CN102113603B - Cocoa butter replacer composition as well as preparation method and application thereof - Google Patents
Cocoa butter replacer composition as well as preparation method and application thereof Download PDFInfo
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- CN102113603B CN102113603B CN 200910247936 CN200910247936A CN102113603B CN 102113603 B CN102113603 B CN 102113603B CN 200910247936 CN200910247936 CN 200910247936 CN 200910247936 A CN200910247936 A CN 200910247936A CN 102113603 B CN102113603 B CN 102113603B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title claims description 36
- 235000019878 cocoa butter replacer Nutrition 0.000 title abstract 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011630 iodine Substances 0.000 claims abstract description 33
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 33
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 31
- 239000008158 vegetable oil Substances 0.000 claims abstract description 26
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 23
- 238000005194 fractionation Methods 0.000 claims abstract description 7
- 244000299461 Theobroma cacao Species 0.000 claims description 40
- 239000003921 oil Substances 0.000 claims description 34
- 235000019198 oils Nutrition 0.000 claims description 34
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 235000018936 Vitellaria paradoxa Nutrition 0.000 claims description 20
- 241001135917 Vitellaria paradoxa Species 0.000 claims description 20
- 235000019197 fats Nutrition 0.000 claims description 20
- 229940057910 shea butter Drugs 0.000 claims description 20
- 235000019219 chocolate Nutrition 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000000314 lubricant Substances 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 238000004332 deodorization Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000019482 Palm oil Nutrition 0.000 claims description 6
- 239000002540 palm oil Substances 0.000 claims description 6
- 239000004166 Lanolin Substances 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- 244000044822 Simmondsia californica Species 0.000 claims description 5
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 5
- 235000019486 Sunflower oil Nutrition 0.000 claims description 5
- 235000008524 evening primrose extract Nutrition 0.000 claims description 5
- 239000010475 evening primrose oil Substances 0.000 claims description 5
- 229940089020 evening primrose oil Drugs 0.000 claims description 5
- 235000019388 lanolin Nutrition 0.000 claims description 5
- 229940039717 lanolin Drugs 0.000 claims description 5
- 239000000944 linseed oil Substances 0.000 claims description 5
- 235000021388 linseed oil Nutrition 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- 239000002600 sunflower oil Substances 0.000 claims description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 abstract 4
- 239000004615 ingredient Substances 0.000 abstract 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 229940110456 cocoa butter Drugs 0.000 description 8
- 235000019868 cocoa butter Nutrition 0.000 description 8
- 235000006708 antioxidants Nutrition 0.000 description 7
- 239000004519 grease Substances 0.000 description 6
- 238000002372 labelling Methods 0.000 description 6
- 235000016709 nutrition Nutrition 0.000 description 6
- 238000007670 refining Methods 0.000 description 6
- 229930003427 Vitamin E Natural products 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 235000019165 vitamin E Nutrition 0.000 description 5
- 229940046009 vitamin E Drugs 0.000 description 5
- 239000011709 vitamin E Substances 0.000 description 5
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000003648 triterpenes Chemical class 0.000 description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000000787 lecithin Substances 0.000 description 3
- 229940067606 lecithin Drugs 0.000 description 3
- 235000010445 lecithin Nutrition 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229940093625 propylene glycol monostearate Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 2
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 235000008939 whole milk Nutrition 0.000 description 2
- RJKPEKIHHFNMGS-UHFFFAOYSA-N 2,4-ditert-butyl-3-methylphenol Chemical compound CC1=C(C(C)(C)C)C=CC(O)=C1C(C)(C)C RJKPEKIHHFNMGS-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- -1 alcohol ester Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000006255 coating slurry Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
Landscapes
- Confectionery (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention discloses a cocoa butter replacer composite as well as a preparation method and an application thereof. The composite contains an ingredient A from vegetable oil, wherein the iodine value of the ingredient A is 45-56g I/100g; and the ingredient A accounts for 70-100% by calculating with the total mass of the composite. The cocoa butter replacer composite provided by the invention is obtained by carrying out fractionation, hydrogenation and the like on the vegetable oil.
Description
Technical field
The present invention relates to field of food, relate in particular to a kind of chocolate coating substitute of cocoa fat composition and method of making the same and purposes.
Background technology
Substitute of cocoa fat is the substitute of natural cocoa butter, low price, aboundresources, its physical characteristic below 20 ℃, has preferably hardness, fragility and shrinkage, coating and mouthfeel near cocoa butter, in chocolate manufacture process, need not temperature adjustment, simplified technique.
