CN102113511A - Sterilization composite containing azoxystrobin and application - Google Patents

Sterilization composite containing azoxystrobin and application Download PDF

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Publication number
CN102113511A
CN102113511A CN 201010003845 CN201010003845A CN102113511A CN 102113511 A CN102113511 A CN 102113511A CN 201010003845 CN201010003845 CN 201010003845 CN 201010003845 A CN201010003845 A CN 201010003845A CN 102113511 A CN102113511 A CN 102113511A
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fluoxastrobin
weight
parts
bactericidal composition
flusilazole
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CN102113511B (en
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侯华民
张善学
王少龙
杜丽芬
蔡敷文
蒋端望
刘益帅
周道龙
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Hainan Zhengye Biotechnology Co ltd
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Hainan Zhengye Zhongnong Hi Tech Co Ltd
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Abstract

The utility model relates to a sterilization composite containing azoxystrobin and application. The composite mainly comprises two compounds A and B with effective quantity, the A is the azoxystrobin, the B is selected one from myclobutanil, flusilazole, mancozeb and dimethomorph, and the compounds A and B have the following parts by weight: 50-1 and 1-50. The composite can be used for preventing and curing powdery mildew, rust disease, downy mildew, anthracnose, phytophthora infestans, leaf spot, cladosporium cucumerinum and the like on frumentum, vegetables and fruit trees, and particularly has good effect on sigatoka, erysiphe graminis, phytophthora capsici leonian, cucumber downy mildew and venturia nashicola.

