CN102087720B - Non-contact type electronic tag with anti-false and anti-transfer function and preparation method thereof - Google Patents

Non-contact type electronic tag with anti-false and anti-transfer function and preparation method thereof Download PDF

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Publication number
CN102087720B
CN102087720B CN 201110046625 CN201110046625A CN102087720B CN 102087720 B CN102087720 B CN 102087720B CN 201110046625 CN201110046625 CN 201110046625 CN 201110046625 A CN201110046625 A CN 201110046625A CN 102087720 B CN102087720 B CN 102087720B
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Prior art keywords
antenna
material coating
electronic tag
functional high
chip
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CN102087720A (en
Inventor
徐良衡
杨凯
陶金
何晓栋
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SHANGHAI TECHSUN RFID TECHNOLOGY Co.,Ltd.
Shanghai Tianchen micro nano technology Co., Ltd
Original Assignee
SHANGHAI TIANCHEN RADIOFREQUENCY TECHNOLOGY CO LTD
SHANGHAI TIANCHENG ANTICOUNTERFEIT TECHNOLOGY CO LTD
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Priority to CN 201110046625 priority Critical patent/CN102087720B/en
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Abstract

The invention provides a non-contact type electronic tag with anti-false and anti-transfer function and a preparation method thereof, wherein the electronic tag consists of a support layer, a functional high polymer material coating, an antenna and a chip; the functional high polymer material coating is compounded on one side of the support layer; the antenna is fixed on the other side of the functional high polymer material coating; the chip is bonded on the antenna; and the functional high polymer material coating comprises the following compounds in percentages by weight: 5-90% of light solidified type resin, 1-5% of light trigger and 9-94% of connection resin. The electronic tag is attached on goods or the surface of the outer package of goods; when the label of RFID (Radio Frequency Identification Devices) needs to be peeled, the material on the surface of the support layer is capable of being peeled easily, while the parts of the RFID chip and the antenna are still glued on the surface of the package of goods and have the performance of frangibility so as to be incapable of being peeled completely; and the antenna of the RFID is damaged when peeling to lose reading and writing functions so that the effect of safe guard against falsification is achieved.

