CN102140046A - Compound fertilizer granulating agent and preparation method thereof - Google Patents
Compound fertilizer granulating agent and preparation method thereof Download PDFInfo
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- CN102140046A CN102140046A CN2011101065283A CN201110106528A CN102140046A CN 102140046 A CN102140046 A CN 102140046A CN 2011101065283 A CN2011101065283 A CN 2011101065283A CN 201110106528 A CN201110106528 A CN 201110106528A CN 102140046 A CN102140046 A CN 102140046A
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Abstract
The invention relates to a compound fertilizer granulating agent and a preparation method thereof. The compound fertilizer granulating agent comprises the following components in percentage by mass: 40 to 60 percent of molasses, 5 to 20 percent of polyvinyl alcohol formaldehyde condensation compound solution, 10 to 15 percent of lignosulfonate and the balance of water. The preparation method comprises the following steps of: dissolving lignosulfonate in water, and stirring uniformly; and adding the polyvinyl alcohol formaldehyde condensation compound solution into the solution, adding the molasses into the mixed solution, and stirring uniformly to obtain the compound fertilizer granulating agent. The compound fertilizer granulating agent is in the liquid state at the normal temperature and is water-soluble, can be added into fertilizer slurry directly without being heated in the using process, and is easy to operate and small in used amount; rounded fertilizer granules can be prepared only by 2 to 5 kilograms/ton of fertilizers without influencing the total nutrients of fertilizers, and high-concentration compound fertilizers are easy to produce; and the fertilizer granules have high strength, so that the fertilizers are difficult to pulverize and agglomerate in the processes of production, transportation and storage, and the quality of the fertilizers is ensured.
Description
Technical field
The present invention relates to a kind of compound fertilizer granulating agent and preparation method thereof.
Background technology
Composite fertilizer is meant in nitrogen, phosphorus, three kinds of nutrients of potassium to have the fertilizer of only being made by chemical process of the two breeding branch amounts of showing at least, is a kind of of composite fertilizer.Advantages such as composite fertilizer has the nutrient content height, minor component is few and physical behavior is good for balance fertilizing, improve utilization rate of fertilizer, promote the stable high yield of crop that crucial effect is arranged.
The solid composite fertilizer overwhelming majority that countries in the world and China are produced is a granulated fertilizer, and granulated fertilizer has following advantage aspect physicals: 1. specific surface area is little, reduces the possibility of caking.2. have good flowability, be convenient to mechanized handling and fertilising.3. bulk density is little, has reduced packing relatively, stores or trucking costs.4. the dissolution rate of granulated fertilizer in soil is slower, can alleviate or eliminate the injury to crop root, and the leaching that also can reduce the nitrogen nutrient simultaneously runs off.
For composite fertilizer, if want to cause the round shaped grain shape must add binding agent.The most frequently used binding agent has: clay class (comprising clay, chalk soil, kaolin etc.), phosphogypsum, fused(calcium magnesium)phosphate etc.Adopt above-mentioned binding agent can have some shortcomings:
1. cohesive force is not strong, and the fertiliser granulates intensity of producing is low, and fertilizer is easy disintegrating in the production and transport process, and efflorescence causes fertilizer agglomeration, and is mobile poor, is not easy to mechanized handling and fertilising.
2. useless composition adds manyly more, and the effective constituent of fertilizer is low more.If adopt above binding agent just to be difficult to produce high-concentration compound fertilizer, yet high densityization is a megatrend of current composite fertilizer industry development; High densityization is not only compound fertilizer, and is the direction of the whole fertilizer industry development in the world.High concentration fertilizer has the advantage that unit nutrient cost, transportation and cost of marketing are lower than low-analysis fertilizer.
At above-mentioned variety of problems, developing new compound fertilizer granulating binding agent becomes the task of top priority.
Summary of the invention
The objective of the invention is to overcome the deficiency of existing inorganic granulating agent, a kind of compound fertilizer granulating agent and preparation method thereof is provided, this compound fertilizer granulating agent normal temperature is down for liquid and water-soluble entirely, good fluidity, in use, need not heating can directly add in the fertilizer slurry, simple to operate, consumption is little, only needs 2-5 kilogram/ton fertilizer just can produce mellow and full fertilizer particle, can not influence the fertilizer total nutrient substantially, so easier one-tenth produces high-concentration compound fertilizer, produce fertiliser granulates intensity height, make fertilizer produce transportation, deposit in the process, be difficult for efflorescence, prevent fertilizer agglomeration to a certain extent, thereby guarantee the quality of fertilizer.
For achieving the above object, a kind of compound fertilizer granulating agent provided by the invention, each component is by mass percentage, it is characterized in that: molasses 40-60%, polyvinyl alcohol and formol condensed substance solution 5-20%, sulfonated lignin 10-15%, surplus is a water, and each component sum is 100%.