Description

Contain the bactericidal composition and the application of Fluoxastrobin
Technical field
The present invention relates to a kind of bactericidal composition that contains Fluoxastrobin, can be used for preventing and treating powdery mildew on cereal class, vegetables, the fruit tree, rust, downy mildew, anthracnose, late blight, leaf spot, scab etc., especially effective to sigatoka, wheat powdery mildew, capsicum epidemic disease, cucumber downy mildew, pear scab.
Background technology
Powdery mildew, rust, downy mildew, anthracnose, late blight etc. are the important diseases on cereal class, vegetables, the fruit tree etc.Once be used to prevent and treat the medicine such as tpn, carbendazim of sigatoka, medicines such as the sulphur of control wheat powdery mildew, triazolone, tmtd, thiophanate-methyl, medicines such as the metalaxyl of control capsicum epidemic disease, mancozeb, prevent and treat the medicine such as mancozeb, Kocide SD of downy mildew, prevent and treat the medicine such as mancozeb, carbendazim, thiophanate-methyl of pear scab, they are owing to use continuously, and disease has produced serious resistance to these medicaments, and these medicaments have been difficult to reach desirable preventive effect.
Fluoxastrobin (azoxystrobin) is a kind of brand-new β methoxy acrylic bactericide of Syngenta Co.,Ltd research and development, and tool is protected, treats, rooted out, infiltration and systemic activity.Be the mitochondrial respiratory inhibitor, promptly, suppressed the respiration of pathogen, make pathogen loss of life power by shifting to the electronics of cromoci at cytochrome B c1.Fluoxastrobin almost all has good active to all Mycophytes diseases such as powdery mildew, rust, glume blight, net blotch, scab, downy mildew, rice blast etc., and crop safety and Environmental compatibility are good.The azoxystrobin formulations product has the Amici to reach (25% Fluoxastrobin suspending agent) and paints green (50% azoxystrobin water dispersible granule).
But also there are not Fluoxastrobin and nitrile bacterium azoles composition at present, the relevant report of Fluoxastrobin and Flusilazole composition, Fluoxastrobin and mancozeb composition, Fluoxastrobin and dimethomorph composition.
Summary of the invention
At above-mentioned situation, the object of the present invention is to provide the bactericidal composition that contains Fluoxastrobin, it is that bactericide with two kinds of different structures, the different mechanisms of action carries out composite, be to prevent and treat the resistance disease, enlarge fungicidal spectrum and improve the effective way of drug effect, the more important thing is and avoid or delay the generation of insect new composition resistance.
Another object of the present invention provides this purposes that contains the bactericidal composition of Fluoxastrobin.
The objective of the invention is to realize by following measures:
The bactericidal composition that contains Fluoxastrobin is characterized in that said composition mainly includes A and the two kinds of compounds of B and the mixture of effect amount, and A is a Fluoxastrobin, and B is selected from a kind of in nitrile bacterium azoles, Flusilazole, mancozeb, the dimethomorph.The parts by weight of this bactericidal composition 1 component are: Fluoxastrobin 50~1, nitrile bacterium azoles 1~50; The parts by weight of these bactericidal composition 2 components are: Fluoxastrobin 50~1, Flusilazole 1~50; The parts by weight of these bactericidal composition 3 components are: Fluoxastrobin 50~1, mancozeb 1~50; The parts by weight of these bactericidal composition 4 components are: Fluoxastrobin 50~1, dimethomorph 1~50.
The described bactericidal composition that contains Fluoxastrobin is mixed with wetting powder, water dispersible granules, microemulsion, suspending agent, aqueous emulsion with solvent, auxiliary agent, the carrier used always.
The described bactericidal composition that contains Fluoxastrobin, can prevent and treat powdery mildew, rust, downy mildew, anthracnose, eqpidemic disease, leaf spot, scab, especially sigatoka, wheat powdery mildew, capsicum epidemic disease, cucumber downy mildew, pear scab on cereal class, vegetables, the fruit tree.
