CN102093006B - Fly ash dry-mixed mortar - Google Patents

Fly ash dry-mixed mortar Download PDF

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Publication number
CN102093006B
CN102093006B CN2010106086760A CN201010608676A CN102093006B CN 102093006 B CN102093006 B CN 102093006B CN 2010106086760 A CN2010106086760 A CN 2010106086760A CN 201010608676 A CN201010608676 A CN 201010608676A CN 102093006 B CN102093006 B CN 102093006B
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Prior art keywords
mixed mortar
dry
flyash
mixed
weight proportion
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CN102093006A (en
Inventor
赵同习
王爱民
王庆珍
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Shandong Cheng Hua enterprise Klc Holdings Ltd
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Jinan High-Tech Area Industrial Waste Utilization Research & Development Center
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/021Ash cements, e.g. fly ash cements ; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration ; Kiln dust cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/06Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
    • C04B40/0608Dry ready-made mixtures, e.g. mortars at which only water or a water solution has to be added before use
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/56Opacifiers
    • C04B2103/58Shrinkage reducing agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses fly ash dry-mixed mortar, belonging to the field of the ready mixed and dry-mixed mortar material for building. The dry-mixed mortar is prepared by mixing the following ingredients in parts by weight: 25-30 parts of fly ash, 0-5 parts of cement, 65-75 parts of aggregate, 0.15-0.3 part of composite exciting agent, 0.03-0.05 part of water retention agent and 0.3-0.5 part of anti-cracking agent. Compared with the prior art, the fly ash dry-mixed mortar of the invention directly uses fly ash as cementing material and is characterized by energy saving, environmental protection, low material cost and the like.

