CN102110858B - Chargeable zinc ion battery by taking oxide of vanadium as cathode - Google Patents
Chargeable zinc ion battery by taking oxide of vanadium as cathode Download PDFInfo
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- CN102110858B CN102110858B CN2009102389121A CN200910238912A CN102110858B CN 102110858 B CN102110858 B CN 102110858B CN 2009102389121 A CN2009102389121 A CN 2009102389121A CN 200910238912 A CN200910238912 A CN 200910238912A CN 102110858 B CN102110858 B CN 102110858B
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- zinc ion
- zinc
- vanadium
- ion battery
- cathode
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- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 22
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 22
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003792 electrolyte Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000007774 positive electrode material Substances 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000011532 electronic conductor Substances 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- 238000005260 corrosion Methods 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 239000011149 active material Substances 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 abstract description 21
- 229910052725 zinc Inorganic materials 0.000 abstract description 17
- 230000002441 reversible effect Effects 0.000 abstract description 6
- 230000007246 mechanism Effects 0.000 abstract description 3
- 238000004146 energy storage Methods 0.000 abstract description 2
- 238000003780 insertion Methods 0.000 abstract description 2
- 230000037431 insertion Effects 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000010405 anode material Substances 0.000 abstract 1
- 239000010406 cathode material Substances 0.000 abstract 1
- 229910021541 Vanadium(III) oxide Inorganic materials 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 7
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 239000006230 acetylene black Substances 0.000 description 5
- 238000002484 cyclic voltammetry Methods 0.000 description 4
- 239000006258 conductive agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009102389121A CN102110858B (en) | 2009-12-29 | 2009-12-29 | Chargeable zinc ion battery by taking oxide of vanadium as cathode |
Applications Claiming Priority (1)
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CN2009102389121A CN102110858B (en) | 2009-12-29 | 2009-12-29 | Chargeable zinc ion battery by taking oxide of vanadium as cathode |
Publications (2)
Publication Number | Publication Date |
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CN102110858A CN102110858A (en) | 2011-06-29 |
CN102110858B true CN102110858B (en) | 2013-04-17 |
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CN2009102389121A Active CN102110858B (en) | 2009-12-29 | 2009-12-29 | Chargeable zinc ion battery by taking oxide of vanadium as cathode |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102324579A (en) * | 2011-09-07 | 2012-01-18 | 清华大学深圳研究生院 | A kind of Zinc ion battery |
CN103400974B (en) * | 2013-08-09 | 2016-01-06 | 重庆大学 | Vanadium system oxide makes application and the sol-gel process for preparing thereof of magnesium secondary battery cathode material |
MX2016016760A (en) * | 2014-06-16 | 2017-07-11 | Ttsb S R L | Rechargeable battery containing zinc ions. |
CA2962296C (en) | 2015-06-08 | 2018-11-13 | University Of Waterloo | Electrode materials for rechargeable zinc cells and batteries produced therefrom |
CN108878877B (en) * | 2018-07-03 | 2021-01-05 | 中国科学院宁波材料技术与工程研究所 | Positive electrode active material for aqueous zinc ion secondary battery and aqueous zinc ion secondary battery |
CN109650441B (en) * | 2018-12-19 | 2021-07-06 | 广东工业大学 | Vanadium-zinc-heptaoxide positive electrode material of battery and preparation method thereof |
EP3921068B1 (en) * | 2019-02-05 | 2024-06-19 | Council Of Scientific & Industrial Research | A metal ion battery having ionomer membrane separator and free-standing electrode |
