CN102110858A - Chargeable zinc ion battery by taking oxide of vanadium as cathode - Google Patents

Chargeable zinc ion battery by taking oxide of vanadium as cathode Download PDF

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CN102110858A
CN102110858A CN2009102389121A CN200910238912A CN102110858A CN 102110858 A CN102110858 A CN 102110858A CN 2009102389121 A CN2009102389121 A CN 2009102389121A CN 200910238912 A CN200910238912 A CN 200910238912A CN 102110858 A CN102110858 A CN 102110858A
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zinc
ion battery
zinc ion
chargeable
vanadium
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CN102110858B (en
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康飞宇
徐成俊
李宝华
杜鸿达
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Shenzhen Cubic Science Co ltd
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Shenzhen Graduate School Tsinghua University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

The invention discloses a chargeable zinc ion battery. A cathode is made from an oxide material of vanadium; an anode is made from a material which mainly comprises zinc elements; electrolyte is liquid or gel which takes the soluble salt of zinc as a solute, takes water as a solvent and has ionic conductivity. By utilizing reversible insertion or removal of zinc ions in a cathode material lattice, and the energy storage mechanism that an anode material which mainly comprises the zinc elements is oxidized or the zinc ions are reduced on the surface of the anode, the battery has the characteristics that: the battery is high in capacity and chargeable.

