CN102167771A - Anti-corrosion primer emulsion and preparation method thereof - Google Patents
Anti-corrosion primer emulsion and preparation method thereof Download PDFInfo
- Publication number
- CN102167771A CN102167771A CN2010105607173A CN201010560717A CN102167771A CN 102167771 A CN102167771 A CN 102167771A CN 2010105607173 A CN2010105607173 A CN 2010105607173A CN 201010560717 A CN201010560717 A CN 201010560717A CN 102167771 A CN102167771 A CN 102167771A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- mixture
- monomer
- percent
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses anti-corrosion primer emulsion for water-based high-corrosion-resistance air-conditioning aluminum foil paint and a preparation method thereof. The anti-corrosion primer emulsion comprises the following components in percentage by weight: 8 to 15 percent of styrene, 12 to 20 percent of butyl acrylate, 0 to 2.5 percent of methyl methacrylate, 6 to 8 percent of (methyl) ethyl acrylate, 0.3 to 0.7 percent of (methyl) acrylic acid, 0 to 1.2 percent of vinyl acetate, 1 to 8 percent of phosphate functional monomer, 1 to 5 percent of emulsifier, 0.1 to 0.5 percent of initiator, 0.6 to 1.0 percent of pH regulator and the balance of deionized water. In the preparation method of the acrylic acid emulsion, the phosphate functional monomer is added and a polymerizable composite emulsifier takes part in seeded emulsion polymerization, so that stability and corrosion resistance of the acrylic acid emulsion are improved.
Description
Technical field
The present invention relates to air-conditioning paper tinsel coating emulsion technical field, particularly a kind of ACRYLIC EMULSION of using of water-based high corrosion resistance aluminum foil paint for air-conditioning and preparation method thereof.
Background technology
Aluminium foil can protect unlined aluminium not corroded from the aluminum oxide film that forms one deck densification in air; but in the time of in being in moist acid or alkali environment; oxide film reacts easily and disappears; thereby lose provide protection, rapid oxidation and galvanic corrosion then take place in interior metal aluminium, produce by " white powder "; have a strong impact on the working efficiency of air-condition heat exchanger; shorten the work-ing life of air conditioner aluminium foil, and breed bacteria on it, produce peculiar smell, spread disease germs.Therefore needing has the erosion resistance requirement or carries out surface treatment to obtain the highly corrosion resistant protection at the aluminium that the drying and watering cycle condition is used work.Be coated with last layer to have filming of erosion resistance be a kind of effective anti-corrosion method on the surface.Along with the development of air-conditioning towards lightweight, miniaturization, high energy efficiency ratio, be used for aluminum foil thickness at present and reduced to about 0.1mm, spacing of fin is less than 2mm, and is also just more and more higher to the rotproofing requirement of fin surface.
At present, the matrix that air-conditioning paper tinsel protective system is used has Resins, epoxy, ACRYLIC EMULSION, mainly has following problem:
(1) preservative effect is outstanding: obvious corrosion, under 25 ℃ of conditions, promptly take place behind the immersion 5min in thickness 0.8 μ m in 20%NaOH or 10%HCl;
(2) stability of emulsion is bad, and condensation product is many, and viscosity can change with the prolongation of storage period;
(3) the emulsion taste is heavier, bubble ratio is more, not environmental protection of working-yard.
Summary of the invention
The objective of the invention is to overcome above shortcoming, provide a kind of preservative effect to give prominence to, hang down prescription of the ACRYLIC EMULSION of steeping, have aromatising flavour, stable performance and preparation method thereof.
Technical scheme of the present invention: a kind of anti-corrosion primer emulsion, its main ingredient and content following (weight percent):
Vinyl monomer: 27.3-55.4%;
Emulsifying agent: 1-5%;
Initiator: 0.1-0.5%;
PH conditioning agent: 0.6-1.0%;
Deionized water: surplus.
The percentage composition of each component of described vinyl monomer and shared emulsion is: vinylbenzene 8-15%, butyl acrylate 12-20%, methyl methacrylate 0-2.5%, (methyl) Hydroxyethyl acrylate 6-8%, (methyl) vinylformic acid 0.3-0.7%, vinyl acetate 0-1.2%, phosphoric acid ester function monomer: 1-8%.