Beneficial effect of the present invention is: 1, synergistic effect is obvious: field test results shows, Fluoxastrobin and myclobutanil compositional are composite to wheat powdery mildew, pear scab to sigatoka, Fluoxastrobin and Flusilazole, and Fluoxastrobin and mancozeb are composite composite to cucumber downy mildew is all had the notable synergistic effect to capsicum epidemic disease, Fluoxastrobin and dimethomorph; 2, enlarge fungicidal spectrum: the azoxystrobin compound agent can prevent and treat the multiple diseases in the agricultural production; 3, reduce use cost: have a synergistic effect because of composite, reduced access times, reduced use cost; 4, delay pesticide resistance: Fluoxastrobin is the mitochondrial respiratory inhibitor, and tool is protected, treats, rooted out, infiltration and systemic activity.Behind other several composite reagents, germ is difficult for developing immunity to drugs.
Embodiment
The invention will be further described below in conjunction with embodiment, and embodiment is a preferred composition of the present invention, but the present invention is not confined to composition and application example in the present embodiment.
One: 12.5% Fluoxastrobin myclobutanil micro-emulsion of embodiment is prevented and treated sigatoka
Fluoxastrobin 2.5g is mixed with nitrile bacterium azoles 10g, fully dissolve with DMF5g and methyl alcohol 10g, add phenethyl phenol polyethenoxy ether 5g and agricultural newborn 500#5g, mixture is stirred in agitator, water complements to 100g, has both got 12.5% Fluoxastrobin myclobutanil micro-emulsion.
Two: 40% Fluoxastrobin Flusilazoles of embodiment water dispersible granules control wheat powdery mildew
Fluoxastrobin 30g, Flusilazole 10g, naphthalenesulfonate formaldehyde condensation compound 10g, sodium alkyl benzene sulfonate 5g, white carbon 45g are mixed, mixture is carried out granulation after the ultra-fine grinding, drying, screening, both made 40% Fluoxastrobin Flusilazole water dispersible granules.
Embodiment Fluoxastrobin mancozeb wettable powder control in three: 50% capsicum epidemic disease
Fluoxastrobin 25g, mancozeb 25g, sodium lignin sulfonate 15g, sodium alkyl benzene sulfonate 5g, kaolin 30g are mixed,, both must be mixed with 50% Fluoxastrobin mancozeb wettable powder each component drying, cooling, levigate.
Four: 25% Fluoxastrobin dimethomorphs of embodiment suspending agent control cucumber downy mildew
Fluoxastrobin 20g, dimethomorph 5g, sodium lignin sulfonate 3g, the withered powder 5g of tea, bentonite 5g, Magnesiumaluminumsilicate 2g, ethylene glycol 10g are fully mixed, add water 25g and fully grind, water complements to 100g, is mixed with 25% Fluoxastrobin dimethomorph suspending agent.
Five: 20% Fluoxastrobin Flusilazoles of embodiment aqueous emulsion is prevented and treated pear scab
Fluoxastrobin 10g, Flusilazole 10g are mixed, fully dissolve with carrene 5g and dimethylbenzene 10g, add phenethyl phenol polyethenoxy ether 5g, agricultural newborn 500#5g, water slowly adds and stirs, and water complements to 100g, has both got 20% Fluoxastrobin Flusilazole aqueous emulsion.
One: 12.5% Fluoxastrobin myclobutanil micro-emulsion of Application Example is prevented and treated sigatoka
1, test is handled: prepare 12.5% azoxystrobin water dispersible granule and 12.5% myclobutanil micro-emulsion contrasts as medicament, above-mentioned 12.5% Fluoxastrobin myclobutanil micro-emulsion, 12.5% azoxystrobin water dispersible granule and 12.5% myclobutanil micro-emulsion, 3 medicaments all are mixed with 2000 times of liquid, and other establishes the clear water contrast.
2, test method: sub-district area 20m is established in every processing 2, the area of 10 tikka of investigation (long * wide) before the dispenser, mark is listed, conventional constant even spraying.Make regular check on the scab size behind the medicine, calculate by the diffusion inhibiting rate and respectively handle preventive effect.
3, result of the test sees the following form:
Medicament Extension rate Lesion area (cm before the medicine 2) 10d preventive effect (%)
12.5% Fluoxastrobin myclobutanil micro-emulsion 2000 1.05 ?91.8
12.5% azoxystrobin water dispersible granule 2000 1.46 ?74.0
12.5% myclobutanil micro-emulsion 2000 1.58 ?81.2
The clear water contrast - 1.33 ?-
Two: 40% Fluoxastrobin Flusilazoles of Application Example water dispersible granules control wheat powdery mildew
1, test is handled: prepare 40% azoxystrobin water dispersible granule and 40% Flusilazole missible oil and be made as the medicament contrast, above-mentioned 40% Fluoxastrobin Flusilazole water dispersible granules, 40% azoxystrobin water dispersible granule and 40% Flusilazole missible oil all are mixed with 2000 times of liquid, and other establishes the clear water contrast.
