CN102120847A - Solar nano liner composition with anions and silver ions for sterilization and processing technology thereof - Google Patents
Solar nano liner composition with anions and silver ions for sterilization and processing technology thereof Download PDFInfo
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- CN102120847A CN102120847A CN2011100933698A CN201110093369A CN102120847A CN 102120847 A CN102120847 A CN 102120847A CN 2011100933698 A CN2011100933698 A CN 2011100933698A CN 201110093369 A CN201110093369 A CN 201110093369A CN 102120847 A CN102120847 A CN 102120847A
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Abstract
The invention discloses a formula of a solar nano polypropylene liner with anions and silver ions for sterilization, comprising the following substances in parts by weight: 5-8 parts of activated carbon, 5-8 parts of anion material, 2.5-6 parts of coupling agent, 3-8 parts of silver nitrate solution and 70-85 parts of carrier resin. A preparation method of the solar nano polypropylene liner comprises the following steps of: soaking the activated carbon and six-ring rock in a silver nitrate solution, drying and calcining to prepare silver-infiltrated activated carbon and silver-infiltrated six-ring rock by adopting a constant-temperature oscillation method, then preparing nano-scale fine powder with a soaking and calcining method, then adding the carrier resin, the coupling agent and a dispersing agent, carrying out high speed kneading, and extruding through double screws to prepare the solar nano polypropylene liner. The invention adopts an activated carbon and six-ring rock combined adsorption mode, simultaneously the six-ring rock can release anions and far infrared rays, and the anions and the silver ions act together to play a dual sterilization role.
Description
Technical field
The present invention relates to a kind of nano material, be specifically related to a kind of negative ion and silver ion for sterilization sun power nanometer inner bag composition and complete processing thereof of being used for.
Background technology
Along with developing gradually of sun power industry, the water consumption of sun power also occupies the integral part of people's life, as the quality of the domestic water of having a bath also more and more comes into one's own.And China's vast rural area water quality environment and city have a long way to go, because the rural water mostly is digging well to get water, common shallow well generally can only be got shallow ground water, and do not pass through purifying treatment, contain silt, corrodibility fluorine chlorion is more, monitoring report according to the issue of state environmental monitoring master station shows: the whole nation has 3.2 hundred million people's waters dangerous at present, and this wherein has 2.6 hundred million people's water to belong to high fluorine chlorine water.
Since the nineties, the research and development of silver-colored sterilization material are subjected to very big attention.Ag in the sterilization material is generally with Ag
+The absorption bacterium.Work as Ag
+During the microbial bacterial contact, can the strong adsorption bacterium.What bacterium relied plays respiratory enzyme by Ag
+Catalysis is transformed into and loses its respiratory microorganism, and the bacterium housing construction is destroyed, causes it dead rapidly.Ag
+Fungicidal activity is quite strong, and consumption is few, and general consumption can be sterilized for the ppm level, and human body is not had influence.Experiment shows tissue Ag＜0.01mg%, and unnecessary silver can pass through the very fast eliminating of digestive tube, can not cause human organ and tissue injury.
Ag
+To photo-labile, need be preparing carriers has slow releasing function to antibiotic activeconstituents inorganic antiseptic therefore with gac.But the gac itself as carrier does not have sterilizing function, thereby makes the sterilizing ability of existing inorganic antiseptic limited.
Summary of the invention
The purpose of the embodiment of the invention is the defective at above-mentioned prior art, and a kind of negative ion and silver ions one same-action are provided, and plays the double sterilization effect, the negative ion that sterilizing ability is stronger and silver ion for sterilization sun power nanometer inner bag and complete processing thereof.
The technical scheme taked of the present invention is to achieve these goals: a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag composition of being used for comprises following substances in parts by weight:
5～8 parts of inorganic adsorbing materials; 5～8 parts of anion materials; 70～85 parts of vector resins; 2.5～6 parts of coupling agents; 3～8 parts of silver nitrate solutiones; 1～3 part of dispersion agent.
Described anion material is six ring stones, tourmalinite, opal or bamboo charcoal powder.
Described inorganic adsorbing material is gac, zeolite or silica gel.