Described emulsifying agent is a mixed emulsifier, comprises at least two kinds in alkylphenol polyvinyl sulfuric acid ammonium/sodium, sodium laurylsulfonate, sodium lauryl sulphate, polyoxyethylene nonylphenol ether, the allyloxy hydroxide sodium dimercaptosulphanatein.
Described phosphoric acid ester function monomer is at least a in alkyl (aryl) phosphoric acid ester, Fatty Alcohol(C12-C14 and C12-C18) (alkylphenol) polyoxyethylene ether phosphate, alkylol amide phosphoric acid ester, imidazolines phosphoric acid ester, hydroxyethyl phosphate tensio-active agent, polyphosphazene polymer phosphoric acid ester, the siloxanes phosphoric acid ester.
Described initiator is Potassium Persulphate or ammonium persulphate.
Described PH conditioning agent is a thanomin.
Can add aromatoising substance in the above-mentioned primer emulsion.
Above-mentioned water-repellent preservation solidifying priming paint agent preparation of compositions method, preparation process is as follows:
A, in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, add compound emulsifying agent 1-5% and deionized water 45-50% successively, under 45 ℃ of-65 ℃ of conditions stirring and emulsifying 5-30 minute, make mixture A;
B, in the special-purpose stock chest of monomer, be weighed into vinylbenzene 8-15%, butyl acrylate 12-20%, methyl methacrylate 0-2.5%, (methyl) Hydroxyethyl acrylate 6-8%, (methyl) vinylformic acid 0.3-0.7%, vinyl acetate 0-1.2%, phosphoric acid ester function monomer: 1-8% successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into initiator 0.1-0.5% and deionized water 15-20%, mix, make mixture C;
D, the monomer mixture B of 4%-8% weight is added in the reactor among the step a, stirred 5-30 minute down at 78 ℃-90 ℃;
E, the mixture C of 20%-40% weight is added in the reactor among the step a, stirred 10-60 minute down, make seed emulsion at 78 ℃-90 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor, and monomer mixture B and mixture C can drip synchronously or mixture C dripped than monomer mixture B hysteresis in 5-10 minute, under 78 ℃ of-90 ℃ of conditions, all dripped 1.5-3 hour, dropwise the back and under 83 ℃ of-90 ℃ of conditions, be incubated 0.5-1.5 hour;
G, be cooled to 40 ℃ after, with PH conditioning agent thanomin emulsion is adjusted into 8.5-9.5, can add aromatoising substance, stir, make ACRYLIC EMULSION.
The anti-corrosion primer emulsion of the inventive method preparation, selected the phosphoric acid ester functional monomer for use, increased and the wet sticking power of base material, preservative effect is outstanding, is the primary coat of matrix preparation with this emulsion, at thickness in monolayer 0.8 μ m, under 25 ℃ of conditions, soaking 60min among 20%NaOH or the 10%HCl does not still have corrosion, and along with the prolongation of time, anticorrosion advantage is obvious more.Simultaneously, the present invention selects for use the polymerizable mixed emulsifier to participate in seeded emulsion polymerization, has improved the stability of emulsion, almost do not have condensation product, and bubble is few; And, can add a small amount of aromatoising substance and carry out the taste improvement in the preparation later stage.Use the water-based anticorrosive paint of ACRYLIC EMULSION preparation of the present invention to have good environmental protection and antiseptic property.
Embodiment
Below in conjunction with embodiment technical solution of the present invention is done further detailed description, but embodiments of the present invention are not limited thereto.