2, test method: sub-district area 20m is established in every processing 2, 5 investigation in the preceding sub-district of dispenser, every 20 strain, the occurring degree of classification investigation blade powdery mildew, mark is listed, conventional constant even spraying.Make regular check on the state of an illness behind the medicine, refer to calculate by disease and respectively handle preventive effect.
3, result of the test sees the following form:
Medicament Extension rate Disease refers to (%) before the medicine 10d preventive effect (%)
40% Fluoxastrobin Flusilazole water dispersible granules 2000 53.8 ?89.5
40% azoxystrobin water dispersible granule 2000 46.5 ?82.5
40% Flusilazole missible oil 2000 36.4 ?79.8
The clear water contrast - 40.1 ?-
Application Example Fluoxastrobin mancozeb wettable powder control in three: 50% capsicum epidemic disease
1, test is handled: prepare 50% Fluoxastrobin wetting powder and 75% mancozeb wettable powder and establish the medicament contrast, above-mentioned 50% Fluoxastrobin mancozeb wettable powder, 50% Fluoxastrobin wetting powder and 75% mancozeb wettable powder all are mixed with 2000 times of liquid, and other establishes the clear water contrast.
2, test method: sub-district area 20m is established in every processing 2, 5 investigation in the preceding sub-district of dispenser, every 10 strain, the occurring degree of classification investigation blade eqpidemic disease, mark is listed, conventional constant even spraying.Make regular check on the state of an illness behind the medicine, refer to calculate by disease and respectively handle preventive effect.
3, result of the test sees the following form:
Medicament Extension rate Disease refers to (%) before the medicine 10d preventive effect (%)
50% Fluoxastrobin mancozeb wettable powder 2000 36.5 ?82.0
50% Fluoxastrobin wetting powder 2000 47.4 ?80.3
75% mancozeb wettable powder 2000 31.6 ?67.8
The clear water contrast - 42.7 ?-
Four: 25% Fluoxastrobin dimethomorphs of Application Example suspending agent control cucumber downy mildew
1, test is handled: prepare 25% Fluoxastrobin suspending agent and 25% dimethomorph missible oil and establish the medicament contrast, above-mentioned 25% Fluoxastrobin dimethomorph suspending agent, 25% Fluoxastrobin suspending agent and 25% dimethomorph missible oil all are mixed with 2000 times of liquid, other establishes the clear water contrast.
2, test method: sub-district area 20m is established in every processing 2, investigation 5 strains in every sub-district before the dispenser, the occurring degree of classification investigation blade downy mildew, mark is listed, conventional constant even spraying.Make regular check on the state of an illness behind the medicine, refer to calculate by disease and respectively handle preventive effect.
3, result of the test sees the following form:
Medicament Extension rate Disease refers to (%) before the medicine 10d preventive effect (%)
25% Fluoxastrobin dimethomorph suspending agent 2000 40.1 ?84.6
25% Fluoxastrobin suspending agent 2000 47.9 ?76.5
25% dimethomorph missible oil 2000 28.5 ?78.8
The clear water contrast - 34.4 ?-
Five: 20% Fluoxastrobin Flusilazoles of Application Example aqueous emulsion is prevented and treated pear scab
1, test is handled: prepare 25% Fluoxastrobin suspending agent and 25% dimethomorph missible oil and establish the medicament contrast, above-mentioned 20% Fluoxastrobin Flusilazole aqueous emulsion, 20% azoxystrobin water emulsion and 20% Flusilazole aqueous emulsion all are mixed with 2000 times of liquid, other establishes the clear water contrast.
2, test method: sub-district area 20m is established in every processing 2, investigation 3 strains in every sub-district before the dispenser, 2 branches of every strain investigation, the occurring degree of classification investigation blade scab, mark is listed, conventional constant even spraying.Make regular check on the state of an illness behind the medicine, refer to calculate by disease and respectively handle preventive effect.
3, result of the test sees the following form:
Medicament Extension rate Disease refers to (%) before the medicine 10d preventive effect (%)
20% Fluoxastrobin Flusilazole aqueous emulsion 2000 25.7 ?90.2
20% azoxystrobin water emulsion 2000 34.3 ?84.0
20% azoxystrobin water emulsion 2000 36.5 ?80.4
The clear water contrast - 30.8 ?-