Description

Oxide with vanadium is the chargeable Zinc ion battery of positive pole
Technical field
The invention belongs to the battery technology field, be specifically related to a kind of zinc ion and take off embedding and at the chargeable zinc ion battery of negative pole reduction or oxidation at positive electrode active materials.
Background technology
Along with constant development of economy, must cause the scarcity of petroleum resources and the pollution of environment, so the development and utilization of the comprehensive high-efficiency of new green power has become very necessary problem.The primary cell of comparing, secondary cell can repeat repeatedly to carry out charge and discharge cycles, can make full use of raw material, so its more economical practicality.
It is anodal with manganese dioxide that the application of CN 101540417A Chinese invention patent discloses a kind of first, with zinc is negative pole, with the solution that contains zinc ion is the chargeable Zinc ion battery of electrolyte, zinc ion is deviate from manganese dioxide process electrolyte then in the negative pole deposition when charging, and said process is just opposite during discharge.
The mechanism of this Zinc ion battery stored electrons is as follows:
Anodal:
Negative pole:
Figure G2009102389121D00012
Take off the embedding behavior owing to use zinc ion positive electrode reversible, therefore this battery that fills zinc ion has the capacity height, and characteristics such as have extended cycle life.This Zinc ion battery can be widely used in fields such as individual digital notepad, Blectronic Organizers, mobile phone, cordless telephone, beeper, electronic toy, game machine, portable data terminals, personal audio video-unit, experimental provision, palmtop computer.
This performance of filling Zinc ion battery is subjected to the performance impact of positive electrode, and in order further to improve the performance of chargeable Zinc ion battery, and seeking the positive electrode of new function admirable unreal is a kind of good method.
Summary of the invention
The purpose of this invention is to provide a kind of new secondary cell.
Vanadium has multiple valence state, has multiple oxide, and the oxide of vanadium has multiple crystal formation, and recently, the inventor has found divalent zinc ion (Zn first 2+) in the aqueous solution at the oxide material V of vanadium 2O 5, V 6O 13, VO 2, V 3O 7, V 6O 14Deng in the reversible behavior that embeds fast and deviate from, the embedding behavior of this zinc ion has characteristics such as capacity height, degree of reversibility be good.On the other hand, zinc can carry out reversible electrochemical deposition and dissolving in the aqueous solution.Find that at this we have invented a kind of chargeable zinc ion battery on basis, its oxide with vanadium is a positive electrode active materials, and zinc is negative active core-shell material, contains Zn 2+The aqueous solution is electrolyte, when charging zinc ion deviate from the oxide of positive electrode active materials vanadium through electrolyte then in the negative pole deposition, negative pole zinc is dissolved as in zinc ion is embedded into the positive electrode vanadium through electrolyte the tunnel of oxide during discharge.
The concrete scheme of the secondary cell that the present invention proposes is as follows:
A kind of chargeable Zinc ion battery, form by positive pole, negative pole, marginal barrier film and the electrolyte that contains zwitterion and have an ionic conductivity, it is characterized in that: the active material of described negative pole is based on zinc element, but the active material of described positive pole is oxide or its hyrate of occlusion and the vanadium that discharges zinc ion, and described electrolyte is that the soluble-salt with zinc is that solute, water are solvent and liquid state with ionic conductivity or gel state material.
The oxide of described vanadium can be vanadic oxide (V 2O 5), 13 oxidations, six vanadium (V 6O 13), vanadium dioxide (VO 2), seven oxidations, three vanadium (V 3O 7) or 14 oxidations, six vanadium (V 6O 14) etc.
Described negative pole can be the alloy of simple metal zinc or zinc.Described negative pole also can adopt following scheme: negative pole comprises collector and the negative electrode film that is attached on the collector, and this negative electrode film can be made by zinc powder and binding agent, also can further add corrosion inhibiter and/or electron conduction agent in negative electrode film.Wherein, binding agent can be selected polytetrafluoroethylene, water-soluble rubber, poly-inclined to one side tetrafluoroethene or cellulose; The addition of corrosion inhibiter is below 1% of negative electrode film quality, and corrosion inhibiter is used for restraining or eliminating zinc element evolving hydrogen reaction, the oxide of preferred indium, the hydroxide or the metallic copper of indium; The addition of electron conduction agent is below 50% of negative electrode film quality, preferred graphite, carbon black, acetylene black, charcoal fiber or carbon nanotube.
Described positive pole comprises collector and the cathode film that is attached on the collector, and this cathode film is made by described active material (being the oxide of vanadium or the hyrate of this oxide), electron conduction agent and the binding agent of positive pole.Wherein, the electron conduction agent is graphite, carbon black, acetylene black, charcoal fiber or carbon nanotube, and addition is below 50% of cathode film quality; Binding agent is polytetrafluoroethylene, water-soluble rubber, poly-inclined to one side tetrafluoroethene or cellulose, and addition is below 20% of cathode film quality.Zinc ion can carry out reversible embedding and deviate from the lattice of positive electrode active materials, with the positive electrode active materials Mass Calculation, the capacity that described positive electrode active materials stores zinc ion is not less than 100mAh/g.
The inorganic salts of zinc such as the preferred zinc nitrate of the soluble-salt of described zinc, zinc sulfate or zinc chloride.Can wait and regulate electrolytical pH value by adding acid, alkali or cushioning liquid 3~7.
The chargeable Zinc ion battery of the present invention can be made button, column type or square structure.
Battery of the present invention utilizes zinc ion (Zn 2+) in the oxide lattice of vanadium reversible insertion or deviate from, simultaneously the negative material based on zinc element carries out oxidation or zinc ion (Zn 2+) in the energy storage mechanism of negative terminal surface reduction, this battery has the high and chargeable characteristics of capacity.The experiment proved that the chargeable Zinc ion battery of the present invention has good high rate performance, reversibility and cycle performance.This Zinc ion battery can be predicted and fields such as individual digital notepad, Blectronic Organizers, mobile phone, cordless telephone, beeper, electronic toy, game machine, portable data terminals, personal audio video-unit, experimental provision, palmtop computer can be widely used in.
Description of drawings
The vanadic oxide electrode that Fig. 1 makes for embodiment 1 is at 1mol L -1ZnSO 4Sweep speed is 1mV s in the electrolyte -1The time the single electrode cyclic voltammogram.
The chargeable Zinc ion battery that Fig. 2 makes for embodiment 1 is 1mV s in sweep speed -1The time cyclic voltammogram.
The chargeable Zinc ion battery that Fig. 3 makes for embodiment 1 is at 250mA g -1(with the positive electrode active materials Mass Calculation) discharges and charging curve first.
The chargeable Zinc ion battery that Fig. 4 makes for embodiment 2 is at 300mA g -1(with the positive electrode active materials Mass Calculation) discharges and charging curve first.
Embodiment
Embodiment 1:
Be coated on the stainless steel foil after vanadic oxide, conductive agent acetylene black and polyfluortetraethylene of binding element mixed with 7: 2: 1 mass ratio, be cut into a certain size, oven dry makes the vanadic oxide electrode slice in vacuum.It is work electrode that the vanadic oxide electrode slice is adopted in the single electrode test, is to electrode, with Hg/Hg with the metal platinum electrode 2SO 4(in saturated K 2SO 4) detect for reference electrode.The vanadic oxide electrode is at 1mol L -1ZnSO 4Cyclic voltammogram in the aqueous solution such as Fig. 1, sweep speed is 1mV s -1, there are two oxidation peak and two reduction peak to occur as can be seen, deviate from and embed in that vanadic oxide is intracell corresponding to zinc ion.
With the vanadic oxide electrode slice is positive pole, is negative pole with the thick zinc paper tinsel of 0.1mm, and electrolyte is 1mol L -1ZnSO 4The aqueous solution is assembled into chargeable Zinc ion battery.This battery is at 1mV s -1Cyclic voltammetry curve under the sweep speed such as Fig. 2, the result is consistent with the single electrode test result.This battery is at 250mA g -1Repeatedly charge and discharge cycles curve under the constant current as shown in Figure 3, this as can be seen battery can repeat to discharge and recharge and be that rechargeable battery, the capacity under this electric current are 300mAh g -1(with the positive electrode active materials Mass Calculation), coulombic efficiency is near 100%.The result shows that the filled Zinc ion battery that this oxide with vanadium is a positive electrode active materials has the high characteristics of capacity, and it is the capacity of the chargeable Zinc ion battery of positive pole with manganese dioxide that its capacity is higher than disclosed in the application of CN101540417A Chinese invention patent.
Embodiment 2:
Be after 40: 50: 10 the mixed, to be pressed on the stainless (steel) wire by mass ratio with zinc powder, conductive agent acetylene black and polyfluortetraethylene of binding element, be cut into a certain size, oven dry makes the zinc powder electrode in vacuum.Vanadic oxide electrode with embodiment 1 preparation is a positive pole, is negative pole with this zinc powder electrode, and the zinc powder quality is ten times of vanadic oxide quality, and electrolyte is 0.1mol L -1ZnSO 4The aqueous solution is assembled into the buckle type rechargeable Zinc ion battery.Embodiment 2 obtained Zinc ion batteries are at 300mA g -1The charge and discharge cycles curve is seen Fig. 4 under (with the positive electrode active materials Mass Calculation) constant current, and battery capacity is 268mAh g -1, coulombic efficiency is more than 90%.
Embodiment 3:
Be coated on the stainless steel foil after seven oxidations, three vanadium, conductive agent acetylene black and polyfluortetraethylene of binding element mixed with 7: 2: 1 mass ratio, be cut into a certain size, oven dry makes seven oxidations, three vanadium electrode slices in vacuum.
With seven oxidations, three vanadium sheets is positive pole, is negative pole with the thick zinc paper tinsel of 0.1mm, and electrolyte is 1mol L -1ZnSO 4The aqueous solution is assembled into chargeable Zinc ion battery.After tested, this battery is at 200mA g -1Capacity under the constant current is 280mAh g -1(with the positive electrode active materials Mass Calculation), coulombic efficiency is more than 90%.