The rheological characteristic of chocolate coating slurry is much better than chocolate mass, and the former is higher than the latter by fat content.At present, along with the day by day more new development of chocolate coating food products market, also develop rapidly as grease material and fat or oil composition goods of one of most important raw-food material.
Non-bay acid type substitute of cocoa fat (Cocoa Butter Re-placer, CBR) be a kind of with vegetable oil (rice bran oil, cottonseed oil, soya-bean oil, palm wet goods) for raw material, through come unstuck, a series of tristearin of being processed into such as depickling, decolouring, deodorization, hydrogenation, fractionation.Because its raw material sources are extensive, cheap, stearic physical behavior is similar to cocoa butter, price only is 1/3rd of cocoa butter, so in the situation in short supply at cocoa bean, that international market price rises steadily, be used for replacing cocoa butter by many countries, be widely used in the production of chocolate and part candy.
But traditional CBR heat resistance is poor, and mouthfeel is bad, the chocolate coating serious cracking of making.Therefore this area is in the urgent need to providing a kind of heat resistanceheat resistant type, and mouthfeel is good, and cost is low, is rich in nutritional labeling, and the chocolate coating of anti-cracking is with non-bay acid type substitute of cocoa fat (Cocoa Butter Re-placer, CBR).
Summary of the invention
The present invention aims to provide a kind of substitute of cocoa fat composition and method of making the same and purposes.
Another object of the present invention provides a kind of chocolate coating.
In a first aspect of the present invention, a kind of substitute of cocoa fat composition is provided, it is the composition A of 45-56g I/100g that described composition contains an iodine value from vegetable oil; In the gross weight of composition, the content of described composition A is 70-100%.
In another preference, described composition also contains acceptable emulsifying agent and antioxidant on the bromatology; In the gross weight of composition, the content of described emulsifying agent is 0.01-20%, and the content of described antioxidant is 0.0001-10%.
In another preference, described lubricant component A prepares by following steps:
(a) be that the vegetable oil of 50-60gI/100g divides and carries with iodine value, obtain the liquid oils that iodine value is 60-70gI/100g; With
(b) liquid oils that step (a) is obtained is carried out hydrogenation and is obtained the lubricant component A that iodine value is 45-56g I/100g.
In another preference, described vegetable oil is selected from shea butter, rapeseed oil, soybean oil, SIMMONDSIA CHINENSIS SEED OIL, lanolin, grape-kernel oil, evening primrose oil, linseed oil or sunflower oil.
In a second aspect of the present invention, a kind of preparation method of aforesaid substitute of cocoa fat composition provided by the invention is provided, described method comprises step:
(1) is that the vegetable oil of 50-60g I/100g divides and carries with iodine value, obtains the liquid oils that iodine value is 60-70gI/100g;
(2) liquid oils that step (1) is obtained is carried out hydrogenation and is obtained the lubricant component A that iodine value is 45-56g I/100g; With
(3) lubricant component A is decoloured, deodorization processes, and obtains aforesaid substitute of cocoa fat composition provided by the invention.
In another preference, in step (3) lubricant component A decoloured, after deodorization processes, add acceptable emulsifying agent and antioxidant on the bromatology, obtain aforesaid composition provided by the invention.
In another preference, described vegetable oil is selected from following one or more: shea butter, palm oil, rapeseed oil, soybean oil, SIMMONDSIA CHINENSIS SEED OIL, lanolin, grape-kernel oil, evening primrose oil, linseed oil and sunflower oil; Selected in described minute to divide from solvent and carry or dry fractionation.
In another preference, described solvent divides the solvent in carrying to be selected from acetone, benzinum, cyclohexane, ethanol or No. 6 solvent naphthas (requiring with reference to GB 1669-96).
In a third aspect of the present invention, provide a kind of purposes of aforesaid substitute of cocoa fat composition provided by the invention, for the preparation of chocolate or chocolate coating.
In a fourth aspect of the present invention, provide the application of liquid oils on the preparation substitute of cocoa fat from shea butter.
Accordingly, the invention provides a kind of heat resistanceheat resistant type, mouthfeel is good, and cost is low, is rich in nutritional labeling, and the chocolate coating of anti-cracking is with non-bay acid type substitute of cocoa fat (Cocoa Butter Re-placer, CBR)
The specific embodiment
The inventor is through extensive and deep research, the resulting a kind of heat resistanceheat resistant types of processing such as some vegetable oil are put forward by dividing, hydrogenation have been surprised to find that, mouthfeel is good, cost is low, be rich in nutritional labeling, the chocolate coating CBR of anti-cracking has fundamentally solved this and has perplexed insider's quality problem always.Based on this, finished the present invention.