Described molasses are the cane sugar factory molasses.
Described polyvinyl alcohol and formol condensed substance solution is that mass concentration is that polyvinyl formal solution or the commercially available mass concentration of 5-10% is 801 glue of 5-10%, and 801 glue also claim polyvinyl formal solution.
Described sulfonated lignin are calcium lignin sulphonate.
The preparation method of a kind of compound fertilizer granulating agent of the present invention, its preparation process is:
1, calcium lignin sulphonate is water-soluble, stir, obtain solution A;
2, polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
3, molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
The advantage of the existing granulating agent of the present invention:
(1) this granulating agent is for water-soluble entirely, and is easy to use.
(2) cohesiveness is strong.
(3) consumption is little, produces 1 ton of fertilizer, only needs to add the agent of 2-5 kilogram compound fertilizer granulating, does not influence the total nutrient of fertilizer.
(4) be applicable to multiple granulation mode, as rotary drum and granulating disc.
(5) the fertiliser granulates intensity height of producing, average anti-crushing pressure 20-40N.
Embodiment
The embodiment of a kind of compound fertilizer granulating agent of the present invention and preparation thereof below is provided, and each material by mass percentage among each embodiment.
Embodiment 1
Molasses 40%, polyvinyl alcohol and formol condensed substance solution 5%, wherein polyvinyl alcohol and formol condensed substance solution is that mass concentration is 5% polyvinyl formal solution, calcium lignin sulphonate 15%, water 40%.
1,15% calcium lignin sulphonate is dissolved in 40% water, stirs, obtain solution A;
2,5% polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
3,40% molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
Embodiment 2
Molasses 60%, polyvinyl alcohol and formol condensed substance solution 20%, wherein polyvinyl alcohol and formol condensed substance solution is that commercially available mass concentration is 5% 801 glue (801 glue also claim poly-ethanol formal solution), calcium lignin sulphonate 10%, water 10%.
1,10% calcium lignin sulphonate is dissolved in 10% water, stirs, obtain solution A;
2,20% polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
3,60% molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
Embodiment 3.
Molasses 55%, polyvinyl alcohol and formol condensed substance solution 15%, wherein polyvinyl alcohol and formol condensed substance solution is that mass concentration is 10% polyvinyl formal solution, calcium lignin sulphonate 12%, water 18%.
1,12% calcium lignin sulphonate is dissolved in 18% water, stirs, obtain solution A;
2,15% polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
3,55% molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
Embodiment 4
Molasses 50%, polyvinyl alcohol and formol condensed substance solution 15%, wherein polyvinyl alcohol and formol condensed substance solution is that commercially available mass concentration is 10% 801 glue (801 glue also claim poly-ethanol formal solution), calcium lignin sulphonate 15%, water 20%.
1,15% calcium lignin sulphonate is dissolved in 20% water, stirs, obtain solution A;
2,15% polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
3,50% molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
With the compound fertilizer granulating agent that the above embodiments 1 make, producing 1 ton of fertilizer, only need to add 2 kilograms of compound fertilizer granulating agent, do not influence the total nutrient of fertilizer, and the fertiliser granulates intensity height that can produce, anti-crushing pressure reaches 40N.
Claims (5)
1. compound fertilizer granulating agent, each component is characterized in that by mass ratio: molasses 40-60%, polyvinyl alcohol and formol condensed substance solution 5-20%, sulfonated lignin 10-15%, surplus is a water, each component sum is 100%.
2. the preparation method of compound fertilizer granulating agent according to claim 1 is characterized in that preparation process is:
(1), sulfonated lignin are water-soluble, stir, obtain solution A;
(2), polyvinyl alcohol and formol condensed substance solution is joined in the solution A, stirring obtains solution B;
(3), molasses are joined in the solution B, stir, obtain the compound fertilizer granulating agent.
3. the preparation method of compound fertilizer granulating agent according to claim 2 is characterized in that: described molasses are the cane sugar factory molasses.
4. the preparation method of compound fertilizer granulating agent according to claim 2, it is characterized in that: described polyvinyl alcohol and formol condensed substance solution is that mass concentration is that polyvinyl formal solution or the commercially available mass concentration of 5-10% is 801 glue of 5-10% scope, and 801 glue also claim polyvinyl formal solution.
5. the preparation method of compound fertilizer granulating agent according to claim 2 is characterized in that: described sulfonated lignin are calcium lignin sulphonate.