Claims (10)

1. chargeable Zinc ion battery is made up of positive pole, negative pole, marginal barrier film and the electrolyte that contains zwitterion and have an ionic conductivity, it is characterized in that:
The active material of described negative pole is based on zinc element,
But the active material of described positive pole is occlusion and oxide or its hyrate that discharges the vanadium of zinc ion,
Described electrolyte is that the soluble-salt with zinc is that solute, water are solvent and liquid state with ionic conductivity or gel state material.
2. chargeable Zinc ion battery according to claim 1 is characterized in that: the oxide of described vanadium is vanadic oxide, 13 oxidations, six vanadium, vanadium dioxide, seven oxidations, three vanadium or 14 oxidations, six vanadium.
3. chargeable Zinc ion battery according to claim 2 is characterized in that: described positive pole comprises collector and the cathode film that is attached on the collector, and this cathode film is made by described active material, electron conduction agent and the binding agent of positive pole.
4. chargeable Zinc ion battery according to claim 1 is characterized in that: described negative pole is the alloy of simple metal zinc or zinc.
5. chargeable Zinc ion battery according to claim 1 is characterized in that: described negative pole comprises collector and the negative electrode film that is attached on the collector, and this negative electrode film is made by zinc powder and binding agent.
6. chargeable Zinc ion battery according to claim 1 is characterized in that: described negative pole comprises collector and the negative electrode film that is attached on the collector, and this negative electrode film is made by zinc powder, binding agent and corrosion inhibiter.
7. chargeable Zinc ion battery according to claim 1 is characterized in that: described negative pole comprises collector and the negative electrode film that is attached on the collector, and this negative electrode film is made by zinc powder, binding agent and electron conduction agent.
8. chargeable Zinc ion battery according to claim 1, it is characterized in that: described negative pole comprises collector and the negative electrode film that is attached on the collector, this negative electrode film is made by zinc powder, binding agent, corrosion inhibiter and electron conduction agent, the addition of electron conduction agent is below 50% of negative electrode film quality, and the addition of corrosion inhibiter is below 1% of negative electrode film quality.
9. according to each described chargeable Zinc ion battery of claim 1-8, it is characterized in that: with the positive electrode active materials Mass Calculation, the capacity that described positive electrode active materials stores zinc ion is not less than 100mAh/g.
10. according to each described chargeable Zinc ion battery of claim 1-8, it is characterized in that: the soluble-salt of described zinc is zinc nitrate, zinc sulfate or zinc chloride.
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102324579A (en) * 2011-09-07 2012-01-18 清华大学深圳研究生院 A kind of Zinc ion battery
CN103400974A (en) * 2013-08-09 2013-11-20 重庆大学 Application of vanadium oxide in serving as magnesium secondary battery cathode material and sol-gel preparation method thereof
WO2016197236A1 (en) * 2015-06-08 2016-12-15 Adams Brian D Electrode materials for rechargeable zinc cells and batteries produced therefrom
CN106575758A (en) * 2014-06-16 2017-04-19 特斯博有限责任公司 Rechargeable battery containing zinc ions
CN108878877A (en) * 2018-07-03 2018-11-23 中国科学院宁波材料技术与工程研究所 A kind of water system zinc ion cathode active material for secondary battery and a kind of water system zinc ion secondary cell
CN109650441A (en) * 2018-12-19 2019-04-19 广东工业大学 One kind seven aoxidizes three vanadium Zinc ion battery positive electrodes and preparation method thereof
CN111129451A (en) * 2019-12-12 2020-05-08 中南大学 VN fusiform nanorod with core-shell structure and preparation method and application thereof
CN111640921A (en) * 2020-05-22 2020-09-08 大连海事大学 Preparation method of vanadium compound electrode material and application of vanadium compound electrode material in water-based zinc ion battery
CN112803096A (en) * 2021-01-21 2021-05-14 中国地质大学(武汉) Energy storage and capacity integrated battery
CN112993217A (en) * 2019-12-13 2021-06-18 中国科学院大连化学物理研究所 Preparation method of organic-inorganic hybrid material based on vanadium pentoxide and application of organic-inorganic hybrid material in zinc ion battery
JP2022523142A (en) * 2019-02-05 2022-04-21 カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ Metal ion battery with ionomer membrane separator and self-supporting electrode
CN114725391A (en) * 2022-04-06 2022-07-08 华南理工大学 Zinc-ion battery positive electrode material and preparation method and application thereof
CN116110723A (en) * 2023-02-08 2023-05-12 华南农业大学 Photoelectric positive electrode, preparation method and application thereof