Description

The flyash dry-mixed mortar
Technical field
The present invention relates to a kind of premixing dry-mixed mortar material for building, specifically a kind of flyash dry-mixed mortar.
Background technology
Along with the development of society, people improve constantly the requirement of construction quality, environmental requirement and civilized construction, and the advantage that is dry mixed mortar obtains more and more people's favor.
In the prior art, the main gelling material of dry-mixed mortar is cement or gypsum, and the consumption of cement mostly is not less than about 15%, and the consumption of gypsum also is not less than 30%.Although flyash also can be used as supplementary cementitious material or filler uses, consumption can not surpass 10%, otherwise the problems such as mortar cracking, hollowing very easily occur.
On the other hand, China is one of a few country take coal as main energy sources in the world, and coal accounts in Energy Mix more than 75%, the coal-fired topsoil that causes, water pollutes, and a large amount of generations of flyash all seriously threatening ecotope.At present, flyash at building materials, build the worker, build the road, the comprehensive utilization work of the aspect such as backfill, agricultural is fully under way, even so, the comprehensive utilization ratio of flyash also can only reach about 65%, still have every year more than 200,000,000 ton flyash to store up, occupy cultivated land, pollute.
Summary of the invention
Technical assignment of the present invention is for above-mentioned the deficiencies in the prior art, and a kind of energy-conserving and environment-protective are provided, the flyash dry-mixed mortar that the cost of material is low.
Technical assignment of the present invention is realized in the following manner: the flyash dry-mixed mortar is mixed by the batching of following weight proportion:
Flyash 25-30 part
Cement 0-5 part
Aggregate 65-75 part
Exciting agent 0.15-0.3 part
Water-holding agent 0.03-0.05 part
Anti-fissuring agent 0.3-0.5 part,
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
In order to make it can better be applicable to exterior wall, flyash dry-mixed mortar of the present invention can also be mixed by the batching of following weight proportion:
Flyash 25-30 part
Cement 0-5 part
Aggregate 65-75 part
Exciting agent 0.15-0.3 part
Water-holding agent 0.03-0.05 part
Anti-fissuring agent 0.3-0.5 part
Hydrophobizing agent 0.1-1 part,
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
Further,
Described hydrophobizing agent is polymkeric substance redispersible powder, sodium stearate or Zinic stearas.
The fineness of described flyash is preferably 300~500 orders.
Described aggregate is the mixture of one or more materials in the pulverized particles of Machine-made Sand, river sand, water-granulated slag or building waste, and the fineness of aggregate is less than 4 millimeters.
Described water-holding agent can be water-holding agent general in the prior art, such as polyvinyl alcohol, polyoxygenated alkanes etc., preferably use the mixture of one or more materials in methylcellulose gum, Vltra tears, hydroxyethylmethyl-cellulose or the treated starch (as: organic phosphate starch, cationic starch, anionic starch, vinyl cyanide starch etc.).
Described anti-fissuring agent can be anti-fissuring agent general in the prior art, preferably uses xylon, polyacrylonitrile fibre, fibrous magnesium silicate, steel fiber, glass fibre or aluminium powder.
Above-mentioned flyash preferably uses I and II flyash; Cement preference uses the above cement of 425#.
The present invention is by adding water-holding agent and compound activator etc., with appropriate proportioning, this low activity activity of materials of flyash is improved, the condition of namely utilizing the reduction flyash such as water-holding agent and exciting agent to react makes material (flyash or flyash and cement) form final mortar product by hydration reaction.
In the present invention, cement plays the effect of further increase mortar strength, in most cases needn't add.When needing the motar of higher-strength, can add a small amount of cement.
Flyash dry-mixed mortar of the present invention compared with prior art has following outstanding beneficial effect:
(1) need not or with a small amount of cement, directly take flyash as gelling material, overcome in the prior art and can only do the deficiency that supplementary cementitious material or filler are produced dry-mixed mortar with flyash, the all technical of product meets the indices requirement in the national sector standard fully, energy-conservation, reduction of discharging, cost are low, for utilization of fly ash has increased a new way;
(2) consumption of flyash can reach more than 30% in the product, has solved the shortcoming of mortar cracking, hollowing when the flyash consumption is excessive in the existing dry-mixed mortar;
(3) all raw materials are environment-friendly materials, really accomplish nontoxicly, adapt to people to the requirement of environmental protection;
(4) various raw materials are commercially available common product, are easy to realize, cost is low.
Embodiment
Explain below with specific embodiment flyash dry-mixed mortar of the present invention being done.
Embodiment one (plastering on inner walls dry-mixed mortar):
Prescription:
First level flour coal ash (325 order): 29Kg Machine-made Sand: 67Kg (fineness is less than 4mm)
Compound activator: 0.2Kg methylcellulose gum: 0.03Kg
Xylon: 0.4Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.
Embodiment two (external wall plastering dry-mixed mortar):
Prescription:
First level flour coal ash (325 order): 29Kg Machine-made Sand: 67Kg (fineness is less than 4mm)
Compound activator: 0.2Kg methylcellulose gum: 0.03Kg
Xylon: 0.4Kg polymkeric substance redispersible powder: 0.6Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.
In the construction process, water consumption is 150 ± 5 millimeters standard water consumption calculating by the slip diffusion diameter.Should metope is fully moistening before the construction, material is fully mixed, thereby produce better intensity.
According to the used standard method of China's building trade, to technical feature test result such as the following table of above-described embodiment:
Embodiment three (plastering on inner walls dry-mixed mortar):
Prescription:
Second class powered coal ash (400 order): 26Kg normal silicate 425# cement: 2Kg
Water-granulated slag: 73Kg (fineness is less than 4mm) compound activator: 0.25Kg
Hydroxyethylmethyl-cellulose: 0.04Kg polyacrylonitrile fibre: 0.4Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.
Embodiment four (external wall plastering dry-mixed mortar):
Prescription
Second class powered coal ash (400 order): 26Kg normal silicate 425# cement: 2Kg
Water-granulated slag: 73Kg (fineness is less than 4mm) compound activator: 0.25Kg
Hydroxyethylmethyl-cellulose: 0.04Kg polyacrylonitrile fibre: 0.4Kg
Sodium stearate: 0.8Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.
Embodiment five (plastering on inner walls dry-mixed mortar):
Prescription:
Second class powered coal ash (460 order): 28Kg building waste pulverized particles: 70Kg (fineness is less than 4mm)
Compound activator: 0.3Kg vinyl cyanide starch: 0.05Kg
Aluminium powder: 0.4Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.
Embodiment four (external wall plastering dry-mixed mortar):
Prescription
Second class powered coal ash (460 order): 28Kg building waste pulverized particles: 70Kg (fineness is less than 4mm)
Compound activator: 0.3Kg vinyl cyanide starch: 0.05Kg
Aluminium powder: 0.4Kg Zinic stearas: 0.5Kg
Described compound activator is by AL 2(SO 4) 3, KAL (SO 4) 212H 2O, Na 2SO 3, trolamine is with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
The preparation method:
Behind the various raw materials of above-mentioned prescription accurate measurement, mixing, positive mechanical formula stir and namely get target product.

Claims (7)

1. the flyash dry-mixed mortar is characterized in that, is mixed by the batching of following weight proportion:
Figure FSB00000998036900011
Described compound activator is by Al 2(SO 4) 3, KAl (SO 4) 212H 2O, Na 2SO 3And trolamine was with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
2. the flyash dry-mixed mortar is characterized in that, is mixed by the batching of following weight proportion:
Figure FSB00000998036900012
Described compound activator is by Al 2(SO 4) 3, KAl (SO 4) 212H 2O, Na 2SO 3And trolamine was with 2.5: 2: 1: 1 weight proportion is composite to be obtained.
3. flyash dry-mixed mortar according to claim 2 is characterized in that, described hydrophobizing agent is polymkeric substance redispersible powder, sodium stearate or Zinic stearas.
4. flyash dry-mixed mortar according to claim 1 and 2 is characterized in that, the fineness of described flyash is 300~500 orders.
5. flyash dry-mixed mortar according to claim 1 and 2 is characterized in that, described aggregate is the mixture of one or more materials in the pulverized particles of Machine-made Sand, river sand, water-granulated slag or building waste, and the fineness of aggregate is less than 4 millimeters.
6. flyash dry-mixed mortar according to claim 1 and 2 is characterized in that, described water-holding agent is the mixture of one or more materials in methylcellulose gum, Vltra tears, hydroxyethylmethyl-cellulose or the treated starch.
7. flyash dry-mixed mortar according to claim 1 and 2, it is characterized in that: described anti-fissuring agent is xylon, polyacrylonitrile fibre, fibrous magnesium silicate, steel fiber, glass fibre or aluminium powder.
CN2010106086760A 2010-12-28 2010-12-28 Fly ash dry-mixed mortar Active CN102093006B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380146A (en) * 2016-08-30 2017-02-08 卓达新材料科技集团威海股份有限公司 Preparation method of alkali-activated fly ash decoration mortar

