: 0.1mA/cm
2Normal capacity: 2.5-5mAh/cm
2Storage life: 3 years; Heavy metal free (promptly not mercurous, plumbous, cadmium).
The paper battery main active of Finland Enfucell company exploitation is zinc, manganese dioxide and zinc chloride electrolyte.Its main performance: monomer voltage: 1.5V; Capacity: 2-3mA/cm
2Thickness: 0.5-0.8mm; Storage life: 2 years.
Still there is a patent 02274195.x paper battery (utility model) to it is characterized in that being coated with seal zinc negative pole in addition in the one side of substrate (paper or plastics), another side is coated with positive pole and calcium chloride, magnesium chloride, the ammonium chloride ink be made up of manganese dioxide and graphite and forms electrolytical mixed layer, be connected electric conductor respectively on negative electrode layer and the mixed layer, constitute paper battery.
201010235600.8 1 kinds of flexible printed paper battery anti-counterfeiting labels of patent is characterized in that comprising the false proof realization part in front end paper battery, external trigger device, excitation control circuit and rear end.The front end paper battery is made up of hull cell main body, anode and battery cathode, the thick 0.4-1.0mm that is about of battery, and voltage 1.5-3.0 V, continuous firing electric current 0.1-0.5mA, size 6.5mm * 6.5mm-39mm * 39mm, reserve of electricity are 0.54-20mA.(power paper STD-20 paper battery)
In sum, present paper battery mainly is its composition of improvement on the basis of original zinc-manganese dioxide battery, and is carrier with paper, adopts flexibility that printing technology makes, light weight, plastic battery.
Summary of the invention
The object of the present invention is to provide paper mold battery of a kind of composite bed electroactive material and preparation method thereof.
The present invention is a carrier with the fibrous paper material, the electroactive material that will form with manganese dioxide, conductive agent, electrolyte at first, and printing, spraying plating or be coated in the surface of fibrous paper material constitute the ground floor electroactive material layer based on manganese dioxide; After dried slightly, spraying plating or the electroactive material formed coated with metal nano material, conductive agent, electrolyte again on its surface, constitute second layer electroactive material layer, connect positive and negative electrode respectively on the two sides of paper mold electroactive material layer then, thereby constitute the paper mold battery device of a double-deck electroactive material.
Fibrous paper material of the present invention is commercially available various paper, preferred pulp layered paper or filter paper.
Ground floor electroactive material layer of the present invention is that it is formulated to add deionized water by the weight ratio of manganese dioxide, conductive agent, electrolyte=1: 0.01-0.2: 0.01-0.2.
The nanometer electroactive material of second layer electroactive material layer of the present invention is that it is formulated to add deionized water by metal nano material, conductive agent, electrolyte=1: 0.01-0.2: 0.01-0.2 by weight.
Metal nano material of the present invention is Nano Silver, nanometer copper, nanometer nickel, nanostructured manganese or nanometer iron etc.
Conductive agent of the present invention is one or more in carbon nano-tube, superfine graphite powder, acetylene black, the Graphene.
Electrolyte of the present invention is one or more in zinc chloride, nickel chloride, copper chloride, sodium chloride, ammonium chloride, manganese chloride, the iron chloride.
It is of the present invention that manganese dioxide electroactive material and metal nano electroactive material are adsorbed on the technology that the surface of fibrous paper material adopts is methods such as printing, spraying plating, silk screen seal, coating.
Positive electricity of the present invention is silver, copper or nickel metal forming very, and negative electricity is aluminium or zinc metal forming very.Described electrode is printing or pastes in fibrous paper surface.
The present invention is to be main active substances with manganese dioxide, electric conducting material, metal nano material and electrolyte, and what make by printing, spraying plating, coating is the composite bed paper mold battery of carrier with the fibrous paper.
The main performance of the composite bed paper mold battery that the present invention makes:
Monomer voltage: 1.2-1.5V; Many bulk voltages: 2-5V or higher; Thickness: 1.0-1.2mm; Electric capacity: 2-8mA/cm
2Effective area is that many bodies battery of 2-4cm2 can be lighted various LED pipes, can also start the vibrator of mobile phone.
Embodiment
The present invention will be described further by following examples.
Embodiment 1.
At first getting Copper Foil (as positive pole) and zinc paper tinsel (as negative pole) is attached to respectively on two fibrous paper, according to manganese dioxide: carbon nano-tube: zinc chloride: ammonium chloride=1:0.01:0.1:0.1 is made into electroactive material, add appropriate amount of deionized water, fully grind and make slurry, then slurry is coated in the surface of an other pulp layered paper.After dried slightly, again by nanometer copper: carbon nano-tube: copper chloride=1:0.01:0.2, add appropriate amount of deionized water and be made into slurry, be coated in the surface of manganese dioxide electroactive layer, again Copper Foil is closely contacted with electroactive material, the another side that applies the pulp layered paper of slurry is contacted with the zinc paper tinsel, and respectively pick out lead-in wire at Copper Foil and zinc paper tinsel end, envelope is moulded and is made the paper mold battery at last.