Description

Has Lontactless electronic tag of anti-transfer function and preparation method thereof
Technical field
The present invention relates to a kind of Lontactless electronic tag with anti-transfer function and preparation method thereof.
Background technology
Radio frequency identification (being called for short RFID) technology is identified destination object automatically and is obtained related data by radiofrequency signal, and identification work need not artificial interference, can work in various environment, can identify a plurality of labels simultaneously, and is swift and convenient to operate.After 2004, the RFID technology obtains vigorous growth, and potentiality have a wide range of applications in fields such as warehouse logistics, product false proof, products in circulation and product maintenance trackings.In the application of product false proof, RFID with its safety, efficient, quick, storage volume is big, store information change waits characteristics to be called as " the electronics patron saint " of a new generation freely.
Simultaneously, radio RF recognition technology is because the UID sign indicating number whole world of its chip is unique, information stability, counterfeit cost is high, can store bulk information, and can simply read and write, special-purpose recognition device that the consumer provides by the businessman identity of recognition value easily can be made, and the all-the-way tracking in the circulation of commodities can be used for realizing.
It is that base material is produced that RFID label in the market adopts paper or mylar more, especially at present the aluminium etch pattern RFID label that is widely used, restriction in view of its aluminium etch process and chip binding technology, prepared RFID label and base material tight bond, the stability of good processing and use is provided, but it has also limited it at commodity circulation, especially the application in commodity counterfeit prevention field.The lawless person can not destroy its physical arrangement with complete the peeling off of RFID label on the genuine piece commodity by the certain physics chemical means, label still can be read, it is affixed on the counterfeit goods again, just is difficult to distinguish with genuine piece, just lost its meaning as false proof and logistics management.
Summary of the invention
The object of the present invention is to provide a kind of Lontactless electronic tag with anti-transfer function and preparation method thereof, to overcome the above-mentioned defective that prior art exists.
Lontactless electronic tag with anti-transfer function of the present invention is made up of supporting layer, functional high molecule material coating, antenna and chip;
Described functional high molecule material coating is compounded in a side of supporting layer, and described antenna is fixed on the opposite side of functional high molecule material coating, and described chip attach is on antenna, and is preferred, can be bonding by electric conductivity thermosetting resin and antenna;
Described electric conductivity thermosetting resin, as the TB3373C of 6998 or triple bond company of the XH9850 of Japanese NAMICS company, UNINWELL company etc., perhaps other electric conductivity thermosetting resins commonly used do not have special requirement;
The material of described supporting layer (1) is selected from polyester, PP (polypropylene), PVC (Polyvinylchloride) or PE (tygon) etc.;
Described polyester such as PET (polyethylene terephthalate);
Described functional high molecule material coating (2) comprises following components in weight percentage:
The solid type resin 5~90% of light
Light trigger 1~5%
Binding resin 9~94%
Each percentages of ingredients sum is 100%.
Preferably, the percentage by weight of described functional high molecule material coating (2) consists of:
The solid type resin 25%~55% of light
Light trigger 1%~3
Binding resin 42~74%
Each percentages of ingredients sum is 100%.
The solid type resin of described light is light-cured acrylic resin or light-cured polyurethane etc., can adopt the Dongyang chemical industry DY5300, DY6200, UV1201, the UV1205 of the auspicious magnificent chemical industry in Yantai, the synchronous chemical industry TB8522B in Guangdong etc.;
Described light trigger is selected from benzophenone, 1173 (2-hydroxy-2-methyl-1-phenylacetone), AIBN (azoisobutyronitrile), BPO (benzoyl peroxide) or benzophenone etc.;
Described binding resin is selected from EVA (ethylene-vinyl acetate copolymer), PS (polystyrene), PMMA (polymethylmethacrylate), PC (polycarbonate), PVC (Polyvinylchloride), PE (tygon), acryl resin or epoxy resin etc.;
Described antenna (3) can be aluminium etching antenna, copper etching antenna, conductive silver paste printed antenna, conducting polymer printed antenna, electroless copper antenna or vacuum copper facing antenna etc., can adopt the method for bibliographical informations such as " the silk-screen printing technique parameter study of intelligent label antenna ", " radio frequency identification RFID electrically conductive ink and printed antenna technology ", " three kinds of method for makings of RFID antenna ", " the gravure etching method is made the RFID antenna ", " principle of electroless copper, application and prospect ", " vacuum aluminium plating process brief introduction " to be prepared;
Preparation method with Lontactless electronic tag of anti-transfer function of the present invention comprises the steps:
(1) after each component adding solvent with energy macromolecule material coating (2), coat on the supporting layer, dried 1~5 minute for 100~120 ℃, preferably adopt infrared oven dry, place then and carry out photocuring under the ultraviolet light, be 3~30 seconds set time, acquisition has applied the supporting layer of macromolecule material coating (2), the described supporting layer that applies macromolecule material coating (2), the fastness of functional high molecule material coating and supporting layer greatly descends, can easily peel off, become release layer, and have frangible performance;
Described solvent is selected from ethyl acetate, butyl acetate, isopropyl alcohol, butanone, toluene, dimethylbenzene, normal butyl alcohol or ethanol equal solvent, and the total weight solid content of each component of macromolecule material coating is 15~45%;
(2) at the functional high molecule material coating surface of the product of step (1), directly printing conductive silver slurry or conducting polymer materials form printed antenna, can adopt serigraphy, intaglio printing, flexographic printing or hectographic printing etc.;
Described conducting polymer such as polyacetylene, polythiophene, polyaniline, polyphenylene ethylene or polyhenylene etc., serigraphy, intaglio printing, flexographic printing or offset printing method, in relevant handbook or document, as in the documents such as " the silk-screen printing technique parameter study of intelligent label antenna ", " radio frequency identification RFID electrically conductive ink and printed antenna technology " detailed report being arranged, the present invention repeats no more;
Perhaps:
Aluminium foil or Copper Foil and above-mentioned functions macromolecule material coating is compound by adhesive, and printed antenna pattern on aluminium foil or Copper Foil is again handled the back through acid solution or alkali lye etching and deinking and is formed etching antenna; Adoptable mode of printing is serigraphy, intaglio printing, flexographic printing, hectographic printing etc.; Concrete, the method that can consult bibliographical informations such as " three kinds of method for makings of RFID antenna ", " the gravure etching method is made the RFID antenna ";
