CN101643349A - Light masonry mortar with heat insulation and preservation - Google Patents

Light masonry mortar with heat insulation and preservation Download PDF

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Publication number
CN101643349A
CN101643349A CN200910055754A CN200910055754A CN101643349A CN 101643349 A CN101643349 A CN 101643349A CN 200910055754 A CN200910055754 A CN 200910055754A CN 200910055754 A CN200910055754 A CN 200910055754A CN 101643349 A CN101643349 A CN 101643349A
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China
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percent
heat insulation
masonry mortar
preservation
light
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Pending
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CN200910055754A
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Chinese (zh)
Inventor
赵立群
叶蓓红
陈宁
赵磊
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Shanghai Building Science Research Institute Group Co Ltd
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Shanghai Building Science Research Institute Group Co Ltd
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Priority to CN200910055754A priority Critical patent/CN101643349A/en
Publication of CN101643349A publication Critical patent/CN101643349A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a light masonry mortar with heat insulation and preservation, comprising the following components by weight percent: 20 percent to 65 percent of portland cement, 5 percent to 50 percent of fly ashes, 0 percent to 50 percent of furnace bottom slag, 0 percent to 55 percent of slag, 10 percent to 23 percent of vitrified microspheres, 0.1 percent to 1.0 percent of water retention and thickening materials, 0.1 percent to 0.5 percent of lignocellulose and 0.1 percent to 1.0 percent of water reducing agent. The mortar has the dry density of 750 to 1000 kg/m<3>, the thermal conductivity of 0.15 to 0.20 w/m k, the lowest compressive strength of 5 Mpa and the liner shrinkage rate of less than 0.1 percent, satisfies the requirements of heat insulation and preservation of an energy-saving building, has the advantages of favorable heat insulation and preservation performance, favorable water retention, favorable workability, high adhesion strength of a wall body, simple construction, energy saving, environmental protection and the like, completely avoids the occurrence of the phenomenon of cold bridge, and efficiently prevents dry-shrinkage cracking and the phenomenon ofmoisture absorption of the wall surface.