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CN104250078A (en) * 2013-06-25 2014-12-31 神华集团有限责任公司 Dry-mixed mortar, mortar and application thereof
CN103936352B (en) * 2014-03-27 2016-02-24 滁州市三和纤维制造有限公司 A kind of high-strength insulation mortar containing fibrous magnesium silicate
CN104496296A (en) * 2014-11-24 2015-04-08 芜湖中民科技建材有限公司 Dry-mixed waterproof freeze-proof mortar and preparation method thereof
CN104496298A (en) * 2014-11-24 2015-04-08 芜湖中民科技建材有限公司 Dry-mixed wear-resistant floor mortar, and preparation method thereof
CN104478317A (en) * 2014-11-24 2015-04-01 芜湖中民科技建材有限公司 Dry-mixed polyphenyl granule thermal insulation mortar and preparation method thereof
CN104478316A (en) * 2014-11-24 2015-04-01 芜湖中民科技建材有限公司 Dry-mixed wear-resistant ground mortar and preparation method thereof
CN104478319A (en) * 2014-11-24 2015-04-01 芜湖中民科技建材有限公司 Dry mixing waterproof and anti-freezing mortar and preparation method thereof
CN104496318A (en) * 2014-12-20 2015-04-08 王小波 Compression-resistant fireproof plaster mortar and preparation method thereof
CN106747124A (en) * 2017-02-07 2017-05-31 福州大学 A kind of very-high performance mortar for building puzzle joint
CN107298556A (en) * 2017-05-19 2017-10-27 上海漕源新型建材有限公司 A kind of flyash dry-mixed plastering mortar and preparation method thereof
CN107827399A (en) * 2017-11-09 2018-03-23 安徽艾米伦特建材科技有限公司 Cement mortar and preparation method thereof
CN107915449B (en) * 2017-12-14 2020-09-29 盐城工学院 Dry-mixed masonry mortar and preparation method thereof
CN110655346A (en) * 2019-09-29 2020-01-07 湖南中岩建材科技有限公司 Machine-made sand regulator and preparation method thereof
CN113601701A (en) * 2021-08-10 2021-11-05 山东望意阳海绵城市建设有限公司 Preparation method of dry-mixed mortar
CN114276088B (en) * 2022-01-18 2023-03-17 中国矿业大学 High-strength building block material with high content of fly ash and preparation method thereof

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CN101570417A (en) * 2009-04-21 2009-11-04 同济大学 Recycled fine aggregate building heat insulation mortar and preparation method thereof
CN101643349A (en) * 2009-07-31 2010-02-10 上海市建筑科学研究院(集团)有限公司 Light masonry mortar with heat insulation and preservation
CN101648799A (en) * 2009-07-13 2010-02-17 河南省绿韵建材有限公司 Compound thermal-insulation material and preparation method thereof

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101519296A (en) * 2009-03-30 2009-09-02 上海英硕聚合物材料有限公司 Thermal insulation bonding mortar with high bonding strength
CN101570417A (en) * 2009-04-21 2009-11-04 同济大学 Recycled fine aggregate building heat insulation mortar and preparation method thereof
CN101648799A (en) * 2009-07-13 2010-02-17 河南省绿韵建材有限公司 Compound thermal-insulation material and preparation method thereof
CN101643349A (en) * 2009-07-31 2010-02-10 上海市建筑科学研究院(集团)有限公司 Light masonry mortar with heat insulation and preservation

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Publication number Priority date Publication date Assignee Title
CN106380146A (en) * 2016-08-30 2017-02-08 卓达新材料科技集团威海股份有限公司 Preparation method of alkali-activated fly ash decoration mortar

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Owner name: JINAN CHENGHUA ENVIRONMENTAL TECHNOLOGY DEVELOPMEN

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Address after: 250101 G, North Zone, University Science Park, Ji'nan hi tech Zone, Shandong

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Address after: 250101 Shandong province Ji'nan City hi tech Development Zone, No. 750 Hua Road No. 8 Building 4 unit 301 room

Patentee after: Shandong Cheng Hua enterprise Klc Holdings Ltd

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Patentee before: Jinan Chenghua Environmental Technology Development Center