CN107033745A - A kind of nano-coating material and preparation method thereof - Google Patents
A kind of nano-coating material and preparation method thereof Download PDFInfo
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- CN107033745A CN107033745A CN201710434239.3A CN201710434239A CN107033745A CN 107033745 A CN107033745 A CN 107033745A CN 201710434239 A CN201710434239 A CN 201710434239A CN 107033745 A CN107033745 A CN 107033745A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of nano-coating material and preparation method thereof, the nano-coating material includes the raw material of following parts by weight：44 30 50 parts of epoxy resin E, 10 20 parts of nano titanium oxide, 15 25 parts of diatomite, 3 10 parts of zirconia ceramics powder, 15 parts of graphite, 13 parts of glycerine glycerinate, 5 15 parts of butenoic acid ethyl, 16 parts of ATBC, 0.5 2 parts of neopelex, 0.4 0.8 parts of thickener, 0.2 0.6 parts of age resistor.Preparation method comprises the following steps：Epoxy resin E 44 modification：By epoxy resin E 44, diatomite, zirconia ceramics powder, glycerine glycerinate temperature reaction, cool down, crush, sieving；Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed and reacted in input autoclave, cooling obtains mixture a；Granulation, extrusion obtain the nano-coating material.The coating material of the present invention has excellent acidproof, alkaline-resisting, Corrosion Protection and mechanical strength, composition environmental protection, is suitable as the coating of automobile, furniture.
Description
Technical field
The present invention relates to nano coating technical field, and in particular to a kind of nano-coating material and preparation method thereof.
Background technology
With the continuous progress and the continuous improvement of living standard of science and technology, requirement of the consumer to quality of life is also increasingly
It is high.In coating industry, environmental protection, energy-conservation are coating preparation and the development trend of coating process.Three points of coating, seven points of applications are right
For reduction ambient influnence, protection consumer health, the quality assurance of coating process seems more crucial.In order to ensure application
The environmental protection and energy saving of process, do not require nothing more than that coating products are environmentally friendly in itself, and the whole production and supply chain including construction link
Environmental protection will be realized.
The patent of invention of application number 201611185613.2 discloses a kind of nano environmental protection coating material, by following quality point
Several formula compositions：6-10 parts of graphite, 9-11 parts of PPG, 10-20 parts of phenolic resin, rutile titanium dioxide 3-4
Part, 4-6 parts of bentonite polyphenyl ester, 50-70 parts of zirconia ceramics powder, 4-8 parts of aromatic polyester, 4-6 parts of polyester, 7-9 parts of zirconium colloidal sol,
3-5 parts of blanc fixe, the nano environmental protection coating is environmentally friendly, widely used, is that the nano-coating material of environmental protection is carried
Foundation is supplied.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of nano-coating material and preparation method thereof,
The coating material has excellent acidproof, alkaline-resisting, Corrosion Protection and mechanical strength, composition environmental protection, be suitable as automobile,
The coating of furniture.
The present invention solves technical problem and adopted the following technical scheme that：
A kind of nano-coating material, includes the raw material of following parts by weight：30-50 parts of epoxy resin E-44, nano titanium oxide
10-20 parts, 15-25 parts of diatomite, 3-10 parts of zirconia ceramics powder, 1-5 parts of graphite, 1-3 parts of glycerine glycerinate, butylene
5-15 parts of acetoacetic ester, 1-6 parts of ATBC, 0.5-2 parts of neopelex, 0.4-0.8 parts of thickener, age resistor
0.2-0.6 parts.
Preferably, the nano-coating material includes the raw material of following parts by weight：Part, nanometer two of epoxy resin E-44 45
16 parts of titanium oxide, 22 parts of diatomite, 8 parts of zirconia ceramics powder, 2 parts of graphite, 3 parts of glycerine glycerinate, butenoic acid ethyl
10 parts, 5 parts of ATBC, 1.2 parts of neopelex, 0.6 part of thickener, 0.3 part of age resistor.
Preferably, the thickener is sodium carboxymethylcellulose, propylene glycol alginate, hydroxyethyl cellulose, hydroxypropyl
One or more combinations in methylcellulose.
Preferably, the age resistor is antioxidant A P, antioxidant A W, antioxidant 4010NA, age resistor 4030, age resistor
One or more in DNP.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-120
DEG C, stirring reaction 10-15 minutes under conditions of 2-3Mpa, be cooled to room temperature and obtain mixture a；
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed, normal temperature
Stirring 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.