Perhaps:
First printing conductive material again by chemical deposition deposited copper on Seed Layer, obtains the electroless copper antenna as Seed Layer on the above-mentioned functions macromolecule material coating;
Described conductive material is selected from the E-820B of RL1206, ACHESON company of sharp Shinco or EO-427SS etc.
Perhaps:
On the above-mentioned functions macromolecule material coating, by the direct vacuum copper facing of template, to form vacuum copper facing antenna; The vacuum copper coating, the method that can consult bibliographical informations such as " principle of electroless copper, application and prospect ", " vacuum aluminium plating process brief introduction ".
(3) with chip by the heat curing-type conducting resinl with chip attach in above-mentioned with the antenna that forms on, consult and use the rfid interrogator that is complementary with chip, carry out the typing of data, obtain described Lontactless electronic tag with anti-transfer function.
Label of the present invention contains antenna and chip one side coated with adhesive in use at the label back side, be affixed on commodity or commodity external packing surface again, can use after 24 hours.When wanting to peel off the RFID label, the surface support layer material can be peeled off easily, and the part of RFID chip and antenna still is pasted on the commodity packaging surface, it has extremely frangible performance, can't be by complete peeling off, the antenna of RFID on it can be destroyed when peeling off, and loses read-write capability, reaches the effect of safety anti-fake.
The present invention is by among the RFID label production technology that the introducing of speciality polymer material is traditional, the process means of recycling uniqueness, prepare the RFID label with anti-transfer function, make and have nonrecoverable performance, namely after being affixed on the product, anti-transfer RFID label just can not be stripped from or shift, in case it is namely destroyed to be stripped from or to shift its physical arrangement, its contained information can't be read, and reaches the purpose that can't reuse.
Description of drawings
Fig. 1 is the Lontactless electronic tag structural representation with anti-transfer function.
Embodiment
Referring to Fig. 1, invent described Lontactless electronic tag with anti-transfer function, formed by supporting layer (1), functional high molecule material coating (2), antenna (3) and chip (4);
Described functional high molecule material coating (2) is compounded in a side of supporting layer (1), and described antenna (3) is fixed on the opposite side of functional high molecule material coating (2), and described chip (4) is bonded on the antenna (3).
Embodiment 1
Be support layer material with the PET film, each component that can macromolecule material coating (2) is added solvent after, use coating machine, coat on the supporting layer;
The functional high molecule material percentage by weight consists of:
Light-cured acrylic resin 25%
BPO (benzoyl peroxide) 1%
PMMA (polymethylmethacrylate) 74%
Solvent is ethyl acetate, and the total weight solid content of each component of macromolecule material coating is 25%;
The light-cured acrylic resin is the DY5300 of Dongyang chemical industry;
By infrared drying tunnel oven dry, re-using power is that 5 kilowatts of ultraviolet curing equipments are cured, and be 10 seconds set time, and coating thickness is 20 microns; Use 400 order serigraphy conductive silver pastes in functional high molecule material coating again, the oven dry back forms the RFID antenna, and the RFID chip is bondd by the heat curing-type conducting resinl, utilizes the rfid interrogator that is complementary with chip, carry out the typing of data, obtain product.
Embodiment 2
Be support layer material with the PET film, each component that can macromolecule material coating (2) is added solvent after, use coating machine, coat on the supporting layer;
The functional high molecule material percentage by weight consists of:
Light-cured polyurethane 40%
1173 (2-hydroxy-2-methyls-1-phenylacetone) 3%
EVA (ethylene-vinyl acetate copolymer) 57%
Solvent is butyl acetate, and the total weight solid content of each component of macromolecule material coating is 35%;
Light-cured polyurethane is the DY6200 of Dongyang chemical industry;
And by infrared drying tunnel oven dry, re-using power is that 10 kilowatts of ultraviolet curing equipments are cured, and be 5 seconds set time, and coating thickness is 20 microns; 16 micron thickness aluminium foils and above-mentioned functions macromolecule material coating are compound by adhesive, again at the mode printed antenna pattern of aluminium foil by intaglio printing, through acid solution or alkali lye etching and deinking processing back formation etching antenna; Then the RFID chip is bondd by the heat curing-type conducting resinl; Utilize the rfid interrogator that is complementary with chip to carry out the typing of data, obtain product.
Embodiment 3
Be support layer material with the PET film, each component that can macromolecule material coating (2) is added solvent after, use coating machine, coat on the supporting layer;
The functional high molecule material percentage by weight consists of:
Light-cured acrylic resin: 30%
AIBN (azoisobutyronitrile): 2%
EVA (ethylene-vinyl acetate copolymer): 68%
Solvent is ethyl acetate, and the total weight solid content of each component of macromolecule material coating is 30%;
The light-cured acrylic resin is the UV1201 of the auspicious magnificent chemical industry in Yantai;
By infrared drying tunnel oven dry, re-using power is 10 kilowatts of ultraviolet curing equipments, is cured, and be 15 seconds set time, and coating thickness is 30 microns; Using 500 order serigraphy conductive silver pastes as Seed Layer earlier on the functional high molecule material coating again, again by chemical deposition deposited copper on Seed Layer, to form the electroless copper antenna; And then the RFID chip bondd by the heat curing-type conducting resinl.Utilize the rfid interrogator that is complementary with chip to carry out the typing of data, obtain product.
Embodiment 4
Be support layer material with the PET film, each component that can macromolecule material coating (2) is added solvent after, use coating machine, coat on the supporting layer;
The functional high molecule material percentage by weight consists of:
Light-cured polyurethane: 55%
Benzophenone: 3%
PS (polystyrene): 42%
Solvent is dimethylbenzene, and the total solid content of each component of macromolecule material coating is 20%;
The light-cured acrylic resin is the TB8522B of the synchronous chemical industry in Guangdong;
And by infrared drying tunnel oven dry, re-using power is that 10 kilowatts of ultraviolet curing equipments are cured, and be 5 seconds set time, and coating thickness is 20 microns; Pass through the direct vacuum copper facing of template at the above-mentioned functions macromolecule material coating, to form vacuum copper facing antenna; Then the RFID chip is bondd by the heat curing-type conducting resinl.
Utilize the rfid interrogator that is complementary with chip to carry out the typing of data, obtain product.

