CN102108271A - Method for preparing water transferring glue - Google Patents
Method for preparing water transferring glue Download PDFInfo
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- CN102108271A CN102108271A CN 201010602741 CN201010602741A CN102108271A CN 102108271 A CN102108271 A CN 102108271A CN 201010602741 CN201010602741 CN 201010602741 CN 201010602741 A CN201010602741 A CN 201010602741A CN 102108271 A CN102108271 A CN 102108271A
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- transfer adhesive
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- water transfer
- polyvinyl alcohol
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Abstract
The invention discloses a method for preparing water transferring glue. The method comprises the following steps: dissolving poval in deionized water, then adding polyacrylic acid and evenly mixing, then adding a tackifier, a rapid penetrating agent and dibutyl phthalate, dioctyl phthalate or di-amyl phthalate and mixing so as to obtain a polymer system 1; dissolving nano montmorillonite in the deionized water, adding a surface active agent and dispersing with ultrasonic wave, and then adding inorganic pigment so as to obtain a nano system 2; mixing the polymer system 1 with the nano system 2, heating to 60 DEG C, and dispersing with ultrasonic wave so as to obtain the water transferring glue. The nano montmorillonite is added in the water transferring glue, thereby effectively improving the transfer ratio of ink on a transfer printing paper and simultaneously solving the pollution problem of solvent type transferring glue and the energy consumption problem of heat transferring glue.
Description
Technical field
The present invention relates to a kind of method for preparing the water transfer adhesive, be specifically related to a kind of method of adding nano material preparation water transfer adhesive.
Background technology
Because environmental stress continues to increase, the pattern of low-carbon (LC) is the mode of production and the mode of life of Future Society, the printing mode that shifts is a revolution in the printing industry, trans-printing pattern originally all has different shortcomings, there is the drawback of power consumption in hot transfer adhesive, and organic solvent can bring pollution problem, has damaged operator's health, has brought new carrying capacity of environment.Limited its use.
Summary of the invention
The objective of the invention is to solve the problem of the existence in the above-mentioned existing field, provide with low cost, prepare easy, and the low method for preparing the water transfer adhesive of carrying capacity of environment.
For achieving the above object, the technical solution used in the present invention is:
1) polyvinyl alcohol and the deionized water mass ratio by 1: 20 is dissolved in the deionized water, and then the polyacrylic acid post-heating to 90 of quality such as adding and polyvinyl alcohol ℃, stir and add tackifier and permeate agent again after two hours, keep temperature to continue to stir 30 minutes, add softening agent stirring under 70 ℃ again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: quickly penetrating agent: the mass ratio of softening agent is: 100: 5-10: 1-2: 0.5-2;
2) nano imvite is dissolved in the deionized water of 50 times of quality, adds the tensio-active agent of polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
The molecular weight of described polyvinyl alcohol is 10000.
Described polyacrylic molecular weight is 8000, and molecular weight distribution is 1.3-1.8.
Described tackifier are nano imvite, coupling agent modified polynite or carboxymethyl starch.
Described quickly penetrating agent is an ethylene glycol, glycerol, and molecular weight is 5000 polyvinyl alcohol.
Described softening agent is dibutyl phthalate, dioctyl phthalate (DOP) or diamyl phthalate
Described tensio-active agent is sodium laurylsulfonate, stearic acid, Sodium dodecylbenzene sulfonate or tween.
Described inorganic salt material is Z 250, copper sulfate, Xiao Suangu, zinc oxide or titanium oxide.
The present invention adds nano imvite, can improve the rate of transform of printing ink on the transfer printing paper effectively, and the rate of transform of Yellow ink can reach 97.7%; The rate of transform 99.8% of magenta ink; The rate of transform 98.2% of cyan ink; The tusche rate of transform reaches 98.7%; Solved the pollution problem that solvent-borne type transfer adhesive volatilization benzene class, ketone organic high molecular compound bring simultaneously; Solved the energy consumption issues that hot transfer adhesive needs.Traditional hot transfer adhesive needs the temperature more than 220 ℃ just can finish moment and paper is peeled off, and transfer adhesive of the present invention can be finished peeling off of paper and printing ink at normal temperatures.Actual effect according to the transfer adhesive after not adding and adding compares: the glue after the interpolation, transfer efficiency has improved 70%.
