CN102161730B - Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof - Google Patents

Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof Download PDF

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Publication number
CN102161730B
CN102161730B CN2010106223414A CN201010622341A CN102161730B CN 102161730 B CN102161730 B CN 102161730B CN 2010106223414 A CN2010106223414 A CN 2010106223414A CN 201010622341 A CN201010622341 A CN 201010622341A CN 102161730 B CN102161730 B CN 102161730B
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China
Prior art keywords
wire
hdpe
lldpe
steel
frame
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CN2010106223414A
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CN102161730A (en
Inventor
倪立营
孔凡河
张超
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Shandong Donghong Pipe Industry Co Ltd
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Qufu Donghong Industry Co Ltd
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Priority to CN2010106223414A priority Critical patent/CN102161730B/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

The invention relates to a special adhesive resin for a wire-frame-reinforced polyethylene tube and a production method thereof. The special adhesive resin for a wire-frame-reinforced polyethylene tube is mainly used for bonding the outer layer, wire and inner layer of a wire-mesh-frame-reinforced polyethylene tube. The special adhesive resin for a wire-frame-reinforced polyethylene tube is prepared from the following raw materials in percentage by weight: 30-90% of HDPE (high-density polyethylene), 8-40% of LLDPE (linear low-density polyethylene), 0.1-10% of maleic anhydride, 0.01-1% of peroxide crosslinking agent and 0.01-1% of acetone. The production method comprises the following steps: carrying out pre-reaction on the maleic anhydride, peroxide and acetone, mixing with the HDPE and LLDPE, and carrying out thermal granulation. By using the product provided by the invention, the peel strength among the outer layer, wire and inner layer of the wire-mesh-frame-reinforced polyethylene tube is up to more than 500N/25mm.

Description

A kind of steel-wire carcass strengthens polyvinyl piping materials special bonding resin and method of manufacture thereof
Technical field
The present invention relates to plastics tubing, be specially a kind of steel-wire carcass and strengthen polyvinyl piping materials special bonding resin, mainly use steel-wire carcass and strengthen bonding between polyvinyl piping materials skin, steel wire, the internal layer.
Background technology
At present; Domestic do not have specialty to be applicable to that steel-wire carcass strengthens the special-purpose adhering resin of polyvinyl piping materials; It is the grafts of singly depositing that existing steel-wire carcass strengthens the employed adhering resin of polyvinyl piping materials, and its shortcoming is that cost is high, stripping strength is low, the use difficulty is big, is prone to bubble etc.
Summary of the invention
In order to overcome the defective of prior art, reduce the production use cost, improve stripping strength, be prone to use, stop bubble appearance etc., the present invention to provide a kind of steel-wire carcass to strengthen polyvinyl piping materials special bonding resin and method of manufacture thereof.
The technical scheme that the present invention taked is: a kind of steel-wire carcass strengthens polyvinyl piping materials special bonding resin; Its material composition weight ratio is: HDPE 30-90%, LLDPE 8-40%, maleic anhydride 0.1-10%; Peroxide cross-linking agent 0.01-1%, acetone 0.01-1%; Wherein, HDPE is a high density polyethylene(HDPE), tensile strength >=23Mpa, elongation at break >=600%, Vicat softening point >=120 ℃, more than the melt flow rate(MFR) 1g/10min; LLDPE is a linear low density polyethylene, fracture tensile strength >=10Mpa, elongation at break >=1000%, Vicat softening point >=95 ℃, more than the melt flow rate(MFR) 20g/10min.
More specifically the material composition weight ratio is: HDPE 70%, and LLDPE 20%, maleic anhydride 2%, peroxide cross-linking agent 0.1%, acetone 0.1%.
Said peroxide cross-linking agent is a Di Cumyl Peroxide 99.
Its production technique comprises the steps:
Earlier maleic anhydride and superoxide are mixed;
Add acetone, restir evenly becomes small powder, deposits more than 10 hours at 10 ℃ of-50 ℃ of room temperature inner openings of temperature, and this process can make maleic anhydride, superoxide and acetone carry out pre-reaction;
HDPE, LLDPE are joined 1.5-10 minute one-tenth of stirring compound in the spice machine together with above-mentioned small powder;
Above-mentioned compound is sent into dual-screw-stem machine carry out graft reaction and granulation, 200 ℃-240 ℃ of melt temperatures of control, the residence time 30-240 second of material in machine barrel.
Beneficial effect of the present invention: a kind of steel-wire carcass strengthens polyvinyl piping materials special bonding resin; In macromolecular chain, add polar group (maleic anhydride) with the grafting form; Guaranteeing to increase cementability under higher draw tensile strength and the elongation at break situation; Suitably add LLDPE, can significantly improve workability.Process using is reacted again earlier, and the grafted method reduces difficulty of processing.Use steel-wire carcass of the present invention to strengthen the steel-wire carcass enhancing polyvinyl piping materials that polyvinyl piping materials special bonding production of resins goes out; Stripping strength between its skin, steel wire, the internal layer reaches 500N/25mm above (seeing accompanying drawing 1), satisfies its needed stripping strength requirement fully.And reduce the production use cost, stop bubble appearance etc.
Description of drawings
Below in conjunction with accompanying drawing the present invention is further specified.
The steel-wire carcass enhancing polyvinyl piping materials that Fig. 1 produces for using the present invention, the power of the stripping strength between its skin, steel wire, the internal layer-deformation curve figure.
Embodiment
Embodiment:: a kind of steel-wire carcass strengthens polyvinyl piping materials special bonding resin, material composition weight ratio: HDPE70%, LLDPE20%, maleic anhydride 2%, Di Cumyl Peroxide 99 linking agent 0.1%, acetone 0.1%.
Its production technique comprises the steps:
Earlier maleic anhydride and superoxide are mixed;
Add acetone, restir evenly becomes small powder, deposits more than 10 hours at 10 ℃ of-50 ℃ of room temperature inner openings of temperature, and this process can make maleic anhydride, superoxide and acetone carry out pre-reaction;
HDPE, LLDPE joined in the spice machine together with above-mentioned small powder stirred 1.5-10 minute;
Above-mentioned compound is sent into dual-screw-stem machine carry out graft reaction and granulation, 200 ℃-240 ℃ of melt temperatures of control, the residence time 30-240 second of material in machine barrel.