Each embodiment component and weight are as follows:
Embodiment 1 preparation process:
A, add each composition of emulsifying agent among the embodiment 1 successively in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, stirring and emulsifying is 30 minutes under 45 ℃ of conditions, makes mixture A;
B, in the special-purpose stock chest of monomer, be weighed into each component of vinyl monomer among the embodiment 1 successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into initiator component among the embodiment 1, mix, make mixture C;
D, the monomer mixture B of 4% weight is added reactor among the step a, stirred 15 minutes down at 80 ℃;
E, the mixture C of 20% weight is added in the reactor among the step a, stirred 30 minutes down, make seed emulsion at 80 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor, wherein mixture C lags behind than monomer mixture B and dripped in 5 minutes, all drips 3 hours under 80 ℃ of conditions, dropwises the back 85 ℃ of insulations 1 hour down;
G, be cooled to 40 ℃ after, with thanomin emulsion is adjusted into 8.5, add aromatoising substance 0.01%, stir, make ACRYLIC EMULSION.
Embodiment 2 preparation processes:
A, add each component of emulsifying agent among the embodiment 2 successively in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, stirring and emulsifying is 5 minutes under 65 ℃ of conditions, makes mixture A;
B, in the special-purpose stock chest of monomer, be weighed into each component of vinyl monomer among the embodiment 2 successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into an initiator component among the embodiment 2, mix, make mixture C;
D, the monomer mixture B of 5% weight is added reactor among the step a, stirred 5 minutes down at 82 ℃;
E, the mixture C of 25% weight is added in the reactor among the step a, stirred 60 minutes down, make seed emulsion at 82 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor synchronously continuously, under 82 ℃ of conditions, all dripped 2 hours, dropwise the back 88 ℃ of insulations 1.5 hours down;
G, be cooled to 40 ℃ after, with thanomin emulsion is adjusted into 9.0, stir, make ACRYLIC EMULSION.
Embodiment 3 preparation processes:
A, add each component of emulsifying agent among the embodiment 3 successively in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, stirring and emulsifying is 10 minutes under 60 ℃ of conditions, makes mixture A;
B, in the special-purpose stock chest of monomer, be weighed into each component of vinyl monomer among the embodiment 3 successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into an initiator component among the embodiment 3, mix, make mixture C;
D, the monomer mixture B of 6% weight is added reactor among the step a, stirred 20 minutes down at 85 ℃;
E, the mixture C of 30% weight is added in the reactor among the step a, stirred 40 minutes down, make seed emulsion at 85 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor synchronously continuously, under 85 ℃ of conditions, all dripped 2 hours, dropwise the back 90 ℃ of insulations 40 minutes down;
G, be cooled to 40 ℃ after, with thanomin emulsion is adjusted into 9.0, add aromatoising substance 0.02%, stir, make ACRYLIC EMULSION.
Embodiment 4 preparation processes:
A, add each component of emulsifying agent among the embodiment 4 successively in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, stirring and emulsifying is 12 minutes under 62 ℃ of conditions, makes mixture A;
B, in the special-purpose stock chest of monomer, be weighed among the embodiment 4 vinyl monomer successively and give component, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into each component of initiator among the embodiment 4, mix, make mixture C;
D, the monomer mixture B of 7% weight is added reactor among the step a, stirred 20 minutes down at 78 ℃;
E, the mixture C of 35% weight is added in the reactor among the step a, stirred 35 minutes down, make seed emulsion at 78 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor synchronously continuously, under 78 ℃ of conditions, all dripped 2.5 hours, dropwise the back 83 ℃ of insulations 0.5 hour down;
G, be cooled to 40 ℃ after, with thanomin emulsion is adjusted into 9.2, add aromatoising substance 0.01%, stir, make ACRYLIC EMULSION.
Embodiment 5 preparation processes:
A, add each component of emulsifying agent among the embodiment 5 successively in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, stirring and emulsifying is 15 minutes under 55 ℃ of conditions, makes mixture A;
B, in the special-purpose stock chest of monomer, be weighed into each component of vinyl monomer among the embodiment 5 successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into each component of initiator among the embodiment 5, mix, make mixture C;
D, the monomer mixture B of 8% weight is added reactor among the step a, stirred 30 minutes down at 87 ℃;
E, the mixture C of 40% weight is added in the reactor among the step a, stirred 10 minutes down, make seed emulsion at 87 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor synchronously continuously, under 87 ℃ of conditions, all dripped 1.5 hours, dropwise the back 90 ℃ of insulations 0.5 hour down;
G, be cooled to 40 ℃ after, with thanomin emulsion is adjusted into 9.5, stir, make ACRYLIC EMULSION.