Preferably, the step（1）Crushing uses Universalpulverizer, and the speed of mainshaft is 950r/min, and discharging-material size is 2-
5mm。
Preferably, the step（2）Speed of agitator is 600-800r/min.
Preferably, the step（3）The rotating speed of single screw extrusion machine is 120-150rpm/min, and draw ratio is 15-20：1.
Compared with prior art, the present invention has following beneficial effect：
（1）The nano-coating material of the present invention, composition environmental protection, with excellent acidproof, alkaline-resisting, Corrosion Protection and machinery
Intensity, preparation method is easy easily to be repeated, and is suitable as the coating of automobile, furniture.
（2）In the nano-coating material composition of the present invention, epoxy resin E-44 have stable chemical property, water-resistance,
Solvent resistance and mechanical performance, bonding force are strong, and shrinkage factor is small, and resistance to voltage is excellent；Nano titanium oxide has very high chemistry
Stability, heat endurance, Superhydrophilic, dispersiveness, and can be contacted completely with food；Diatomite has that porosity is big, absorb
The strong, chemical property of property is stable, wear-resisting, it is heat-resisting the features such as, excellent surface property, increase-volume, thickening and attached can be provided for coating
Put forth effort.Zirconia ceramics powder has high tenacity, high-flexural strength and high-wearing feature, and excellent heat-proof quality, thermal coefficient of expansion connects
The advantages of being bordering on steel；Graphite is soft, there is greasy feeling, the performance corroded with good high temperature resistant, acid and alkali-resistance and organic solvent；Fourth
Olefin(e) acid ethyl ester is typically used as the softening agent of coating；ATBC compatibility is good, and cold-resistant, fast light, water resistance is excellent, plasticising
Efficiency high, is a kind of plasticizer of environment-friendly type；Neopelex acid and alkali-resistance, resistance to hard water, are a kind of conventional anion
Surfactant.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1.
A kind of nano-coating material, includes the raw material of following weight：Epoxy resin E-44 45g, nano titanium oxide 16g, diatom
Native 22g, zirconia ceramics powder 8g, graphite 2g, glycerine glycerinate 3g, butenoic acid ethyl 10g, ATBC 5g,
Neopelex 1.2g, thickener sodium carboxymethylcellulose 0.6g, antioxidant A P 0.3g.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：By epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine glycerinate
Be mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-60 mesh sieves, obtain
To modified epoxy resin E-44；Wherein, crush and use Universalpulverizer, the speed of mainshaft is 950r/min, and discharging-material size is
2-5mm。
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-
120 DEG C, under conditions of 2-3Mpa with 600-800r/min speed stirring reactions 10-15 minutes, be cooled to room temperature and obtain mixture
a。
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed,
Stirring at normal temperature 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.Wherein, Single screw extrusion
The rotating speed of machine is 120-150rpm/min, and draw ratio is 15-20：1.
Embodiment 2.
A kind of nano-coating material, includes the raw material of following weight：Epoxy resin E-44 42g, nano titanium oxide 13g, diatom
Native 20g, zirconia ceramics powder 6g, graphite 2g, glycerine glycerinate 1g, butenoic acid ethyl 8g, ATBC 2g, ten
Dialkyl benzene sulfonic acids sodium 0.8g, thickener hydroxyethyl cellulose 0.5g, antioxidant 4010NA 0.3g.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；Wherein, crush and use Universalpulverizer, the speed of mainshaft is 950r/min, is gone out
Material granularity is 2-5mm.
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-
120 DEG C, under conditions of 2-3Mpa with 600-800r/min speed stirring reactions 10-15 minutes, be cooled to room temperature and obtain mixture
a。
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed,
Stirring at normal temperature 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.Wherein, Single screw extrusion
The rotating speed of machine is 120-150rpm/min, and draw ratio is 15-20：1.
Embodiment 3.
A kind of nano-coating material, includes the raw material of following weight：Epoxy resin E-44 46g, nano titanium oxide 12g, diatom
Native 16g, zirconia ceramics powder 10g, graphite 2g, glycerine glycerinate 1g, butenoic acid ethyl 15g, ATBC 5g,
Neopelex 0.8g, thickener propylene glycol alginate 0.6g, antioxidant D NP 0.5g.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；Wherein, crush and use Universalpulverizer, the speed of mainshaft is 950r/min, is gone out
Material granularity is 2-5mm.
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-
120 DEG C, under conditions of 2-3Mpa with 600-800r/min speed stirring reactions 10-15 minutes, be cooled to room temperature and obtain mixture
a。
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed,
Stirring at normal temperature 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.Wherein, Single screw extrusion
The rotating speed of machine is 120-150rpm/min, and draw ratio is 15-20：1.