CBR provided by the invention (or being called substitute of cocoa fat) can also add emulsifying agent, antioxidant etc. take vegetable oil as primary raw material; Composition iodine value from vegetable oil among the CBR provided by the invention is 45-56gI/100g, gross weight in this composition, the content of unsaponifiable matter wherein (such as triterpene substance, phytosterol and/or vitamin E) is no less than 4%, preferably is no less than 7%; In the gross weight of CBR provided by the invention, be 70-100% from the content of the composition of vegetable oil.In the gross weight of CBR provided by the invention, the content of emulsifying agent is 0.01-20%, and the content of antioxidant is 0.0001-10%.
Composition from vegetable oil among the CBR provided by the invention is to use to divide first to carry, rear catalyst mixing hydrogenation process and obtaining.Particularly, may further comprise the steps:
The first step is that the vegetable oil of 50-60g I/100g carries out carrying in one or multi-channel minute with iodine value, obtains the liquid oils that iodine value is 60-70g I/100g;
Second step carries out hydrogenation with the liquid oils that the first step obtains, and makes iodine value reduce to 45-56g I/100g;
In the 3rd step, refining obtains among the CBR provided by the invention composition from vegetable oil.
Minute bag in the first step is drawn together solvent and is divided and carry and dry fractionation.Described solvent divide carry in the volume ratio of employed solvent and vegetable oil be 2-4: 1, described solvent is selected from acetone, benzinum, cyclohexane, ethanol, No. 6 organic solvents such as solvent; Preferably, can carry out repeatedly solvent and divide and carry, such as but not limited to 2-4 time.Described dry fractionation can be under the growing the grain temperature of-5 ℃ to 35 ℃ (can select to be fit to the growing the grain temperature of different oil according to different oil), vegetable oil is carried out the normal pressure growing the grain, obtain the mixture of solid oil and liquid oils, then cling at 1-40, preferably under the pressure of 5 bar, mixture to gained carries out press filtration, obtains liquid oils.
Can use the oil hydrogenation catalyst of this area routine in the hydrogenation of second step, such as but not limited to, the mixing of copper, nickel, lanthanum, Cerium, cobalt, manganese or these metals.The addition of described oil hydrogenation catalyst is with the grease weighing scale, and percentage is 0.01-5%.
Refining in the 3rd step comprises the processing such as decolouring, deodorization.So-called decolouring is that the magazines such as employed catalyst and pigment in the above-mentioned hydrogenation are removed, and can use the method for this area routine to carry out, such as but not limited to, utilize the suction-operated decolouring of carclazyte, active carbon.So-called deodorization can use the method for this area routine to carry out, such as but not limited to, 210-260 ℃ of vacuum deodorization.
CBR provided by the invention just can obtain after above-mentioned three steps of process, preferably, can be added into emulsifying agent, antioxidant.
Employed vegetable oil is selected from following one or more among the CBR provided by the invention: shea butter, high iodine value palm oil, rapeseed oil, soybean oil, SIMMONDSIA CHINENSIS SEED OIL, lanolin, grape-kernel oil, evening primrose oil, linseed oil and sunflower oil; Preferred shea butter or shea butter and the palmitic miscella of high iodine value.Shea butter (shea butter) is a kind of grease that originates in Africa, contain the triterpene substance, phytosterol and the vitamin E that are no less than 4% (the contained ratio of general vegetable oil is less than 1%), these nutriments are at health care, medicine, and the daily use chemicals industry has been widely used.
Employed emulsifying agent comprises lecithin among the CBR provided by the invention, tween, polyglycereol castor-oil plant alcohol ester (PGPR), propylene glycol monostearate (PGMS) etc.; Employed antioxidant comprises TBHQ (TBHQ), 2,6-di-tert-butyl hydroxy toluene (BHT), butylhydroxy anisole (BHA), vitamin E, and rosemary, Xue MingRosma rinus officinalis.
Use CBR provided by the invention can prepare a kind of chocolate coating, the gross weight in described coating wherein contains: the 10-20% cocoa power; 40-50% sugar; 20-40% CBR provided by the invention; The 5-20% whole milk powder; With 0.2-1% phosphatide.
The above-mentioned feature that the present invention mentions, or the feature that embodiment mentions can any combination.All features that this case specification discloses can with any composition forms and usefulness, each feature that discloses in the specification can anyly provide the alternative characteristics of identical, impartial or similar purpose to replace.Therefore except special instruction is arranged, the feature that discloses only is the general example of equalization or similar features.