Described vector resin is nano polypropylene master batch, polyethylene terephthalate, polyethylene, polymethylmethacrylate, polyvinyl chloride, polyvinylidene dichloride, polycarbonate, polymeric amide, Resins, epoxy, urethane, chlorinatedpolyethylene, acrylonitrile-butadiene-styrene copolymer, styrene-butadiene block copolymer.
Described coupling agent is titanate coupling agent or silicon ester coupling agent.
Described dispersion agent is polyvinyl alcohol or stearic acid.
The present invention also provides the complete processing of a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag, may further comprise the steps:
Silver nitrate solution is immersed in gac and the six ring stones, adopt the preparation of constant temperature succusion, through super-dry, make after the calcining and ooze active carbon of silver and ooze silver six ring stones, make nano level fine powder body then, the impregnation-calcination method adds vector resin, coupling agent, dispersion agent then, carry out high speed and mediate, extrude, adopt the hollow blow molding method through twin screw, extrudate cools off through tank, makes sun power nano polypropylene inner bag after the air cooling.
The preferred technical scheme of the present invention is: the complete processing of a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag may further comprise the steps:
The silver nitrate solution that gac and six ring stones are put into 0.6%-1% soaked a 1-1.5 hour, through 95 ℃-105 ℃ dry 2.5-3.5 hour, 210 ℃-230 ℃ calcinings 1.5-2.5 hour, after make ooze active carbon of silver and ooze silver six the ring stones, adopt intercalation compounding to make nano level fine powder body, add vector resin, coupling agent, dispersion agent then, 460r/min mediates 15～20min at rotating speed, after twin screw extrude, adopt the hollow blow molding method, extrudate cools off through tank, makes sun power nano polypropylene inner bag after the air cooling.
Gac has extremely strong adsorptive power, and because the hydrophobicity of activated carbon surface and huge specific surface area, not only can adsorb organism and part inorganic impurity in the tap water behind the carrying silver with absorbent charcoal effectively, if not only to remove speed fast for the absorption silver ions on the gac, and remove efficient and improve greatly.It is relevant that the sterilization mechanism of silver ions and silver ions can adsorb microbial bacterial consumingly, microbial bacterial by silver ions absorption after, the respiratory enzyme that rises that relies just loses effect, the bacterium housing construction is destroyed, microbial bacterial is dead rapidly.Silver ions shows stronger oxidation capacity, destroys the metabolism of bacterial cell, has stoped the breeding of microorganism.In addition, can intensive attract the sulfydryl of bacterial body endoproteinase, and combination rapidly, make the gene enzyme loss of activity of bacterium, cause bacterium death.After thalline is killed, Ag
+Dissociate out again,, carry out killing of a new round, till bacterium all kills with other thalline effect.
The major function of negative ion has: 1. permanent anion emission function, the Air quality of adjusting surrounding environment; 2. stronger biological ripple emission function stimulates circulation, and the human activin immunocyte prevents human senescence and early ageing; 3. persistent antibiotic, bactericidal property can be killed harmful bacterium, does not injure human body again; 4. good deodoriging properties removes peculiar smell, keeps good living space; 5. can discharge the various trace elements that human body needs, be of value to HUMAN HEALTH; 6. superior interfacial activity effect can be saved the consumption of washing composition, and helps the purification of environment.
The beneficial effect of the embodiment of the invention is: compared with prior art, the suction type that patent of the present invention adopts gac and six ring stones to combine, six ring stones can discharge negative ion simultaneously, and negative ion and silver ions one same-action play the effect of double sterilization.Nanometer PP of the present invention (polypropylene) inner bag is not increasing the effect of double sterilization disinfectant on scaling and the etch-proof basis.Six ring stones are releasing far infrared, the radiating capacity that the energy that far infrared rays discharges is absorbed by object passes to particles such as the intravital atom of thing, molecule, makes these particle generation irregular movements, causes the thermogenic action of object, be called an effect of far infrared rays, be also referred to as warming effect.Infrared rays has the intensive penetration power to human body skin, subcutis.The effect that extraneous infrared radiation human body produces can make that skin is corresponding with hypodermic temperature to be increased, and promotes the circulation and the metabolism of blood, promotes people's health.