Claims (4)

1. have the Lontactless electronic tag of anti-transfer function, it is characterized in that, formed by supporting layer (1), functional high molecule material coating (2), antenna (3) and chip (4);
Described functional high molecule material coating (2) is compounded in a side of supporting layer (1), and described antenna (3) is fixed on the opposite side of functional high molecule material coating (2), and described chip (4) is bonded on the antenna (3) by the electric conductivity thermosetting resin;
Described functional high molecule material coating (2) comprises the composition of following percentage by weight:
The solid type resin 5~90% of light
Light trigger 1~5%
Binding resin 9~94%
Each percentages of ingredients sum is 100%;
The solid type resin of described light is light-cured acrylic resin or light-cured polyurethane;
Described light trigger is selected from benzophenone, 1173(2-hydroxy-2-methyl-1-phenylacetone), the AIBN(azoisobutyronitrile), the BPO(benzoyl peroxide) or benzophenone;
Described binding resin is selected from the EVA(ethylene-vinyl acetate copolymer), the PS(polystyrene), the PMMA(polymethylmethacrylate), the PC(polycarbonate), the PVC(Polyvinylchloride), the PE(tygon), acryl resin or epoxy resin;
Described antenna (3) is aluminium etching antenna, copper etching antenna, conductive silver paste printed antenna, conducting polymer printed antenna, electroless copper antenna or vacuum copper facing antenna.
2. the Lontactless electronic tag with anti-transfer function according to claim 1 is characterized in that, the percentage by weight of described functional high molecule material coating (2) consists of:
The solid type resin 25~55% of light
Light trigger 1~3%
Binding resin 42~74%
Each percentages of ingredients sum is 100%.
3. the Lontactless electronic tag with anti-transfer function according to claim 1 and 2 is characterized in that, the material of described supporting layer (1) is selected from polyester, polypropylene, Polyvinylchloride or tygon.
4. according to each described preparation method with Lontactless electronic tag of anti-transfer function of claim 1~3, it is characterized in that, comprise the steps:
(1) will be able to coat on the supporting layer after each component adding solvent of macromolecule material coating (2), infrared oven dry, place and carry out photocuring under the ultraviolet light, obtain to have applied the supporting layer of macromolecule material coating (2), the described supporting layer that applies macromolecule material coating (2);
(2) at the functional high molecule material coating surface of the product of step (1), directly printing conductive silver slurry or conducting polymer materials;
Perhaps:
Aluminium foil or Copper Foil and above-mentioned functions macromolecule material coating is compound by adhesive, and printed antenna pattern on aluminium foil or Copper Foil is again handled the back through acid solution or alkali lye etching and deinking and is formed etching antenna;
Perhaps:
First printing conductive material again by chemical deposition deposited copper on Seed Layer, obtains the electroless copper antenna as Seed Layer on the above-mentioned functions macromolecule material coating;
Perhaps:
On the above-mentioned functions macromolecule material coating, by the direct vacuum copper facing of template, to form vacuum copper facing antenna;
(3) with chip by the heat curing-type conducting resinl with chip attach in above-mentioned with the antenna that forms on, consult and use the rfid interrogator that is complementary with chip, carry out the typing of data, obtain described Lontactless electronic tag with anti-transfer function.
CN 201110046625 2011-02-25 2011-02-25 Non-contact type electronic tag with anti-false and anti-transfer function and preparation method thereof Active CN102087720B (en)

