CN102094354A - Method for modifying ash after cigarette burning - Google Patents
Method for modifying ash after cigarette burning Download PDFInfo
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- CN102094354A CN102094354A CN2010105741596A CN201010574159A CN102094354A CN 102094354 A CN102094354 A CN 102094354A CN 2010105741596 A CN2010105741596 A CN 2010105741596A CN 201010574159 A CN201010574159 A CN 201010574159A CN 102094354 A CN102094354 A CN 102094354A
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- whisker
- cigarette
- cigarette burning
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- paper
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Abstract
The invention discloses a method for modifying ash after cigarette burning. The method is characterized by using whisker substances as fillers to be added to the cigarette paper, wherein the whisker substances include one or more of metal oxide whiskers, metal hydroxide whiskers, saline whiskers and other whiskers; the weight percent of the whiskers in the finished cigarette paper is 1-30%; and the average length of the whiskers is not less than 5 microns. The cigarettes produced from the cigarette paper prepared by the method have better ash continuity and stronger ash holding capabilities and are free of wide-range ash dropping.
Description
Technical field
The invention belongs to cigarette producing field, be specifically related to a kind of method of wrapping ash behind the cigarette burning of improving.
Background technology
The proterties that the surface that the kind of filler and combustion adjuvant and content are embodied after to cigarette burning in the cigarette paper is promptly wrapped ash has very big influence, and the especially Chinese consumer of consumer pays special attention to the characteristic of bag ash, think that good bag ash should be that certain cementation is arranged between the cigarette ash, breach is little, can not fall down easily and make cigarette burning awl place present blowzy outward appearance, influence environmental sanitation simultaneously yet.For satisfying consumers in general's requirement, each tobacco mechanism particularly cigarette paper production firm has dropped into a large amount of manpower and financial resources in improving this problem of cigarette bag ash, has also obtained certain achievement, is no lack of bag ash cigarette preferably in the market.Studies show that in the past that in cigarette paper adding acylate helps bonding between cigarette ash, but close with the kind and the relation with contents of salt.We find under study for action, after whisker class material adds cigarette paper as filler, can greatly improve cigarette bag ash proterties.
The application of whisker class material in cigarette paper still do not have report both at home and abroad, but many researchs are arranged in paper production, and its purpose is not the character after being to burn.JP3174313 (A) uses the whisker of carbon containing, is in order to increase strength of paper, electric conductivity and anti-flammability.JP2221491 (A) uses ZnOw, is in order paper to be had absorb light, shockproof, anti-noise, function such as antistatic and fire-retardant.JP2005120510(A)
The content of application protection is: adopt the calcium carbonate of forms such as needle-like, column, spindle shape and whisker shape to produce printing paper, purpose is in order to improve paper of whiteness, opacity and smoothness etc., so that further colored printing.
Summary of the invention
The object of the invention provides a kind of method of improving bag ash behind the cigarette burning, use this method preparation cigarette paper the cigarette ash continuity better, to hold grey ability stronger, do not fall ash easily.
A kind of method of wrapping ash behind the cigarette burning of improving: use whisker class material to add in the cigarette paper as filler, described whisker class material comprises: one or more in metallic oxide crystal whisker, metal hydroxides whisker, metallic salt whisker and other whisker.
Described metallic oxide crystal whisker comprises: one or more in magnesia crystal whisker, ZnOw, alumina whisker, titanium oxide whisker, cupric oxide whisker, manganese oxide whisker and the tin oxide whisker.
Described metal hydroxides whisker comprises: one or more in magnesium hydroxide crystal whisker, zinc hydroxide whisker, aluminium hydroxide whisker, manganous hydroxide whisker and the apatite hydroxide whisker.
Described salt whisker comprises: one or more in alkali magnesium sulfate crystal whisker, basic magnesium chloride whisker, magnesium carbonate whisker, calcium sulfate crystal whiskers, calcium carbonate crystal whisker, potassium titanate crystal whisker and the sodium titanate crystal whisker.
Described other whisker comprises: one or more in carbon whisker, titanium carbide crystal whisker, titanium nitride whisker, aluminium nitride whisker and the zinc sulphide whisker.
The whisker weight percentage ranges is 1-30% in finished cigarettes paper, with 3-10% the best.
Described whisker average length is not less than 5 microns; To be not less than 20 microns for good.
Used whisker can be the combination of multiple whisker, also can be single whisker, and material need not pass through any processing, directly adds cigarette paper and gets final product with in the slurry;
This cigarette paper calcium carbonate content, quantitatively, character such as the kind of air permeability and combustion adjuvant and use amount thereof compare no significant difference with regular-size cigarette paper.