Embodiment 2.
At first getting Copper Foil (as positive pole) and zinc paper tinsel (as negative pole) is attached to respectively on two fibrous paper, according to manganese dioxide: superfine graphite powder: zinc chloride: ammonium chloride=1:0.2:0.1:0.1 is made into electroactive material, add appropriate amount of deionized water, fully grind and make slurry, then slurry is coated in the surface of an other pulp layered paper.After dried slightly, press Nano Silver again: carbon nano-tube: zinc chloride=1:0.01:0.15, add appropriate amount of deionized water and be made into slurry, slurry is coated in the surface of manganese dioxide electroactive layer, again Copper Foil is closely contacted with electroactive material, the another side that applies the pulp layered paper of slurry is contacted with the zinc paper tinsel, and go out lead-in wire in a termination of Copper Foil and zinc paper tinsel, envelope is moulded and is made the paper mold battery at last.
Embodiment 3.
At first getting nickel foil (as positive pole) and zinc paper tinsel (as negative pole) is attached to respectively on two fibrous paper, according to manganese dioxide: acetylene black: zinc chloride: ammonium chloride=1:0.2:0.1:0.1 is made into electroactive material, add appropriate amount of deionized water, fully grind and make slurry, then slurry is printed on the surface of an other filter paper.After dried slightly, again by nanometer nickel: carbon nano-tube: nickel chloride: ammonium chloride=1:0.015:0.1:0.05, add appropriate amount of deionized water and be made into slurry, spraying plating is on the surface of manganese dioxide electroactive layer, again Copper Foil is closely contacted with electroactive material, the another side that applies the filter paper of slurry is contacted with the zinc paper tinsel, and respectively pick out lead-in wire at Copper Foil and zinc paper tinsel end, envelope is moulded and is made the paper mold battery at last.
Embodiment 4.
At first getting Copper Foil (as positive pole) and aluminium foil (as negative pole) is attached to respectively on two fibrous paper, according to nano-manganese dioxide: carbon nano-tube: zinc chloride: ammonium chloride=1:0.05:0.05:0.1 is made into electroactive material, add appropriate amount of deionized water, fully grind and make slurry, then slurry is coated in the surface of an other filter paper.After dried slightly, again by nanometer iron: carbon nano-tube: iron chloride=1:0.01:0.1, add appropriate amount of deionized water and be made into slurry, slurry is coated in the surface of manganese dioxide electroactive layer, again Copper Foil is closely contacted with electroactive material, the another side that applies the filter paper of slurry is contacted with aluminium foil, and respectively pick out lead-in wire at Copper Foil and AL-foil, envelope is moulded and is made the paper mold battery at last.
Embodiment 5.
At first getting Copper Foil (as positive pole) and zinc paper tinsel (as negative pole) is attached to respectively on two fibrous paper, according to nano-manganese dioxide: carbon nano-tube: zinc chloride: ammonium chloride=1:0.015:0.1:0.05 is made into electroactive material, add appropriate amount of deionized water, fully grind and make slurry, then slurry is coated in the surface of an other fibrous paper.After dried slightly, press nanostructured manganese again: carbon nano-tube: manganese chloride=1:0.01:0.15, add appropriate amount of deionized water and be made into slurry, slurry is coated in the surface of manganese dioxide electroactive layer, again Copper Foil is closely contacted with electroactive material, the another side that applies the fibrous paper of slurry is contacted with the zinc paper tinsel, and respectively pick out lead-in wire at Copper Foil and zinc paper tinsel end, envelope is moulded and is made the paper mold battery at last.
Claims (7)
1. composite bed paper mold battery, with the fibrous paper material is carrier, the two sides of electroactive material layer connects positive and negative electrode respectively, it is characterized in that the electroactive material layer forms by two-layer different electroactive material is folded layer by layer, wherein ground floor electroactive material layer is pressed manganese dioxide: conductive agent: the weight ratio composition of electrolyte=1: 0.01-0.2: 0.01-0.2; Second layer electroactive material layer is pressed metal nano material: conductive agent: the weight ratio of electrolyte=1: 0.01-0.2: 0.01-0.2 is formed.
2. paper mold battery according to claim 1 is characterized in that described metal nano material is Nano Silver, nanometer copper, nanometer nickel, nanostructured manganese or nanometer iron.
3. paper mold battery according to claim 1 is characterized in that described conductive agent is one or more in carbon nano-tube, superfine graphite powder, acetylene black, the Graphene.
4. paper mold battery according to claim 1 is characterized in that described electrolyte is one or more in zinc chloride, nickel chloride, copper chloride, sodium chloride, ammonium chloride, manganese chloride, the iron chloride.
5. paper mold battery according to claim 1 is characterized in that described fibrous paper material is pulp layered paper or filter paper.