Embodiment 4.
A kind of nano-coating material, includes the raw material of following weight：Epoxy resin E-44 48g, nano titanium oxide 14g, diatom
Native 17g, zirconia ceramics powder 5g, graphite 4g, glycerine glycerinate 2g, butenoic acid ethyl 13g, ATBC 5g,
Neopelex 1.5g, thickener hydroxypropyl methyl cellulose 0.6g, antioxidant A W 0.3g.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；Wherein, crush and use Universalpulverizer, the speed of mainshaft is 950r/min, is gone out
Material granularity is 2-5mm.
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-
120 DEG C, under conditions of 2-3Mpa with 600-800r/min speed stirring reactions 10-15 minutes, be cooled to room temperature and obtain mixture
a。
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed,
Stirring at normal temperature 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.Wherein, Single screw extrusion
The rotating speed of machine is 120-150rpm/min, and draw ratio is 15-20：1.
Embodiment 5.
A kind of nano-coating material, includes the raw material of following weight：Epoxy resin E-44 50g, nano titanium oxide 20g, diatom
Native 20g, zirconia ceramics powder 10g, graphite 5g, glycerine glycerinate 3g, butenoic acid ethyl 15g, ATBC 5g,
Neopelex 1.8g, thickener hydroxyethyl cellulose 0.8g, antioxidant 4010NA 0.5g.
The preparation method of above-mentioned nano-coating material, comprises the following steps：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；Wherein, crush and use Universalpulverizer, the speed of mainshaft is 950r/min, is gone out
Material granularity is 2-5mm.
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-
120 DEG C, under conditions of 2-3Mpa with 600-800r/min speed stirring reactions 10-15 minutes, be cooled to room temperature and obtain mixture
a。
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed,
Stirring at normal temperature 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.Wherein, Single screw extrusion
The rotating speed of machine is 120-150rpm/min, and draw ratio is 15-20：1.
Nano-coating material prepared by the embodiment of the present invention 1 is sprayed on steel plate, measures various aspects of performance.When drying
Between：Surface drying≤5h, does solid work≤24h；280 DEG C of heat resistance：5.6h pass through；Resistance to 45% sulfuric acid：36 days without exception；Resistance to 20% hydroxide
Sodium：25 days without exception；Viscosity：≥79s；Impact strength：56-60cm.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, also should be regarded as the present invention
Protection domain.
Claims (8)
1. a kind of nano-coating material, it is characterised in that include the raw material of following parts by weight：30-50 parts of epoxy resin E-44,
10-20 parts of nano titanium oxide, 15-25 parts of diatomite, 3-10 parts of zirconia ceramics powder, 1-5 parts of graphite, glycerine triglycerin acid
1-3 parts of ester, 5-15 parts of butenoic acid ethyl, 1-6 parts of ATBC, 0.5-2 parts of neopelex, thickener 0.4-
0.8 part, 0.2-0.6 parts of age resistor.
2. nano-coating material according to claim 1, it is characterised in that the nano-coating material includes following weight
The raw material of part：45 parts of epoxy resin E-44,16 parts of nano titanium oxide, 22 parts of diatomite, 8 parts of zirconia ceramics powder, graphite 2
Part, 3 parts of glycerine glycerinate, 10 parts of butenoic acid ethyl, 5 parts of ATBC, 1.2 parts of neopelex,
0.6 part of thickener, 0.3 part of age resistor.
3. nano-coating material according to claim 1, it is characterised in that the thickener be sodium carboxymethylcellulose,
One or more combinations in propylene glycol alginate, hydroxyethyl cellulose, hydroxypropyl methyl cellulose.
4. nano-coating material according to claim 1, it is characterised in that the age resistor is antioxidant A P, age resistor
One or more in AW, antioxidant 4010NA, age resistor 4030, antioxidant D NP.
5. the preparation method of the nano-coating material according to claim 1-4 any one, it is characterised in that including as follows
Step：
（1）The modification of epoxy resin E-44：According to parts by weight by epoxy resin E-44, diatomite, zirconia ceramics powder, glycerine
Glycerinate is mixed evenly, be warming up to 70-80 DEG C reaction 30-40 minute after, naturally cool to room temperature, crush, mistake 40-
60 mesh sieves, obtain modified epoxy resin E-44；
（2）Nano titanium oxide, graphite, butenoic acid ethyl, ATBC are mixed in input autoclave, in 100-120
DEG C, stirring reaction 10-15 minutes under conditions of 2-3Mpa, be cooled to room temperature and obtain mixture a；
（3）Modified epoxy resin E-44, mixture a, neopelex, thickener, age resistor are mixed, normal temperature
Stirring 2-3 hours, comminutor granulation, single screw extrusion machine extrusion obtains the nano-coating material.