Claims (6)
1. an anti-corrosion primer emulsion is characterized in that, the main ingredient of described anti-corrosion primer emulsion and content (weight percent) are as follows:
Vinyl monomer: 27.3-55.4%;
Emulsifying agent: 1-5%;
Initiator: 0.1-0.5%;
PH conditioning agent: 0.6-1.0%;
Deionized water: surplus;
The component of described vinyl monomer and the weight percent of shared emulsion are: vinylbenzene 8-15%, butyl acrylate 12-20%, methyl methacrylate 0-2.5%, (methyl) Hydroxyethyl acrylate 6-8%, (methyl) vinylformic acid 0.3-0.7%, vinyl acetate 0-1.2%, phosphoric acid ester function monomer: 1-8%.
2. anti-corrosion primer emulsion as claimed in claim 1, it is characterized in that: described emulsifying agent is a mixed emulsifier, comprises at least two kinds in alkylphenol polyvinyl sulfuric acid ammonium/sodium, sodium laurylsulfonate, sodium lauryl sulphate, polyoxyethylene nonylphenol ether, the allyloxy hydroxide sodium dimercaptosulphanatein.
3. anti-corrosion primer emulsion as claimed in claim 1 is characterized in that: described phosphoric acid ester function monomer is at least a in alkyl (aryl) phosphoric acid ester, Fatty Alcohol(C12-C14 and C12-C18) (alkylphenol) polyoxyethylene ether phosphate, alkylol amide phosphoric acid ester, imidazolines phosphoric acid ester, hydroxyethyl phosphate tensio-active agent, polyphosphazene polymer phosphoric acid ester, the siloxanes phosphoric acid ester.
4. anti-corrosion primer emulsion as claimed in claim 1 is characterized in that: described initiator is Potassium Persulphate or ammonium persulphate.
5. anti-corrosion primer emulsion as claimed in claim 1 is characterized in that: described PH conditioning agent is a thanomin.
6. the preparation method of an anti-corrosion primer emulsion is characterized in that, preparation process is:
A, in water cooler, agitator, thermometer, dropping funnel four-hole bottle are housed, add compound emulsifying agent 1-5% and deionized water 45-50% successively, under 45 ℃ of-65 ℃ of conditions stirring and emulsifying 5-30 minute, make mixture A;
B, in the special-purpose stock chest of monomer, be weighed into vinylbenzene 8-15%, butyl acrylate 12-20%, methyl methacrylate 0-2.5%, (methyl) Hydroxyethyl acrylate 6-8%, (methyl) vinylformic acid 0.3-0.7%, vinyl acetate 0-1.2%, phosphoric acid ester function monomer: 1-8% successively, mix, make monomer mixture B;
C, in the special-purpose stock chest of initiator, be weighed into initiator 0.1-0.5% and deionized water 15-20%, mix, make mixture C;
D, the monomer mixture B of 4%-8% weight is added in the reactor among the step a, stirred 5-30 minute down at 78 ℃-90 ℃;
E, the mixture C of 20%-40% weight is added in the reactor among the step a, stirred 10-60 minute down, make seed emulsion at 78 ℃-90 ℃;
F, residual monomer mixture B and mixture C are added drop-wise in the reactor, and monomer mixture B and mixture C can drip synchronously or mixture C dripped than monomer mixture B hysteresis in 5-10 minute, under 78 ℃ of-90 ℃ of conditions, all dripped 1.5-3 hour, dropwise the back and under 83 ℃ of-90 ℃ of conditions, be incubated 0.5-1.5 hour;
G, be cooled to 40 ℃ after, with PH conditioning agent thanomin emulsion is adjusted into 8.5-9.5, stir, make ACRYLIC EMULSION.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105607173A CN102167771A (en) | 2010-11-26 | 2010-11-26 | Anti-corrosion primer emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105607173A CN102167771A (en) | 2010-11-26 | 2010-11-26 | Anti-corrosion primer emulsion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102167771A true CN102167771A (en) | 2011-08-31 |
Family