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CN 201110106528 CN102140046B (en) | 2011-04-27 | 2011-04-27 | Compound fertilizer granulating agent and preparation method thereof |
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CN 201110106528 CN102140046B (en) | 2011-04-27 | 2011-04-27 | Compound fertilizer granulating agent and preparation method thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432403A (en) * | 2011-09-30 | 2012-05-02 | 瓮福(集团)有限责任公司 | Coating fertilizer special for soybean and preparation method for coating fertilizer |
CN102731215A (en) * | 2012-07-12 | 2012-10-17 | 湖北富邦科技股份有限公司 | Granulating agent for preparing large-particle potassium sulfate or ammonium chloride |
CN102850140A (en) * | 2012-09-29 | 2013-01-02 | 广西力源肥业科技农化有限公司 | Anti-blocking compound fertilizer and preparation method thereof |
CN106927954A (en) * | 2017-04-14 | 2017-07-07 | 安徽博硕科技有限公司 | A kind of compound fertilizer granulating agent |
CN109704842A (en) * | 2017-10-26 | 2019-05-03 | 三江侗族自治县中吉牛势测土配肥中心 | A kind of fruit-specific fertilizer of pellet containing selenium |
CN109796278A (en) * | 2019-03-29 | 2019-05-24 | 四川轻化工大学 | A kind of preparation method of the binder suitable for low concentration compound fertilizer |
CN110128215A (en) * | 2019-06-19 | 2019-08-16 | 华南农业大学 | A kind of anticaking agent and preparation method thereof suitable for pulvis water-soluble fertilizer |
CN110803959A (en) * | 2019-11-29 | 2020-02-18 | 烟台市烟农富邦肥料科技有限公司 | Special granulating agent for producing round granular calcium magnesium phosphate fertilizer and application thereof |
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JP2001213679A (en) * | 2000-01-28 | 2001-08-07 | Denki Kagaku Kogyo Kk | Fertilizer for rice crop |
CN1390812A (en) * | 2002-07-02 | 2003-01-15 | 张夫道 | Adhesive for granulating mixed organic fertilizer and its preparing process |
JP2003246618A (en) * | 2001-11-21 | 2003-09-02 | Co-Op Chem Co Ltd | Collapsible granular gypsum |
JP2006021968A (en) * | 2004-07-08 | 2006-01-26 | Nippon Denko Kk | Granular fertilizer and its manufacturing method |
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Patent Citations (4)
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JP2001213679A (en) * | 2000-01-28 | 2001-08-07 | Denki Kagaku Kogyo Kk | Fertilizer for rice crop |
JP2003246618A (en) * | 2001-11-21 | 2003-09-02 | Co-Op Chem Co Ltd | Collapsible granular gypsum |
CN1390812A (en) * | 2002-07-02 | 2003-01-15 | 张夫道 | Adhesive for granulating mixed organic fertilizer and its preparing process |
JP2006021968A (en) * | 2004-07-08 | 2006-01-26 | Nippon Denko Kk | Granular fertilizer and its manufacturing method |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432403A (en) * | 2011-09-30 | 2012-05-02 | 瓮福(集团)有限责任公司 | Coating fertilizer special for soybean and preparation method for coating fertilizer |
CN102432403B (en) * | 2011-09-30 | 2013-07-17 | 瓮福(集团)有限责任公司 | Coating fertilizer special for soybean and preparation method for coating fertilizer |
CN102731215A (en) * | 2012-07-12 | 2012-10-17 | 湖北富邦科技股份有限公司 | Granulating agent for preparing large-particle potassium sulfate or ammonium chloride |
CN102850140A (en) * | 2012-09-29 | 2013-01-02 | 广西力源肥业科技农化有限公司 | Anti-blocking compound fertilizer and preparation method thereof |
CN102850140B (en) * | 2012-09-29 | 2014-04-09 | 广西力源肥业科技农化有限公司 | Anti-blocking compound fertilizer and preparation method thereof |
CN106927954A (en) * | 2017-04-14 | 2017-07-07 | 安徽博硕科技有限公司 | A kind of compound fertilizer granulating agent |
CN109704842A (en) * | 2017-10-26 | 2019-05-03 | 三江侗族自治县中吉牛势测土配肥中心 | A kind of fruit-specific fertilizer of pellet containing selenium |
CN109796278A (en) * | 2019-03-29 | 2019-05-24 | 四川轻化工大学 | A kind of preparation method of the binder suitable for low concentration compound fertilizer |
CN109796278B (en) * | 2019-03-29 | 2022-07-01 | 四川轻化工大学 | Preparation method of binder suitable for low-concentration compound fertilizer |
CN110128215A (en) * | 2019-06-19 | 2019-08-16 | 华南农业大学 | A kind of anticaking agent and preparation method thereof suitable for pulvis water-soluble fertilizer |
CN110803959A (en) * | 2019-11-29 | 2020-02-18 | 烟台市烟农富邦肥料科技有限公司 | Special granulating agent for producing round granular calcium magnesium phosphate fertilizer and application thereof |
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