Embodiment
The invention will be further described below in conjunction with specific embodiment, but not as a limitation of the invention.
Embodiment 1
Take by weighing raw material (kilogram) according to following weight:
Gac 60; Six ring stones 70; Titanate coupling agent 45; Silver nitrate solution 50; Nano polypropylene master batch 800;
The model of nano polypropylene master batch is preferred: NH01, its manufacturer are that Yuyao echo nanometer is moulded industry limited liability company.
The complete processing of a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag:
It is between 0.6% silver nitrate solution soaks 1 hour that 60 kilograms of gacs and 70 kilogram six ring stone is put into 50 kilograms, concentration, through 100 ℃ of dryings 3 hours, 220 ℃ of calcinings 2 hours, after make ooze active carbon of silver and ooze silver six the ring stones, adopt intercalation compounding to make nano level fine powder body, add 800 kilograms of nano polypropylene master batches, 45 kilograms of titanate coupling agents, 20 kilograms of polyvinyl alcohol then, 460r/min mediates 20min at rotating speed, after twin screw is extruded, make sun power nano polypropylene inner bag.
Embodiment 2
Take by weighing raw material (kilogram) according to following weight:
Gac 50; 80 parts in six ring stones; Titanate coupling agent 25; Silver nitrate solution 80; Nano polypropylene master batch 850; Stearic acid 30.
The complete processing of a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag:
It is between 1% silver nitrate solution soaks 1.5 hours that 50 kilograms of gacs and 80 kilogram six ring stone is put into 80 kilograms, mass percent concentration, 95-105 ℃ of drying of process 3.5 hours, 230 ℃ of calcinings 1.5 hours, after make ooze active carbon of silver and ooze silver six the ring stones, adopt intercalation compounding to make nano level fine powder body, add 850 kilograms of nano polypropylene master batches, 25 kilograms of titanate coupling agents, 30 kilograms of stearic acid then, 460r/min mediates 15min at rotating speed, after twin screw is extruded, make sun power nano polypropylene inner bag.
Embodiment 3
Take by weighing raw material (kilogram) according to following weight:
Gac 80; Six ring stones 50; Silicon ester coupling agent 60; Silver nitrate solution 30; Nano polypropylene master batch 700; Polyvinyl alcohol 10.
The complete processing of a kind of negative ion and silver ion for sterilization sun power nano polypropylene inner bag:
It is between 0.8% silver nitrate solution soaks 1 hour that 80 kilograms of gacs and 50 kilogram six ring stone is put into 30 kilograms, mass percent concentration, through 105 ℃ of dryings 2.5 hours, 210 ℃ of calcinings 2.5 hours, after make ooze active carbon of silver and ooze silver six the ring stones, adopt intercalation compounding to make nano level fine powder body, add 700 kilograms of nano polypropylene master batches, 60 kilograms of silicon ester coupling agents, 10 kilograms of polyvinyl alcohol then, 460r/min mediates 20min at rotating speed, after twin screw is extruded, make sun power nano polypropylene inner bag.
Embodiment 4
Take by weighing raw material (kilogram) according to following weight:
Zeolite 70, opal 60; Titanate coupling agent 45; Silver nitrate solution 50; Polypropylene 750; Polyvinyl alcohol 15.
5～8 parts of inorganic adsorbing materials; 5～8 parts of anion materials; 70～85 parts of vector resins; 2.5～6 parts of coupling agents; 3～8 parts of silver nitrate solutiones; 1～3 part of dispersion agent.
Complete processing such as embodiment 1.
Embodiment 5
Take by weighing raw material (kilogram) according to following weight:
Silica gel 70, tourmalinite 70; Silicon ester coupling agent 25; Silver nitrate solution 75; Polyvinyl chloride 750; Stearic acid 25.
Complete processing such as embodiment 1.
Above-described embodiment, the present invention embodiment a kind of more preferably just, the common variation that those skilled in the art carries out in the technical solution of the present invention scope and replacing all should be included in protection scope of the present invention.