Description

A kind of light masonry mortar with heat insulation and preservation
Technical field
The present invention relates to a kind of masonry mortar, specifically, relates to a kind of light masonry mortar with heat insulation and preservation that is used for body of wall porous light thermal insulation brick or light heat insulation blocks, belongs to building material technical field.
Background technology
Along with improving constantly that environment protection and save energy are required, the energy-saving heat preserving technology of architectural exterior-protecting construction has become one of important energy-saving building technology approach of China.Energy-conservation, sharp useless heat insulating novel wall material has been obtained the development of advancing by leaps and bounds, and novel energy-conserving materials for walls such as porous light thermal insulation brick or light heat insulation blocks obtain more and more widely application at various non-bearings, bearing wall.But still major part is built light and heat insulating wall bricks by laying bricks or stones with common masonry mortar in the market, and common masonry mortar is generally sand-cement slurry or mixed mortar, and the dry density of this class mortar is generally 1600~1800kg/m 3, thermal conductivity is 0.8~1.10w/mk, and the dry density of light heat insulation blocks is generally 450~950kg/m 3, thermal conductivity is 0.15~0.35w/mk, because both thermal conductivity gaps are bigger, causes whole masonry to have " cold bridge " phenomenon, reaches about 25% by building the power loss that mortar joint causes by laying bricks or stones, does not reach heat preservation effect; And it is also a lot of that the coefficient of shrinkage between the two differs, and whole masonry is affected the intensity of masonry in the drying and watering cycle process, has seriously influenced the quality of whole body of wall.
Heat-insulating masonry mortar of the prior art mainly contains haydite, granular polystyrene and pearlstone etc. by its light skeletal branch.The porcelain granule light weight aggregate thermal insulation mortar, because haydite surface irregularity porous, water regain is big, it is poor to cause newly mixing the haydite mortar working, is difficult for construction; Pearlstone and granular polystyrene light skeletal thermal insulation mortar water-absorbent are big, easily efflorescence, volume receipts mistake rate is big in the slip construction, easily cause the low and hollowing cracking of product later strength, and the granular polystyrene organic materials is inflammable, fire line is poor, high temperature produce obnoxious flavour and ageing-resistant, weathering resistance is low and workability is poor.In addition, all more than 0.4w/mk, though granular polystyrene light skeletal thermal insulation mortar thermal conductivity is lower than 0.25w/mk, its ultimate compression strength is low, generally at 3MPa for the thermal conductivity of haydite and pearlstone light skeletal thermal insulation mortar.Chinese patent literature CN200710025669.6 discloses a kind of energy-saving heat-insulating masonry mortar, and the component prescription and the weight percent of this masonry mortar are: cement 17~23, flyash 15~55; furnace bottom slag 10~55; glass bead 0~25, admixture 0.7~1.2, wooden sodium water reducer 0.05~0.10.Dry density≤the 1600kg/m of the masonry mortar of this patent 3Minimum ultimate compression strength is 2.5MPa, thermal conductivity≤0.24w/mk, though this patent has solved the " cold bridge " problem because of masonry mortar that uses and the big whole masonry that produces of the thermal conductivity gap between porous light thermal insulation brick or the light heat insulation blocks to a certain extent, but the gap between the dry density of the masonry mortar of this patent and porous light thermal insulation brick or the light heat insulation blocks is still bigger, and water-retentivity is relatively poor, and porous light thermal insulation brick or light heat insulation blocks have stronger water-absorbent, therefore, use the masonry mortar of being prepared, have easy dry shrinkage and cracking, easily the moisture absorption and with problems such as the body of wall adhesion strength is low.
Summary of the invention
The objective of the invention is at the above-mentioned existing in prior technology defective and the market requirement, a kind of have good workability, water-retentivity are provided, with body of wall adhesion strength height, on dry-shrinkage deformed, heat conductivility, be close with porous light thermal insulation brick or light heat insulation blocks, can prevent the metope dry shrinkage and cracking and the moisture absorption, satisfy heat insulation, the light masonry mortar with heat insulation and preservation that insulation requires of energy saving building.
For achieving the above object, the technical solution used in the present invention is as follows:
Light masonry mortar with heat insulation and preservation of the present invention, the weight percent that it is formed and each is formed is as follows: silicate cement 20~65, flyash 5~50, furnace bottom slag 0~50, slag 0~55, glass bead 10~23, water-keeping thickening material 0.1~1.0, wood fibre 0.1~0.5, water reducer 0.1~1.0.
Described flyash can be one or more the mixture in the low calcium fly ash of I level, the low calcium fly ash of II level, I level high-calcium fly ass, the II level high-calcium fly ass, the low calcium fly ash of preferred II level.
The solid waste that preferred power plant of described furnace bottom slag or steel mill discharge after broken and screening granularity less than the particle of 5mm.
The granularity that preferred power plant of described slag or steel mill discharge is less than the ground granulated blast furnace slag of 5mm.
Described glass bead preferable particle size is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is the glass bead of 0.040~0.055w/mk.
Described water-keeping thickening material can be one or more the mixture in ether of cellulose, mortar densification powder, polyvinyl alcohol powder, slaked lime, the starch ethers, preferred cellulose ether.
Described water reducer can be one or more the mixture in naphthalene water reducer, melamine water reducing agent, calcium lignin sulphonate, the polycarboxylate dehydragent, preferred naphthalene water reducer.
The preparation of light masonry mortar with heat insulation and preservation of the present invention is at first each constitutive material to be added in the stirrer by proportioning to mix, and adds water then and stirs, and slurry consistency is controlled between 70~80mm gets final product.
Compared with prior art, beneficial effect of the present invention is as follows:
1. the dry density of masonry mortar of the present invention is 750~1000kg/m 3Thermal conductivity is 0.15~0.20w/mk, minimum ultimate compression strength is 5MPa, linear shrinkage ratio is less than 0.1%, be close with porous light thermal insulation brick or light heat insulation blocks dry density, thermal conductivity, therefore, the heat preservation and insulation of masonry mortar of the present invention is good, has thoroughly avoided the generation of " cold bridge " phenomenon.