6. the preparation method of the described composite bed paper mold of claim 1 battery, it is characterized in that with the fibrous paper material be carrier, at first will be with the electroactive material of manganese dioxide, conductive agent, electrolyte composition, spraying plating or be coated in the surface of fibrous paper material constitutes the ground floor electroactive material layer based on manganese dioxide; After dried slightly, spraying plating or the electroactive material formed coated with metal nano material, conductive agent, electrolyte again on its surface, constitute second layer electroactive material layer, connect positive and negative electrode respectively on the two sides of paper mold electroactive material layer then, constitute the paper mold battery of double-deck electroactive material.
7. preparation method according to claim 6 is characterized in that of the present invention manganese dioxide electroactive material and metal nano electroactive material are adsorbed on the technology that the surface of fibrous paper material adopts is methods such as printing, spraying plating, silk screen seal, coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110083420 CN102170000B (en) | 2011-04-02 | 2011-04-02 | Composite layer paper battery and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110083420 CN102170000B (en) | 2011-04-02 | 2011-04-02 | Composite layer paper battery and preparation method |
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| CN102170000A true CN102170000A (en) | 2011-08-31 |
| CN102170000B CN102170000B (en) | 2013-05-22 |
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| CN 201110083420 Expired - Fee Related CN102170000B (en) | 2011-04-02 | 2011-04-02 | Composite layer paper battery and preparation method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102610786A (en) * | 2011-12-20 | 2012-07-25 | 南昌大学 | Preparation method of ternary composite paper battery positive electrode |
| CN102760891A (en) * | 2012-06-25 | 2012-10-31 | 南昌大学 | Liquid activated zinc-manganese paper battery and preparation method thereof |
| CN108018742A (en) * | 2017-12-17 | 2018-05-11 | 李巧珍 | A kind of preparation method of highly conductive antibacterial water proof type conductive paper |
| EP4008837A1 (en) | 2020-12-03 | 2022-06-08 | Robert Murray-Smith | Paper based materials for the storage of electrical energy |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5469725A (en) * | 1977-11-15 | 1979-06-05 | Matsushita Electric Ind Co Ltd | Layerrbuilt dry element battery |
| JPH0289696A (en) * | 1988-09-28 | 1990-03-29 | Kimoto & Co Ltd | Card-type audio generator |
| CN2558092Y (en) * | 2002-07-16 | 2003-06-25 | 刘勃 | Paper cell |
| CN101404340A (en) * | 2007-09-24 | 2009-04-08 | 恩福塞尔公司 | Thin battery with longer life time |
| CN201608230U (en) * | 2010-01-28 | 2010-10-13 | 吴立 | Environment-friendly paper battery |
-
2011
- 2011-04-02 CN CN 201110083420 patent/CN102170000B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5469725A (en) * | 1977-11-15 | 1979-06-05 | Matsushita Electric Ind Co Ltd | Layerrbuilt dry element battery |
| JPH0289696A (en) * | 1988-09-28 | 1990-03-29 | Kimoto & Co Ltd | Card-type audio generator |
| CN2558092Y (en) * | 2002-07-16 | 2003-06-25 | 刘勃 | Paper cell |
| CN101404340A (en) * | 2007-09-24 | 2009-04-08 | 恩福塞尔公司 | Thin battery with longer life time |
| CN201608230U (en) * | 2010-01-28 | 2010-10-13 | 吴立 | Environment-friendly paper battery |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102610786A (en) * | 2011-12-20 | 2012-07-25 | 南昌大学 | Preparation method of ternary composite paper battery positive electrode |
| CN102610786B (en) * | 2011-12-20 | 2014-06-18 | 南昌大学 | Preparation method of ternary composite paper battery positive electrode |
| CN102760891A (en) * | 2012-06-25 | 2012-10-31 | 南昌大学 | Liquid activated zinc-manganese paper battery and preparation method thereof |
| CN102760891B (en) * | 2012-06-25 | 2014-11-26 | 南昌大学 | Liquid activated zinc-manganese paper battery and preparation method thereof |
| CN108018742A (en) * | 2017-12-17 | 2018-05-11 | 李巧珍 | A kind of preparation method of highly conductive antibacterial water proof type conductive paper |
| EP4008837A1 (en) | 2020-12-03 | 2022-06-08 | Robert Murray-Smith | Paper based materials for the storage of electrical energy |
| WO2022117761A1 (en) | 2020-12-03 | 2022-06-09 | Kabel Premium Pulp & Paper Gmbh | Paper based materials for the storage of electrical energy |
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| Publication number | Publication date |
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| CN102170000B (en) | 2013-05-22 |
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Effective date of registration: 20180408 Address after: 342500 Jiangxi province Ruijin economic and Technological Development Zone Jinlong two road innovation and entrepreneurial incubator base Patentee after: Ruijin Hongdu Industrial Investment Development Co. Ltd. Address before: 999 No. 330031 Jiangxi province Nanchang Honggutan University Avenue Patentee before: Nanchang University |
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