Embodiment
Embodiment 1:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir and add tackifier nano imvite and permeate agent ethylene glycol after two hours again, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid dibutylester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 5: 1: 0.5;
2) nano imvite is dissolved in the deionized water of 50 times of quality, the tensio-active agent sodium laurylsulfonate that adds polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye Z 250 that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Embodiment 2:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir and add coupling agent modified polynite of tackifier and permeate agent glycerol after two hours again, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid dioctyl ester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 8: 1.5: 1;
2) nano imvite is dissolved in the deionized water of 50 times of quality, adds the tensio-active agent stearic acid of polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye copper sulfate that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Embodiment 3:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir that to add tackifier carboxymethyl starch and permeate agent molecular weight after two hours again be 5000 polyvinyl alcohol, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid diamyl ester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 10: 2: 2;
2) nano imvite is dissolved in the deionized water of 50 times of quality, the tensio-active agent sodium laurylsulfonate, stearic acid, Sodium dodecylbenzene sulfonate or the tween that add polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye Z 250, copper sulfate, Xiao Suangu, zinc oxide or the titanium oxide that add polynite quality 10% again make nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Embodiment 4:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir that to add tackifier nano imvite and permeate agent molecular weight after two hours again be 5000 polyvinyl alcohol, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid dioctyl ester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 6: 1.5: 0.8;
2) nano imvite is dissolved in the deionized water of 50 times of quality, adds the tensio-active agent tween of polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye zinc oxide that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Embodiment 5:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir and add coupling agent modified polynite of tackifier and permeate agent glycerol after two hours again, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid diamyl ester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 9: 1.8: 1.7;
2) nano imvite is dissolved in the deionized water of 50 times of quality, the tensio-active agent sodium laurylsulfonate that adds polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye titanium oxide that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Embodiment 6:1) being 10000 polyvinyl alcohol and deionized water with molecular weight is dissolved in the deionized water by 1: 20 mass ratio, and then the molecular weight of quality such as adding and polyvinyl alcohol is 8000, molecular weight distribution is the polyacrylic acid post-heating to 90 ℃ of 1.3-1.8, stir and add tackifier carboxymethyl starch and permeate agent ethylene glycol after two hours again, keep temperature to continue to stir 30 minutes, add the stirring under 70 ℃ of plasticizer phthalic acid dibutylester again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: permeate agent: the mass ratio of softening agent is: 100: 7: 1.6: 1.2;
2) nano imvite is dissolved in the deionized water of 50 times of quality, adds the tensio-active agent tristearin of polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye Z 250 that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
Claims (8)
1. method for preparing the water transfer adhesive is characterized in that:
1) polyvinyl alcohol and the deionized water mass ratio by 1: 20 is dissolved in the deionized water, and then the polyacrylic acid post-heating to 90 of quality such as adding and polyvinyl alcohol ℃, stir and add tackifier and permeate agent again after two hours, keep temperature to continue to stir 30 minutes, add softening agent stirring under 70 ℃ again and made polymeric system 1 in 1 hour;
Polyvinyl alcohol wherein: tackifier: quickly penetrating agent: the mass ratio of softening agent is: 100: 5-10: 1-2: 0.5-2;
2) nano imvite is dissolved in the deionized water of 50 times of quality, adds the tensio-active agent of polynite quality 2% then, disperseed 120 minutes in ultrasonic wave, the mineral dye that adds polynite quality 10% again makes nanometer system 2;
3) will make polymeric system 1 and nanometer system 2 and be mixed and heated to 60 ℃ with 100: 1 mass ratio, ultrasonic dispersing obtained the water transfer adhesive in 60 minutes.
2. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: the molecular weight of described polyvinyl alcohol is 10000.
3. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described polyacrylic molecular weight is 8000, and molecular weight distribution is 1.3-1.8.
4. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described tackifier are nano imvite, coupling agent modified polynite or carboxymethyl starch.
5. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described quickly penetrating agent is an ethylene glycol, glycerol, and molecular weight is 5000 polyvinyl alcohol.
6. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described softening agent is dibutyl phthalate, dioctyl phthalate (DOP) or diamyl phthalate
7. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described tensio-active agent is sodium laurylsulfonate, stearic acid, Sodium dodecylbenzene sulfonate or tween.
8. the method for preparing the water transfer adhesive according to claim 1 is characterized in that: described inorganic salt material is Z 250, copper sulfate, Xiao Suangu, zinc oxide or titanium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106027419A CN102108271B (en) | 2010-12-23 | 2010-12-23 | Method for preparing water transferring glue |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106027419A CN102108271B (en) | 2010-12-23 | 2010-12-23 | Method for preparing water transferring glue |
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| CN102108271A true CN102108271A (en) | 2011-06-29 |
| CN102108271B CN102108271B (en) | 2012-11-07 |
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| CN2010106027419A Expired - Fee Related CN102108271B (en) | 2010-12-23 | 2010-12-23 | Method for preparing water transferring glue |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103724854A (en) * | 2013-12-03 | 2014-04-16 | 常州大学 | Nano-composite near-infrared absorbent and preparation method thereof |
| CN105038442A (en) * | 2015-08-04 | 2015-11-11 | 上海乘鹰新材料有限公司 | Mold-pressing holographic water transfer printing coating and preparation method thereof |
| CN105349069A (en) * | 2015-12-04 | 2016-02-24 | 常德市雄鹰科技有限责任公司 | Water-based back glue for transfer paper and preparation method of water-based back glue |
| CN106280841A (en) * | 2016-09-22 | 2017-01-04 | 佛山慧创正元新材料科技有限公司 | A kind of thermal transfer mould release |
| CN110218535A (en) * | 2019-06-21 | 2019-09-10 | 江苏国胶新材料有限公司 | A kind of one-component Facing material transfer adhesive and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1363628A (en) * | 2002-01-16 | 2002-08-14 | 郝喜海 | Method for regulating dissolving speed of water-soluble film |
-
2010
- 2010-12-23 CN CN2010106027419A patent/CN102108271B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1363628A (en) * | 2002-01-16 | 2002-08-14 | 郝喜海 | Method for regulating dissolving speed of water-soluble film |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103724854A (en) * | 2013-12-03 | 2014-04-16 | 常州大学 | Nano-composite near-infrared absorbent and preparation method thereof |
| CN103724854B (en) * | 2013-12-03 | 2016-07-06 | 常州大学 | A kind of nano combined near infrared absorbent and preparation method thereof |
| CN105038442A (en) * | 2015-08-04 | 2015-11-11 | 上海乘鹰新材料有限公司 | Mold-pressing holographic water transfer printing coating and preparation method thereof |
| CN105038442B (en) * | 2015-08-04 | 2018-04-06 | 上海乘鹰新材料有限公司 | A kind of moldable holographic water transfer coating and preparation method thereof |
| CN105349069A (en) * | 2015-12-04 | 2016-02-24 | 常德市雄鹰科技有限责任公司 | Water-based back glue for transfer paper and preparation method of water-based back glue |
| CN105349069B (en) * | 2015-12-04 | 2017-08-29 | 常德市雄鹰科技有限责任公司 | A kind of transfer paper aqueous back of the body gluing and preparation method thereof |
| CN106280841A (en) * | 2016-09-22 | 2017-01-04 | 佛山慧创正元新材料科技有限公司 | A kind of thermal transfer mould release |
| CN106280841B (en) * | 2016-09-22 | 2019-04-05 | 陈龙 | A kind of thermal transfer mould release |
| CN110218535A (en) * | 2019-06-21 | 2019-09-10 | 江苏国胶新材料有限公司 | A kind of one-component Facing material transfer adhesive and preparation method thereof |
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| CN102108271B (en) | 2012-11-07 |
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