Claims (8)
1. one kind is used for negative ion and silver ion for sterilization sun power nano polypropylene inner bag composition, comprises following substances in parts by weight:
5～8 parts of inorganic adsorbing materials; 5～8 parts of anion materials; 70～85 parts of vector resins; 2.5～6 parts of coupling agents; 3～8 parts of silver nitrate solutiones; 1～3 part of dispersion agent.
2. negative ion and the silver ion for sterilization sun power nano polypropylene inner bag composition of being used for according to claim 1 is characterized in that, described anion material is six ring stones, tourmalinite, opal or bamboo charcoal powder.
3. the prescription of negative ion according to claim 1 and silver ion for sterilization sun power nano polypropylene inner bag is characterized in that described inorganic adsorbing material is gac, zeolite or silica gel.
4. negative ion and the silver ion for sterilization sun power nano polypropylene inner bag composition of being used for according to claim 1, it is characterized in that described vector resin is nano polypropylene master batch, polyethylene terephthalate, polyethylene, polymethylmethacrylate, polyvinyl chloride, polyvinylidene dichloride, polycarbonate, polymeric amide, Resins, epoxy, urethane, chlorinatedpolyethylene, acrylonitrile-butadiene-styrene copolymer, styrene-butadiene block copolymer.
5. negative ion and the silver ion for sterilization sun power nano polypropylene inner bag composition of being used for according to claim 1 is characterized in that described coupling agent is titanate coupling agent or silicon ester coupling agent.
6. negative ion and the silver ion for sterilization sun power nano polypropylene inner bag composition of being used for according to claim 1 is characterized in that described dispersion agent is polyvinyl alcohol or stearic acid.
7. the complete processing of each described negative ion of claim 1-6 and silver ion for sterilization sun power nano polypropylene inner bag may further comprise the steps:
Silver nitrate solution is immersed in gac and the six ring stones, adopt the preparation of constant temperature succusion, through super-dry, make after the calcining and ooze active carbon of silver and ooze silver six ring stones, make nano level fine powder body then, the impregnation-calcination method adds vector resin, coupling agent, dispersion agent then, carry out high speed and mediate, extrude, adopt the hollow blow molding method through twin screw, extrudate cools off through tank, makes sun power nano polypropylene inner bag after the air cooling.
8. complete processing according to claim 7 is characterized in that, may further comprise the steps:
The silver nitrate solution that gac and six ring stones are put into 0.6%-1% soaked a 1-1.5 hour, through 95 ℃-105 ℃ dry 2.5-3.5 hour, 210 ℃-230 ℃ calcinings 1.5-2.5 hour, after make ooze active carbon of silver and ooze silver six the ring stones, adopt intercalation compounding to make nano level fine powder body, add vector resin, coupling agent, dispersion agent then, 460r/min mediates 15～20min at rotating speed, after twin screw extrude, adopt the hollow blow molding method, extrudate cools off through tank, makes sun power nano polypropylene inner bag after the air cooling.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100933698A CN102120847A (en) | 2011-04-14 | 2011-04-14 | Solar nano liner composition with anions and silver ions for sterilization and processing technology thereof |
| CN2012101069325A CN102634114A (en) | 2011-04-14 | 2012-04-12 | Solar nanometer liner composite for anion and silver ion sterilization and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100933698A CN102120847A (en) | 2011-04-14 | 2011-04-14 | Solar nano liner composition with anions and silver ions for sterilization and processing technology thereof |
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|---|---|
| CN102120847A true CN102120847A (en) | 2011-07-13 |
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|---|---|---|---|