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* Cited by examiner, † Cited by third party
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CN103839099B (en) * 2014-03-10 2017-01-25 上海天臣防伪技术股份有限公司 Radio frequency identification label and manufacturing method thereof

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CN102982364B (en) * 2011-09-05 2015-09-23 上海天臣防伪技术股份有限公司 Wireless radio frequency identification mark with anti-transfer function and preparation method thereof
CN102779282B (en) * 2012-06-19 2015-04-08 孙国华 Product identity recognition and authentication system
CN102915461B (en) * 2012-08-07 2016-01-20 厦门英诺尔电子科技股份有限公司 There is frangible RFID of anti-transfer function high frequency and preparation method thereof
CN102838865B (en) * 2012-09-20 2014-07-09 天津博苑高新材料有限公司 Rupture diaphragm for anti-fake RFID (Radio Frequency Identification Device) label and preparation method thereof
CN102999777B (en) * 2012-11-08 2016-04-20 上海天臣防伪技术股份有限公司 Radio frequency identification electronic label and preparation method thereof
CN103029901B (en) * 2012-12-18 2015-03-18 贵州茅台酒股份有限公司 Sealing device with radio frequency identification function and preparation method thereof
CN103778462A (en) * 2014-02-12 2014-05-07 山东泰宝防伪技术产品有限公司 Metal-resisting anti-transfer electronic tag and manufacturing method thereof
CN104449174B (en) * 2014-12-04 2017-04-19 武汉华工图像技术开发有限公司 Holographic anti-counterfeiting coating for anti-counterfeiting of certificate card and preparation method of holographic anti-counterfeiting coating
WO2023178546A1 (en) * 2022-03-23 2023-09-28 上海航空印刷有限公司 Novel rfid tag antenna manufacturing method

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CN101000659A (en) * 2006-12-26 2007-07-18 上海复旦天臣新技术有限公司 Lontactless electronic tag with anti-false and anti-transfer function and preparation method thereof
CN101477639A (en) * 2009-01-15 2009-07-08 上海复旦天臣新技术有限公司 Self-adhering type wireless radio frequency antifalsification label and using method

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CN101477639A (en) * 2009-01-15 2009-07-08 上海复旦天臣新技术有限公司 Self-adhering type wireless radio frequency antifalsification label and using method

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Address after: 5, building 1, building 127, Lane 200433, Cathay Road, Yangpu District, Shanghai

Applicant after: Shanghai Tiancheng Anticounterfeit Technology Co.,Ltd.

Co-applicant after: Shanghai Tianchen Radiofrequency Technology Co.,Ltd.

Address before: 5, building 1, building 127, Lane 200433, Cathay Road, Yangpu District, Shanghai

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Address after: 5, building 1, building 127, Lane 200433, Cathay Road, Yangpu District, Shanghai

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Address before: 5, building 1, building 127, Lane 200433, Cathay Road, Yangpu District, Shanghai

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