ID=44489105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105607173A Pending CN102167771A (en) | 2010-11-26 | 2010-11-26 | Anti-corrosion primer emulsion and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102167771A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263140A (en) * | 2014-09-29 | 2015-01-07 | 无锡康柏斯机械科技有限公司 | Marine anti-fouling and corrosion-resistant coating |
| CN105153343A (en) * | 2015-09-29 | 2015-12-16 | 南通瑞普埃尔生物工程有限公司 | Acrylate copolymeric mini-emulsion for heavy anti-corrosion coating and preparation method of acrylate copolymeric mini-emulsion |
| CN105153828A (en) * | 2015-09-25 | 2015-12-16 | 南通瑞普埃尔生物工程有限公司 | Acrylic ester copolymer emulsion used for high-water-resistance heavy anti-corrosion coating and preparation method thereof |
| CN105218725A (en) * | 2015-09-23 | 2016-01-06 | 南通瑞普埃尔生物工程有限公司 | A kind of preparation method of high adhesive force heavy-duty coating acrylate copolymer emulsion |
| CN105462419A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Wear resistance type antirust acrylic acid coating having high hardness and applied to pump valve |
| CN105482599A (en) * | 2015-12-02 | 2016-04-13 | 铜陵市肆得科技有限责任公司 | High-temperature-resistant pump valve water-based anti-rust coating |
| CN105694554A (en) * | 2014-11-29 | 2016-06-22 | 上海门普来新材料股份有限公司 | Industrial waterborne inorganic polyphosphoester anticorrosive coating and preparation method thereof |
| CN106317984A (en) * | 2016-08-25 | 2017-01-11 | 常熟市裕华计量检测咨询服务有限公司 | Measurement and detection equipment |
| CN106565893A (en) * | 2016-10-21 | 2017-04-19 | 中山市巴德富化工科技有限公司 | Water-based styrene-acrylic emulsion for primer and topcoat integrated metallic paint and preparation method of water-based styrene-acrylic emulsion |
| CN107434837A (en) * | 2017-09-08 | 2017-12-05 | 江门市制漆厂有限公司 | A kind of priming paint acrylic resin and preparation method thereof |
| CN110627951A (en) * | 2019-10-18 | 2019-12-31 | 四川轻化工大学 | Cationic water-based acrylic emulsion for anticorrosive primer and preparation method thereof |
-
2010
- 2010-11-26 CN CN2010105607173A patent/CN102167771A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263140A (en) * | 2014-09-29 | 2015-01-07 | 无锡康柏斯机械科技有限公司 | Marine anti-fouling and corrosion-resistant coating |
| CN105694554A (en) * | 2014-11-29 | 2016-06-22 | 上海门普来新材料股份有限公司 | Industrial waterborne inorganic polyphosphoester anticorrosive coating and preparation method thereof |
| CN105218725A (en) * | 2015-09-23 | 2016-01-06 | 南通瑞普埃尔生物工程有限公司 | A kind of preparation method of high adhesive force heavy-duty coating acrylate copolymer emulsion |
| WO2017049696A1 (en) * | 2015-09-23 | 2017-03-30 | 南通瑞普埃尔生物工程有限公司 | Acrylic ester copolymer emulsion for high-adhesion heavy-duty anticorrosion coating, and preparation method therefor |
| CN105153828A (en) * | 2015-09-25 | 2015-12-16 | 南通瑞普埃尔生物工程有限公司 | Acrylic ester copolymer emulsion used for high-water-resistance heavy anti-corrosion coating and preparation method thereof |
| CN105153343A (en) * | 2015-09-29 | 2015-12-16 | 南通瑞普埃尔生物工程有限公司 | Acrylate copolymeric mini-emulsion for heavy anti-corrosion coating and preparation method of acrylate copolymeric mini-emulsion |
| WO2017054269A1 (en) * | 2015-09-29 | 2017-04-06 | 南通瑞普埃尔生物工程有限公司 | Acrylate copolymer miniemulsion for heavy anti-corrosion coating and preparation method therefor |
| CN105462419A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Wear resistance type antirust acrylic acid coating having high hardness and applied to pump valve |
| CN105482599A (en) * | 2015-12-02 | 2016-04-13 | 铜陵市肆得科技有限责任公司 | High-temperature-resistant pump valve water-based anti-rust coating |
| CN106317984A (en) * | 2016-08-25 | 2017-01-11 | 常熟市裕华计量检测咨询服务有限公司 | Measurement and detection equipment |