| CN2011100933698A Pending CN102120847A (en) | 2011-04-14 | 2011-04-14 | Solar nano liner composition with anions and silver ions for sterilization and processing technology thereof |
| CN2012101069325A Pending CN102634114A (en) | 2011-04-14 | 2012-04-12 | Solar nanometer liner composite for anion and silver ion sterilization and preparation process thereof |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012101069325A Pending CN102634114A (en) | 2011-04-14 | 2012-04-12 | Solar nanometer liner composite for anion and silver ion sterilization and preparation process thereof |
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| CN103772891A (en) * | 2014-01-24 | 2014-05-07 | 南通红石科技发展有限公司 | ABS/PC (Acrylonitrile Butadiene Styrene/Polycarbonate) antibacterial material and preparation method thereof |
| CN103772822A (en) * | 2014-01-24 | 2014-05-07 | 南通红石科技发展有限公司 | Polypropylene antibacterial material and preparation method thereof |
| CN105017677A (en) * | 2015-06-29 | 2015-11-04 | 苏州佑君环境科技有限公司 | Electrostatic dust collection adsorption film and production method thereof |
| CN105032345A (en) * | 2015-06-24 | 2015-11-11 | 何相华 | Negative-ion activated carbon and preparation method thereof |
| CN108727000A (en) * | 2018-06-28 | 2018-11-02 | 泉州市顶优优工业设计有限公司 | A kind of antimildew and antibacterial ceramics chopsticks and its manufacturing method |
| CN109592189A (en) * | 2017-09-30 | 2019-04-09 | 上海住邦电器有限公司 | Nano-silver anion restraining and sterilizing bacteria liner enamelled vessel |
| PL423543A1 (en) * | 2017-11-22 | 2019-06-03 | Bogucki Wojciech Pphu Anna | Method for enriching polymer composites |
| CN112694677A (en) * | 2021-01-08 | 2021-04-23 | 会通新材料股份有限公司 | Bamboo charcoal and tourmaline composite Ag-loaded antibacterial agent, antibacterial polypropylene composition and preparation method |
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| CN1151418A (en) * | 1995-12-01 | 1997-06-11 | 唐文德 | Prepn. method of polyethylene products containing germicide |
| CN101575190A (en) * | 2008-05-05 | 2009-11-11 | 张金玲 | Multifunctional pyranoid stone master batch for releasing negative ions and transmitting far infrared rays |
-
2011
- 2011-04-14 CN CN2011100933698A patent/CN102120847A/en active Pending
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2012
- 2012-04-12 CN CN2012101069325A patent/CN102634114A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103772891A (en) * | 2014-01-24 | 2014-05-07 | 南通红石科技发展有限公司 | ABS/PC (Acrylonitrile Butadiene Styrene/Polycarbonate) antibacterial material and preparation method thereof |
| CN103772822A (en) * | 2014-01-24 | 2014-05-07 | 南通红石科技发展有限公司 | Polypropylene antibacterial material and preparation method thereof |
| CN103772822B (en) * | 2014-01-24 | 2016-01-20 | 南通红石科技发展有限公司 | A kind of polypropylene antibacterial material and preparation method thereof |
| CN105032345A (en) * | 2015-06-24 | 2015-11-11 | 何相华 | Negative-ion activated carbon and preparation method thereof |
| CN105017677A (en) * | 2015-06-29 | 2015-11-04 | 苏州佑君环境科技有限公司 | Electrostatic dust collection adsorption film and production method thereof |
| CN109592189A (en) * | 2017-09-30 | 2019-04-09 | 上海住邦电器有限公司 | Nano-silver anion restraining and sterilizing bacteria liner enamelled vessel |
| PL423543A1 (en) * | 2017-11-22 | 2019-06-03 | Bogucki Wojciech Pphu Anna | Method for enriching polymer composites |
| CN108727000A (en) * | 2018-06-28 | 2018-11-02 | 泉州市顶优优工业设计有限公司 | A kind of antimildew and antibacterial ceramics chopsticks and its manufacturing method |
| CN112694677A (en) * | 2021-01-08 | 2021-04-23 | 会通新材料股份有限公司 | Bamboo charcoal and tourmaline composite Ag-loaded antibacterial agent, antibacterial polypropylene composition and preparation method |
| CN112694677B (en) * | 2021-01-08 | 2022-03-22 | 会通新材料股份有限公司 | Bamboo charcoal and tourmaline composite Ag-loaded antibacterial agent, antibacterial polypropylene composition and preparation method |
| CN116330788A (en) * | 2023-03-07 | 2023-06-27 | 山东天元重工有限公司 | Motor car decorative plate and preparation method thereof |
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| CN102634114A (en) | 2012-08-15 |
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Open date: 20110713 |