Traditional cigarette paper generally only adopts this single filler of calcium carbonate in producing, and the effect of calcium carbonate mainly is to improve opaque, whiteness, the flexibility of paper and reduce cost, and its particle diameter does not have obviously influence to cigarette bag ash about 3 microns.Whisker class material is because its length has reached tens of microns, though cigarette paper burning back whisker changes a lot, but the moment burning is not enough to destroy fully its structure, in cigarette ash, still can play a supporting role, the pyroreaction thing of some whisker also may bond together with other combustion product in the cigarette paper, the common bag ash well that forms.
Compared with the prior art the present invention has remarkable advantage:
A. cigarette paper combustion back grey is white, and it is stronger to hold grey ability, does not fall ash easily;
B. the used material safety and environmental protection of the present invention meets the requirement of food additives fully.
The specific embodiment
The cigarette paper that adopts above technology to produce is used for production of cigarettes and can improves cigarette bag ash, now further specifies in conjunction with the embodiments, and can not limit the present invention:
Embodiment 1
Use the inventive method and prepare cigarette paper:
Get 500 kilograms of wood pulps, handle the back in the usual way and add ordinary calcium carbonate, regulate the calcium carbonate flow, make that weight of calcium carbonate percentage is 30% in the finished cigarettes paper.At capacity is that to add average length in 2000 kilograms the modulation jar be 26.7 microns 300 kilograms of magnesia crystal whiskers, adds water to the container scale, stirs, and a control modulation jar rate of discharge makes that the whisker percentage by weight is 5.6% in the finished cigarettes paper.Prepare certain density combustion adjuvant: potassium citrate and natrium citricum, the two mixes the back and adds in combustion adjuvant interpolation place, make that two kinds of combustion adjuvant content are respectively 1.0% and 0.2% in corresponding oxide on finished cigarettes paper, papermaking process is produced cigarette paper routinely, control cigarette paper characteristic is on equipment: quantitative 28 gram/rice 2, air permeability 60 Ke Ruisita, cigarette paper (except that adding whisker, the routine that other technical parameter is the big production of cigarette paper requires).
Adopt the cigarette paper and regular-size cigarette paper (quantitatively, air permeability is identical with the former with combustion adjuvant) of method for preparing respectively, identical pipe tobacco and other auxiliary material, the production method cigarette becomes cigarette routinely, the grey proterties of analysis of cigarette burning back bag, the breach area accounts for the selection area area ratio when calculating quiet combustion, does the breach area of testing cigarette bag ash as can be known significantly reduce, result such as following table 1: the index energy expression effect that whether also has other?
Table 1
| Wrap grey breach area and account for selection area area ratio (%) | |
| The contrast cigarette | 4.87 |
| The test cigarette | 2.35 |
Embodiment 2
Use the inventive method and prepare cigarette paper:
Get 500 kilograms of wood pulps, handle the back in the usual way and add ordinary calcium carbonate, regulate the calcium carbonate flow, make that weight of calcium carbonate percentage is 30% in the finished cigarettes paper.At capacity is that to add average length in 2000 kilograms the modulation jar be 38.4 microns 200 kilograms of alkali magnesium sulfate crystal whiskers, average length is 31.0 microns 200 kilograms of ZnOws, add water to the container scale, stir, control modulation jar rate of discharge makes that the whisker percentage by weight is 7.2% in finished cigarettes paper.Prepare certain density combustion adjuvant: potassium citrate and natrium citricum, the two mixes the back and adds in combustion adjuvant interpolation place, make that two kinds of combustion adjuvant content are respectively 1.0% and 0.2% in corresponding oxide on finished cigarettes paper, papermaking process is produced cigarette paper routinely, control cigarette paper characteristic is on equipment: quantitative 28 gram/rice 2, air permeability 60 Ke Ruisita, cigarette paper (except that adding whisker, the routine that other technical parameter is the big production of cigarette paper requires).