6. the preparation method of nano-coating material according to claim 5, it is characterised in that the step（1）Crushing makes
With Universalpulverizer, the speed of mainshaft is 950r/min, and discharging-material size is 2-5mm.
7. the preparation method of nano-coating material according to claim 5, it is characterised in that the step（2）Stirring turns
Speed is 600-800r/min.
8. the preparation method of nano-coating material according to claim 5, it is characterised in that the step（3）Single screw rod
The rotating speed of extruder is 120-150rpm/min, and draw ratio is 15-20：1.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107601971A (en) * | 2017-10-18 | 2018-01-19 | 徐宏伟 | A kind of rub resistance automotive coatings and its preparation technology |
| CN112875694A (en) * | 2021-01-19 | 2021-06-01 | 青海凯金新能源材料有限公司 | Preparation method of composite graphite negative electrode material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1709988A (en) * | 2005-07-05 | 2005-12-21 | 北京国科京彪新材料科技有限公司 | High-temperature thermal-insulation anticorrosive nano coating and its preparing method |
| CN101012350A (en) * | 2006-11-07 | 2007-08-08 | 苏州裕丰装饰门窗有限公司 | Special-purpose energy-saving environment-friendly type nano coating for aluminum alloy sections (door and window) and preparing method thereof |
| CN103819998A (en) * | 2012-11-16 | 2014-05-28 | 苏州裕丰装饰门窗有限公司 | Heat insulating coating as well as coating method, paint and preparing method thereof |
| CN104449200A (en) * | 2013-09-25 | 2015-03-25 | 苏州裕丰装饰门窗有限公司 | Heat-insulation heat-preservation powdered paint, preparation method and coating method of heat-insulation heat-preservation powdered paint, coating formed by using coating method and application of coating |
| CN104610841A (en) * | 2015-01-20 | 2015-05-13 | 安徽斯瑞尔阀门有限公司 | Nano-ceramic-modified epoxy resin paint as well as application thereof to metal valves |
| CN105885627A (en) * | 2016-05-09 | 2016-08-24 | 安徽爱莱特照明灯具有限公司 | High-thermal-conductivity insulating paint for arc-resistant LED lamp base and manufacturing method thereof |
| CN106590315A (en) * | 2016-12-20 | 2017-04-26 | 青岛巨能管道设备有限公司 | Nanometer environment-friendly coating material |
-
2017
- 2017-06-09 CN CN201710434239.3A patent/CN107033745A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1709988A (en) * | 2005-07-05 | 2005-12-21 | 北京国科京彪新材料科技有限公司 | High-temperature thermal-insulation anticorrosive nano coating and its preparing method |
| CN101012350A (en) * | 2006-11-07 | 2007-08-08 | 苏州裕丰装饰门窗有限公司 | Special-purpose energy-saving environment-friendly type nano coating for aluminum alloy sections (door and window) and preparing method thereof |
| CN103819998A (en) * | 2012-11-16 | 2014-05-28 | 苏州裕丰装饰门窗有限公司 | Heat insulating coating as well as coating method, paint and preparing method thereof |
| CN104449200A (en) * | 2013-09-25 | 2015-03-25 | 苏州裕丰装饰门窗有限公司 | Heat-insulation heat-preservation powdered paint, preparation method and coating method of heat-insulation heat-preservation powdered paint, coating formed by using coating method and application of coating |
| CN104610841A (en) * | 2015-01-20 | 2015-05-13 | 安徽斯瑞尔阀门有限公司 | Nano-ceramic-modified epoxy resin paint as well as application thereof to metal valves |
| CN105885627A (en) * | 2016-05-09 | 2016-08-24 | 安徽爱莱特照明灯具有限公司 | High-thermal-conductivity insulating paint for arc-resistant LED lamp base and manufacturing method thereof |
| CN106590315A (en) * | 2016-12-20 | 2017-04-26 | 青岛巨能管道设备有限公司 | Nanometer environment-friendly coating material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107601971A (en) * | 2017-10-18 | 2018-01-19 | 徐宏伟 | A kind of rub resistance automotive coatings and its preparation technology |
| CN112875694A (en) * | 2021-01-19 | 2021-06-01 | 青海凯金新能源材料有限公司 | Preparation method of composite graphite negative electrode material |
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