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102324579A (en) * 2011-09-07 2012-01-18 清华大学深圳研究生院 A kind of Zinc ion battery
CN103400974A (en) * 2013-08-09 2013-11-20 重庆大学 Application of vanadium oxide in serving as magnesium secondary battery cathode material and sol-gel preparation method thereof
CN103400974B (en) * 2013-08-09 2016-01-06 重庆大学 Vanadium system oxide makes application and the sol-gel process for preparing thereof of magnesium secondary battery cathode material
CN106575758A (en) * 2014-06-16 2017-04-19 特斯博有限责任公司 Rechargeable battery containing zinc ions
WO2016197236A1 (en) * 2015-06-08 2016-12-15 Adams Brian D Electrode materials for rechargeable zinc cells and batteries produced therefrom
US9780412B2 (en) 2015-06-08 2017-10-03 Adams Brian D Electrode materials for rechargeable zinc cells and batteries produced therefrom
CN108878877A (en) * 2018-07-03 2018-11-23 中国科学院宁波材料技术与工程研究所 A kind of water system zinc ion cathode active material for secondary battery and a kind of water system zinc ion secondary cell
CN109650441A (en) * 2018-12-19 2019-04-19 广东工业大学 One kind seven aoxidizes three vanadium Zinc ion battery positive electrodes and preparation method thereof
JP2022523142A (en) * 2019-02-05 2022-04-21 カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ Metal ion battery with ionomer membrane separator and self-supporting electrode
JP7265019B2 (en) 2019-02-05 2023-04-25 カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ METAL-ION BATTERY WITH IONOMER MEMBRANE SEPARATOR AND FREE-STANDING ELECTRODES
EP3921068A4 (en) * 2019-02-05 2023-08-16 Council Of Scientific & Industrial Research A metal ion battery having ionomer membrane separator and free-standing electrode
CN111129451A (en) * 2019-12-12 2020-05-08 中南大学 VN fusiform nanorod with core-shell structure and preparation method and application thereof
CN112993217A (en) * 2019-12-13 2021-06-18 中国科学院大连化学物理研究所 Preparation method of organic-inorganic hybrid material based on vanadium pentoxide and application of organic-inorganic hybrid material in zinc ion battery
CN111640921A (en) * 2020-05-22 2020-09-08 大连海事大学 Preparation method of vanadium compound electrode material and application of vanadium compound electrode material in water-based zinc ion battery
CN112803096A (en) * 2021-01-21 2021-05-14 中国地质大学(武汉) Energy storage and capacity integrated battery
CN114725391A (en) * 2022-04-06 2022-07-08 华南理工大学 Zinc-ion battery positive electrode material and preparation method and application thereof
CN116110723A (en) * 2023-02-08 2023-05-12 华南农业大学 Photoelectric positive electrode, preparation method and application thereof

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