Adopt the cigarette paper and regular-size cigarette paper (quantitatively, air permeability is identical with the former with combustion adjuvant) of method for preparing respectively, identical pipe tobacco and other auxiliary material, the production method cigarette becomes cigarette routinely, the grey proterties of analysis of cigarette burning back bag, the breach area accounts for the selection area area ratio when calculating quiet combustion, the breach area of testing cigarette bag ash as can be known significantly reduces, result such as following table 2:
Table 2
| Wrap grey breach area and account for selection area area ratio (%) | |
| The contrast cigarette | 4.87 |
| The test cigarette | 1.94 |
Embodiment 3
Use the inventive method and prepare cigarette paper:
Get 500 kilograms of wood pulps, handle the back in the usual way and add ordinary calcium carbonate, regulate the calcium carbonate flow, make that weight of calcium carbonate percentage is 30% in the finished cigarettes paper.At capacity is that to add average length in 2000 kilograms the modulation jar be 40.3 microns 250 kilograms of calcium carbonate crystal whiskers, average length is 17.7 microns a calcium sulfate crystal whiskers double centner, add water to the container scale, stir, a control modulation jar rate of discharge makes that the whisker percentage by weight is 6.3% in the finished cigarettes paper.Prepare certain density combustion adjuvant: potassium citrate and natrium citricum, the two mixes the back and adds in combustion adjuvant interpolation place, make that two kinds of combustion adjuvant content are respectively 1.0% and 0.2% in corresponding oxide on finished cigarettes paper, papermaking process is produced cigarette paper routinely, control cigarette paper characteristic is on equipment: quantitative 28 gram/rice 2, air permeability 60 Ke Ruisita, cigarette paper (except that adding whisker, the routine that other technical parameter is the big production of cigarette paper requires).
Adopt the cigarette paper and regular-size cigarette paper (quantitatively, air permeability is identical with the former with combustion adjuvant) of method for preparing respectively, identical pipe tobacco and other auxiliary material, the production method cigarette becomes cigarette routinely, the grey proterties of analysis of cigarette burning back bag, the breach area accounts for the selection area area ratio when calculating quiet combustion, the breach area of testing cigarette bag ash as can be known significantly reduces, result such as following table 3:
Table 3
| Wrap grey breach area and account for selection area area ratio (%) | |
| The contrast cigarette | 4.87 |
| The test cigarette | 2.08 |
Claims (9)
1. one kind is improved the method for wrapping ash behind the cigarette burning, it is characterized in that: use whisker class material to add in the cigarette paper as filler, described whisker class material comprises: one or more in metallic oxide crystal whisker, metal hydroxides whisker, salt whisker and other whisker.
2. the method for wrapping ash behind the cigarette burning of improving according to claim 1, it is characterized in that: described metallic oxide crystal whisker comprises: one or more in magnesia crystal whisker, ZnOw, alumina whisker, titanium oxide whisker, cupric oxide whisker, manganese oxide whisker and the tin oxide whisker.
3. the method for wrapping ash behind the cigarette burning of improving according to claim 1, it is characterized in that: described metal hydroxides whisker comprises: one or more in magnesium hydroxide crystal whisker, zinc hydroxide whisker, aluminium hydroxide whisker, manganous hydroxide whisker and the apatite hydroxide whisker.
4. the method for wrapping ash behind the cigarette burning of improving according to claim 1, it is characterized in that: described salt whisker comprises: one or more in alkali magnesium sulfate crystal whisker, basic magnesium chloride whisker, magnesium carbonate whisker, calcium sulfate crystal whiskers, calcium carbonate crystal whisker, potassium titanate crystal whisker and the sodium titanate crystal whisker.
5. the method for wrapping ash behind the cigarette burning of improving according to claim 1, it is characterized in that: described other whisker comprises: one or more in carbon whisker, titanium carbide crystal whisker, titanium nitride whisker, aluminium nitride whisker and the zinc sulphide whisker.
6. according to any described method of wrapping ash behind the cigarette burning of improving among the claim 1-5, it is characterized in that: the whisker weight percentage ranges is 1-30% in finished cigarettes paper.
7. the method for wrapping ash behind the cigarette burning of improving according to claim 6, it is characterized in that: the whisker weight percentage ranges is 3-10% in finished cigarettes paper.
8. the method for wrapping ash behind the cigarette burning of improving according to claim 6, it is characterized in that: described whisker average length is not less than 5 microns.