2. because of being added with water-keeping thickening material and wood fibre in the masonry mortar of the present invention, therefore, has good water-retaining property, body of wall adhesion strength height, controlled to greatest extent because of the hollowing that the mortar dehydration causes, the generation of cracking phenomena, the metope dry shrinkage and cracking and the moisture absorption be can effectively prevent, heat insulation, the insulation requirement of energy saving building satisfied.
3. also to have workability good in the present invention, easy construction, advantages such as energy-conserving and environment-protective.
Embodiment
The present invention is described in further detail and completely below in conjunction with embodiment:
Embodiment 1
At first the water reducer of the wood fibre of the water-keeping thickening material of the glass bead of the flyash of the silicate cement of 65 weight parts, 11 weight parts, 23 weight parts, 0.1 weight part, 0.3 weight part and 0.6 weight part is added in the stirrer and stir; adding water then stirs; slurry consistency is controlled between 70~80mm, promptly gets light masonry mortar with heat insulation and preservation of the present invention.
Described flyash is the low calcium fly ash of II level; The particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk; Described water-keeping thickening material is an ether of cellulose; Described water reducer is a naphthalene water reducer.
The physicochemical property detected result of gained masonry mortar is shown in Table 1:
The physicochemical property detected result of table 1 gained masonry mortar
Test item Dry density (kg/m 3) Thermal conductivity (w/mk) Ultimate compression strength (MPa) Water retention (%) Linear shrinkage ratio (10 -4)
Detected result ??766.3 ??0.1723 ??5.7 ??96.3 ??6.47
Embodiment 2
At first the water reducer of the wood fibre of the water-keeping thickening material of the glass bead of the flyash of the silicate cement of 31 weight parts, 50 weight parts, 17.4 weight parts, 1.0 weight parts, 0.5 weight part and 0.1 weight part is added in the stirrer and stir; adding water then stirs; slurry consistency is controlled between 70~80mm, promptly gets light masonry mortar with heat insulation and preservation of the present invention.
Described flyash is the low calcium fly ash of II level; The particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk; Described water-keeping thickening material is an ether of cellulose; Described water reducer is a naphthalene water reducer.
The physicochemical property detected result of gained masonry mortar is shown in Table 2:
The physicochemical property detected result of table 2 gained masonry mortar
Test item Dry density (kg/m 3) Thermal conductivity (w/mk) Ultimate compression strength (MPa) Water retention (%) Linear shrinkage ratio (10 -4)
Detected result ??953.5 ??0.1924 ??8.0 ??95.8 ??7.53
Embodiment 3
At first the water reducer of the wood fibre of the water-keeping thickening material of the glass bead of the furnace bottom slag of the flyash of the silicate cement of 33.5 weight parts, 5 weight parts, 50 weight parts, 10 weight parts, 0.4 weight part, 0.1 weight part and 1.0 weight parts is added in the stirrer and stir; adding water then stirs; slurry consistency is controlled between 70~80mm, promptly gets light masonry mortar with heat insulation and preservation of the present invention.
Described flyash is the low calcium fly ash of II level; Described furnace bottom slag be power plant or the steel mill solid waste of discharging after broken and screening granularity less than the particle of 5mm; The particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk; Described water-keeping thickening material is an ether of cellulose; Described water reducer is a naphthalene water reducer.
The physicochemical property detected result of gained masonry mortar is shown in Table 3:
The physicochemical property detected result of table 3 gained masonry mortar
Test item Dry density (kg/m 3) Thermal conductivity (w/mk) Ultimate compression strength (MPa) Water retention (%) Linear shrinkage ratio (10 -4)
Detected result ??944.6 ??0.1905 ??7.8 ??96.1 ??7.18
Embodiment 4
At first the water reducer of the wood fibre of the water-keeping thickening material of the glass bead of the slag of the flyash of the silicate cement of 20 weight parts, 13.5 weight parts, 55 weight parts, 10 weight parts, 0.4 weight part, 0.1 weight part and 1.0 weight parts is added in the stirrer and stir; adding water then stirs; slurry consistency is controlled between 70~80mm, promptly gets light masonry mortar with heat insulation and preservation of the present invention.
Described flyash is the low calcium fly ash of II level; Described slag is the ground granulated blast furnace slag of power plant or the steel mill granularity of discharging less than 5mm; The particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk; Described water-keeping thickening material is an ether of cellulose; Described water reducer is a naphthalene water reducer.
The physicochemical property detected result of gained masonry mortar is shown in Table 4:
The physicochemical property detected result of table 4 gained masonry mortar
Test item Dry density (kg/m 3) Thermal conductivity (w/mk) Ultimate compression strength (MPa) Water retention (%) Linear shrinkage ratio (10 -4)
Detected result ??951.2 ??0.1956 ??7.9 ??97.0 ??8.41
Embodiment 5
At first the water reducer of the wood fibre of the water-keeping thickening material of the glass bead of the slag of the furnace bottom slag of the flyash of the silicate cement of 20 weight parts, 16.7 weight parts, 25 weight parts, 27 weight parts, 10 weight parts, 0.5 weight part, 0.3 weight part and 0.5 weight part is added in the stirrer and stir; adding water then stirs; slurry consistency is controlled between 70~80mm, promptly gets light masonry mortar with heat insulation and preservation of the present invention.
Described flyash is the low calcium fly ash of II level; Described furnace bottom slag be power plant or the steel mill solid waste of discharging after broken and screening granularity less than the particle of 5mm; Described slag is the ground granulated blast furnace slag of power plant or the steel mill granularity of discharging less than 5mm; The particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk; Described water-keeping thickening material is an ether of cellulose; Described water reducer is a naphthalene water reducer.
The physicochemical property detected result of gained masonry mortar is shown in Table 5:
The physicochemical property detected result of table 5 gained masonry mortar
Test item Dry density (kg/m 3) Thermal conductivity (w/mk) Ultimate compression strength (MPa) Water retention (%) Linear shrinkage ratio (10 -4)
Detected result ??949.3 ??0.1927 ??8.0 ??95.6 ??7.49