Major advantage of the present invention is:
1, CBR heat resistanceheat resistant provided by the invention, cost is low, is rich in nutritional labeling.
2, CBR preparation technology provided by the invention is simple.
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used for explanation the present invention and be not used in and limit the scope of the invention.The experimental technique of unreceipted actual conditions in the following example is usually according to normal condition or the condition of advising according to manufacturer.Unless otherwise indicated, otherwise all percentage, ratio, ratio or umber by weight.
Unit in the percent weight in volume among the present invention is well-known to those skilled in the art, for example refers to the weight of solute in 100 milliliters solution.
Unless otherwise defined, employed all specialties are identical with the meaning that scientific words and one skilled in the art are familiar with in the literary composition.In addition, any method similar or impartial to described content and material all can be applicable in the inventive method.The usefulness that better implementation method described in the literary composition and material only present a demonstration.
The shea butter that uses in the embodiment of the invention is available from oil chemical industry (Shanghai) Co., Ltd. in good
The oil hydrogenation catalyst 9908 that uses in the embodiment of the invention is believed ten thousand rich (Shanghai) Chemical trade Co., Ltd available from the village.
The oil hydrogenation catalyst 9920 that uses in the embodiment of the invention is believed ten thousand rich (Shanghai) Chemical trade Co., Ltd available from the village.
Solid fat performance is to measure by international method AOCS Cd16b-93 method to obtain in the embodiment of the invention.
Embodiment 1
CBR 1
Shea butter (iodine value 50-60gI/100g), acetone divides and raises shea butter liquid oil (iodine value 60-70gI/100g), carry out hydrogenation take 9908 as catalyst (addition 0.1% (with the weighing scale of grease)) again, reaction temperature 150-200 ℃, pressure 1-5bar, iodine value is down to 45-56gI/100g, then carries out refining and forms, add lecithin, obtain CBR 1.The results are shown in Table 1 and table 2.
Table 1
Table 2
Embodiment 2
CBR 2
Shea butter (iodine value 55-60gI/100g), benzinum divides and raises shea butter liquid oil (iodine value 60-70gI/100g), (addition 0.02% (take the weighing scale of grease) carries out hydrogenation as catalyst with 9908 (additions 0.08%) and 9920 again, reaction temperature 150-200 ℃, pressure 1-5bar, iodine value is down to 45-56gI/100g, then carries out refining and forms, add PGPR 0.2% (in the gross weight of the CBR that obtains), obtain CBR 2.The results are shown in Table 3.
Table 3
Embodiment 3
CBR 3
Shea butter can obtain shea butter liquid oil (iodine value 60-70gI/100g) through dry fractionation, carries out 9908 hydrogenations or 9920+9908 mixing hydrogenation (with the condition of embodiment 1) again, then carries out refining, the results are shown in Table 4.
Table 4
Embodiment 4
CBR 4
Shea butter can be through too raising shea butter liquid oil (iodine value 60-70gI/100g), and and high iodine value palm oil (iodine value 56-70gI/100g) mix (iodine value of the vegetable oil that obtains after the mixing is 56-70) with 7: 3 weight ratio, carry out again 9908 hydrogenations or 9920+9908 mixing hydrogenation (with the condition of embodiment 1), then carry out refining, the results are shown in Table 5.
Table 5
Comparative example
With conventional art, namely take palm oil and soya-bean oil as raw material, add catalysts selective (9908) hydrogenation and form hydrogenation result such as table 6.
Table 6
The result shows that there is following shortcoming in traditional product: the heat resistance in winter is good, but in summer, the heat resistance of this product is not good.And the expensive raw material price that adopts.
Heat resistance experiment contrast
With embodiment 1,2,3 and comparative example make chocolate coating.
Coating formula is:
14.5% cocoa power
45% Icing Sugar
30% grease
10% whole milk powder
0.5% lecithin
According to the chocolate preparation method of traditional substitute of cocoa fat, be made into chocolate, be placed in 35 ℃ of insulating boxs 9 days, observe the surface state hand-manipulating of needle in-degree of going forward side by side and detect.Result such as table 7.
Table 7
| Surface state | Hardness (needle penetration) | |
| Embodiment 1 | Dry glossy | 88 |
| Embodiment 2 | Dry glossy | 85 |
| Embodiment 3 | Dry glossy | 90 |
| Embodiment 4 | Dry glossy | 86 |
| Comparative example | Moistening tarnish | 110 |
Remarks: needle penetration is larger, and hardness is larger.