| CN106565893A (en) * | 2016-10-21 | 2017-04-19 | 中山市巴德富化工科技有限公司 | Water-based styrene-acrylic emulsion for primer and topcoat integrated metallic paint and preparation method of water-based styrene-acrylic emulsion |
| CN106565893B (en) * | 2016-10-21 | 2019-02-05 | 成都巴德富科技有限公司 | A kind of bottom surface unification metallic paint waterborne styrene-acrylic emulsion and preparation method thereof |
| CN107434837A (en) * | 2017-09-08 | 2017-12-05 | 江门市制漆厂有限公司 | A kind of priming paint acrylic resin and preparation method thereof |
| CN107434837B (en) * | 2017-09-08 | 2019-10-29 | 江门市制漆厂有限公司 | A kind of priming paint acrylic resin and preparation method thereof |
| CN110627951A (en) * | 2019-10-18 | 2019-12-31 | 四川轻化工大学 | Cationic water-based acrylic emulsion for anticorrosive primer and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102167771A (en) | Anti-corrosion primer emulsion and preparation method thereof | |
| CN101077955B (en) | Antiseptic and hydrophilic coating and its preparation method | |
| CN102167946A (en) | Waterborne anti-corrosive primer and preparation method thereof | |
| CN102167947A (en) | Waterborne anticorrosive primer acrylic resin composition and preparation method thereof | |
| CN106565893B (en) | A kind of bottom surface unification metallic paint waterborne styrene-acrylic emulsion and preparation method thereof | |
| WO2017049696A1 (en) | Acrylic ester copolymer emulsion for high-adhesion heavy-duty anticorrosion coating, and preparation method therefor | |
| CN105820719B (en) | A kind of air-conditioner foil primary coat and preparation method thereof | |
| CN1246896A (en) | Surface treatment composition for metallic material and method for treatment | |
| CN101798479A (en) | Highly-corrosion-resistant water-based anticorrosive paint for hydrophilic coated aluminum foil, application and using method | |
| CN105175615A (en) | Water-based environment-friendly film-forming material applied in steel fastener surface, and preparation method and application thereof | |
| CN102167945A (en) | Hydrophilic paint and preparation method thereof | |
| CN105885608A (en) | Water-based anti-freezing paint and preparation method thereof | |
| CN105295632A (en) | Environment-friendly furniture coating and preparation method thereof | |
| CN103059681A (en) | Water-based quick-drying externally-crosslinked functional paint and preparation method thereof | |
| CN101434819A (en) | Aqueous adhesive for binding rubber and metal and preparation thereof | |
| CN114181616B (en) | Chromium-free low-temperature curing water-based zinc-aluminum coating and preparation method and application thereof | |
| CN105814236A (en) | Surface treatment agent for metal material and production method for surface-treated metal material | |
| CN101381577B (en) | Water-soluble baking finish special for compressor and preparation method thereof | |
| CN109852181A (en) | The preparation method of epoxy modified acrylic resin antirust emulsion | |
| WO2017054268A1 (en) | Multi-component copolymer aqueous anti-corrosion emulsion dedicated for rust converting primer and preparation method therefor | |
| CN110190235A (en) | A kind of aqueous solution type lithium battery ceramic diaphragm adhesive specially and its preparation method and application | |
| WO2023206768A1 (en) | Salt-fog-resistant self-drying acrylate emulsion and preparation method therefor and application thereof | |
| CN102719188B (en) | Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof | |
| JP2010070603A (en) | Aqueous rust-preventive coating composition | |
| CN103421415A (en) | Ultraviolet light curing hydrophilic aluminum foil paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110831 |