Claims (10)

1. light masonry mortar with heat insulation and preservation; it is characterized in that the weight percent that it is formed and each is formed is as follows: silicate cement 20~65, flyash 5~50, furnace bottom slag 0~50, slag 0~55, glass bead 10~23, water-keeping thickening material 0.1~1.0, wood fibre 0.1~0.5, water reducer 0.1~1.0.
2. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, described flyash is one or more the mixture in the low calcium fly ash of I level, the low calcium fly ash of II level, I level high-calcium fly ass, the II level high-calcium fly ass.
3. light masonry mortar with heat insulation and preservation according to claim 2 is characterized in that, described flyash is the low calcium fly ash of II level.
4. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, described furnace bottom slag be power plant or the steel mill solid waste of discharging after broken and screening granularity less than the particle of 5mm.
5. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, described slag is the ground granulated blast furnace slag of power plant or the steel mill granularity of discharging less than 5mm.
6. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, the particle diameter of described glass bead is 0.2~1.0mm, and accumulation unit weight is 80~200kg/m 3, thermal conductivity is 0.040~0.055w/mk.
7. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, described water-keeping thickening material is one or more the mixture in ether of cellulose, mortar densification powder, polyvinyl alcohol powder, slaked lime, the starch ethers.
8. light masonry mortar with heat insulation and preservation according to claim 7 is characterized in that, described water-keeping thickening material is an ether of cellulose.
9. light masonry mortar with heat insulation and preservation according to claim 1 is characterized in that, described water reducer is one or more the mixture in naphthalene water reducer, melamine water reducing agent, calcium lignin sulphonate, the polycarboxylate dehydragent.
10. light masonry mortar with heat insulation and preservation according to claim 9 is characterized in that, described water reducer is a naphthalene water reducer.
CN200910055754A 2009-07-31 2009-07-31 Light masonry mortar with heat insulation and preservation Pending CN101643349A (en)

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CN102093006A (en) * 2010-12-28 2011-06-15 济南高新区工业废弃物利用研发中心 Fly ash dry-mixed mortar
CN102249603A (en) * 2010-05-21 2011-11-23 安徽省建筑科学研究设计院 Composite fireproof insulating plate used in fireproof isolation area of external wall external insulation system
CN103043940A (en) * 2012-12-31 2013-04-17 中国矿业大学 Thickening powder for preparing dry-mixed plastering mortar
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CN106220066A (en) * 2016-08-04 2016-12-14 南京工业大学 A kind of bottom slag is modified and the method for preparing dry powder and mortar with it and application
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CN109400047B (en) * 2017-08-18 2021-08-17 武汉质高环保科技有限公司 Masonry mortar and preparation method thereof
CN111807761A (en) * 2019-04-12 2020-10-23 耀星(廊坊)建筑材料有限公司 QHJ light active energy-saving masonry material
CN110642578A (en) * 2019-11-13 2020-01-03 南京中旌科技发展有限公司 Mildew-proof cement mortar and production process thereof
CN111848058A (en) * 2020-08-17 2020-10-30 康亚男 Building energy-saving heat-insulating material and preparation method thereof
CN114853427A (en) * 2022-06-13 2022-08-05 诸暨市幄肯中智新材料有限公司 Enhanced polymer ball filled light composite material and preparation method thereof
RU2793518C1 (en) * 2022-06-23 2023-04-04 Федеральное государственное бюджетное образовательное учреждение высшего образования "Петербургский государственный университет путей сообщения Императора Александра I" Heat-insulating masonry mortar

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Application publication date: 20100210