Claims (7)

1. the bactericidal composition that contains Fluoxastrobin is characterized in that said composition mainly includes A and two kinds of compounds of B of effect amount, and A is a Fluoxastrobin, and B is selected from a kind of in nitrile bacterium azoles, Flusilazole, mancozeb, the dimethomorph.
2. the described bactericidal composition that contains Fluoxastrobin of claim 1, it is characterized in that: the parts by weight of Fluoxastrobin are 50~1, the parts by weight of nitrile bacterium azoles are 1~50.
3. the described bactericidal composition that contains Fluoxastrobin of claim 1, it is characterized in that: the parts by weight of Fluoxastrobin are 50~1, the parts by weight of Flusilazole are 1~50.
4. the described bactericidal composition that contains Fluoxastrobin of claim 1, it is characterized in that: the parts by weight of Fluoxastrobin are 50~1, the parts by weight of mancozeb are 1~50.
5. the described bactericidal composition that contains Fluoxastrobin of claim 1, it is characterized in that: the parts by weight of Fluoxastrobin are 50~1, the parts by weight of dimethomorph are 1~50.
6. as the described bactericidal composition that contains Fluoxastrobin of claim 1~5, be mixed with wetting powder, water dispersible granules, microemulsion, suspending agent, aqueous emulsion with commonly used solvent, auxiliary agent, carrier.
7. as the described bactericidal composition that contains Fluoxastrobin of claim 1~5, the application of powdery mildew, rust, downy mildew, anthracnose, eqpidemic disease, leaf spot, scab, the especially sigatoka on control cereal class, vegetables, fruit tree, wheat powdery mildew, capsicum epidemic disease, cucumber downy mildew, pear scab aspect.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012070961A3 (en) * 2010-11-26 2012-08-02 Sapec-Agro, Sa Fungicidal mixture
CN102835407A (en) * 2012-09-17 2012-12-26 常华 Bactericidal composition of azoxystrobin and mancozeb
CN102835418A (en) * 2012-08-22 2012-12-26 广西田园生化股份有限公司 Sterilization combination containing simeconazole and methoxy acrylic ester germicides
CN103027050A (en) * 2011-12-21 2013-04-10 湖北仙隆化工股份有限公司 Pesticide composition containing azoxystrobin and myclobutanil
WO2015079334A1 (en) 2013-11-26 2015-06-04 Upl Limited A method for controlling rust
CN107114387A (en) * 2017-05-26 2017-09-01 广西力拓农业开发有限公司 A kind of bactericidal composition for being used to prevent and treat citrus disease
CN114668027A (en) * 2022-02-16 2022-06-28 江苏农爱田生物科技有限公司 Pharmaceutical composition for preventing garlic rust and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101069511B (en) * 2006-05-09 2012-12-05 陶氏农业科学公司 Stabilized fungus-killing agent composition
JP2010150230A (en) * 2008-05-09 2010-07-08 Nissan Chem Ind Ltd Germicidal composition

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012070961A3 (en) * 2010-11-26 2012-08-02 Sapec-Agro, Sa Fungicidal mixture
CN103027050A (en) * 2011-12-21 2013-04-10 湖北仙隆化工股份有限公司 Pesticide composition containing azoxystrobin and myclobutanil
CN102835418A (en) * 2012-08-22 2012-12-26 广西田园生化股份有限公司 Sterilization combination containing simeconazole and methoxy acrylic ester germicides
CN102835407A (en) * 2012-09-17 2012-12-26 常华 Bactericidal composition of azoxystrobin and mancozeb
GB2532700B (en) * 2013-11-26 2016-08-31 Upl Ltd A method for controlling rust
GB2532700A (en) * 2013-11-26 2016-05-25 Upl Ltd A method for controlling rust
WO2015079334A1 (en) 2013-11-26 2015-06-04 Upl Limited A method for controlling rust
EP3073826A4 (en) * 2013-11-26 2016-10-19 Upl Ltd A method for controlling rust
EP3073826B1 (en) 2013-11-26 2019-10-30 UPL Limited A method for controlling soybean rust
EP4014741A1 (en) * 2013-11-26 2022-06-22 UPL Ltd A method for controlling rust
EP4014738A1 (en) * 2013-11-26 2022-06-22 UPL Ltd A method for controlling rust
EP4018828A1 (en) * 2013-11-26 2022-06-29 UPL Ltd A method for controlling rust
CN107114387A (en) * 2017-05-26 2017-09-01 广西力拓农业开发有限公司 A kind of bactericidal composition for being used to prevent and treat citrus disease
CN114668027A (en) * 2022-02-16 2022-06-28 江苏农爱田生物科技有限公司 Pharmaceutical composition for preventing garlic rust and preparation method thereof

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