9. the method for wrapping ash behind the cigarette burning of improving according to claim 8, it is characterized in that: described whisker average length is not less than 20 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010574159.6A CN102094354B (en) | 2010-12-06 | 2010-12-06 | Method for modifying ash after cigarette burning |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010574159.6A CN102094354B (en) | 2010-12-06 | 2010-12-06 | Method for modifying ash after cigarette burning |
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| CN102094354A true CN102094354A (en) | 2011-06-15 |
| CN102094354B CN102094354B (en) | 2014-06-11 |
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| CN201010574159.6A Active CN102094354B (en) | 2010-12-06 | 2010-12-06 | Method for modifying ash after cigarette burning |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104350204A (en) * | 2012-06-01 | 2015-02-11 | 德尔福特集团有限公司 | Cigarette paper comprising lamellar filler |
| CN105220560A (en) * | 2015-07-27 | 2016-01-06 | 杭州华丰纸业有限公司 | The preparation method of the thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less |
| CN106638151A (en) * | 2016-10-27 | 2017-05-10 | 中烟摩迪(江门)纸业有限公司 | Improved ash-packaged cigarette paper and production method thereof |
| CN108914676A (en) * | 2018-07-25 | 2018-11-30 | 佛山市高明区爪和新材料科技有限公司 | A kind of fine and close preparation method for wrapping grey cigarette paper |
| CN109793265A (en) * | 2019-01-25 | 2019-05-24 | 安徽中烟工业有限责任公司 | A kind of cigarette paper with infrared radiation heating function |
| CN115214216A (en) * | 2022-08-18 | 2022-10-21 | 云南中烟工业有限责任公司 | Multi-layer composite cigarette paper structure with good ash wrapping performance and manufacturing method |
| WO2024036778A1 (en) * | 2022-08-18 | 2024-02-22 | 云南中烟工业有限责任公司 | Multi-layer composite cigarette paper structure having good ash-wrapping performance, and manufacturing method |
Citations (3)
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|---|---|---|---|---|
| US5103844A (en) * | 1990-06-07 | 1992-04-14 | R. J. Reynolds Tobacco Company | Cigarette paper and cigarette incorporating same |
| CN1446979A (en) * | 2003-01-17 | 2003-10-08 | 安县纸业有限公司 | Sterilization, bacteriostasis papers as well as manufacturing methods and usage |
| CN101435176A (en) * | 2008-12-31 | 2009-05-20 | 湖南中烟工业有限责任公司 | Cigarette paper for reducing harmful substance contents of carbon monoxide, oxynitride and phenols in cigarette smoke gas and preparation thereof |
-
2010
- 2010-12-06 CN CN201010574159.6A patent/CN102094354B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5103844A (en) * | 1990-06-07 | 1992-04-14 | R. J. Reynolds Tobacco Company | Cigarette paper and cigarette incorporating same |
| CN1446979A (en) * | 2003-01-17 | 2003-10-08 | 安县纸业有限公司 | Sterilization, bacteriostasis papers as well as manufacturing methods and usage |
| CN101435176A (en) * | 2008-12-31 | 2009-05-20 | 湖南中烟工业有限责任公司 | Cigarette paper for reducing harmful substance contents of carbon monoxide, oxynitride and phenols in cigarette smoke gas and preparation thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104350204A (en) * | 2012-06-01 | 2015-02-11 | 德尔福特集团有限公司 | Cigarette paper comprising lamellar filler |
| CN104350204B (en) * | 2012-06-01 | 2017-03-08 | 德尔福特集团有限公司 | Cigarette paper including flake stuffing |
| CN105220560A (en) * | 2015-07-27 | 2016-01-06 | 杭州华丰纸业有限公司 | The preparation method of the thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less |
| CN106638151A (en) * | 2016-10-27 | 2017-05-10 | 中烟摩迪(江门)纸业有限公司 | Improved ash-packaged cigarette paper and production method thereof |
| CN108914676A (en) * | 2018-07-25 | 2018-11-30 | 佛山市高明区爪和新材料科技有限公司 | A kind of fine and close preparation method for wrapping grey cigarette paper |
| CN109793265A (en) * | 2019-01-25 | 2019-05-24 | 安徽中烟工业有限责任公司 | A kind of cigarette paper with infrared radiation heating function |
| CN115214216A (en) * | 2022-08-18 | 2022-10-21 | 云南中烟工业有限责任公司 | Multi-layer composite cigarette paper structure with good ash wrapping performance and manufacturing method |
| CN115214216B (en) * | 2022-08-18 | 2023-09-22 | 云南中烟工业有限责任公司 | Multilayer composite cigarette paper structure with good ash wrapping performance and manufacturing method |
| WO2024036778A1 (en) * | 2022-08-18 | 2024-02-22 | 云南中烟工业有限责任公司 | Multi-layer composite cigarette paper structure having good ash-wrapping performance, and manufacturing method |
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| Publication number | Publication date |
|---|---|
| CN102094354B (en) | 2014-06-11 |
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