Claims (4)

1. a steel-wire carcass strengthens polyvinyl piping materials special bonding resin, it is characterized in that its material composition weight ratio is: HDPE 30-90%, LLDPE 8-40%, maleic anhydride 0.1-10%, peroxide cross-linking agent 0.01-1%, acetone 0.01-1%; Wherein, HDPE is a high density polyethylene(HDPE), tensile strength >=23Mpa, elongation at break >=600%, Vicat softening point >=120 ℃, more than the melt flow rate(MFR) 1g/10min; LLDPE is a linear low density polyethylene, fracture tensile strength >=10Mpa, elongation at break >=1000%, Vicat softening point >=95 ℃, more than the melt flow rate(MFR) 20g/10min.
2. a kind of steel-wire carcass as claimed in claim 1 strengthens polyvinyl piping materials special bonding resin, and its characteristic in its material composition weight ratio is: HDPE 70%, and LLDPE 20%, maleic anhydride 2%, peroxide cross-linking agent 0.1%, acetone 0.1%.
3. according to claim 1 or claim 2 a kind of steel-wire carcass strengthens polyvinyl piping materials special bonding resin, it is characterized in that said peroxide cross-linking agent is a Di Cumyl Peroxide 99.
4. a kind of steel-wire carcass as claimed in claim 1 strengthens the working method of polyvinyl piping materials special bonding resin, it is characterized in that comprising the steps:
Maleic anhydride and superoxide are mixed;
Add acetone, restir evenly becomes small powder;
In 10 ℃-50 ℃ of temperature, above-mentioned small powder opening was deposited more than 10 hours;
HDPE, LLDPE are joined 1.5-10 minute one-tenth of stirring compound in the spice machine together with above-mentioned small powder;
Above-mentioned compound is sent into the dual-screw-stem machine granulation, 200 ℃-240 ℃ of melt temperatures of control, the residence time 30-240 second of material in machine barrel.
CN2010106223414A 2010-12-30 2010-12-30 Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof Active CN102161730B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010106223414A CN102161730B (en) 2010-12-30 2010-12-30 Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010106223414A CN102161730B (en) 2010-12-30 2010-12-30 Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof

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CN102161730A CN102161730A (en) 2011-08-24
CN102161730B true CN102161730B (en) 2012-11-21

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102993535B (en) * 2011-09-08 2014-08-06 中国石油天然气股份有限公司 Polyethylene resin composition for pipes
CN105778836B (en) * 2016-04-14 2018-04-03 苏州隆芝耀新材料有限公司 A kind of armorphous block copolymer-modified polyethylene glue
CN106349976B (en) * 2016-09-12 2019-06-14 广州鹿山新材料股份有限公司 A kind of steel wire enhancing effective adhering resin of polyethylene hot water and preparation method thereof
CN107057617A (en) * 2017-04-27 2017-08-18 安徽国登管业科技有限公司 Effective adhering resin of steel plastic compount and preparation method thereof
CN107400487A (en) * 2017-08-04 2017-11-28 金旸（厦门）新材料科技有限公司 Grafted polyethylene PUR and preparation method for steel wire mesh frame PE pipes
CN109049746B (en) * 2018-06-11 2020-09-18 台州市港泰铝塑板有限公司 Production process of aluminum-plastic panel

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101270269A (en) * 2008-05-08 2008-09-24 王成人 Colorful adhesion agent for ground burying steel pipeline trilaminar corrosion protection and preparation method thereof
CN101429413A (en) * 2008-11-18 2009-05-13 广州市鹿山化工材料有限公司 Double-layer composite hot melt adhesive film for bonding metal and plastic

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2237100T3 (en) * 1998-05-26 2005-07-16 Arkema STRUCTURES THAT INCLUDE HALF-DENSITY POLYETHYLENEES AND BINDERS USED IN THESE STRUCTURES.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101270269A (en) * 2008-05-08 2008-09-24 王成人 Colorful adhesion agent for ground burying steel pipeline trilaminar corrosion protection and preparation method thereof
CN101429413A (en) * 2008-11-18 2009-05-13 广州市鹿山化工材料有限公司 Double-layer composite hot melt adhesive film for bonding metal and plastic

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Address after: 273100 light industrial park, Shandong, Qufu

Patentee after: Shandong East macro Group Co.,Ltd.

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