The nutritional labeling assessment:
Embodiment 1,2,3 contains the unsaponifiable matter (assay method is national standard method GBT 5535.2-2008) that is no less than 7% (the contained ratio of comparative example is less than 1%), be mainly triterpene substance, phytosterol and vitamin E, these nutriments are at health care, medicine, and the daily use chemicals industry has been widely used.
Products taste of the present invention is the same with original product.Its advantage has:
Heat resistance: in winter or summer, the heat resistance of this product is all good.
Cost: lower more than 1000 yuan/tons than traditional product.
Nutritional labeling: contain the triterpene substance, phytosterol and the vitamin E that are no less than 4% (the contained ratio of general vegetable oil is less than 1%), these nutriments are at health care, medicine, and the daily use chemicals industry has been widely used.
The above only is preferred embodiment of the present invention, be not to limit essence technology contents scope of the present invention, essence technology contents of the present invention is broadly to be defined in the claim scope of application, any technology entity or method that other people finish, if defined identical with the claim scope of application, also or a kind of change of equivalence, all will be regarded as being covered by among this claim scope.
Claims (9)
1. substitute of cocoa fat composition, it is the lubricant component A of 45-56gI/100g that described composition contains an iodine value from vegetable oil; In the gross weight of composition, the content of described lubricant component A is 70-100%; It is characterized in that described lubricant component A prepares by following steps:
(a) be that the vegetable oil of 50-60g I/100g divides and carries with iodine value, obtain the liquid oils that iodine value is 60-70gI/100g;
(b) liquid oils that step (a) is obtained is carried out hydrogenation and is obtained the lubricant component A that iodine value is 45-56g I/100g.
2. composition as claimed in claim 1 is characterized in that, described composition also contains acceptable emulsifying agent and antioxidant on the bromatology; In the gross weight of composition, the content of described emulsifying agent is 0.01-20%, and the content of described antioxidant is 0.0001-10%.
3. composition as claimed in claim 1 is characterized in that, described vegetable oil is selected from shea butter, palm oil, rapeseed oil, soybean oil, SIMMONDSIA CHINENSIS SEED OIL, lanolin, grape-kernel oil, evening primrose oil, linseed oil or sunflower oil.
4. preparation is characterized in that such as the method for the arbitrary described substitute of cocoa fat composition of claim 1-3 described method comprises step:
(1) is that the vegetable oil of 50-60g I/100g divides and carries with iodine value, obtains the liquid oils that iodine value is 60-70gI/100g;
(2) liquid oils that step (1) is obtained is carried out hydrogenation and is obtained the lubricant component A that iodine value is 45-56g I/100g; With
(3) lubricant component A is decoloured, deodorization processes.
5. method as claimed in claim 4 is characterized in that, in step (3) lubricant component A is decoloured, after deodorization processes, adds acceptable emulsifying agent and antioxidant on the bromatology.
6. such as claim 4 or 5 described methods, it is characterized in that described vegetable oil is selected from: shea butter, palm oil, rapeseed oil, soybean oil, SIMMONDSIA CHINENSIS SEED OIL, lanolin, grape-kernel oil, evening primrose oil, linseed oil and sunflower oil; Selected in described minute to divide from solvent and carry or dry fractionation.
7. method as claimed in claim 6 is characterized in that, described solvent divides the solvent in carrying to be selected from acetone, benzinum, cyclohexane, ethanol or No. 6 solvent naphthas.
8. the purposes such as the arbitrary described substitute of cocoa fat composition of claim 1-3 is characterized in that, for the preparation of chocolate or chocolate coating.
9. be the application of liquid oils on the preparation substitute of cocoa fat of 45-56g I/100g from the shea butter iodine value.
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| CN104126673A (en) * | 2013-05-03 | 2014-11-05 | 丰益(上海)生物技术研发中心有限公司 | Peanut oil body composition and application thereof |
| CN103815104B (en) * | 2013-09-30 | 2016-08-24 | 安徽康尔美油脂有限公司 | A kind of method utilizing chemically catalyzed interesterification method to prepare cacaolike butter |
| CN108289469A (en) * | 2015-12-02 | 2018-07-17 | 日清奥利友集团株式会社 | Cladding fat or oil composition |
| CN106879750A (en) * | 2015-12-16 | 2017-06-23 | 嘉里特种油脂（上海）有限公司 | A kind of crisp point special fat of Chinese style |
| CN106262624A (en) * | 2016-08-25 | 2017-01-04 | 宁夏宁杨清真食品有限公司 | The cold and dressed with sauce material of Spiced chicken with chili sauce and processing method |
| MX2019014385A (en) * | 2017-06-07 | 2020-08-06 | Aak Ab Publ | Shea based cocoa substitute. |
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