CN111129451B (en) * | 2019-12-12 | 2021-04-20 | 中南大学 | VN fusiform nanorod with core-shell structure and preparation method and application thereof |
CN112993217A (en) * | 2019-12-13 | 2021-06-18 | 中国科学院大连化学物理研究所 | Preparation method of organic-inorganic hybrid material based on vanadium pentoxide and application of organic-inorganic hybrid material in zinc ion battery |
CN111640921A (en) * | 2020-05-22 | 2020-09-08 | 大连海事大学 | Preparation method of vanadium compound electrode material and application of vanadium compound electrode material in water-based zinc ion battery |
CN112803096B (en) * | 2021-01-21 | 2022-04-01 | 中国地质大学(武汉) | Energy storage and capacity integrated battery |
CN114284484A (en) * | 2021-12-27 | 2022-04-05 | 王俊英 | Preparation method and application of cobalt-based MOF-loaded vanadium dioxide zinc ion battery positive electrode material |
CN114725391A (en) * | 2022-04-06 | 2022-07-08 | 华南理工大学 | Zinc-ion battery positive electrode material and preparation method and application thereof |
CN116110723A (en) * | 2023-02-08 | 2023-05-12 | 华南农业大学 | Photoelectric positive electrode, preparation method and application thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5342712A (en) * | 1993-05-17 | 1994-08-30 | Duracell Inc. | Additives for primary electrochemical cells having manganese dioxide cathodes |
CN1109641A (en) * | 1993-04-20 | 1995-10-04 | 蓄电池技术股份有限公司 | Manganese dioxide positive electrode for rechargeable alkaline cells, and cells containing the same |
CN1238569A (en) * | 1998-06-10 | 1999-12-15 | 株式会社华仁电池 | Aqueous zinc sulfate (II) rechargeable cell containing manganese (II) salt and carbon powder |
CN1357934A (en) * | 2000-12-13 | 2002-07-10 | 深圳市比亚迪实业有限公司 | Manganese dioxide electrode and primary alkaline zinc-manganese battery thereof |
-
2009
- 2009-12-29 CN CN2009102389121A patent/CN102110858B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1109641A (en) * | 1993-04-20 | 1995-10-04 | 蓄电池技术股份有限公司 | Manganese dioxide positive electrode for rechargeable alkaline cells, and cells containing the same |
US5342712A (en) * | 1993-05-17 | 1994-08-30 | Duracell Inc. | Additives for primary electrochemical cells having manganese dioxide cathodes |
CN1238569A (en) * | 1998-06-10 | 1999-12-15 | 株式会社华仁电池 | Aqueous zinc sulfate (II) rechargeable cell containing manganese (II) salt and carbon powder |
CN1357934A (en) * | 2000-12-13 | 2002-07-10 | 深圳市比亚迪实业有限公司 | Manganese dioxide electrode and primary alkaline zinc-manganese battery thereof |
Non-Patent Citations (4)
Title |
---|
.《锌离子在水相介质Zn/V_2O_5二次电池中的迁移性能研究》.《电化学》.1998,第4卷(第2期),170-175. * |
周家宏 * |
潘谷平 * |
薛宽宏 * |
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CN102110858A (en) | 2011-06-29 |
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Owner name: SHENZHEN HANSHU NEW ENERGY TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHENZHEN GRADUATE SCHOOL, TSINGHUA UNIV. Effective date: 20150514 |
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Effective date of registration: 20150514 Address after: 518101, Guangdong, Shenzhen, Xixiang, Baoan District iron Gang Reservoir Road, the Peach Garden science and Technology Innovation Park, fourth sub Park, 1, 2 floor Patentee after: SHENZHEN CUBIC-SCIENCE Co.,Ltd. Address before: Shenzhen Graduate School of Guangdong Province, Shenzhen City Xili 518055 Nanshan District University City Tsinghua University Patentee before: Graduate School at Shenzhen, Tsinghua University |
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Address after: Room 401, Unit 1, Building 1, Xinchen New Materials Pilot Industrialization Base, No. 300, Shutianpu Road, Shutianpu Community, Matian Street, Guangming District, Shenzhen, Guangdong Province, 518000 Patentee after: SHENZHEN CUBIC-SCIENCE Co.,Ltd. Address before: 518101 Building 1, 2nd Floor, Taohuayuan Science and Technology Innovation Park Fourth Branch, Tiegang Reservoir Road, Xixiang, Bao'an District, Shenzhen, Guangdong Province Patentee before: SHENZHEN CUBIC-SCIENCE Co.,Ltd. |
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